Preparation and Characterization of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 Complexes

Document Type : Research Article


Department of Chemistry, Faculty of Science, Teacher Training University, P.O. Box 15614 Tehran, I.R. IRAN



We have recently synthesized Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 complexes. The reaction of TiCl3(THF)3 with NaBH4 in dry THF gave flat blue crystals, Ti(BH4)3(THF)3. The reaction of VCl3 with NaBH4 in presence of N, N, N', N'- tetramethylethylenediamine, TMEDA, produced violet crystals, V(BH4)2(TMEDA)2. Vibrational and magnetic properties of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 have been studied.


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