Application of Copper Vanadate Nanoparticles for Removal of Methylene Blue from Aqueous Solution: Kinetics, Equilibrium, and Thermodynamic Studies

Document Type: Research Article


1 Department of Chemistry, Savadkooh Branch, Islamic Azad University, Savadkooh, I.R. IRAN

2 Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, I.R. IRAN

3 Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, I.R. IRAN

4 Department of Life Science Engineering, Faculty of New Sciences and Technologies, University of Tehran, Tehran, I.R. IRAN


Copper vanadate nanoparticles were synthesized by a simple coprecipitation method in an aqueous medium and the products were used as adsorbents for eliminating methylene blue (MB) from water. The structure and morphology of the produced nanoparticles were evaluated through X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis. The results indicated that the particles were 22-40 nm in diameter. Further, batch adsorption experiments were performed to evaluate the potential capability of the product for the removal of MB and optimizing the adsorption conditions. The effects of pH, the quantity of the adsorbent, contact time, dye concentration, and temperature on adsorption were determined. Fitting of the experimental data into the Langmuir and Freundlich adsorption models revealed good compliance with the Langmuir model with a maximum adsorption capacity of 151.5 mg/g at pH= 4.0. Evaluation of the kinetic and thermodynamic parameters showed that the adsorption process follows a pseudo-second-order kinetic model and reaches equilibrium after 10 min. The desorption of the dye and recycling potential of the adsorbent was also studied.


Main Subjects

[4] Qu S., Huang F., Yu S., Chen G., Kong J., Magnetic Removal of Dyes from Aqueous Solution Using Multi-Walled Carbon Nanotubes Filled with Fe2O3 Particles, J. Hazard. Mater., 160(2-3): 643-647 (2008).

[5] Chen S., Zhang J., Zhang C., Yue Q., Li Y., Li C., Equilibrium and Kinetic Studies of Methyl Orange and Methyl violet Adsorption on Activated Carbon Derived from Phragmites Australis, Desalination 252(1-3): 149-156 (2010).

[6] Pugazhenthiran N., Ramkumar S., Kumar P.S., Anandan S., In-situ Preparation of Heteropolytungstic Acid on TiMCM-41 Nanoporous Framework for Photocatalytic Degradation of Textile Dye Methyl Orange, Microp. Mesop. Mater., 131(1-3): 170-176 (2010).

[7] Oei B.C., Ibrahim S., Wang S., Ang, H.M., Surfactant Modified Barley Straw for Removal of Acid and Reactive Dyes from Aqueous Solution, Bioresource Technol., 100(18): 4292-4295 (2009).

[8] Jalil A.A., Triwahyono S., Adama S.H., Rahima N.D., Aziz M.A.A., Hairomc N.H.H., Razali N.A.M., Abidin M.A.Z., Khairul M., Mohamadiah A., Adsorption of Methyl Orange from Aqueous Solution Onto Calcined Lapindo Volcanic Mud, J. Hazard. Mater., 181: 755-762 (2010).

[9] Cheung W.H., Szeto Y.S., McKay G., Enhancing the Adsorption Capacities of Acid Dyes by Chitosan Nano Particles, Bioresource Technol., 100(3): 1143-1148 (2009).

[10] Hajiaghababaei L., Abozari S., Badiei A., Zarabadi Poor P., Dehghan Abkenar S., Ganjali M.R., Mohammadi Ziarani G., Amino Ethyl-Functionalized SBA-15: A Promising Adsorbent for Anionic and Cationic Dyes Removal, Iran. J. Chem. Chem. Eng. (IJCCE), 36(1): 97-108 (2017).

[12] Dehghan Abkenar S., Khobi M., Tarasi R., Hosseini M., Shafiee A., Gangali M.R., Fast Removal of Methylene Blue from Aqueous Solution using Magnetic-modified Fe3O4 Nanoparticles, J. Environ. Chem. Eng., 141(1): 04014049 (2015).

[14] Li L., Liu S., Zhu T., Application of Activated Carbon Derived from Scrap Tires for Adsorption of Rhodamine B, J. Environ. Sci., 22(8): 1273-1280 (2010).

[17] Zhao K., Zhao G., Li P., Gao J., Lv B., Li D., A Novel Method for Photodegradation of High –Chroma Dye Wastewater via Electrochemical Pre- Oxidation, Chemosphere, 80(4): 410-415 (2010).

[18] Rajeev J., Megha M., Shalini S., Alok M., Removal of the Hazardous Dye Rhodamine B Through Photocatalytic and Adsorption Treatments, J. Environ. Management, 85(4): 956-964 (2007).

[19] Malik R., Ramteke D.R., Wate S.R., Adsorption of Malachite Green on Ground Nut Shell Waste Based Powdered Activated Carbon, Waste Management, 27(9): 1129-1138 (2007).

[20] Wu J.S., Liu C.H., Chu K.H., Suen S.Y., Removal of Cationic Dye Methyl Violet 2B from Water by Cation Exchange Membranes, J. Membrane Sci., 309(1-2): 239-245 (2008).

[21] Beakou B.H., El Hassani K., M.A. Houssaini, Belbahloul M., Oukani E., Anouar A., Novel Activated Carbon from Manihot Escuenta Crantz for Removal of Methylene Blue, Sustainable Environ. Res., 27(5): 215-222 (2017).

[22] Karaca S., Gurses A., Acıkyıldız M., Ejder M., Adsorption of Cationic Dye from Aqueous Solutions by Activated Carbon, Microp. Mesop. Mater., 115(3): 376-382 (2008).

[23] Weng, C. H., and Y. F. Pan., Adsorption of a cationic Dye (methylene blue) onto Spent Activated Clay, Journal of Hazardous Materials 144 (1-2): 355-362 (2007).

[24] Alpat K.S., Ozbayrak O., Alpat S., Akcay H., The Adsorption Kinetics and Removal of Cationic Dye, Toluidine Blue O, from Aqueous Solution with Turkish Zeolite, J. Hazard. Mater. 151(1): 213-220 (2008).

[25] Noroozi B., Sorial G.A., Bahrami H., Arami M., Equilibrium and Kinetic Adsorption Study of a Cationic Dye by a Natural Adsorbent—Silkworm Pupa, J. Hazard. Mater., 139(1): 167–174 (2007).

[26] Mittal A., Mittal J., Malviya A., Kaur D., Gupta V.K., Adsorption of Hazardous dye Crystal Violet from Wastewater by Waste Materials, J. Coll. Interf. Sci., 343(2): 463-473 (2010).

[27] Kamranifar M., Naghizadeh A., Montmorillonite Nanoparticles in Removal of Textile Dyes from Aqueous Solutions: Study of Kinetics and Thermodynamics, Iran. J. Chem. Chem. Eng. (IJCCE), 36(6): 127-137 (2017).

[28] Borghei Y.S., Hosseini M., Ganjali M.R., Fluorometric Determination of Micro RNA via FRET between Silver Nanoclusters and CdTe Quantum Dots, Microchim. Acta, 184(12): 4713–4721 (2017).

[29] Borghei Y.S., Hosseini M., Ganjali M.R., Detection of Large Deletion in Human BRCA1 Gene in Human Breast Carcinoma MCF-7 Cells by Using DNA− Silver Nanoclusters, Methods Applications in Fluorescence, 6(1): 015001 (2017).

[30] Sabet F.S., Hosseini M., Khabbaz H., Dadmehr M., Ganjali M.R., FRET-Based Aptamer Biosensor for Selective and Sensitive Detection of Aflatoxin B1 in Peanut and Rice, Food Chem., 220: 527-532 (2017).

[31] Ahmadi S. H., Davar P., Manbohi H., Adsorptive Removal Reactive Orange 122from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent, Iran. J. Chem. Chem. Eng.(IJCC), 35: 63-73 (2016).

[34] Han G.H., Yang S.Z., Huang Y.F., Yang J., Chai W.C., Zhang R., Chen D.L., Hydrothermal Synthesis and Electrochemical Sensing Properties of Copper Vanadate Nanocrystals with Controlled Morphologies, Transactions of Nonferrous Metal. Soc. China, 27: 1105−1116 (2017).

[36] Rahimi-Nasrabadi M., Pourmortazavi S.M., Ganjali M.R., Novrouzi P., Faridbod F., Sadeghpour Karimi M., Preparation of Dysprosium Carbonate and Dysprosium Oxide Efficient Photocatalyst Nanoparticles through Direct Carbonation and Precursor Thermal Decomposition, J. Mater. Sci., 28(4): 3325-3336 (2017).

[37] Rahimi-Nasrabadi M., Pourmortazavi S.M., Sadeghpour Karimi M., Aghazadeh M., Ganjali M.R., Norouzi P., “Erbium(Iii) Tungstate Nanoparticles; Optimized Synthesis and Photocatalytic Evaluation, J. Mater. Sci., 28(9): 6399-6406 (2017).

[38] Rahimi-Nasrabadi M., Pourmortazavi S.M., Aghazadeh M., Ganjali M.R., Sadeghpour Karimi M., Novrouzi P., Samarium Carbonate and Samarium Oxide; Synthesis, Characterization and Evaluation of the Photo-Catalytic Behavior, J. Mater. Sci., 28(7): 5574-5583 (2017).

[39] Rahimi-Nasrabadi M., Mizani F., Hosseini M., Homayoun Keihan A., Ganjali M.R., Detection of Hydrogen Peroxide and Glucose by Using Tb2(MoO4)3 Nanoplates as Peroxidase Mimics, Spectrochim. Acta Part A, 186: 82-88 (2017).

[40] Lagergren S., About the Theory of so-Called Adsorption of Soluble Substances, Kungliga Svenska Vetens Kapsakademiens Handlingar 24: 1-39 (1898).

[41] Ho Y.S., McKay G., Sorption of Dye from Aqueous Solution by Peat, Chem. Eng. J. 70(2): 115-124 (1998).

[42] Langmuir I., The Constitution and Fundamental Properties of Solids and Liquids, J. Am. Chem. Soc. 38(1): 2221-2295 (1916).

[43] Freundlich H.M.F., Over the Adsorption in Solution, J. Phys. Chem. 57: 385-471 (1906).

[44] Haghseresht F., Lu G., Adsorption Characteristics of Phenolic Compounds onto Coal-Reject-Derived Adsorbents, Energy & Fuels 12(6): 1100-1107 (1998).

[46] Yang J., Zhang M., Zhang Y., Ding L., Zheng J., Xu J., Facile Synthesis of Magnetic Magnesium Silicate Hollow Nanotubes with High Capacity for Removal of Methylene Blue, J. Alloy. Comp., 721: 722-778 (2017).

[47] Zhang Z., Kong J., Novel Magnetic Fe3O4@C Nanoparticles as Adsorbents for Removal of Organic Dyes from Aqueous Solution, J. Hazard. Mater., 193: 325–329 (2011).

[48] Asfaram A., Ghaedi M., Ahmadi Azqhandi M.H., Goudarzi A., Hajati S., Ultrasound-Assisted Binary Adsorption of Dyes onto Mn@ CuS/ZnS-NC-AC as a Novel Adsorbent: Application of Chemometrics for Optimization and Modeling, J. Indust. Eng. Chem., 54: 377-388 (2017).

[49] Wang P., Cao M., Wang C., Ao Y, Hou J, Qian J., Kinetics and Thermodynamics of Adsorption of Methylene Blue by a Magnetic Graphene-Carbon Nanotube Composite, Appl. Surface Sci., 290: 116–124 (2014).