Mohammadian-Abriz, A., Majdan-Cegincara, R. (2018). Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(4), 235-252.

Ali Mohammadian-Abriz; Roghayeh Majdan-Cegincara. "Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37, 4, 2018, 235-252.

Mohammadian-Abriz, A., Majdan-Cegincara, R. (2018). 'Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(4), pp. 235-252.

Mohammadian-Abriz, A., Majdan-Cegincara, R. Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 2018; 37(4): 235-252.

Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model

^{1}Department of Chemical Engineering, East Azarbaijan Science and Research Branch, Islamic Azad University, Tabriz, I.R. IRAN

^{2}Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN

Abstract

A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation) and Eyring absolute rate theory were used to fit the viscosity values of ternary aqueous solutions of polymer + electrolyte with considering temperature dependency. The local composition models which are available for correlating the thermodynamic properties of ternary polymer + electrolyte solutions (ternary-Wilson, ternary-modified NRTL, and ternary-modified Wilson) with Eyring absolute rate theory were also used for fitting the viscosity values of ternary solutions for the first time. THe fitting quality of Eyring-TNRF-mNRTL model was compared with these models. The equations of apparent molar volume were also derived from TNRF-mNRTL, ternary-Wilson, ternary-modified NRTL, and ternary-modified Wilson models. These equations were used for correlating the apparent molar volume and density values of ternary polymer + electrolyte solutions.

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