Comparing Nanocomposites of TiO2/SBA-15 and TiO2/GO for Removal of Phenol out of Aqueous Solutions

Document Type : Research Article


1 Department of Environmental Pollution, Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, I.R. IRAN

2 Department of Biotechnology and Environment, Research Institute of Petroleum Industry, Tehran, I.R. IRAN

3 Research Institute of Petroleum Industry, Tehran, I.R. IRAN


Since phenol is toxic and yet its biologic reduction and removal is so difficult, strict limits are applied for the discharge of phenol-containing substances in the environment. Discharge
of phenol-containing industries, sewages into natural waters is a serious threat to human health.
In this study, the main objective is to consider the possibility of removing phenol with high initial concentration using a Heterogeneous Photocatalytic process. First, the absorbent SBA-15 and Graphene oxide(GO), which are the most efficient absorbents among others for phenol removal, and then, nanocomposites
Titanium dioxide(TiO2)/SBA-15 and TiO2/GO were synthesized. Then, the structural and physical properties of nanocomposites were identified through X-Ray Diffraction (XRD), Brunauer–Emmett–Teller (BET), Field Emission Scanning Electron Microscopy (FESEM)
Transmission Electron Microscopy (TEM) analysis. Considering the results of the Response Surface Method (RSM) for phenol removal in the initial study, nanocomposites TiO2 / SBA-15 and TiO2 / GO were used to remove the same amount of phenol from aqueous solutions.


Main Subjects

[1] Busca Guido, Berardinelli Silvia, Resini Carlo, Arrighi Laura, Technologies for the Removal of Phenol from Fluid Streams: A Short Review of Recent Developments, Journal of Hazardous Materials (2008).
[2] Chong Meng Nan, Jin Bo, Chow Christopher W.K., Saint Chris, Recent Developments In Photocatalytic Water Treatment Technology, A Review, Water Research, 44: 2997-3027 (2010).
[3] Comninellis Christos., Kapalka Agnieszka, Malato Sixto, Parsons Simon A., Poulios Ioannis Mantzavinos Dionissios Advanced Oxidation Processes for Water Treatment: Advances and Trends for R&D, Journal of Chemical Technology and Biotechnology, J. Chem. Technol. Biotechnol., 83: 769-776 (2008).
[4] Devi L.G., Rajashekhar K.E., A Kinetic Model Based on Nonlinear Regression Analysis is Proposed for the Degradation of Phenol Under UV/Solar Light Using Nitrogen Doped TiO2,Journal of Molecular Catalysis A: Chemical, 334: 65e76 (2011).
[5] Grabowska Ewelina, Reszczynska Joanna, Zaleska Adriana Mechanism of Phenol Photodegradation
in The Presence of Pure and Modified-TiO2
, A Review,Water Research, 46: 5453-547I (2012).
[6] Guo, Z., Ma, R., Li, G. “Degradation of Phenol by Nanomaterials TiO2 in Wastewater, Chemical Engineering Journal 119: 55e59 (2006).
[7] Hussain M., Ceccarelli R., Marchisio D.L., Fino D., Russo N., Geobaldo F Synthesis, Characterization, and Photocatalytic Application of Novel TiO2 Nanoparticles, Chemical Engineering Journal, 157: 45–51(2010).
[10] Peiro´ A.M., Ayllo´ N.A., Peral J., Dome´Nech X., Tio2-Photocatalyzed Degradation of Phenol and Ortho-Substituted Phenolic Compounds, Applied Catalysis B: Environmental, 30: 359e373 (2001).
[11] Qiong Z., Yunqiu H., Xiaogang C., Donghu H., Linjiang L., Ting Y., Lingli J., Structure and Photocatalytic Properties of TiO2-GO Intercalated Composite, Materials Science, 56(3): 331-339 (2011).
[12] Rasalingam Shivatharsiny, Peng Rui, Koodali Ranjit T., Removal of Hazardous Pollutants from Wastewaters: Applications of Tio2-Sio2 Mixed Oxide Materials, Journal of Nanomaterials, Article ID 617405, 42 Pages (2014).
[13] Sobczy_Nski, A., Duczmal, Ł., Zmudzi_Nski, W. “Phenol Destruction by Photocatalysis on TiO2”:
An Attempt to Solve The Reaction Mechanism. Journal of Molecular Catalysis A: Chemical, 213: 225-230 (2004).
[14] Štengl Václav, Bakardjieva  Snejana , Matys Grygar Tomáš, Bludská Jana, Kormunda Martin., TiO2-GO Nanocomposite as Advanced Photocatalytic Materials”, Chemistry Central Journal (2013).
[15] Tan Lling Lling, Ong Wee-Jun, Chai Siang-Piao, Abdul Rahman Mohamed “Reduced Graphene Oxide-TiO2 Nanocomposite as a Promising Visible-Light-Active Photocatalyst for the Conversion of Carbon Dioxide”, Nanoscale Research Letters, 8:465, Licensee Springer (2013).
[16] Tryba, B., Morawski, A.W., Inagaki, M., Toyoda, M. The Kinetics of Phenol Decomposition under
UV Irradiation with and Without H2O2
on TiO2, Fe-TiO2 and Fe-C-TiO2 Photocatalysts, Applied Catalysis B: Environmental, 63: 215e221 (2006a).
[17] Tryba, B., Morawski, A.W., Inagaki, M., Toyoda, M. Mechanism of Phenol Decomposition on Fe-C-TiO2 and Fetio2 Photocatalysts via Photo-Fenton Process, Journal of Photochemistry and Photobiology A: Chemistry, 179: 224e228 (2006b).
[18] Van Grieken R., Iglesias J., Morales V., Garcia R.A., Synthesis and Characterization of SBA-15 Materials Functionalized with Olefinic Groups and Subsequent Modification Through Oxidation Procedures, Microporous And Mesoporous Materials, 131: 321-330 (2010).
[19] Yu C. B., Wei C., Lv J., Liu H. X., Meng L.T., Preparation and Thermal Properties of Mesoporous Silica/Phenolic Resin Nanocomposites via in Situ Polymerization, Express Polymer Letters, 6(10): 783–793 (2012).
[20] Sohrabi S., Akhlaghian F., The Effect of Fe-Loading and Calcination Temperature on the Activity of Fe/TiO2 in Phenol Degradation, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35(2): 43-50 (2016).
[21] Pardeep Singh, Sonu , Pankaj Raizada, Anita Sudhaik, Pooja Shandilya, Pankaj Thakur, Shilpi Agarwal, Vinod Kumar Gupta, Enhanced Photocatalytic Activity and Stability of Agbr/Biobr/Graphene Heterojunction for Phenol Degradation under Visible Light, Journal of Saudi Chemical Society, 23(5):
586-599 (2019).
[22] Aboubakr M. Abdullah, Noora J. Al-Thani, Khouloud Tawbi, H. Al-Kandari, Carbon/Nitrogen-Doped TiO2: New Synthesis Route, Characterization and Application for Phenol Degradation, Arabian Journal of Chemistry, 9(2): 229-237 (2016).