Photocatalytic efficiency of Mg-Al doped Cobalt Ferrite nanoparticles for degradation of Methylene blue dye

Articles in Press

Document Type : Research Article

Authors

1 Department of Chemistry Sant Longowal Institute of Engineering and Technology Longowal Sangrur-148106, Punjab, India.

2 Department of Chemistry, Sant Longowal Institute of Engineering and Technology, Longowal, Sangrur (Punjab) -148106

Abstract

The present study aims to determine the photocatalytic degradation efficiency on organic Methylene blue (MB) dye by using Mg0.5Co0.5Al0.5Fe1.5O4 spinel ferrite nanoparticles as a photocatalyst. All metal nitrates and sodium hydroxide were used as raw chemicals in the co-precipitation method for the synthesis of Mg0.5Co0.5AlxFe2-xO4 (x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9 mole %) spinel ferrites nanoparticles. The synthesized nanoparticles were characterized by X-ray diffraction (XRD), Field emission Scanning electron microscope (FE-SEM), Energy dispersive spectrometer (EDS) mapping, Fourier transform infrared (FT-IR), PL photoluminescence spectra, UV–visible spectroscopy and N2 absorption-desorption isotherm method. XRD confirms the spinel cubic structure of spinel ferrite nanoparticles. Interplanar distance (d) and crystalline size (D) are calculated by using Bragg’s equation and Scherrer’s relationship respectively. SEM and EDS confirmed the morphological and elemental analysis of spinel ferrites. UV spectrum of the synthesized photocatalyst was studied and compared the energy band gap between the undoped, Mg doped and Mg-Al doped cobalt spinel ferrites. PL photoluminescence spectra were analyzed to investigate the transfer, relocation, and recombination process of charge carriers. The surface area of the synthesized photocatalysts was in the range of 26.38-32.47 m2g-1. The photocatalysis of Mg-Al doped cobalt spinel ferrite nanoparticles was carried out for the degradation of MB dye under visible light irradiation. The amount of photocatalyst (spinel ferrite) used, duration under irradiation, pH level, starting dye concentration and H2O2 concentration were all factors in the photocatalytic degradation of MB dye. The maximum percentage degradation (%) of MB dye was analyzed and calculated at pH 9. The MB dye (20 ppm) maximum degraded by 2 g/L of spinel ferrite nanoparticles in 120 min. of visible light irradiation.

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Iranian Journal of Chemistry and Chemical Engineering

Articles in Press, Accepted Manuscript
Available Online from 11 September 2023

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