Document Type: Research Article
Department of Chemistry, Faculty of Science, Golestan University, Gorgan, I.R. IRAN
Shahid Beheshti Shining Brilliant Talent High School, Education in Behshahr, Behshahr, I.R. IRAN
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, I.R. IRAN
Institute of Physic of the Czech Academy of Sciences, Na Slovance 2, 182 21 Prague, CZECH Republic
In this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized by elemental analysis (CHN) and single-crystal X-ray diffraction. Microparticles of 1 were prepared by an ultrasonic bath assisted synthesis and characterized
by Scanning Electron Microscopy (SEM) and elemental analysis. Thermal stability of 1 was studied by ThermoGravimetry (TG) and Differential Thermal Analysis (DTA). The structure of 1 consists of 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate groups in an end-to-end fashion, with Cu×××Cu separation 5.686(4) Å.