Surface Chemistry and Catalysis: Understanding Interfaces for Enhanced Reactivity

Document Type : Review Article

Authors

1 Electroanalytical Chemistry Laboratory, Department of Chemistry, Azarbaijan Shahid Madani University, Iran

2 cellular & molecular research center.Urmia University of Medical Sciences

3 Faculty of Physics, University of Kurdistan, Sanandaj, Iran

4 Department of Mineral Processing, Tarbiat Modares University, Tehran, Iran

5 Chemical Engineering Department, Amirkabir University of Technology, Tehran, Iran

Abstract

Catalysis stands as a cornerstone of modern chemical processes, shaping industries from energy to pharmaceuticals. This review embarks on a comprehensive journey through the intricate interplay between surface chemistry and catalytic reactivity. Employing a rigorous methodology involving literature from Scopus, Web of Science, and Google Scholar, we explore key topics. Surface chemistry takes center stage, delving into the principles of adsorption and desorption on catalytic surfaces, guided by forces like van der Waals and electrostatic interactions. Surface reaction mechanisms unveil how surface arrangements drive reaction pathways and selectivity. Catalyst-substrate interactions underscore the synergy between active sites, coordination chemistry, and binding energies. Comparing heterogeneous and homogeneous catalysis, we discern distinct advantages and challenges for each approach. Nanocatalysis unveils how nanoparticle size and morphology revolutionize reactivity, with implications spanning environmental sustainability to energy conversion. Catalyst design strategies, encompassing surface area optimization and hierarchical structures, enrich our toolkit. Characterization techniques, from X-ray spectroscopy to electron microscopy, lay bare structural intricacies. Real-world industrial applications illustrate catalysis's impact across petrochemicals, pharmaceuticals, and environmental remediation. Challenges of catalyst stability, transient intermediates, and complex multi-step reactions underscore the evolving landscape. As we conclude, the potential of catalysis to address global challenges shines bright. With innovative techniques and collaborative efforts, catalytic science charts a course towards a sustainable future, poised to tackle society's most pressing issues.

Keywords

Main Subjects