Chemistry Department, Tehran University, Tehran, I.R. IRAN
10.30492/ijcce.1988.12273
Abstract
The nitrite ® nitro isomerization in nitritopentaamine cobalt (III) halides has been known. In this paper, the effect of the size of the counter ions (noncoordinated groups) on the rate of isomerization in nitritopentaamine cobalt (III) halides, is reported. The rate of isomerization is decreased by increasing the size of the counter ions. This decrease is explained on the basis of steric interaction between the nitro groups in the inner sphere and the counter ions in the outer sphere of these complexes.
Heravi, G. H., & Abedini, M. (1988). Kinetic Study of the Linkage Isomers in [Co(NH3)5ONO]X2 (X=Cl¯, Br¯, I¯) in the Solid State in KBr Discs. Iranian Journal of Chemistry and Chemical Engineering, 7(1), 28-32. doi: 10.30492/ijcce.1988.12273
MLA
Gholam Hossein Heravi; Mansour Abedini. "Kinetic Study of the Linkage Isomers in [Co(NH3)5ONO]X2 (X=Cl¯, Br¯, I¯) in the Solid State in KBr Discs". Iranian Journal of Chemistry and Chemical Engineering, 7, 1, 1988, 28-32. doi: 10.30492/ijcce.1988.12273
HARVARD
Heravi, G. H., Abedini, M. (1988). 'Kinetic Study of the Linkage Isomers in [Co(NH3)5ONO]X2 (X=Cl¯, Br¯, I¯) in the Solid State in KBr Discs', Iranian Journal of Chemistry and Chemical Engineering, 7(1), pp. 28-32. doi: 10.30492/ijcce.1988.12273
VANCOUVER
Heravi, G. H., Abedini, M. Kinetic Study of the Linkage Isomers in [Co(NH3)5ONO]X2 (X=Cl¯, Br¯, I¯) in the Solid State in KBr Discs. Iranian Journal of Chemistry and Chemical Engineering, 1988; 7(1): 28-32. doi: 10.30492/ijcce.1988.12273