Inhibition of Copper Corrosion by Ethanolamine in 100 ppm NaCl

Document Type : Research Article

Authors

1 Laboratoire d’Ingénierie Des Surfaces (L. I. S.)-Université Badji Mokhtar B.P. 12 - 23000 Annaba, ALGERIE

2 INSA-Lyon, MATEIS CNRS UMR5510,F-69621 Villeurbanne, FRANCE

Abstract

We study copper corrosion inhibition by ethanolamine (ETA)with (0, 0.2 ,0.3,0.4,0.5) vol.% concentrations in 100 ppm NaCl solution. This work is carried out by potentiodynamic measurements and Electrochemical Impedance Spectroscopy (EIS). The substrates' surface morphologies are examined by Scanning Electron Microscopy (SEM). ETAis characterized by NMR spectra of ETA1H and 13C and Fourier Transform InfraRed Spectroscopy (FT-IR).Quantum chemical calculation (DFT) is conducted to correlate the adsorption mechanism with  ETAmolecule structure. The results show thatETA acts as a mixed inhibitor; so at 0.4 vol. %, the current density ( i ) and the polarization resistance (Rp) are respectively 0.8µA/cm2 and 28.62 Ω.cm2 with  99.78%  corresponding  efficiency . ETA adsorption obeys to Langmuir isotherm and takes place on the copper surface through chemical and physical mixed-type adsorption. 

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References

[1] Qudah -M.A.Al, Inhibition of copper corrosion by flavonoids in nitric acid, E-Journal of Chemistry, 8(1): 326-332 (2011).
[2] Crousier J., Pardessus L., Crousier J.P., Voltammetry Study of Copper in Chloride Solution, Electrochim. Acta, 33 (8): 1039-1042 (1988).
[3] Kabasakaloglu.M, Kıyak.T, Şendil.O, Asan. A, Electrochemical Behavior of Brass in 0.1 M NaCl, Applied Surface Science,193(1-4):167-174 (2002).
[4] Wang. C, Chen.S, Zhao. S, Inhibition Effect of  AC-Treated, Mixed Self-Assembled Film of Phenylthiourea and 1-Dodecanethiol on Copper Corrosion, J. Electrochem. Soc, 151(1): B11-B15 (2004).
[5] Khaled .K.F, Studies of the Corrosion Inhibition of Copper in Sodium Chloride Solutions Using Chemical and Electrochemical Measurements, Mater. Chem. Phys., 125: 427-433(2011).
[6] Hammouti B., Dafali A., Touzani R., Bouachrine M., Inhibition of Copper Corrosion by Bipyrazole Compound in Aerated 3% NaCl, J. Saudi. Chem. Soc., 16: 413-418 (2012).
[7] Li W., Hu L., Zhang S., Hou B., Effects of Two Fungicides on the Corrosion Resistance of Copper in 3.5 NaCl Solution under Various Conditions, Corros.Sci., 53: 735-745 (2011).
[8] Sudheer, Quraishi M.A., Electrochemical and Theoretical Investigation of Triazole Derivates on Corrosion Inhibition Behaviour of Copper in Hydrochloric Acid Medium, Corros.Sci., 70: 161-169 (2013).
[9] Gardiner .D.J, Gorvin A.C., Gutteridge C., Jackson A.R.W., Raper E.S., In Situ Characterization of Corrosion Inhibition Complexes on Copper Surfaces Using Raman Microscopy, Corros. Sci.,25:1019-1027 (1985).
[10] Sherif E.M., Park S.M., Inhibition of Copper Corrosion in Acidic Pickling Solutions by N-phenyl-1,4-phenylenediamine, Electrochim. Acta, 51: 4665-4673 (2006).
[11] Khaled K.F., Experimental and Atomistic Simulation Studies of Corrosion Inhibition of Copper by A New Benzotriazole Derivative in Acid Medium, Electrochim .Acta ,54(18):4345-4352 (2009).
[12]Yan C.W.,  Lin H.C., Cao C.N., Investigation of Inhibition of 2-mercaptobenzoxazole for Copper Corrosion, Electrochim.Acta,45:2815-2821 (2000).
[13] Solmaz R., Ece Altunbas S., Ali D., Gùlfeza K., The Investigation of Synergistic Inhibition Effect of Rhodanine and Iodide Ion on the Corrosion of Copper in Sulphuric Acid Solution, Corros. Sci., 53: 3231- 3240 (2011).
[14]  Zhang D.Q., An Z.X., Pan Q.Y., Gao L.X., Zhou G.D., Comparative Study of Bis- Piperidiniummethyl Urea and Mono-Piperi diniummethyl-Urea as Volatile Corrosion Inhibitors for Mild Steel, Corro.Sci., 48(6):1437-1448(2006).
[15]Ali E., Mohammad G., Reza M., Hossein M., Javad S., Electrochemical and DFT Study on the Inhibition of 316L Stainless Steel Corrosion in Acidic Medium by 1-(4-nitrophenyl)-5-amino-1H-tetrazole, RSC.Adv,4, p.2031-2037 (2014).
[16] Kertit .S , Hammouti. B, Corrosion Inhibition of Iron in 1M HCl by 1-phenyl-5-mercapto- 1,2,3,4- tetrazole, Appl.Surf.Sci., 93, 59-66 (1996).
[17] Larabi L., Benali O., Mekelleche S.M., Harek Y.,2-mercapto-1-methylimidazole as Corrosion Inhibitors for Copper in Hydrochloric Acid, Applied Surface Science, 253(3) , p.1371-1378 (2006).
[18] Barouni K., Bazzi L., Salghi R. Mihit .M., Hammouti B, Albourine A., El Issami S., Some Amino Acids as Corrosion Inhibitors for Copper  in Nitric Acid Solution, Materials  Letters, 62, 3325-3327 (2008).
[19] Avci G., Inhibitor Effect of N,N-Methylenediacrylamide on Corrosion Behavior of Mild Steel in 0.5 M HCl, Mater.Chem.Phys., 112, 234- 238 (2008).
[20] Ali E., Reza M., Ahmad K., A.Y-F, Inhibitory of Newly Synthesized 3-BrPhOXTs on Corrosion of Stainless Steel in Acidic Medium, S. Afr. J. Chem., 67: 198-202 (2014).
[21] Ma H., Chen S., Niu L., Zhao S., Li S., Li D., Inhibition of Copper Corrosion by Several Schiff  Bases in Aerated Halide Solutions, Journal of Applied Electrochemistry, 32: 65-72 (2002).
[22] Ahamad I., Prasad  Quraishi  R.M.A., Inhibition of Mild Steel Corrosion in Acid Solution by  Pheniramine Drug: Experimental and Theoretical Study, Corros. Sci., 52: 3033-3041(2010).
[23] Ali E., Reza M., Maliheh A., Electrochemical Investigation of Inhibitory of New Synthesized 3-(4- Iodophenyl)- 2 Imino-2,3-Dihydrobenzo[d] Oxazol5-yl4-Methyl-benzensulfonate on corrosion of Stainless Steel in Acidic Medium, ., 6 (1): 7-15 (2015).

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