Determination of the Minimum Miscible Pressure of the Supercritical Carbon Dioxide and the Formation Oil System by the Pendant Drop Method

Document Type : Research Article

Authors

1 Department of Petroleum Engineering, Northeast Petroleum University, Daqing, P.R. CHINA

2 Key Laboratory of Enhanced Oil Recovery (Northeast Petroleum University), Ministry of Education, Daqing, P.R. CHINA

3 School of Earth Sciences, Northeast Petroleum University, Daqing, P.R. CHINA

Abstract

Carbon dioxide miscible displacement plays an important role in the field of miscible displacement for enhanced oil recovery. However, there is a very important relationship between the formation of miscible displacement and the minimum miscible pressure. The pendant drop method in the interfacial tension method was firstly used to predict the minimum miscible pressure of the supercritical carbon dioxide and the formation of oil in the test area oilfield. Under the condition of the simulated reservoir temperature 111.5 °C, the interfacial tension of the supercritical carbon dioxide and the formation oil system was tested experimentally by using formation oil samples of the test area oilfield. The range of test pressure was from 10.06 MPa to 28.57 MPa. Besides, the relation curve of the test pressure and the interfacial tension was drawn. The results show that under the reservoir temperature, the interfacial tension between the supercritical carbon dioxide and the formation oil shows an approximately linear downward trend with increasing the test pressure. The mathematical expression was obtained by the linear regression analysis. According to the extrapolation, the vanishing point of the interfacial tension was obtained. Then the minimum miscible pressure of the supercritical carbon dioxide and the formation oil system was determined. The actual test was carried out to verify the result by the pendant drop method. Finally, the minimum miscible pressure of the supercritical carbon dioxide and the formation oil system of the test area oilfield was determined to be 29.4 MPa.

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[1] Kolster C., Masnadi M.S., Krevor S., Dowell N.M., Brandt A.R., CO2 Enhanced Oil Recovery: A Catalyst for Gigatonne-Scale Carbon Capture and Storage Deployment? Energy Environ. Sci., 10: 2594–2608 (2017).
[2] Qin J.SH., Han H.Sh.HhhasHLJS, Liu X.L., Application and Enlightenment of Carbon Dioxide Flooding in the United States of America, Petroleum Exploration and Development, 42(2): 209-216 (2015).
[3] Hekmatzadeh M., Dadvar M., Emadi M.A., Experimental and Numerical Pore Scale Study of Residual Gas Saturation in Water/Gas Imbibition Phenomena, Iran. J. Chem. Chem. Eng. (IJCCE), 34(3): 109-120 (2015).
[4] Moradi S., Rashtchian D., Ghazvini M.G., Emadi M.A., Dabir B., Experimental Investigation and Modeling of Asphaltene Precipitation Due to Gas Injection, Iran. J. Chem. Chem. Eng. (IJCCE), 31(1): 89-98 (2012).
[6] Zhang J., Zhang H.X., Ma L.Y., Liu Y., Zhang L., Performance Evaluation and Mechanism with Different CO2 Flooding Modes in Tight Oil Reservoir with Fractures, J. Petrol. Sci. Eng., 188: 106950 (2020).
[7] Guo P., Hu Y.Sh., Qin J.Sh., Li Sh., Jiao S.J., Chen F., He J., Use of Oil-Soluble Surfactant to Reduce Minimum Miscibility Pressure, Petrol. Sci. Technol., 35(4): 345–350 (2017).
[8] Yang Z. H., Wu W., Dong Zh. X., Lin M. Q., Zhang Sh.W., Zhang J., Reducing the Minimum Miscibility Pressure of CO2 and Crude Oil Using Alcohols, Colloid. Surface. A, 568: 105–112 (2019).
[9] Shahrabadi A., Dabir B., Sadi M., Fasih M., Effect of CO2 Concentration in Injecting Gas on Minimum Miscibility Pressure: Compositional Model and Experimental Study, Iran. J. Chem. Chem. Eng. (IJCCE), 31(1): 113-118 (2012).
[10] Yu H.Y., Lu X., Fu W.R., Wang Y.Q., Xu H., Xie Q.Ch., Qu X.F., Lu J., Determination of Minimum Near Miscible Pressure Region During CO2 and Associated Gas Injection for Tight Oil Reservoir in Ordos Basin, China. Fuel, 263: 116737 (2020). 
[11] Zhao Y.J., Song K.P., Fan G.J., The Minimum Miscible Pressure Research of the Supercritical Carbon Dioxide and Crude Oil System under the Reservoir Condition, Journal of Dalian University of Technology, 57(2): 119-125 (2017).
[13] Almasi D., Abbasi K., Sultana N., Lau W.J., Study on TiO2 Nanoparticles Distribution in Electrospun Polysulfone/TiO2 Composite Nanofiber, Iran. J. Chem. Chem. Eng. (IJCCE), 36(2): 49-53 (2017).
[14] Jahangiri A.R., Sedighi M., Salimi F., Synthesis of Zinc-Sulfate Nano Particles and Detection of Their Induction Time, Nucleation Rate and Interfacial Tension, Iran. J. Chem. Chem. Eng. (IJCCE), 38(6): 45-52 (2019).
[15] Berneti S.M., Varaki M.A., Development of ε-Insensitive Smooth Support Vector Regression for Predicting Minimum Miscibility Pressure in CO2 Flooding, Songklanakarin J. Sci. Technol., 40 (1): 53–59 (2018).
[16] Ebrahimi A., Khamehchi E., The use of Optimization Procedures to Estimate Minimum Miscibility Pressure, Petrol. Sci. Technol., 32(8): 947–957 (2014).
[17] Lian L.M., Qin J.Sh., Yang S.Y., Research Progress and Development Directions of Mathematical Models in CO2 Flooding, Petroleum Geology and Recovery Efficiency, 20(2): 77-82 (2013).
[18] Ghorbani M., Gandomkar A., Montazeri G., Describing a Strategy to Estimate the CO2-Heavy Oil Minimum Miscibility Pressure Based on the Experimental Methods, Energ. Source. Part A, 41(17): 2083–2093 (2019).
[19] Ju B.Sh., Qin J.Sh., Li Zh.P., Chen X.L., A Prediction Model for the Minimum Miscibility Pressure of the CO2-Crude Oil System, Acta Petrolei Sinica, 33(2): 274-277 (2012).
[20] Li D., Li X.L., Zhang Y.H., Sun L.X., Yuan Sh.L., Four Methods to Estimate Minimum Miscibility Pressure of CO2-Oil Based on Machine Learning, Chin. J. Chem., 37: 1271−1278 (2019).
[21] Li Ch.Ch., Pu H., Zhong X., Li Y.H., Zhao J.X., Interfacial Interactions Between Bakken Crude Oil and Injected Gases at Reservoir Temperature: A Molecular Dynamics Simulation Study, Fuel, 276:    -    (2020).
[23] Mutailipu M., Jiang L.L., Liu X.J., Liu Y., Zhao J.F., CO2 and Alkane Minimum Miscible Pressure Estimation by The Extrapolation of Interfacial Tension, Fluid Phase Equilibr, 494: 103–114 (2019).
[24] Ahmadi M.A., Zendehboudi S., James L.A., A Reliable Strategy to Calculate Minimum Miscibility Pressure of CO2-Oil System Miscible Gas Flooding Processes, Fuel, 208: 117–126 (2017).
[25] Zhang K., “Interfacial Characteristics and Application Research on CO2-Formation Oil System”, Ph.D. Dissertation, Beijing: Chinese Academy of Sciences, (2011).
[26] Wang H.T., Lun Z.M., Luo M., Interfacial Tension of CO2/Crude Oil and N2/Crude Oil at High Pressure and High Temperature, Acta Petrolei Sinica, 32(1): 177-180 (2011).
[27] Choubineh A., Mousavi S.R., Ayouri M.V., Ahmadinia M., Choubineh D., Baghban A., Estimation of the CO2-Oil Minimum Miscibility Pressure for Enhanced Oil Recovery, Petrol. Sci. Technol., 34(22): 1847−1854 (2016).
[28] Huang Ch.X., Tang R.J., Yu H.G., Determination of the Minimum Miscibility Pressure of CO2 and Crude Oil System by Hanging Drop Method, Lithologic Reservoirs, 27(1): 127-130 (2015).