An Investigation of the Asphaltene Effect on Wax Precipitation of Iran Asmari Reservoir Dead Crude Oil

Document Type : Research Article

Authors

1 Faculty of Petroleum and Natural Gas Engineering, Sahand Oil and Gas Research Institute, Sahand University of Technology, Tabriz, I.R. IRAN

2 Chemical Engineering Department, Sahand Oil and Gas Research Institute, Sahand University of Technology, Tabriz, I.R. IRAN

Abstract

Wax and asphaltene precipitations cause many problems and high costs in the petroleum industry; therefore, the significance of studying these depositions' behavior is considerable. Evaluating the asphaltene effect on wax precipitation can help find the behavioral trends of waxes and prevent them from precipitating. In this paper, Iran Asmari reservoir Dead Crude oil (IADC) and asphaltene from this oil were used for the experiments. The extracted asphaltene was analyzed by FT-IR analysis. The pour point and wax precipitation content were determined according to the ASTM-D97 Standard test and modified UOP 46-64 method, respectively, and Wax Appearance Temperature (WAT) was measured via differential scanning calorimetry (DSC). At low asphaltene concentrations (0 and 0.057 wt %), adding asphaltene decreased the pour point and wax precipitation content. At asphaltene concentrations of 0.057 wt %, the least wax precipitation content and pour point were measured. A rise in pour point and wax precipitation content was observed at more asphaltene concentrations (0.057-20 wt %). The wax appearance temperature of IADC (36.5 °C) has been decreased in asphaltene-free IADC (25.1 °C). By changing the asphaltene concentration from 0 to 0.1 wt %, the behavior of wax precipitation changed intensely, and this behavior varied gently by increasing the asphaltene concentration from 0.1 to 20 wt %.

Keywords

Main Subjects


[1] Yazdizadeh M., Nourbakhsh H., Jafari Nasr M.R., A Solution Model for Predicting Asphaltene Precipitation, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 33(1): 93-102 (2014).
[2] Thawer R., Nicoll D.C.A., Dick G., Asphaltene Deposition in Production Facilities, SPE Production Engineering, 5(04): 475-80(1990).
[3] Kriz P, Andersen SI, Effect of Asphaltenes on Crude Oil Wax Crystallization, Energy & Fuels,19(3): 948-53 (2005).
[4] del Carmen Garcia M., "Paraffin Deposition in Oil Production", SPE International Symposium on Oilfield Chemistry, Houston, Texas: Society of Petroleum Engineers:7(2001).
[5] Sheu E.Y., Petroleum Asphaltene-Properties, Characterization, and Issues, Energy & Fuels,16(1): 74-82 (2002).
[6] Aiyejina A., Chakrabarti D.P., Pilgrim A., Sastry M.K.S., Wax Formation in Oil Pipelines: A Critical Review, International Journal of Multiphase Flow, 37(7): 671-94 (2011).
[7] Li W., Li H., Da H., Hu K, Zhang Y., Teng L., Influence of Pour Point Depressants (PPDs) on Wax Deposition: A Study on Wax Deposit Characteristics and Pipeline Pigging, Fuel Processing Technology, 217:106817 (2021).
[8] Tabatabaei-Nejad S.A., Khodapanah E., Application of Gaussian Quadrature Method to Characterize Heavy Ends of Hydrocarbon Fluids for Modeling Wax Precipitation, Applied Mathematical Modelling, 35(1): 109-22(2011).
 [9] Turner W.R., Normal Alkanes, Product R&D,10(3): 238-60(1971).
[10] Shock DA., Sudbury J.D., Crockett J.J., Studies of the Mechanism of Paraffin Deposition and Its Control, Journal of Petroleum Technology,7(09): 23-8(1955).
[11] Tabatabaei-Nejad S.A., Khodapanah E, An Investigation on the Sensitivity Analysis of the Parameters of Proposed Wax Precipitation Model, Journal of Petroleum Science and Engineering,68(1): 89-98(2009).
[13] Rehan M., Nizami A-S., Taylan O., Al-Sasi B.O., Demirbas A., Determination of Wax Content in Crude Oil, Petroleum Science and Technology, 34(9): 799-804(2016).
[14] Magnini M., Matar O.K., Fundamental Study of Wax Deposition in Crude Oil Flows in a Pipeline via Interface-Resolved Numerical Simulations, Industrial & Engineering Chemistry Research, 58(47): 21797-816(2019).
[15] D97 AS, Pour Point of Petroleum Products, ASTM International, West Conshohocken, PA (2005).
[16] Theyab M., Wax Deposition Process: Mechanisms, Affecting Factors and Mitigation Methods, Open Access J Sci., 2:112-8(2018).
[17] Tinsley J.F., "The Effects of Polymers and Asphaltenes Upon Wax Gelation and Deposition", Princeton University (2008).
[18] Labes-Carrier C., Rønningsen H.P., Kolnes J., Leporcher E., "Wax Deposition in North Sea Gas Condensate and Oil Systems: Comparison Between Operational Experience and Model Prediction", SPE Annual Technical Conference and Exhibition, All Days.(2002).
[19] Sabbaghi S., Jahanmiri A., Ayatollahi S., Shariaty Niassar M., Mansoori G.A., Characterization of Asphaltene Using Potential Energy and Nanocalculation, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 27(2): 47-58 (2008).
[20] Rastgoo A., Kharrat R., Investigation of Asphaltene Deposition and Precipitation in Production Tubing, International Journal of Clean Coal and Energy, 06: 14-29 (2017).
[21] Li Y., Han S., Lu Y., Zhang J., Influence of Asphaltene Polarity on Crystallization and Gelation of Waxy Oils, Energy & Fuels, 32(2): 1491-7 (2018).
[22] Rashid Z., Wilfred C.D., Gnanasundaram N., Arunagiri A., Murugesan T., A Comprehensive Review on the Recent Advances on the Petroleum Asphaltene Aggregation, Journal of Petroleum Science and Engineering,176: 249-68 (2019).
[23] Mullins O.C., Betancourt S.S., Cribbs M.E., Dubost F.X., Creek J.L., Andrews A.B., et al., The Colloidal Structure of Crude Oil and the Structure of Oil Reservoirs, Energy & Fuels, 21(5): 2785-94 (2007).
[25] Murgich J., Molecular Simulation and the Aggregation of the Heavy Fractions in Crude Oils, Molecular Simulation, 29(6-7): 451-61 (2003).
[26] Mullins O.C., Review of the Molecular Structure and Aggregation of Asphaltenes and Petroleomics, SPE-95801-PA,13(01): 48-57 (2008).
[27] Oliveira G.E., Mansur C.R.E., Lucas E.F., González G., de Souza W.F., The Effect of Asphaltenes, Naphthenic Acids, and Polymeric Inhibitors on the Pour Point of Paraffins Solutions, Journal of Dispersion Science and Technology, 28(3): 349-56 (2007).
[28] Betancourt S.S., Ventura G.T., Pomerantz A.E., Viloria O., Dubost F.X., Zuo J., et al., Nanoaggregates of Asphaltenes in a Reservoir Crude Oil and Reservoir Connectivity, Energy & Fuels, 23(3): 1178-88 (2009).
[29] Abdel-Raouf ME-S., “Crude Oil Emulsions – Composition Stability and Characterization", InTech Publication (2012).
[30] Thanh N.X., Hsieh M., Philp R.P., Waxes and Asphaltenes in Crude Oils, Organic Geochemistry, 30(2): 119-32 (1999).
[32] García M.d.C., Carbognani L., Asphaltene−Paraffin Structural Interactions. Effect on Crude Oil Stability, Energy & Fuels, 15(5): 1021-7(2001).
[33] Venkatesan R., Östlund J-A, Chawla H., Wattana P., Nydén M., Fogler H.S., The Effect of Asphaltenes on the Gelation of Waxy Oils, Energy & Fuels,17(6): 1630-40 (2003).
[34] Li C, Zhu H., Yang F., Liu H, Wang F., Sun G, et al., Effect of Asphaltene Polarity on Wax Precipitation and Deposition Characteristics of Waxy Oils, Energy & Fuels, 33(8):7225-33 (2019).
[35] Tinsley J.F., Jahnke J.P., Dettman H.D., Prud’home R.K., Waxy Gels with Asphaltenes 1: Characterization of Precipitation, Gelation, Yield Stress, and Morphology, Energy & Fuels, 23(4): 2056-64 (2009).
[36] Alcazar-Vara L.A., Buenrostro-Gonzalez E., Characterization of The Wax Precipitation In Mexican Crude Oils, Fuel Processing Technology, 92(12): 2366-74 (2011).
[37] Alcazar-Vara L.A., Garcia-Martinez J.A., Buenrostro-Gonzalez E., Effect of Asphaltenes on Equilibrium and Rheological Properties of Waxy Model Systems, Fuel, 93: 200-12 (2012).
[38] Taheri-Shakib J., Saadati N., Esfandiarian A., Hosseini S.A., Rajabi-Kochi M., Characterizing the Wax-Asphaltene Interaction and Surface Morphology Using Analytical Spectroscopy and Microscopy Techniques, Journal of Molecular Liquids, 302: 112506 (2020).
[39] Xue H., Zhang J., Han S., Sun M., Yan X., Li H., Effect of Asphaltenes on the Structure and Surface Properties of Wax Crystals in Waxy Oils, Energy & Fuels, 33(10): 9570-84 (2019).
[40] Alcazar-Vara L.A., Garcia-Martinez J.A., Buenrostro-Gonzalez E., Effect of Asphaltenes on Equilibrium and Rheological Properties of Waxy Model Systems, Fuel, 93(0): 200-12 (2012).
[41] Testing A.S.f., Materials, "ASTM D6560, Standard Test Method for Determination of Asphaltenes (Heptane Insolubles) in Crude Petroleum and Petroleum Products", ASTM International West Conshohocken, PA, (2000).
[42] Burger E.D., Perkins T.K., Striegler J.H., Studies of Wax Deposition in the Trans Alaska Pipeline, Journal of Petroleum Technology, 33(06): 1075-86 (1981).
[43] Yang X., Kilpatrick P., Asphaltenes and Waxes Do Not Interact Synergistically and Coprecipitate in Solid Organic Deposits†, Energy & Fuels, 19(4): 1360-75 (2005).
[44] Gopinath S., Devan P.K., Optimization and Prediction of Reaction Parameters of Plastic Pyrolysis Oil Production Using Taguchi Method, Iranian Journal of Chemistry and Chemical Engineering, 39(2): 91-103 (2020).
[45] Gopinath S., Devan P.K., Pitchandi K., Production of Pyrolytic Oil from ULDP Plastics Using Silica-Alumina Catalyst and Used as Fuel for DI Diesel Engine, RSC Advances,10(61): 37266-79 (2020).
[46] Pavia D.L., Lampman G.M., Kriz G.S., Vyvyan J.A., "Introduction to Spectroscopy", Cengage Learning (2008).
[47] Al-Huraibi N., Belhaj H.A., "Modeling of Crude Oil Asphaltenes Deposition: In-Depth Colloidal Prospective", SPE Production and Operations Conference and Exhibition, Tunis, Tunisia: Society of Petroleum Engineers:6 (2010).
[48] Dandekar AY, “Petroleum Reservoir Rock and Fluid Properties", CRC Press (2013).
[49] Hoepfner M.P., Limsakoune V., Chuenmeechao V., Maqbool T., Fogler H.S., A Fundamental Study of Asphaltene Deposition, Energy & Fuels, 27(2): 725-35 (2013).
[50] Li H., Zhang J., Xu Q., Hou C., Sun Y., Zhuang Y., et al., Influence of Asphaltene on Wax Deposition: Deposition Inhibition and Sloughing, Fuel, 266: 117047 (2020).