Department of Organic Chemistry, Faculty of Sciences, Shiraz University, Zip code 71454, Shiraz, I.R. IRAN
10.30492/ijcce.1999.10192
Abstract
The kinetics and mechanisms of the substitution reactions of trans-[Co(en)2CNCl]+ with unidentate anions, , CN¯, I¯, , Br¯ and SCN¯ in 60% v/v DMF-H2O binary solvent at 40.0±0.2 °C were studied spectrophotometrically. An Id mechanism was assigned for the replacement of chlorine by , CN¯ and I¯, an Ia one for the entry of and SCN¯, and a D mechanism for Br¯ entry. Comparing the interchange rate constants, ki, values has led to the following trend of reactivity of the anions toward the given substrate:The replacement of chlorine by the anions proceeded with a complete retention of configuration.
Asadi, M., & Rajabloo, H. (1999). The Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent. Iranian Journal of Chemistry and Chemical Engineering, 18(2), 98-103. doi: 10.30492/ijcce.1999.10192
MLA
Mozaffar Asadi; Hassan Rajabloo. "The Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent". Iranian Journal of Chemistry and Chemical Engineering, 18, 2, 1999, 98-103. doi: 10.30492/ijcce.1999.10192
HARVARD
Asadi, M., Rajabloo, H. (1999). 'The Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent', Iranian Journal of Chemistry and Chemical Engineering, 18(2), pp. 98-103. doi: 10.30492/ijcce.1999.10192
VANCOUVER
Asadi, M., Rajabloo, H. The Kinetics and Mechanisms of Substitution Reactions of Trans-[Co(en)2CNCl]+ in Binary Mixed Solvent. Iranian Journal of Chemistry and Chemical Engineering, 1999; 18(2): 98-103. doi: 10.30492/ijcce.1999.10192
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