Development of A Low-Cost Method for Determination of Sulfide Ions in Aluminate Solution of Bayer Process and Sulfide Removal Using Nitrate from It

Document Type : Research Article

Authors

Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, I.R. IRAN

Abstract

Sulfide ions in the solution of the Bayer process can accelerate the corrosion of the equipment and increase the impurity of the final product. In the current investigation, sulfide ions concentration of the aluminate solution during the Bayer process was determined using an indirect and inexpensive method. The method did not require any advanced apparatus, which made it suitable for sulfide concentrations over the range of 0.001-1 g/L. To investigate the source of sulfide ions in the aluminate solution, the chemical composition and crystalline structure of the bauxite used to produce alumina were characterized via XRF, XRD, and SEM analyses. The results demonstrated that the main source of sulfide ions was pyrite in bauxite. The advantages and disadvantages of sulfide removal method by nitrate from aluminate solution were investigated. Thermodynamically, the spontaneity of different half-reactions during the reduction of NO3- and oxidation of S2- was studied. Finally, a technique was proposed for the removal of sulfide ions in the aluminate solution by adding nitrate. Moreover, the effect of nitrate concentration on lowering of sulfide ions concentration was evaluated in practical conditions of the bauxite digestion during the Bayer process. The results demonstrated that in conditions of bauxite digestion (at 270 °C, 52 bar, and 60 minutes) by adding 2.5 g/L nitrate ions, the majority of sulfide ions (more than 96%) were eliminated and their undesirable effects were prevented.

Keywords

Main Subjects

References

[1] Tabereaux Alton T., Peterson Ray D., Aluminum Production, Treatise on Process Metallurgy, 3: 839-917 (2014).
[2] Londry K.L., Suflita J.M., Use of Nitrate to Control Sulfide Generation by Sulfate-Reducing Bacteria Associated with Oily Waste, Journal of Industrial Microbiology & Biotechnology, 22: 582-589 (1999).
[3] Altas L., Buyukgungor H., Sulfide Removal in Petroleum Refinery Wastewater by Chemical Precipitation, Journal of Hazardous Materials, 153: 462-469 (2008).
[4] Wang Y., Kang W., Wu Y., Qi X., Study on the Methods for Removing Sulfide Ion and Sulfate Radical from the Oilfield Sewage, Chin. J. Chem., 29: 1273-1277 (2011).
[5] Nasr-El-Din H.A., AL-Humaidan A.Y., Iron Sulfide Scale: Formation, Removal and Prevention,  SPE68315 (2001).
[6] Vaiopoulou E., Melidis P., Aivasidis A., Sulfide Removal in Wastewater from Petrochemical Industries by Autotrophic Denitrification, Water Research, 39: 4101-4109 (2005).
[7] Shokri A., The Treatment of Spent Caustic in the Wastewater of Olefin Units by Ozonation Followed by Electrocoagulation Process, Desainl. Water Trea., 111: 173-182 (2018).
[8] Xiao-lian H., Wen-mi1 C., Qiao-ling X., Sulfur Phase and Sulfur Removal in High Sulfur-Containing Bauxite, Trans. Nonferrous Met. Soc. China, 21: 1641−1647 (2011).
[9] Li X.B., Niu F., Tan J., Liu G.H., Qi T.G., Peng Z.H., Qiu-sheng Z., Removal of S2− Ion from Sodium Aluminate Solutions with Sodium Ferrite, Trans. Nonferrous Met. Soc. China, 26: 1419−1424 (2016).
[10] Li X.B., Li C.Y., Peng Z.H., Liu G.H., Zhow Q.S., Qi T.G., Interaction of Sulfur with Iron Compounds in Sodium Aluminate Solutions, Trans. Nonferrous Met. Soc. China, 25: 608−614 (2015).
[11] Liu Z., Ma W., Yan H., Xie K., Li D., Zheng L., Li P., Removal of Sulfur by Adding Zinc During the Digestion Process of High-Sulfur Bauxite, Scientific Reports, 7: 17181 (2017)
[12] Abikenova G.K., Kovazlenko V.A., Ambarnikova G.A., Ibragimov A.T., Investigation of the Effect and Behavior of Sulfur Compounds on the Technological Cycle of Alumina Production, Metallurgy of Non-Ferrous Metals, 49(2): 91-96 (2008).
[13] Song C., Peng Z., Wei X., Qi T., The Reaction Behavior of Pyrite in Process of Bayer Digestion, Nonfer. Meta. Sci. Engi, 2(5): 1-5 (2011).
[14] Li X.B, Li C.Y., I., Qi T., Zhow Q.,, Liu G., Peng Z.H., Reaction Behavior of Pyrite During Bayer Digestion at High Temperature, The Chinese Journal of Nonferrous Metals, 23(3): 830−835 (2013).
[15] Chimonyo W., Corin K.C., Wiese J.G., O’Connor C.T., Redox Potential Control During Flotation of a Sulphide Mineral Ore, Min. Eng., 110: 57–64 (2017).
[16] Owusu C., Quast K., Addai-Mensah J., The use of Canola Oil as an Environmentally Friendly Flotation Collector in Sulphide Mineral Processing, Minerals Engineering, 98: 127–136 (2016).
[17] Blight K., Ralph D.E., Thurgate S., Pyrite Surfaces after Bio-Leaching: A Mechanism for Bio-Oxidation, Hydrometallurgy, 58(3): 227–237 (2000).
[18] Gu G.H., Sun X.J., Hu K.T., Li J.H., Qiu G.Z., Electrochemical Oxidation Behavior of Pyrite Bioleaching by Acidthiobacillus Ferrooxidans, Tra. Nonfer. Met. Soc. China, 22(5): 1250–1254 (2012).
[19] Lou Z.N., Xiong Y., Feng X.D., Shan W.J., Zhai, Y.C., Study on the Roasting and Leaching Behavior of High-Sulfur Bauxite Using Ammonium Bisulfate, Hydrometallurgy, 165: 306–311 (2016).
[20] Eccleston E., White J., Development of Roasting Parameters for the ConRoast Process with Low-Sulphur Feedstock, Journal of the South African Institute of Mining and Metallurgy, 109(1): 65–69 (2009).
[21] Jackie Dong, Greg Power, Joanne Loh, James Tardio, Chris Vernon, Suresh Bhargava, Fundamentals of Wet Oxidation of Bayer-Process Liquor: Reactivity of Malonates, In. En. Ch. Re., 49: 5347–5352 (2010).
[22] Lalla A., Arpe R., “12 Years of experience with wet oxidation”, Light Metals-Warrendale-Proceedings, 177–180 (2002).
[23] Standard Methods Committee of the American Public Health Association, American Water Works Association and Water Environment Federation, “4500-S2- sulfide In: Standard Methods For the Examination of Water and Wastewater”, APHA Press, Washington DC, United States, (2018).
[24] Emami M., Mousavi M. F., Barzegar M., Determination of Sulfide in Spring and Wastewater by a New Kinetic Spectrophotometric Method, Journal of the Chinese Chemical Society, 51(3): 517-521 (2004).
[25] Safavi A., Mirzaee M., Kinetic Spectrophotometric Determination of Traces of Sulfide in Nonionic Micellar Medium, Fre. J. An. Ch., 367(7): 645–648 (2000).
[26] Jin Y., Wu H., Tian Y., Chen L., Cheng J., Bi S., Indirect Determination of Sulfide at Ultratrace Levels in Natural Waters by Flow Injection On-Line Sorption in a Knotted Reactor Coupled with Hydride Generation Atomic Fluorescence Spectrometry, Anal. Chem., 79(18): 7176–81 (2007)
[27] Huang R., Zheng X., Qu Y., Highly Selective Electrogenerated Chemiluminescence (ECL) for Sulfide Ion Determination at Multi-Wall Carbon Nanotubes-Modified Graphite Electrode, Anal. Chim. Acta., 582(2): 267–274 (2007).
[28] Colon M., Todoli J.L., Hidalgo M., Iglesias M., Development of Novel and Sensitive Methods for the Determination of Sulfide in Aqueous Samples by Hydrogen Sulfide Generation-Inductively Coupled Plasma-Atomic Emission Spectroscopy, Anal. Chim. Acta., 609(2): 160–168 (2008).
[29] Ying W., Wan-Li K., Dan Z., Jing-Jing Z., Indirect Determination of Sulfur ions in Oilfield Sewage by Inductively Coupled Plasma-Atomic Emission Spectrometry, Chinese J. Anal. Chem., 36(11): 1575–1578 (2008).
[30] Afkhami A., Khalafi L., Indirect Determination of Sulfide by Cold Vapor Atomic Absorption Spectrometry, Microchim Acta, 150(1): 43–46 (2005).
[31] Santos J.C.C., Santos E.B.G.N., Korn M., A Comparison of Flow Injection Methods for Sulfide Determination based on Phenothiazine Dyes Produced from Diverse Aromatic Amines, Microchem J., 90(1): 1–7 (2008).
[32] Giuriati C., Cavalli S., Gorni A., Badocco D., Pastore P., Ion Chromatographic Determination of Sulfide and Cyanide in Real Matrices by Using Pulsed Amperometric Detection on a Silver Electrode, J. Chromatogr A., 1023(1): 105–112 (2004).
[33] Huang D., Xu B., Tang J., Luo J., Chen L., Yang L., Indirect Determination of Sulfide Ions in Water Samples at Trace Level by Anodic Stripping Voltammetry Using Mercury Film Electrode, Anal. Methods, 2(2): 154–158 (2010).
[34] Yang B., Wang S., Tian S., Liu L., Determination of Hydrogen Sulfide in Gasoline by Au Nanoclusters Modified Glassy Carbon Electrode, Electrochem commun, 11(6): 1230–1233 (2009).
[35] Lawrence N.S., Davis J., Jiang L., Jones T.G.J., Davies S.N., Compton R.G., Electrochemically Initiated 1, 4-Nucleophilic Substitutions: A General Strategy for the Analytical Detection of Hydrogen Sulfide, Electroanal An. Int. J. Devoted to Fundam Pract Asp Electroanal, 13(6): 432–436 (2001).
[36] Pandurangappa M., Lawrence N.S., Jiang L., Jones T.G.J., Compton R.G., Physical Adsorption of N, N′-diphenyl-p-phenylenediamine onto Carbon Particles: Application to the Detection of Sulfide, Analyst, 128(5): 473–479 (2003).
[37] Lurie Ju, The Handbook of Analytical Chemistry, Nicholas Babrov, Translator; Moscow: MIR Publishers  307-311 (1978).
Iranian Journal of Chemistry and Chemical Engineering
Volume 42, Issue 4 - Serial Number 126
April 2023
Pages 1242-1250

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