Document Type : Research Article
Authors
1
1. Faculty of Engineering, Department of Chemical Engineering, Soran University 2. Nuzhan Nanofannavar Company, West Azerbaijan Science and Technology Park, Urmia, Iran.
2
Department of Civil Engineering, Faculty of Engineering, Soran University, Soran, Erbil, Kurdistan Region, Iraq
3
4. Department of Cellular and Molecular, Biological Sciences and Technologies, Islamic Azad University Branch of Urmia, Urmia, Iran.
10.30492/ijcce.2024.2020159.6389
Abstract
At present, the escalating magnitude of waste represents a formidable global concern, wherein paper waste alone constitutes approximately 26% of the overall waste deposited in landfills. Thus, the transformation of paper waste into viable products assumes paramount significance. In this study, paper waste was converted to CaCO3 using a thermal process and surface-modified with stearic acid. The effect of environmental pH and process temperature on the crystalline structure and morphology of the product was evaluated. The prepared CaCO3 was used in deactivation of gram-negative agrobacterium tumefaciens and the effect of hydrophobicity on the CaCO3 antibacterial activity was studied. XRD, SEM, FTIR, BET/BJH, contact angle and TEM characterization techniques were utilized to characterize structure and physicochemical properties of prepared CaCO3. According to the XRD analysis, the optimal temperature for the conversion process was 500°C in an air environment without any changes in pH. SEM analysis confirmed that as the calcination temperature increased, the number of cracks and holes on the surface also increased. BET analysis confirmed this by showing a decrease in the specific surface area in the Ca-750 sample. TEM analysis revealed nanoparticles with spherical and irregular spherical geometries, ranging in size from 30 to 90 nm. According to the contact angle analysis, increasing the concentration of stearic acid led to an increase in the contact angle to 121.4°. This increase in contact angle indicates an enhancement in the hydrophobicity of the prepared nanoparticles, which had a synergistic effect on their antibacterial activity. The antibacterial activity test of both prepared hydrophilic and hydrophobic CaCO3 depicted the high antibacterial activity of both CaCO3 while the hydrophobic CaCO3 revealed higher antibacterial activity compared to hydrophilic CaCO3.
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