Leaching Optimization of Sarcheshmeh Copper Concentrate by Application of Taguchi Experimental Design Method

Document Type : Research Article

Authors

1 Department of Mining Engineering, Vali-e-Asr University of Rafsanjan, Kerman, I.R. IRAN

2 Department of Mining Engineering, Isfahan University of Technology, Isfahan, I.R. IRAN

Abstract

Taguchi Method is used as a statistical approach to optimize the process parameters and improve the quality of components that are produced. The present study aimed to illustrate the leaching optimization of Sarcheshmeh copper concentrate using Taguchi’s experimental design. Various operating parameters such as acid concentration (CA), temperature (T), solid percentage (%S), O2 flow rate (O2), extra oxidizing agent (OxA), NaCl concentration(CNaCl), and contact time (t), each at three levels, were selected and their effect on the copper extraction (R%) was analyzed. L27 Orthogonal Array (OA) was employed as the experimental design and the results were analyzed using analysis of variance (ANOVA) and analysis of mean (ANOM). The experiment results indicated that (T) variable was the most significant parameter with 81% contribution to the response. It is also observed that the interactions between (CA and OxA), (CA and Cox), (CA and CNaCl) had no significant effect on the copper dissolution process. Furthermore, (T), (%S), (O2), (CNaCl) and (t) parameters were found to be statistically significant at 95% confidence level for the desired response. The study showed that Taguchi’s method was suitable to optimize the experiments for increasing leaching efficiency.

Keywords

Main Subjects


[1] Hastorun S., Renaud K.M., Lederer G.W., “Recent Trends in the Nonfuel Minerals Industry of Iran”, Report. Reston, V.A,. Report No: 1421, (2016).
[2] Wang S., Copper Leaching from Chalcopyrite Concentrates, JOM., 57(7): 48-51(2005).
[4] Dutrizac J.E., Elemental Sulphur Formation During the Ferric Sulphate Leaching of Chalcopyrite, Can. Metall. Quart., 28(4): 337-44 (1989).
[7] Havlík T., Kammel R., Leaching of Chalcopyrite with Acidified Ferric Chloride and Carbon Tetrachloride Addition, Miner Eng., 8(10): 1125-34 (1995).
[8] Hiroyoshi N., Miki H., Hirajima T., Tsunekawa M., A Model for Ferrous-Promoted Chalcopyrite Leaching, Hydrometallurgy., 57(1): 31-8 (2000).
[9] Joe S., Chida T., Sakoda M., Tamura M., Nakamura H., Kida Y., Effects of PH and Temperature on the Leaching Reaction of Primary Copper Sulfide Fine Ore in Sulfuric Acid Aqueous Solution, J. MMIJ., 125(3): 115-20 (2009).
[10] Veloso T.C., Peixoto J.J.M, Pereira M.S, Leao V.A., Kinetics of Chalcopyrite Leaching in Either Ferric Sulphate or Cupric Sulphate Media in the Presence of Nacl, Int. J. Miner. Process., 148: 147-54 (2016).
[11] Olvera O.G., Rebolledo M., Asselin E., Atmospheric Ferric Sulfate Leaching of Chalcopyrite: Thermodynamics, Kinetics and Electrochemistry, Hydrometallurgy., 165:148-58 (2016).
[12] Ruiz M.C., Montes K.S., Padilla R., Chalcopyrite Leaching in Sulfate–Chloride Media at Ambient Pressure, Hydrometallurgy., 109(1): 37-42 (2011).
[13] Skrobian M., Havlik T., Ukasik M., Effect of NaCl Concentration and Particle Size on Chalcopyrite Leaching in Cupric Chloride Solution, Hydrometallurgy., 77(1): 109-14 (2005).
[14] Barrera-Mendoza G.E., Lapidus G.T., The Effect of Chemical Additives on the Electro-Assisted Reductive Pretreatment of Chalcopyrite, Hydrometallurgy., 158: 35-41 (2015).
[15] Sadrzadeh M., Mohammadi T., Sea Water Desalination Using Electrodialysis, Desalination., 221(1): 440-7 (2008).
[16] Zandevakili S., Ranjbar M., Ehteshamzadeh M., Synthesis of Lithium Ion Sieve Nanoparticles and Optimizing Uptake Capacity by Taguchi Method, Iran. J. Chem. Chem. Eng. (IJCCE), 33(4): 15-24 (2014).
[17]Chou C.S, Yang R.Y., Chen J.H., Chou S.W., The Optimum Conditions For Preparing the Lead-Free Piezoelectric Ceramic of Bi0.5Na0.5TiO3 Using the Taguchi Method, Powder Technol., 199(3): 264-71 (2010).
[18]Liu W.L., Hsieh S.H., Chen W.J., Lee J.H., Study of Nanosized Zinc Oxide on Cu–Zn Alloy Substrate Using Taguchi Method, Surf. Coat. Technol., 201(22–23): 9238-42 (2007).
[20] Norouzbeigi R., Edrissi M., Modification and Optimization of Nano-Crystalline Al2O3 Combustion Synthesis Using Taguchi L16 Array, Mater. Res. Bull., 46(10): 1615-24 (2011).
[21]Sokić M.D., Marković B., Živković D., Kinetics of Chalcopyrite Leaching by Sodium Nitrate in Sulphuric Acid, Hydrometallurgy., 95(3): 273-9 (2009).
[22]Dutrizac J.E., The Dissolution of Chalcopyrite in Ferric Sulfate and Ferric Chloride Media, Metall. Trans. B., 12(2): 371-8 (1981).
[23]Carneiro M.F.C, Leão V.A., The Role of Sodium Chloride on Surface Properties of Chalcopyrite Leached with Ferric Sulphate, Hydrometallurgy., 87(3):73-82 (2007).