Preparation of Surface Amino Modified Magnesium Doped Lithium Manganese Oxide Nanosorbent and Its Investigation for Dye Removal

Document Type : Research Article

Authors

CSIR-Central Salt and Marine Chemicals Research Institute (CSIR-CSMCRI), Council of Scientific & Industrial Research (CSIR), Gijubhai Badheka Marg, Bhavnagar 364002, Gujarat, INDIA

Abstract

Magnesium-doped lithium manganese oxide nanoparticles were modified with 3-aminopropyl-trimethoxysilane and characterized by XRD, FTIR, TGA, and TEM analytical techniques. The sorption of Malachite Green on adsorbent with respect to nanosorbent amount, dye concentration effect, pH influence, and contact time was performed to obtain the maximum adsorption conditions. The pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetic models were evaluated and found better fitting with the pseudo-second-order (R2 = 0.995). The Freundlich isotherm is found to be suitable (R2=0.989) to describe the sorption process of Malachite Green on prepared adsorbent. Malachite Green spiked Lake Water, NKCM (Na+, K+, Ca+2, Mg+2 containing) water, and Sea Water were tested and evaluated for the adsorption capability and found 46.9 %, 44.6%, and 40.7 % removal performance, respectively.

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References

[1] Srivastava S., Sinha R., Roy D., Toxicological Effects of Malachite Green, Aquat. Toxicol., 66(3): 319-329 (2004).
 [2] Gopinathan R., Kanhere J., Banerjee J., Effect of Malachite Green Toxicity on Non Target Soil Organisms, Chemosphere, 120: 637-44 (2015).
[3] Samaneh T., Artificial Neural Network Modelling of Biotreatment of Malachite Green by Spirodelapolyrhiza: Study of Plant Physiologicalresponses and the Dye Biodegradation Pathway, Process Saf. Environ. Prot., 99: 11-19 (2016).
[4] Orlando G.R., Jennifer A.B., Abdellatif E.-G.,  Luis A. G., Enric B., Francisco J. R.-V., Use of a Carbon Felt Iron Oxide Air-Diffusion Cathode for the Mineralization of Malachitegreen Dye by Heterogeneous Electro-Fenton and UVA Photo Electro-Fenton Processes, J. Electroanal. Chem., 767: 40-48 (2016). 
[5] Sharma G., Gupta V.K., Agarwal S., Kumar A., Thakur S., Pathania D., Fabrication and Characterization of Fe@MoPO Nanoparticles: Ion Exchange Behaviour and Photocatalytic Activity Against Malachite Green, J. Mol. Liq., 219: 1137-43 (2016).
[6] Liu G., Abukhadra M.R., El-Sherbeeny A.M., Mostafa A.M., Elmeligy M.A., Insight into the Photocatalytic Properties of Diatomite@Ni/NiO Composite for Effective Photo-Degradation of Malachite Green Dye and Photo-Reduction of Cr (VI) under Visible Light, J, Environ. Manage., 254: 109799 (2019).
 [7] Lavanda A. B., Bhatub M. N., Malghe Y. S., Visible Light Photocatalytic Degradation of Malachite Green Using Modified Titania,  J. Mater. Res. Technol., 8(1): 299-308 (2019).
[8] Aoulad El hadj Ali, Y., Demba N’diaye, A., Ahrouch, M., Sakar, E.H., Raklami, A., Lahcen, A.A., Stitou, M. Dehydrate Sewage Sludge as an Efficient Adsorbent for Malachite Green Removal in Textile Wastewater: Experimental and Theoretical Studies. Chemistry Africa, 1-15 (2022).
[9]   Youssef, A.E.H.A., N'diaye, A.D., Fahmi, D., Kankou, M.S.A., Stitou, M. Adsorption of Congo Red from Aqueous Solution Using Typha Australis Leaves as a Low Cost Adsorbent. Journal of Environmental Treatment Techniques, 9: 534-539 (2021).
[10] Qin Q., Wang Q., Fu D., Ma J., An Efficient Approach for Pb(II) and Cd(II) Removal Using Manganese Dioxide Formed in Situ, Chem. Eng. J., 172(1): 68-74 (2011).
[11] Su Q., Pan B., Pan B., Zhang Q., Zhang W., Lv L., Wang X., Wu J., Zhang Q., Fabrication of Polymer-Supported Nanosized Hydrous Manganese Dioxide (HMO) for Enhanced Lead Removal from Waters, Sci. Total Environ., 407(21): 5471-5477 (2009).
[12] Ensano B.M.B., Luna M.D.G., Rivera K.K.P., Pingul-Ong S.M.B., Ong D.C., Optimization, Isotherm, and Kinetic Studies of Diclofenac Removal from Aqueous Solutions by Fe–Mn Binary Oxide Adsorbents, Environ. Sci. Pollut. Res., 26: 32407- 32419 (2019).
[13] Saravaia H., Gupta H., Popat P., Sodha P., Kulshrestha V., Single-Step Synthesis of Magnesium-Doped Lithium Manganese Oxide Nanosorbent and Their Polymer Composite Beads for Selective Heavy Metal Removal, ACS Appl. Mater. Interfaces, 10: 44059-44070 (2018).
[14] Singh P., Sil A., Nath M., Ray S., Synthesis and Characterization of Li[Mn2-x Mgx]O4 (x = 0.0-0.3) Prepared by Sol-Gel Synthesis, Cerami. Silik., 54(1): 38–46 (2010).
[15] Zhang Y., Su Z., Yao X., Wang Y., Synthesis and Electrochemical Properties of Monoclinic Fluorine-Doped Lithium Manganese Oxide (LixMnO2-yFy) for Lithium Secondary Batteries,  RSC Adv., 5: 90150–57 (2015).
[16] Ling S., Hu S., Sun H., Guo H., Zhu H., Liu M., Sun H., Malachite Green Adsorption Onto Fe3O4@SiO2-NH2: Isotherms, Kinetic and Process Optimization, RSC Adv., 5: 11837-11844 (2015).
[17] Zhang Y., Gao F., Wanjala B., Li Z., Cernigliaro G., Gu Z., High Efficiency Reductive Degradation SiO-Co of a Wide Range of Azo Dyes by Core-Shell Nanoparticles, Appl. Catal., B, 199: 504-513 (2016).
 [18] Kumar K.V., Linear and Non-Linear Regression Analysis for the Sorption Kinetics of Methylene Blue Onto Activated Carbon, J. Hazard. Mater., 137 (3): 1538-1544 (2006).
[19] Hao L., Desai M.K., Wang P., Valiyaveettil S., Successive Extraction of As(V), Cu(II), and P(V) Ions from Water Using Surface Modified Ghee Residue Protein, ACS Sustainable Chem. Eng., 5: 3742-50 (2017).
 [20] Maged A., Ismael I.S., Kharbish S., Sarkar B., Peräniemi S., Bhatnagar A., Enhanced Interlayer Trapping of Pb(II) Ions Within Kaolinite Layers: Intercalation, Characterization, and Sorption Studies, Environ., Sci. Pollut. Res., 27: 1870-1887 (2020).
[21] Xiaoyao A., Qin W., Bin D., Yakun Z., Xin X., Yan L., Yu H., Removal of Basic Dyes (Malachite Green) from Aqueous Medium by Adsorption Onto Amino Functionalized Graphenes in Batch Mode, Desalination and Water Treatment, 53: 818-825 (2015).
 [22] McKay G., Blair H.S., Gardner J.R., Adsorption of Dyes on Chitin. I. Equilibrium Studies, J. Appl. Polym. Sci., 27(8): 3043-57 (1982).
[23] Naseeruteen, F., Hamid N.S.A., Suah F.B.M., Ngah W.S.W.,  Mehamod F.S.,  Adsorption of Malachite Green from Aqueous Solution by Using Novel Chitosan Ionic Liquid Beads, Int. J. Biol. Macromol., 107 (Part A): 1270-77 (2018).
[24] Lee S.-L., Park J.-H., Kim S.-H., Kang S.-W., Cho J.-S., Jeon J.-R., Lee Y.-B.,  Seo D.-C., Sorption Behavior of Malachite Green Onto Pristine Lignin to Evaluate the Possibility as a Dye Adsorbent by Lignin, Appl. Biol. Chem., 62: 1-10 (2019).
[25] Arivoli S., Sundaravadivelu M., Elango K. P., Removal of Basic and Acidic Dyes from Aqueous Solution by Adsorption on a Low Cost Activated Carbon, Kinetic and Thermodynamic Study, Indian J. Chem. Technol., 15: 130-139 (2008).
[26] Sriram G., Uthappa U. T., Kigga M., Jung H.-Y., Altalhi T., Brahmkhatri V., Kurkuri M. D., Xerogel Activated Diatoms as an Effective Hybrid Adsorbent for the Efficient Removal of Malachite Green, New J. Chem., 43: 3810-3820 (2019).
[27] Rajabi M., Mirza B., Mahanpoor K., Mirjalili M., Najafi F., Moradi O., Sadegh H. R., Shahryari-ghoshekandi R., Asif M., Tyagi I., Agarwal S., Gupta V. K., Adsorption of Malachite Green from Aqueous Solution by Carboxylate 3 Group Functionalized Multi-Walled Carbon Nanotubes: Determination of Equilibrium and Kinetics Parameters, J. Ind. Eng. Chem., 34: 130-138(2016).
[28] Tahir S.S., Rauf N., Removal of a Cationic Dye from Aqueous Solutions by Adsorption onto Bentonite Clay, Chemosphere, 63(11): 1842-1848 (2006).
[29] Kavci E., Malachite Green Adsorption onto Modified Pine Cone: Isotherms, Kinetics and Thermodynamics Mechanism, Chem. Eng. Commun., 208(3): 318-327 (2021).
 [30] Alorabi A. Q., Effective Removal of Malachite Green from Aqueous Solutions Using Magnetic Nanocomposite: Synthesis, Characterization, and Equilibrium Study, Adsorpt. Sci. Technol., 2021: 2359110-15.
[31] Ullah S., Rahman A. U., Ullah F., Rashid A., Arshad T., Viglašová E., Galamboš M., M.M. Niyaz., Ullah H., Adsorption of Malachite Green Dye onto Mesoporous Natural Inorganic Clays: Their Equilibrium Isotherm and Kinetics Studies, Water, 13: 965 (2021).
[32] Miyar H.K., Pai A., Goveas L.C., Adsorption of Malachite Green by Extracellular Polymeric Substance of Lysinibacillus sp. SS1: Kinetics and Isotherms, Heliyon, 7(6): 7e07169 (2021).

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