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Feyzi, M., Lorestani Zinatizadeh, A., Nouri, P., Jafari, F. (2018). Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(2), 33-44.
Mostafa Feyzi; Ali Lorestani Zinatizadeh; Parasto Nouri; Fataneh Jafari. "Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37, 2, 2018, 33-44.
Feyzi, M., Lorestani Zinatizadeh, A., Nouri, P., Jafari, F. (2018). 'Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(2), pp. 33-44.
Feyzi, M., Lorestani Zinatizadeh, A., Nouri, P., Jafari, F. Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 2018; 37(2): 33-44.

Catalytic Performance and Characterization of Promoted K-La/ZSM-5 Nanocatalyst for Biodiesel Production

Article 3, Volume 37, Issue 2 - Serial Number 88, March and April 2018, Page 33-44  XML PDF (478.51 K)
Document Type: Research Article
Authors
Mostafa Feyzi email 1; Ali Lorestani Zinatizadeh2; Parasto Nouri2; Fataneh Jafari1
1Department of Physical Chemistry, Faculty of Chemistry, Razi University, P. O. Box 6714967346 Kermanshah, I.R. IRAN
2Department of Applied Chemistry, Faculty of Chemistry, Razi University, Kermanshah, I.R. IRAN
Abstract
The promoted K-La nanocatalysts supported on ZSM-5 zeolite were prepared via wetness impregnation method and tested for biodiesel production from soybean oil. The effects of different weight percentage of La, loading of K as a promoter and calcination conditions on structure and activity of catalyst were investigated. Results showed that the supported catalyst containing 7wt.% of La was promoted with 1wt.% of K is an optimal catalyst for biodiesel production. The best operational conditions were the CH3OH/oil=12/1 molar ratio at 60˚C with mechanical stirring 500 rpm for 3 h. The biodiesel yield reached 90% under the optimal operational conditions. It was found that K-La/ZSM-5 nanocatalyst have high basic sites and catalytic activity for biodiesel production. Characterization of catalysts was carried out by using Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Temperature Programmed Desorption (TPD), X-Ray Diffraction (XRD), Fourier Transform-InfraRed(FT-IR) spectroscopy and N2 adsorption-desorption measurements methods.
Keywords
: Biodiesel; Wetness impregnation; Calcination conditions; Operational condition; Characterization
Main Subjects
Catalysts, Kinetics, Reactor; Energy, Heat Transfer
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