Electrodeposition of Ni3Bi2Se2 Thin Semiconductor Films

Document Type : Research Article

Authors

Institute of Catalysis and Inorganic Chemistry, Named after Acad. M. Nagiyev NAS, AZERBAIJAN

Abstract

The present contribution is devoted to the production of the Ni-Bi-Se thin films widely used in the field of electronics, electrotechnology, and computer technology. During the process, at first, the Bi-Se compound has been formed on the nickel electrode by electrochemical method, and then by thermal treatment of this compound at 673K, ternary compound Ni3Bi2Se2 has been obtained. The results show that as the concentration of bismuth is increasing, its amount in deposited films increases regularly. The formation of the Ni3Bi2Se2 compound was also confirmed by XRD results. The photochemical properties of the obtained compounds were investigated in the dark and light, constant current of 100 nA for 0-600 seconds. With the illumination of the dark samples, the potential shifts from a positive side to a negative side, this decrease indicates that obtained thin films are not only photosensitive, also have n-type conductivity. 

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References

[1] Liu L.N., Li P., Shi J., Li G., Xi N., Wang Y., Liu L., Performance Investigation of Multilayer MoS2 Thin-Film Transistors Fabricated Via Mask-Free Optically Induced Electrodeposition, ACS Appl. Mater. Interfaces, 9: 8361−8370 (2017).
[2] Huseynov G.M., Mammadova N.A., Imanov H.A., Obtaining of Nanosized Compound Sb2S3 on the Basis of Tioasetamid and Antimony (III) Chloride, Chemical Problems, 3: 329-334 (2017).
[3] Wang K., Cheng J., Yang X., Hu R., Fu L., Huang J., Yu J., Li L., Enhanced Photovoltaic Properties in Sb2S3 Planar Heterojunction Solar Cell with a Fast Selenylation Approach. Nanoscale Res. Lett., 13: 270 (2018).
[4] Tao J., Hu X., Xue J., Wang Y., Weng G., Chen S., Zhu Z., Chu J., Investigation of Electronic Transport Mechanisms In Sb2Se3 Thin-Film Solar Cells, Sol. Energy Mater. Sol. C., 197: 1–6 (2019).
[5] Hossain Md.A.,  Merzougui B.A.,  Alharbi F.H.,  Tabet N., Electrochemical Deposition of Bulk MoS2 Thin Films for Photovoltaic Applications, Sol. Energy Mater. Sol. C., 186: 165-174 (2018).
[6] Dunyushkina L.A., “Introduction to Methods for Producing Film Electrolytes for Solid Oxide Fuel Cells: Monograph”, Yekaterinburg: Ural Branch of the Russian Academy of Sciences (2015).
[7] Ohring M., “Materials Science of Thin Films: Deposition and Structure”, 2nd ed., Elsevier, (2002).
[8] Mansurov G.N., Petriy O.A., “Electrochemistry of Thin Metal Films. Monograph”. -M.: MGOU (2011).
[9] Streltsov E.A., Electrochemical Deposition of Thin Films and Nanostructures of Semiconductor Metal Chalcogenides, Bull. BSU., 3: 15-19 (2011).
[10] Bakanov V.I., Larina N.V., Electrochemical Deposition of Bi-Se Nanocrystalline Films, Bull. Tyumen State University, 5: 6-11 (2012).
[11] Rommel S.M., Krach A., Peter P., Weihrich R., Conversion Reactions of Solids: from a Surprising Three-Step Mechanism towards Directed Product Formation, Chem. Eur. J., 22: 6333-6339 (2016).
[12] Rommel S., “Synthesis and Characterization of Nano- and Microcrystalline Ternary MAX-Materials (M = Ni, Co; A = Li, In, Sn, Pb, Tl; X = S, Se, PO4)”, Dissertation zur Erlangung des Doktorgrades der Naturwissenschaften (Dr. Rer. Nat.). Augsburg. 194 p. (2016)
[13] Aliyev А.Sh., Eminov Sh.О., Sultanova Т.Sh., Mejidzadeh V.А., Kuliyev D.А., Jalilova H.D., Tagiyev D.B., Electrochemical Production of Thin Films of Cadmium Sulphide on Nickel Electrodes and Research İnto Their Morphology, Chemical Problems, 14(2): 139-145 (2016).
[14] Aliyev A.Sh., Majidzade V.A., Soltanova N.Sh., Tagiyev D.B., Fateev V.N., Some Features of Electrochemically Deposited CdS Nanowires, Chemical Problems, 16(2): 178-185 (2018).
[15] Majidzade V.A., The Effect of Various Factors on the Composition of Electrolytic Thin Films Sb-Se, Chemical Problems, 16(3): 331-336 (2018).
[16] Majidzade V.A., Aliyev A.Sh., Guliyev P.H., Babanly D.M., Electrodeposition of the Sb2Se3 Thin Films on Various Substrates from the Tartaric Electrolyte, J. Electrochem. Sci. Eng., 10(1): 1-9 (2020).
[17] Majidzade V.A., Aliyev A.Sh., Qasimogli I., Quliyev P.H., Tagiyev D.B., Electrical Properties of Electrochemically Grown Thin Sb2Se3 Semiconductor Films, Inorg. Mater., 55(10): 979–983 (2019).
[18] Majidzade V.A., Cafarova S.F., Aliyev A.Sh., Tagiyev D.B., Influence of Various Factors on the Composition of Electrodeposited Thin Films Mo-S. Azerbaijan Chemical Journal, 3: 6-10 (2018).
[19] Majidzade V.A., Cafarova S.F., Aliyev A.Sh., Nuriyev Y.A., Farhatova N.B., Tagiyev D.B., Electrochemical Deposition of Thin Semiconductive Mo-S Films, Azerbaijan Chemical Journal, 1: 6-13 (2019).
[20] Allazov M.R., Kul Ali Riza, Einullaev A.V., Babanly M.B., T-x-y Diagram of the Ni–Bi–Se System, Russ. J. Inorg. Chem., 51(4): 624–629 (2006).
[21] Takeshi S., Makoto W., Hinatsu Y., Superconductivity in Ternary Chalcogenides Bi2Ni3X2 (X = S, Se), J. Phys.: Condensed Matter, 18(17): 4417-4426 (2006).
[22] Baranov A.I., Olenev A.Y., Popovkin B.A., Crystal and Electronic Structure of Ni3Bi2S2 (parkerite), Russ. Chem. Bull., International Edition, 50(3): 353-358 (2001).
Iranian Journal of Chemistry and Chemical Engineering
Volume 40, Issue 4 - Serial Number 108
September and October 2021
Pages 1023-1029

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