TY - JOUR ID - 10918 TI - Preparation and Characterization of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 Complexes JO - Iranian Journal of Chemistry and Chemical Engineering JA - IJCCE LA - en SN - 1021-9986 AU - Aghabozorg, Hossein AU - Alizadeh, Robabeh AD - Department of Chemistry, Faculty of Science, Teacher Training University, P.O. Box 15614 Tehran, I.R. IRAN Y1 - 1994 PY - 1994 VL - 13 IS - 2 SP - 68 EP - 71 KW - Ti(BH4)3(THF)3 KW - V(BH4)2(TMEDA)2 KW - Preparation KW - vibrational spectra DO - 10.30492/ijcce.1994.10918 N2 - We have recently synthesized Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 complexes. The reaction of TiCl3(THF)3 with NaBH4 in dry THF gave flat blue crystals, Ti(BH4)3(THF)3. The reaction of VCl3 with NaBH4 in presence of N, N, N', N'- tetramethylethylenediamine, TMEDA, produced violet crystals, V(BH4)2(TMEDA)2. Vibrational and magnetic properties of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 have been studied. UR - https://ijcce.ac.ir/article_10918.html L1 - https://ijcce.ac.ir/article_10918_b7c15a213be657b63327307b64d00c28.pdf ER -