Khandar, A., Rezvani, Z. (1999). Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 18(1), 19-23.
Ali Akbar Khandar; Z. Rezvani. "Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues". Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 18, 1, 1999, 19-23.
Khandar, A., Rezvani, Z. (1999). 'Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues', Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 18(1), pp. 19-23.
Khandar, A., Rezvani, Z. Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 1999; 18(1): 19-23.
Synthesis and Cyclic Voltammetric Studies of Bis[5-((4-Alkoxyphenyl)Azo)-N-(nPentyl, nDodecyl)-Salicylaldiminato] Copper(II) Complex Homologues
Department of Inorganic Chemistry, Faculty of Chemistry, Tabriz University, Tabriz, I.R. IRAN
Abstract
5-((4-alkoxyphenyl)azo)salicyladehyde, 5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladimine and bis [5-((4-alkoxyphenyl)azo)-N-(npentyl, ndodecyl)-salicyladiminato]copper(II) [alkoxy=OnCnH2n+1; n=3-7] homologues were synthesized and characterized by elemental analyses, mass and IR spectra. All complex homologues are thermally stable. Cyclic voltammetric studies indicated that all copper complex homologues have a quasi-reversible redox wave and peak current ratio (ipa/ipc)decreasing with increase of alkyl chain length.
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