• Home
  • Browse
    • Current Issue
    • By Issue
    • By Author
    • By Subject
    • Author Index
    • Keyword Index
  • Journal Info
    • About Journal
    • Aims and Scope
    • Editorial Board
    • Editorial Staff
    • Publication Ethics
    • Indexing and Abstracting
    • Related Links
    • FAQ
    • Peer Review Process
    • News
  • Guide for Authors
  • Submit Manuscript
  • Reviewers
  • Contact Us
 
  • Login
  • Register
Home Articles List Article Information
  • Save Records
  • |
  • Printable Version
  • |
  • Recommend
  • |
  • How to cite Export to
    RIS EndNote BibTeX APA MLA Harvard Vancouver
  • |
  • Share Share
    CiteULike Mendeley Facebook Google LinkedIn Twitter Telegram
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Articles in Press
Current Issue
Journal Archive
Volume Volume 36 (2017)
Volume Volume 35 (2016)
Volume Volume 34 (2015)
Volume Volume 33 (2014)
Volume Volume 32 (2013)
Volume Volume 31 (2012)
Volume Volume 30 (2011)
Volume Volume 29 (2010)
Volume Volume 28 (2009)
Volume Volume 27 (2008)
Volume Volume 26 (2007)
Volume Volume 25 (2006)
Volume Volume 24 (2005)
Volume Volume 23 (2004)
Volume Volume 22 (2003)
Volume Volume 21 (2002)
Volume Volume 20 (2001)
Volume Volume 19 (2000)
Volume Volume 18 (1999)
Volume Volume 17 (1998)
Volume Volume 16 (1997)
Volume Volume 15 (1996)
Volume Volume 14 (1995)
Volume Volume 13 (1994)
Volume Volume 12 (1993)
Volume Volume 11 (1992)
Volume Volume 10 (1991)
Volume Volume 9 (1990)
Volume Volume 8 (1989)
Volume Volume 7 (1988)
Volume Volume 6 (1987)
Tavakolyan pour, F., Waqifhusain, S., Rastegar, H., Saber Tehrani, M., Abroomand Azar, P. (2017). Electrochemical oxidation of flavonoids and interaction with DNA on the surface of supramolecular ionic liquid grafted on graphene modified glassy carbon electrode. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), (), -.
Fahimeh Tavakolyan pour; Syed Waqifhusain; Hossein Rastegar; Mohammad Saber Tehrani; parviz Abroomand Azar. "Electrochemical oxidation of flavonoids and interaction with DNA on the surface of supramolecular ionic liquid grafted on graphene modified glassy carbon electrode". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), , , 2017, -.
Tavakolyan pour, F., Waqifhusain, S., Rastegar, H., Saber Tehrani, M., Abroomand Azar, P. (2017). 'Electrochemical oxidation of flavonoids and interaction with DNA on the surface of supramolecular ionic liquid grafted on graphene modified glassy carbon electrode', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), (), pp. -.
Tavakolyan pour, F., Waqifhusain, S., Rastegar, H., Saber Tehrani, M., Abroomand Azar, P. Electrochemical oxidation of flavonoids and interaction with DNA on the surface of supramolecular ionic liquid grafted on graphene modified glassy carbon electrode. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 2017; (): -.

Electrochemical oxidation of flavonoids and interaction with DNA on the surface of supramolecular ionic liquid grafted on graphene modified glassy carbon electrode

Articles in Press, Accepted Manuscript , Available Online from 20 December 2017  XML
Document Type: Research Article
Authors
Fahimeh Tavakolyan pour1; Syed Waqifhusain 1; Hossein Rastegar2; Mohammad Saber Tehrani1; parviz Abroomand Azar1
1Department of Chemistry, Islamic Azad university science and Research Branch, Tehran, Iran
2Food and Drug Control Reference Labratories, 408 valiasr street. Tehran, Iran
Abstract
ABSTARCT: The study of the interaction between DNA and small molecules such as drugs is one of the current general interest and importance. In this paper, the electrochemical investigation of the interaction between some flavonoids such as rutin, quercetin, and hesperidin with dsDNA on the surface of supramolecular ionic liquid grafted on the graphene oxide modified glassy carbon electrode (SIL-GO/GCE) is reported for the first time. The apparent binding constant (K) of the interaction between flavonoids and dsDNA was calculated using the current titrations. The apparent binding constants (K) of rutin, quercetin and hesperidin were calculated to be 4.3×105, 2.1×105 and 9.2×1-6 M-1, respectively. Furthermore, the electrochemical behavior of rutin on the surface of SIL-GO/GCE was studied in details using cyclic voltammetry and linear sweep voltammetry. The mechanism of electrochemical redox reaction of rutin was proposed. When DNA was added into flavonoid solutions, their cathodic peak currents were decreased with few changes in the peak potentials. Furthermore, the interaction between rutin and bovine serum albumin was studied using differential pulse voltammetry. In conclusion, the SIL-GO/GCE provides a promising platform for the study of interaction between DNA and small molecules.
Keywords
KEY WORDS: Graphene oxide; Supramolecular ionic liquids; Electrochemical techniques; flavonoids-DNA intractions
Main Subjects
ElectroChemistry
Statistics
Article View: 72
Home | Glossary | News | Aims and Scope | Sitemap
Top Top

web page hit counter

Journal Management System. Designed by sinaweb.