Department of Chemistry, Shiraz University, Shiraz, I.R. IRAN
10.30492/ijcce.1992.10402
Abstract
A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 mgml-1 at 445 nm with the molar absorptivity of 5.3´103 lmol-1cm-1. The Sandell's sensitivity is 0.80 mg cm-2 for 0.001 absorbance unit. The method has a wide range and is simple, rapid and free from interferences from many cations and anions. The procedure was applied to the determination of palladium in the activated carbon.
Dadfarnia, S. S. M. (1992). Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide. Iranian Journal of Chemistry and Chemical Engineering, 11(1), 14-19. doi: 10.30492/ijcce.1992.10402
MLA
Sh. Shamsipour, M. Dadfarnia. "Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide". Iranian Journal of Chemistry and Chemical Engineering, 11, 1, 1992, 14-19. doi: 10.30492/ijcce.1992.10402
HARVARD
Dadfarnia, S. S. M. (1992). 'Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide', Iranian Journal of Chemistry and Chemical Engineering, 11(1), pp. 14-19. doi: 10.30492/ijcce.1992.10402
VANCOUVER
Dadfarnia, S. S. M. Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide. Iranian Journal of Chemistry and Chemical Engineering, 1992; 11(1): 14-19. doi: 10.30492/ijcce.1992.10402
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