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Li, Y., Ni, S., Wang, Z., Lu, J., Zhang, L. (2018). DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(3), 43-49.
Ya-feng Li; Siyu Ni; Zhen Wang; JingJing Lu; Limei Zhang. "DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37, 3, 2018, 43-49.
Li, Y., Ni, S., Wang, Z., Lu, J., Zhang, L. (2018). 'DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(3), pp. 43-49.
Li, Y., Ni, S., Wang, Z., Lu, J., Zhang, L. DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 2018; 37(3): 43-49.

DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors

Article 5, Volume 37, Issue 3 - Serial Number 89, May and June 2018, Page 43-49  XML PDF (581.75 K)
Document Type: Research Article
Authors
Ya-feng Li email 1; Siyu Ni1; Zhen Wang1; JingJing Lu1; Limei Zhang2
1School of Chemical Engineering, Changchun University of Technology, 130012, Changchun, P. R. CHINA
2Computer Science and Engineering College, Changchun University of Technology, 130012, Changchun, P. R. CHINA
Abstract
In this work, the effects of preparation methods such as CE oven, microwave irradiation, and ultrasound on the morphology, particle size and crystallinity of MIL-53(Fe) are firstly investigated. Furthermore, the methods are utilized to prepare Pt NPs@MIL-53(Fe). As a result, well-defined Pt NPs@MIL-53(Fe) prepared by microwave irradiation exhibits uniformed morphology, high crystallinity, and high-disperse Pt NPs, which has been confirmed by FT-IR, TG, N2 adsorption at 77K, TEM and PXRD. Pt NPs@MIL-53(Fe) composite can selectively catalyze the thiophene hydrogenation over nitrobenzene and benzothiophene hydrogenation. The result shows that the sulfur amount can rapidly be reduced to less than 10 ppm and the crystallinity of reacted Pt NPs@MIL-53(Fe) is unchangeable.
Keywords
Directing self-assembly; Mono-disperse nano-particle; MIL-53(Fe); Catalytic behavior
Main Subjects
Catalysts, Kinetics, Reactor; Inorganic Chemistry
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