TY - JOUR ID - 10968 TI - Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol JO - Iranian Journal of Chemistry and Chemical Engineering JA - IJCCE LA - en SN - 1021-9986 AU - Darvich, Mohammad Raouf AU - Mohammadi Rovshandeh, Jamshid AD - Department of Chemistry, Faculty of Science, Tehran University, P.O. Box 14155-6455 Tehran, I.R. IRAN Y1 - 1995 PY - 1995 VL - 14 IS - 2 SP - 90 EP - 93 KW - Osmylation KW - N-methylmorpholine-N-oxide KW - Cis and trans-2-cyclohexene-cyclohexanol KW - Hydroxylation DO - 10.30492/ijcce.1995.10968 N2 - Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the diol-ketone (4). UR - https://ijcce.ac.ir/article_10968.html L1 - https://ijcce.ac.ir/article_10968_5238a4c9ca54a6c85791b5edc2fbb6f5.pdf ER -