TY - JOUR ID - 12273 TI - Kinetic Study of the Linkage Isomers in [Co(NH3)5ONO]X2 (X=Cl¯, Br¯, I¯) in the Solid State in KBr Discs JO - Iranian Journal of Chemistry and Chemical Engineering JA - IJCCE LA - en SN - 1021-9986 AU - Heravi, Gholam Hossein AU - Abedini, Mansour AD - Chemistry Department, Tehran University, Tehran, I.R. IRAN Y1 - 1988 PY - 1988 VL - 7 IS - 1 SP - 28 EP - 32 KW - Kinetics KW - Linkage isomers KW - Isomerization DO - 10.30492/ijcce.1988.12273 N2 - The nitrite ® nitro isomerization in nitritopentaamine cobalt (III) halides has been known. In this paper, the effect of the size of the counter ions (noncoordinated groups) on the rate of isomerization in nitritopentaamine cobalt (III) halides, is reported. The rate of isomerization is decreased by increasing the size of the counter ions. This decrease is explained on the basis of steric interaction between the nitro groups in the inner sphere and the counter ions in the outer sphere of these complexes. UR - https://ijcce.ac.ir/article_12273.html L1 - https://ijcce.ac.ir/article_12273_0cad1764a30ff7360d69f25e1de88aed.pdf ER -