Lubricant Additive Containing a Novel Nano Hybrid for improving Lithium Greases Extreme Pressure and Anti Wear Properties

Document Type : Research Article

Authors

1 Catalyst Technology Development Division, Research Institute of Petroleum Industry, Tehran, I.R. IRAN

2 Pars Oil Company, Tehran, I.R. IRAN

Abstract

A novel lubricating grease additive comprised of a new nanohybrid and a suitable base fluid has been proposed in this research. The addition of this nano additive (5 wt%) to the lithium grease improves 1.5 times the extreme pressure property and can reduce lithium grease wear scar diameter better than the other similar nanomaterials reported in the previous research. For preparing the nanohybrid, during the hydrothermal synthesis reaction of nano metal borate, a suitable amount of nano transition metal dichalcogenides was added to the reaction vessel under the nitrogen atmosphere and high temperature for 18h. The base fluid comprises fatty amines, fatty oils, fatty amides, fatty acid esters, and Zinc dialkyl dithiophosphate (ZDDP) with optimum ratios. Nano lubricant additive was prepared by adding the 0.1 wt% nanohybrid to the base fluid at 80 oC with mixing for 30 minutes.

Keywords

Main Subjects


[1] He Q., Li A., Guo Y., Liu S., Zhang Y., Kong L., Tribological Properties of Nanometer Cerium Oxide as Additives in Lithium Grease, J. Rare Earths, 36: 209 (2018).
[2] Kumar N., Saini V., Bijwe J., Exploration of Talc Nanoparticles to Enhance the Performance of Lithium Grease, Tribo. Int., 162: 107107 (2021).
[3] Menezes P.L., Nosonovsky M., Kailas S.V., Friction and Wear, Tribol. Scien. Eng., 43 (2013).
[4] Jus A., Kaminski M., Radzikowska W., “Influence of Graphene Nanoflakes Addition on Grease Tribological Properties”, Proc 22th Int. Conf. App.l Phys. Condens Matter. Strbsk e Pleso Slovak, 22 (2016).
[5] Novak C., Kingman D., Stern K., Zou Q., Gara L., Tribological Properties of Paraffinic Oil with Nanodiamond Particles, Tribol. Lubr. Technol., 7: 62 (2015).
[6] Spear J.C., Custer J.P., Batteas J.D., Frictional Properties of Graphene on Silica Surfaces with Nanoscale Roughness, Tribol. Lubr. Technol., 6: 40 (2015).
[7] Carpick R.W., Jackson A., Sawyer W.G., Argibay N., Lee P., Pachon A., Gresham R.W., The Tribology Opportunities Study: Can Tribology Save a Quad? Tribol. Lubr. Technol., 5: 44 (2016).
[8] He Q., Shen Y., Ren F.Z., Li A.L., Volinsky A.A., Numerical Simulation and Experimental Study of the Air-Cooled Motorized Spindle, Proc. IMechE. Part C J. Mech. Eng. Sci., 6: 2357 (2017).
[9] Wang L.B., Wang B., Wang X.B., Liu W.M., Tribological Investigation of CaF2 Nano Crystals as Grease Additives, Tribol. Int., 40: 1170 (2007).
[10] Mohamed A., Osman T.A., Khattab A., Zaki M., Tribological Behavior of Carbon Nano Tubes as an Additive on Lithium Grease, J. Tribol., 137: 011801 (2015).
[11] Radulescu A.V., Radulescu I., Rheological Models for Lithium and Calcium Greases, Mechanics, 59: 67 (2016).
[12] Krawiec S., On the Mechanism of the Synergistic Effect of PTFE and Copper in a Lithium Grease Lubricant, Ind. Lub. Tribol., 63: 171 (2011).
[13] Asadikia A., Agha Mirjalily S.A., Nasirizadeh N., Kargarsharifabad H., Characterization of Thermal and Electrical Properties of Hybrid Nanofluids Prepared with Multi-Walled Carbon Nanotubes and Fe2O3 Nanoparticles, International Communications in Heat and Mass Transfer, 117: 104603 (2020).
[14] Asadikia A., Agha Mirjalily S.A., Nasirizadeh N., Kargarsharifabad H., Hybrid Nanofluid based on CuO Nanoparticles and Singlewalled Carbon Nanotubes: Optimization, Thermal, and Electrical Properties, Int. J. Nano Dimens., 11(3): 277 (2020).
[15] Alaei M., Torkian S., Shams M.H., Rashidi A.M., Simple Method for the Preparation of Fe3O4/MWCNT Nanohybrid as Radar Absorbing Material (RAM), Iran. J. Chem. Chem. Eng. (IJCCE), 37(6): 9-14 (2018).
[16] Alaei M., Rashidi A.M., Mahjoub A., Two Suitable Methods for the Preparation of Inorganic Fullerene-Like (IF) WS2 Nanoparticles, Iran. J. Chem. Chem. Eng. (IJCCE), 28(2): 91-98 (2009).
[17] Jiang M.J., Guo X.C., Dong J.X., Chen G.X., Study on the Lithium Complex Grease, Lubr. Eng., 5: 009 (2000).
[18] Liu H.T., Ji H.M., Hong H.P., Younes H., Tribological Properties of Carbon Nano Tube Grease, Ind. Lubr. Tribol., 66: 579 (2014).
[19] Nan F., Xu Y., Xu B.S., Gao F., Wu Y.X., Li Z.G., Effect of Cu Nano Particles on the Tribological Performance of Attapulgite base Grease, Tribol. Trans., 58: 1031 (2015).
[20] Ji X.B., Chen Y.X., Zhao G.Q., Wang X., Liu W.M., Tribological Properties of CaCO3 Nano Particles as an Additive in Lithium Grease, Tribol. Lett., 41: 113 (2011).
[21] Chang L., Zhang Z., Breidt C., Friedrich K., Tribological Properties of Epoxy Nano Composites: I. Enhancement of the Wear Resistance by Nano-TiO2 Particles, Wear, 25: 141 (2005).
[22] He Q., Li A.L., Shen Y., Design and Application on Experimental Platform for High Speed Bearing with Grease Lubrication, Adv. Mech. Eng., 7: 1 (2015).
[23] Salehi Z., Zinatloo-Ajabshir S., Salavati-Niasari M., Dysprosium Cerate Nano Structures: Facile Synthesis, Characterization, Optical and Photocatalytic Properties, J. Rare Earths, 35: 805 (2017).
[24] Zhao G.Q., Zhao Q., Li M.W., Wang X.B., Liu W.M., Tribological Properties of Nano Calcium Borate as Lithium Grease Additive, Lubr. Sci., 26: 43 (2014).
[25] Chang H., Lan C.W., Chen C.H., Kao M.I., Guo J.B., Anti-Wear and Friction Properties of Nano Particles as Additives in the Lithium Greases, Int. J. Precis. Eng. Manuf., 15: 2059 (2014).
[26] Luo T., Wein X., Zhao H., Cai G., Zheng X., Tribology Properties of Al2O3/TiO2 Nanocomposites as Lubricant Additives, Ceramics Inter., 40: 10103 (2014).
[27] Saffari H.R.M., Soltani R., Alaei M., Soleymani M., Tribological Properties of Water-based Drilling Fluids with Borate Nanoparticles as Lubricant Additives, Journal of Petroleum Science and Engineering, 171: 253 (2018).
[28] Nagaraju G., Tharamani C.N., Chandrappa G.T., Livage J., Hydrothermal synthesis of MoS2 nanofiber bundles via acidification of ammonium heptamolybdate tetrahydrate, Nanoscale Res. Lett., 2: 461 (2007).
[29] Xiang T., Amin R., Lumpur K., Water-based Mud Lubricant using Fatty Acid Polyamine Salts and Fatty Acid Esters, US Patent 9340722 B2, (2016).
[30] Zhang J., Wang A., Yin H., Preparation of Graphite Nanosheets in Different Solvents by Sand Milling and their Enhancement on Tribological Properties of Lithium-based Grease, Chinese Journal of Chemical Engineering, 28: 1177 (2020).
[31] Jun L., Shupping X., Shiyang G., FT-IR and Raman Spectroscopic Study of Hydrated Borates, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 51: 519 (1995).
[32] Goa Y.H., Liu Z.H., Wang X.L., Hydrothermal Synthesis and Thermodynamic Properties of 2ZnO.3B2O3.3H2O, Chemical Thermodynamic, 41: 775 (2009).
[33] Zhao C., Chen Y.K., Jiao Y., Loya A., Ren G.G., The Preparation and Tribological Properties of Surface Modified Zinc Borate Ultra Fine Powder as a Lubricant Additive in Liquid Paraffin, Tribology International, 70: 155 (2014).