Darvich, M., Mohammadi Rovshandeh, J. (1995). Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 14(2), 90-93.
Mohammad Raouf Darvich; Jamshid Mohammadi Rovshandeh. "Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 14, 2, 1995, 90-93.
Darvich, M., Mohammadi Rovshandeh, J. (1995). 'Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 14(2), pp. 90-93.
Darvich, M., Mohammadi Rovshandeh, J. Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 1995; 14(2): 90-93.
Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol
Department of Chemistry, Faculty of Science, Tehran University, P.O. Box 14155-6455 Tehran, I.R. IRAN
Abstract
Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the diol-ketone (4).
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