ORIGINAL_ARTICLE
Facile Synthesis and Electrochemical Performance of Graphene-Modified Cu2O Nanocomposite for Use in Enzyme-Free Glucose Biosensor
Graphene-modified Cu2O nanocomposite was synthesized under facile microwave irradiation of an aqueous solution and has been investigated as an enzyme-free glucose biosensor. Morphology and crystal structure of the graphene-modified Cu2O nanocomposite were investigated by using electron microscopy and X-Ray Diffraction (XRD) analyses. Also, the electrochemical performance of the graphene-modified Cu2O nanocomposite for the measurement of glucose concentration in alkaline media was evaluated by using cyclic voltammetry and chronoamperometric measurements. The electrochemical studies revealed that the graphene-modified nanocomposite electrode exhibited a high performance for non-enzymatic oxidation of glucose with a desirable sensitivity. Also, the fabricated graphene-modified biosensor exhibited a wide linear response for glucose detection in the concentrations ranges from 2 µM to 12 mM and a desirable detection limit of 2 µM. Also, the graphene-modified Cu2O nanocomposite provided an appropriate selective response for glucose detection in the presence of high concentrations of ascorbic acid and dopamine.
https://ijcce.ac.ir/article_33683_d35d87531c455c1ef8e7b052cf58b650.pdf
2020-04-01
1
10
10.30492/ijcce.2020.33683
Electrochemical biosensor
non-enzymatic sensors
Graphene
Cu2O
Glucose
Faranak
Foroughi
f.forooghi.material@gmail.com
1
Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz 7134851154, I.R. IRAN
AUTHOR
Mansour
Rahsepar
mansour.rahsepar@gmail.com
2
Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz 7134851154, I.R. IRAN
LEAD_AUTHOR
Mohammad Jafar
Hadianfard
hadianfa@shirazu.ac.ir
3
Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz 7134851154, I.R. IRAN
AUTHOR
Hasuck
Kim
hasuckim@snu.ac.kr
4
Department of Chemistry, Seoul National University, Seoul, KOREA
AUTHOR
[1] Wang J., Electrochemical Glucose Biosensors, Chem. Rev., 108(2): 814-825 (2008).
1
[2] Hsu Y.-W., T.-K. Hsu C.-L. Sun Y.-T. Nien N.-W. Pu, M.-D. Ger, Synthesis of CuO/Graphene Nanocomposites for Nonenzymatic Electrochemical Glucose Biosensor Applications, Electrochim Acta., 82: 152-157 (2012).
2
[3] Heller A., Feldman B., Electrochemical Glucose Sensors and Their Applications in Diabetes Management, Chem. rev., 108(7): 2482-2505 (2008).
3
[4] Solnica B., Kusnierz-Cabala B., Slowinska-Solnica K., Witek P., Cempa A., Malecki M.T., Evaluation of the Analytical Performance of the Coulometry-Based Optium Omega Blood Glucose Meter, Journal of Diabetes Science and Technology, 5(6): 1612-1617 (2011).
4
[5] Tanaka T., Shutto E., Mizoguchi T., Fukushima K., Coulometric Titration of D (+)-Glucose Using Its Enzymatic Oxidation, Anal. Sci., 17(2): 277-280 (2001).
5
[6] Steiner M.-S., Duerkop A., Wolfbeis O.S., Optical Methods for Sensing Glucose, Chem. Soc. Rev., 40(9): 4805-4839 (2011).
6
[7] Gill R., Bahshi L., Freeman R., Willner I., Optical Detection of Glucose and Acetylcholine Esterase Inhibitors by H2O2‐Sensitive CdSe/ZnS Quantum Dots, Angew. Chem., 120(9): 1700-1703 (2008).
7
[8] Thévenot D.R., Toth K., Durst R.A., Wilson G.S., Electrochemical Biosensors: Recommended Definitions and Classification, Anal. Lett., 34(5): 635-659 (2001).
8
[9] Chen C., Xie Q., Yang D., Xiao H., Fu Y., Tan Y., Yao S., Recent Advances in Electrochemical Glucose Biosensors: A Review, Rsc Adv., 3(14): 4473-4491 (2013).
9
[10] Deng C., Chen J., Chen X., Xiao C., Nie L., Yao S., Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Boron-Doped Carbon Nanotubes Modified Electrode, Biosens. Bioelectron., 23(8): 1272-1277 (2008).
10
[11] Ansari A.A., Alhoshan M., Alsalhi M., Aldwayyan A., Nanostructured Metal Oxides Based Enzymatic Electrochemical Biosensors," Biosensors". (2010), InTech.
11
[12] Toghill K.E., Compton R.G., Electrochemical Non-Enzymatic Glucose Sensors: A Perspective and an Evaluation, Int. J. Electrochem., Sci., 5(9): 1246-1301 (2010).
12
[13] Yang M., Yang Y., Liu Y., Shen G., Yu R., Platinum Nanoparticles-Doped Sol–Gel/Carbon Nanotubes Composite Electrochemical Sensors and Biosensors, Biosens. Bioelectron., 21(7): 1125-1131 (2006).
13
[14] Sun Y., Buck H., Mallouk T.E., Combinatorial Discovery of Alloy Electrocatalysts for Amperometric Glucose Sensors, Anal. Chem., 73(7): 1599-1604 (2001).
14
[15] Jena B.K., Raj C.R., Enzyme‐Free Amperometric Sensing of Glucose by Using Gold Nanoparticles, Chemistry–A Eur. J., 12(10): 2702-2708 (2006).
15
[16] Chen J., Zhang W.-D., Ye J.-S., Nonenzymatic Electrochemical Glucose Sensor Based on MnO 2/MWNTs Nanocomposite, Electrochem. Commun., 10(9): 1268-1271 (2008).
16
[17] Novoselov K.S., Geim A.K., Morozov S.V., Jiang D., Zhang Y., Dubonos S.V., Grigorieva I.V., Firsov A.A., Electric Field Effect in Atomically Thin Carbon Films, Science, 306(5696): 666-669 (2004).
17
[18] Mohd Yazid S.N.A., Md Isa I., Abu Bakar S., Hashim N., Ab Ghani S., A Review of Glucose Biosensors Based on Graphene/Metal Oxide Nanomaterials, Anal. Lett., 47(11): 1821-1834 (2014).
18
[19] Chung R.-J., Wang A.-N., Liao Q.-L., Chuang K.-Y., Non-Enzymatic Glucose Sensor Composed of Carbon-Coated Nano-Zinc Oxide, Nanomaterials., 7(2): 36 (2017).
19
[20] Arya S.K., Saha S., Ramirez-Vick J.E., Gupta V., Bhansali S., Singh S.P., Recent Advances in ZnO Nanostructures and Thin Films for Biosensor Applications, Anal. Chim. Acta., 737: 1-21 (2012).
20
[21] Lu N., Shao C., Li X., Miao F., Wang K., Liu Y., CuO Nanoparticles/Nitrogen-Doped Carbon Nanofibers Modified Glassy Carbon Electrodes for Non-Enzymatic Glucose Sensors with Improved Sensitivity, Ceramics International, 42(9): 11285-11293 (2016).
21
[22] Foroughi F., Rahsepar M., Hadianfard M.J., Kim H., Microwave-Assisted Synthesis of Graphene Modified CuO Nanoparticles for Voltammetric Enzyme-Free Sensing of Glucose at Biological pH Values, Microchim. Acta., 185(1): 57 (2018).
22
[23] Luo Z.J., Han T.T., Qu L.L., Wu X.Y., A Ultrasensitive Nonenzymatic Glucose Sensor Based on Cu2O Polyhedrons Modified Cu Electrode, Chinese Chemical Letters, 23(8): 953-956 (2012).
23
[24] Dai Y., Molazemhosseini A., Abbasi K., Liu C.C., A Cuprous Oxide Thin Film Non-Enzymatic Glucose Sensor Using Differential Pulse Voltammetry and Other Voltammetry Methods and a Comparison to Different Thin Film Electrodes on the Detection of Glucose in an Alkaline Solution, Biosensors, 8(1): 4- (2018).
24
[25] He G., Tian L., Cai Y., Wu S., Su Y., Yan H., Pu W., Zhang J., Li L., Sensitive Nonenzymatic Electrochemical Glucose Detection Based on Hollow Porous NiO, Nanoscale. Res. Lett., 13(1): 3- (2018).
25
[26] Pal N., Saha B., Kundu S.K., Bhaumik A., Banerjee S., A Highly Efficient Non-Enzymatic Glucose Biosensor Based on a Nanostructured NiTiO3/NiO Material, New J. of Chem., 39(10): 8035-8043 (2015).
26
[27] Nontawong N., Amatatongchai M., Jarujamrus P., Tamuang S., Chairam S., Non-Enzymatic Glucose Sensors for Sensitive Amperometric Detection Based on Simple Method of Nickel Nanoparticles Decorated on Magnetite Carbon Nanotubes Modified Glassy Carbon Electrode, Int. J. Electrochem. Sci., 12: 1362-1376 (2017).
27
[28] Zhang H., Zhu Q., Zhang Y., Wang Y., Zhao L., Yu B., One‐Pot Synthesis and Hierarchical Assembly of Hollow Cu2O Microspheres with Nanocrystals‐Composed Porous Multishell and Their Gas‐Sensing Properties, Ad. Func. Mater., 17(15): 2766-2771 (2007).
28
[29] Gou L., Murphy C.J., Solution-Phase Synthesis of Cu2O Nanocubes, Nano. Lett., 3(2): 231-234 (2003).
29
[30] Orel Z.C., Anzlovar A., Drazic G., Zigon M., Cuprous Oxide Nanowires Prepared by an Additive-Free Polyol Process, Cryst. Growth. Des., 7(2): 453-458 (2007).
30
[31] Zhang X., Wang G., Wang Q., Zhao L., Wang M., Fang B., Cupreous Oxide Nanobelts as Detector for Determination of l-Tyrosine, Mater. Sci. Eng. B., 156(1): 6-9 (2009).
31
[32] Zhang X., Wang G., Gu A., Wu H., Fang B., Preparation of Porous Cu2O Octahedron and Its Application as L-Tyrosine Sensors, Solid. State. Commun., 148(11): 525-528 (2008).
32
[33] Zhang X., Wang G., Zhang W., Wei Y., Fang B., Fixure-Reduce Method for the Synthesis of Cu2O/MWCNTs Nanocomposites and Its Application as Enzyme-Free Glucose Sensor, Biosens. Bioelectron., 24(11): 3395-3398 (2009).
33
[34] Novel N., Gas Sensor Based on Cuprous Oxide Thin Films Shishiyanu, Sergiu T.; Shishiyanu, Teodor S.; Lupan, Oleg I, Sensor. Actuat. B-Chem. 113: 468-476 (2006).
34
[35] Rahsepar M., Pakshir M., Kim H., Synthesis of Multiwall Carbon Nanotubes with a High Loading of Pt by a Microwave-Assisted Impregnation Method for Use in the Oxygen Reduction Reaction, Electrochim. Acta., 108: 769-775 (2013).
35
[36] Shao Y., Wang J., Wu H., Liu J., Aksay I.A., Lin Y., Graphene Based Electrochemical Sensors and Biosensors: A Review, Electroanal., 22(10): 1027-1036 (2010).
36
[37] Rahsepar M., Pakshir M., Piao Y., Kim H., Synthesis and Electrocatalytic Performance of High Loading Active PtRu Multiwalled Carbon Nanotube Catalyst for Methanol Oxidation, Electrochim. Acta., 71: 246-251 (2012).
37
[38] Rahsepar M., Pakshir M., Nikolaev P., Safavi A., Palanisamy K., Kim H., Tungsten Carbide on Directly Grown Multiwalled Carbon Nanotube as a co-Catalyst for Methanol Oxidation, Appl. Catal. B- Environ., 127: 265-272 (2012).
38
[39] Rahsepar M., Pakshir M., Nikolaev P., Piao Y., Kim H., A Combined Physicochemical and Electrocatalytic Study of Microwave Synthesized Tungsten Mono-Carbide Nanoparticles on Multiwalled Carbon Nanotubes as a co-Catalyst
39
for a Proton-Exchange Membrane Fuel Cell, Int. J. Hydrogen. Energ,. 39(28): 15706-15717 (2014).
40
[40] Rahsepar M., Pakshir M., Piao Y., Kim H., Preparation of Highly Active 40 wt.% Pt on Multiwalled Carbon Nanotube by Improved Impregnation Method for Fuel Cell Applications, Fuel. Cells., 12(5): 827-834 (2012).
41
[41] Sayah A., Capacitance Properties of Electrochemically Synthesised Polybithiophene-Exfoliated Graphene Composite Films, Iran. J. Chem. Chem. Eng., (IJCCE), 38 (3): 203-210 (2019).
42
[42] Tavakolyan pour F., Waqifhusain S., Rastegar H., Saber Tehrani M., Abroomand Azar P., Electrochemical Oxidation of Flavonoids and Interaction with DNA on the Surface of Supramolecular Ionic Liquid Grafted on Graphene Modified Glassy Carbon Electrode, Iran. J. Chem. Chem. Eng. (IJCCE), 37(3): 117-125 (2018).
43
[43] Geim A.K., Novoselov K.S., The Rise of Graphene, Nat. mater., 6(3): 183-191 (2007).
44
[44] Rahsepar M., Nobakht M.R., Kim H., Pakshir M., Facile Enhancement of the Active Catalytic Sites of N-Doped Graphene as a High Performance Metal-Free Electrocatalyst for Oxygen Reduction Reaction, Appl. Surf. Sci., 447: 182-190 (2018).
45
[45] Schedin F., Geim A., Morozov S., Hill E., Blake P., Katsnelson M., Novoselov K., Detection of Individual Gas Molecules Adsorbed on Graphene, Nat. Mater., 6(9): 652-655 (2007).
46
[46] Huang B., Li Z., Liu Z., Zhou G., Hao S., Wu J., Gu B.-L., Duan W., Adsorption of Gas Molecules on Graphene Nanoribbons and Its Implication for Nanoscale Molecule Sensor, J. Phys. Chem. C., 112(35): 13442-13446 (2008).
47
[47] Foroughi F., Rahsepar M., Kim H., A Highly Sensitive and Selective Biosensor Based on Nitrogen-Doped Graphene for Non-Enzymatic Detection of Uric Acid and Dopamine at Biological pH Value, J. Electroanal, Chem., : - (2018).
48
[48] Zhang F., Li Y., Gu Y.-e., Wang Z., Wang C.,
49
One-Pot Solvothermal Synthesis of a Cu2O/Graphene Nanocomposite and Its Application in an Electrochemical Sensor for Dopamine, Microchim. Acta., 173(1-2): 103-109 (2011).
50
[49] Kim Y.-R., Bong S., Kang Y.-J., Yang Y., Mahajan R.K., Kim J.S., Kim H., Electrochemical Detection of Dopamine in the Presence of Ascorbic Acid Using Graphene Modified Electrodes, Biosens. Bioelectron., 25(10): 2366-2369 (2010).
51
[50] Rahsepar M., Kim H., Microwave-Assisted Synthesis and Characterization of Bimetallic PtRu Alloy Nanoparticles Supported on Carbon Nanotubes, J. Alloy. Compd., 649: 1323-1328 (2015).
52
[51] Rani A., Rajoria P., Agarwal S., Imidazolium Chloride Immobilized Fly Ash as a Heterogenized Organocatalyst for Esterification Reaction under Microwave Irradiation Heating, Iran. J. Chem. Chem. Eng. (IJCCE), 38 (3): 87-96 (2019)
53
[52] Arab-Salmanabadi S., Microwave-Assisted Synthesis of Novel Functionalized Ketenimines and Azadienes via a Solvent-Free Reaction of Isatoic Anhydride, Alkyl-Isocyanides and Dialkyl Acetylenedicarboxylates, Iran. J. Chem. Chem. Eng. (IJCCE), 38(6): 205-211 (2019).
54
[53] Poursattar Marjani A., Khalafy J., Chitan M., Mahmoodi S., Microwave-Assisted Synthesis of Acridine-1,8(2H,5H)-diones via a One-pot, Three Component Reaction, Iran. J. Chem. Chem. Eng. (IJCCE), 36(2): 1-6 (2017).
55
[54] Sistani S., Ehsani M.R., Kazemian H., Microwave Assisted Synthesis of Nano Zeolite Seed for Synthesis Membrane and Investigation of Its Permeation Properties for H2 Separation, Iran. J. Chem. Chem. Eng. (IJCCE), 29(4): 99-104 (2010).
56
[1] Wang J., Electrochemical Glucose Biosensors, Chem. Rev., 108(2): 814-825 (2008).
57
[2] Hsu Y.-W., T.-K. Hsu C.-L. Sun Y.-T. Nien N.-W. Pu, M.-D. Ger, Synthesis of CuO/Graphene Nanocomposites for Nonenzymatic Electrochemical Glucose Biosensor Applications, Electrochim Acta., 82: 152-157 (2012).
58
[3] Heller A., Feldman B., Electrochemical Glucose Sensors and Their Applications in Diabetes Management, Chem. rev., 108(7): 2482-2505 (2008).
59
[4] Solnica B., Kusnierz-Cabala B., Slowinska-Solnica K., Witek P., Cempa A., Malecki M.T., Evaluation of the Analytical Performance of the Coulometry-Based Optium Omega Blood Glucose Meter, Journal of Diabetes Science and Technology, 5(6): 1612-1617 (2011).
60
[5] Tanaka T., Shutto E., Mizoguchi T., Fukushima K., Coulometric Titration of D (+)-Glucose Using Its Enzymatic Oxidation, Anal. Sci., 17(2): 277-280 (2001).
61
[6] Steiner M.-S., Duerkop A., Wolfbeis O.S., Optical Methods for Sensing Glucose, Chem. Soc. Rev., 40(9): 4805-4839 (2011).
62
[7] Gill R., Bahshi L., Freeman R., Willner I., Optical Detection of Glucose and Acetylcholine Esterase Inhibitors by H2O2‐Sensitive CdSe/ZnS Quantum Dots, Angew. Chem., 120(9): 1700-1703 (2008).
63
[8] Thévenot D.R., Toth K., Durst R.A., Wilson G.S., Electrochemical Biosensors: Recommended Definitions and Classification, Anal. Lett., 34(5): 635-659 (2001).
64
[9] Chen C., Xie Q., Yang D., Xiao H., Fu Y., Tan Y., Yao S., Recent Advances in Electrochemical Glucose Biosensors: A Review, Rsc Adv., 3(14): 4473-4491 (2013).
65
[10] Deng C., Chen J., Chen X., Xiao C., Nie L., Yao S., Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Boron-Doped Carbon Nanotubes Modified Electrode, Biosens. Bioelectron., 23(8): 1272-1277 (2008).
66
[11] Ansari A.A., Alhoshan M., Alsalhi M., Aldwayyan A., Nanostructured Metal Oxides Based Enzymatic Electrochemical Biosensors," Biosensors". (2010), InTech.
67
[12] Toghill K.E., Compton R.G., Electrochemical
68
Non-Enzymatic Glucose Sensors: A Perspective and an Evaluation, Int. J. Electrochem., Sci., 5(9): 1246-1301 (2010).
69
[13] Yang M., Yang Y., Liu Y., Shen G., Yu R., Platinum Nanoparticles-Doped Sol–Gel/Carbon Nanotubes Composite Electrochemical Sensors and Biosensors, Biosens. Bioelectron., 21(7): 1125-1131 (2006).
70
[14] Sun Y., Buck H., Mallouk T.E., Combinatorial Discovery of Alloy Electrocatalysts for Amperometric Glucose Sensors, Anal. Chem., 73(7): 1599-1604 (2001).
71
[15] Jena B.K., Raj C.R., Enzyme‐Free Amperometric Sensing of Glucose by Using Gold Nanoparticles, Chemistry–A Eur. J., 12(10): 2702-2708 (2006).
72
[16] Chen J., Zhang W.-D., Ye J.-S., Nonenzymatic Electrochemical Glucose Sensor Based on MnO 2/MWNTs Nanocomposite, Electrochem. Commun., 10(9): 1268-1271 (2008).
73
[17] Novoselov K.S., Geim A.K., Morozov S.V., Jiang D., Zhang Y., Dubonos S.V., Grigorieva I.V., Firsov A.A., Electric Field Effect in Atomically Thin Carbon Films, Science, 306(5696): 666-669 (2004).
74
[18] Mohd Yazid S.N.A., Md Isa I., Abu Bakar S., Hashim N., Ab Ghani S., A Review of Glucose Biosensors Based on Graphene/Metal Oxide Nanomaterials, Anal. Lett., 47(11): 1821-1834 (2014).
75
[19] Chung R.-J., Wang A.-N., Liao Q.-L., Chuang K.-Y., Non-Enzymatic Glucose Sensor Composed of Carbon-Coated Nano-Zinc Oxide, Nanomaterials., 7(2): 36 (2017).
76
[20] Arya S.K., Saha S., Ramirez-Vick J.E., Gupta V., Bhansali S., Singh S.P., Recent Advances in ZnO Nanostructures and Thin Films for Biosensor Applications, Anal. Chim. Acta., 737: 1-21 (2012).
77
[21] Lu N., Shao C., Li X., Miao F., Wang K., Liu Y., CuO Nanoparticles/Nitrogen-Doped Carbon Nanofibers Modified Glassy Carbon Electrodes for Non-Enzymatic Glucose Sensors with Improved Sensitivity, Ceramics International, 42(9): 11285-11293 (2016).
78
[22] Foroughi F., Rahsepar M., Hadianfard M.J., Kim H., Microwave-Assisted Synthesis of Graphene Modified CuO Nanoparticles for Voltammetric Enzyme-Free Sensing of Glucose at Biological pH Values, Microchim. Acta., 185(1): 57 (2018).
79
[23] Luo Z.J., Han T.T., Qu L.L., Wu X.Y.,
80
A Ultrasensitive Nonenzymatic Glucose Sensor Based on Cu2O Polyhedrons Modified Cu Electrode, Chinese Chemical Letters, 23(8): 953-956 (2012).
81
[24] Dai Y., Molazemhosseini A., Abbasi K., Liu C.C.,
82
A Cuprous Oxide Thin Film Non-Enzymatic Glucose Sensor Using Differential Pulse Voltammetry and Other Voltammetry Methods and a Comparison to Different Thin Film Electrodes
83
on the Detection of Glucose in an Alkaline Solution, Biosensors, 8(1): 4- (2018).
84
[25] He G., Tian L., Cai Y., Wu S., Su Y., Yan H.,
85
Pu W., Zhang J., Li L., Sensitive Nonenzymatic Electrochemical Glucose Detection Based on Hollow Porous NiO, Nanoscale. Res. Lett., 13(1):
86
3- (2018).
87
[26] Pal N., Saha B., Kundu S.K., Bhaumik A., Banerjee S., A Highly Efficient Non-Enzymatic Glucose Biosensor Based on a Nanostructured NiTiO3/NiO Material, New J. of Chem., 39(10): 8035-8043 (2015).
88
[27] Nontawong N., Amatatongchai M., Jarujamrus P., Tamuang S., Chairam S., Non-Enzymatic Glucose Sensors for Sensitive Amperometric Detection Based on Simple Method of Nickel Nanoparticles Decorated on Magnetite Carbon Nanotubes Modified Glassy Carbon Electrode, Int. J. Electrochem. Sci., 12: 1362-1376 (2017).
89
[28] Zhang H., Zhu Q., Zhang Y., Wang Y., Zhao L.,
90
Yu B., One‐Pot Synthesis and Hierarchical Assembly of Hollow Cu2O Microspheres with Nanocrystals‐Composed Porous Multishell and Their Gas‐Sensing Properties, Ad. Func. Mater., 17(15): 2766-2771 (2007).
91
[29] Gou L., Murphy C.J., Solution-Phase Synthesis of Cu2O Nanocubes, Nano. Lett., 3(2): 231-234 (2003).
92
[30] Orel Z.C., Anzlovar A., Drazic G., Zigon M., Cuprous Oxide Nanowires Prepared by an Additive-Free Polyol Process, Cryst. Growth. Des., 7(2): 453-458 (2007).
93
[31] Zhang X., Wang G., Wang Q., Zhao L., Wang M., Fang B., Cupreous Oxide Nanobelts as Detector for Determination of l-Tyrosine, Mater. Sci. Eng. B., 156(1): 6-9 (2009).
94
[32] Zhang X., Wang G., Gu A., Wu H., Fang B., Preparation of Porous Cu2O Octahedron and Its Application as L-Tyrosine Sensors, Solid. State. Commun., 148(11): 525-528 (2008).
95
[33] Zhang X., Wang G., Zhang W., Wei Y., Fang B., Fixure-Reduce Method for the Synthesis of Cu2O/MWCNTs Nanocomposites and Its Application as Enzyme-Free Glucose Sensor, Biosens. Bioelectron., 24(11): 3395-3398 (2009).
96
[34] Novel N., Gas Sensor Based on Cuprous Oxide Thin Films Shishiyanu, Sergiu T.; Shishiyanu, Teodor S.; Lupan, Oleg I, Sensor. Actuat. B-Chem. 113: 468-476 (2006).
97
[35] Rahsepar M., Pakshir M., Kim H., Synthesis
98
of Multiwall Carbon Nanotubes with a High Loading of Pt by a Microwave-Assisted Impregnation Method for Use in the Oxygen Reduction Reaction, Electrochim. Acta., 108: 769-775 (2013).
99
[36] Shao Y., Wang J., Wu H., Liu J., Aksay I.A., Lin Y., Graphene Based Electrochemical Sensors and Biosensors: A Review, Electroanal., 22(10): 1027-1036 (2010).
100
[37] Rahsepar M., Pakshir M., Piao Y., Kim H., Synthesis and Electrocatalytic Performance of High Loading Active PtRu Multiwalled Carbon Nanotube Catalyst for Methanol Oxidation, Electrochim. Acta., 71: 246-251 (2012).
101
[38] Rahsepar M., Pakshir M., Nikolaev P., Safavi A., Palanisamy K., Kim H., Tungsten Carbide on Directly Grown Multiwalled Carbon Nanotube
102
as a co-Catalyst for Methanol Oxidation, Appl. Catal. B- Environ., 127: 265-272 (2012).
103
[39] Rahsepar M., Pakshir M., Nikolaev P., Piao Y., Kim H., A Combined Physicochemical and Electrocatalytic Study of Microwave Synthesized Tungsten Mono-Carbide Nanoparticles on Multiwalled Carbon Nanotubes as a co-Catalyst
104
for a Proton-Exchange Membrane Fuel Cell,
105
Int. J. Hydrogen. Energ,. 39(28): 15706-15717 (2014).
106
[40] Rahsepar M., Pakshir M., Piao Y., Kim H., Preparation of Highly Active 40 wt.% Pt on Multiwalled Carbon Nanotube by Improved Impregnation Method for Fuel Cell Applications, Fuel. Cells., 12(5): 827-834 (2012).
107
[41] Sayah A., Capacitance Properties of Electrochemically Synthesised Polybithiophene-Exfoliated Graphene Composite Films, Iran. J. Chem. Chem. Eng., (IJCCE), (2018). [in Press]
108
[42] Tavakolyan pour F., Waqifhusain S., Rastegar H., Saber Tehrani M., Abroomand Azar P., Electrochemical Oxidation of Flavonoids and Interaction with DNA on the Surface of Supramolecular Ionic Liquid Grafted on Graphene Modified Glassy Carbon Electrode, Iran. J. Chem. Chem. Eng. (IJCCE), 37(3): 117-125 (2018).
109
[43] Geim A.K., Novoselov K.S., The Rise of Graphene, Nat. mater., 6(3): 183-191 (2007).
110
[44] Rahsepar M., Nobakht M.R., Kim H., Pakshir M., Facile Enhancement of the Active Catalytic Sites of N-Doped Graphene as a High Performance Metal-Free Electrocatalyst for Oxygen Reduction Reaction, Appl. Surf. Sci., 447: 182-190 (2018).
111
[45] Schedin F., Geim A., Morozov S., Hill E., Blake P., Katsnelson M., Novoselov K., Detection of Individual Gas Molecules Adsorbed on Graphene, Nat. Mater., 6(9): 652-655 (2007).
112
[46] Huang B., Li Z., Liu Z., Zhou G., Hao S., Wu J.,
113
Gu B.-L., Duan W., Adsorption of Gas Molecules on Graphene Nanoribbons and Its Implication for Nanoscale Molecule Sensor, J. Phys. Chem. C., 112(35): 13442-13446 (2008).
114
[47] Foroughi F., Rahsepar M., Kim H., A Highly Sensitive and Selective Biosensor Based on Nitrogen-Doped Graphene for Non-Enzymatic Detection of Uric Acid and Dopamine at Biological pH Value, J. Electroanal, Chem., : - (2018).
115
[48] Zhang F., Li Y., Gu Y.-e., Wang Z., Wang C.,
116
One-Pot Solvothermal Synthesis of a Cu2O/Graphene Nanocomposite and Its Application in an Electrochemical Sensor for Dopamine, Microchim. Acta., 173(1-2): 103-109 (2011).
117
[49] Kim Y.-R., Bong S., Kang Y.-J., Yang Y., Mahajan R.K., Kim J.S., Kim H., Electrochemical Detection of Dopamine in the Presence of
118
Ascorbic Acid Using Graphene Modified Electrodes, Biosens. Bioelectron., 25(10): 2366-2369 (2010).
119
[50] Rahsepar M., Kim H., Microwave-Assisted Synthesis and Characterization of Bimetallic PtRu Alloy Nanoparticles Supported on Carbon Nanotubes, J. Alloy. Compd., 649: 1323-1328 (2015).
120
[51] Rani A., Rajoria P., Agarwal S., Imidazolium Chloride Immobilized Fly Ash as a Heterogenized Organocatalyst for Esterification Reaction under Microwave Irradiation Heating, Iran. J. Chem. Chem. Eng. (IJCCE), : - (2018). [in Press]
121
[52] Arab-Salmanabadi S., Microwave-Assisted Synthesis of Novel Functionalized Ketenimines and Azadienes via a Solvent-Free Reaction of Isatoic Anhydride, Alkyl-Isocyanides and Dialkyl Acetylenedicarboxylates, Iran. J. Chem. Chem. Eng. (IJCCE), : - (2018). [in Press]
122
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124
ORIGINAL_ARTICLE
Synthesis and Characterization of Ni0.5Cu0.5Cr2O4 Nanostructure for Discoloration of Aniline Dye under Visible Light from Wastewater
In this research, pure-phased Ni0.5Cu0.5Cr2O4 synthesis via solid-state method successfully. In the other part, the photocatalytic activity of synthesized Ni0.5Cu0.5Cr2O4 was investigated in various aspects by using Malachite green as a pollutant and compared with the number of previous photocatalysts. The Photocatalysis process is a promising technique for solving many current environmental and energy issues. The environmental pollutant, especially water contaminates, can influence human health, animals, and the ecosystem. Dye as one of the most important pollutants has investigated in this study. In this study, purification and crystal structure of material have been determined by X-Ray powder Diffraction (XRD) method. The results showed that the synthesized Ni0.5Cu0.5Cr2O4 was crystallized in tetragonal structure with space group I 41/AMD. The morphology of obtained materials was modified by Field Emission Scanning Electron Microscope (FESEM). Also, the material was characterized by Fourier-Transform InfraRed (FT-IR) spectroscopy and Thermo Gravimetric Analysis (TGA).
https://ijcce.ac.ir/article_33339_773681b51a467429ac5283bcffb981e1.pdf
2020-04-01
11
19
10.30492/ijcce.2020.33339
Ni0.5Cu0.5Cr2O4
photocatalytic activity
Solid-state
Malachite green
Fatemeh
Soleimani
fatemeh_soleimani68@yahoo.com
1
Department of Chemistry, Semnan University, Semnan 35351-19111, I.R. IRAN
AUTHOR
Mehdi
Salehi
msalehi@semnan.ac.ir
2
Department of Chemistry, Semnan University, Semnan 35351-19111, I.R. IRAN
LEAD_AUTHOR
Ahmad
Gholizadeh
gholizadeh@du.ac.ir
3
School of Physics, Damghan University (DU), Damghan, I.R. IRAN
AUTHOR
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[19] Palanichamy M., Palanisamy P.N., Baskar R., Sakthisharmila P., Sivakumar P., A Comparative Study on the Competitiveness of Photo-Assisted Chemical Oxidation (PACO) with Electrocoagulation (EC) for the Effective Decolorization of Reactive Blue Dye, Iran. J. Chem. Chem. Eng. (IJCCE), 36: 71-85 (2017).
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of SnO2:Co Transparent Conducting Films, Mat. Sci. Semicon. Proc., 13: 162-166, (2010).
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41
ORIGINAL_ARTICLE
Cu-phthalocyanine Coated Hybrid Magnetic Nanoparticles: Preparation and Application in the Synthesis of Mono- and Bis pyrano[2,3-d]pyrimidinones and mono- and Bis-2-amino-4H-pyrans
In this research, Cu-phthalocyanine coated hybrid magnetic nanoparticles have been prepared in a simple method and evaluated as an efficient catalyst in the preparation of mono- and bis-pyrano[2,3-d]pyrimidinones and mono- and bis-2-amino-4H-pyrans from the condensation reaction of 1,3-dimethylbarbituric acid or 4-hydroxycumarin with malononitrile and mono- and bis-aldehydes under ultrasonic irradiation. The catalyst could be easily recovered in the presence of the external magnetic field and reused five times without significant loss of activity and mass. The magnetic nanoparticles were characterized using Fourier Transform InfraRed (FT-IR) spectra, X-Ray Diffraction (XRD) spectroscopy, Scanning Electron Microscopy (SEM), Thermal Gravimetric Analysis (TGA). The results showed the spherical structures of hybrid magnetic nanoparticles and the average size is about 37 nm.
https://ijcce.ac.ir/article_34794_97f6e1b79138a6414b8981feb3560aff.pdf
2020-04-01
21
31
10.30492/ijcce.2020.34794
Hybrid magnetic nanoparticles
Phthalocyanine
Pyrano[2,3-d]pyrimidinone
2-Amino-4H-pyran
ultrasonic irradiation
Ali Reza
Karimi
ar_karimi55@yahoo.com
1
Department of Chemistry, Faculty of Science, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
LEAD_AUTHOR
Fatemeh
Bagherian
f.bagheriyan@yahoo.com
2
Department of Chemistry, Faculty of Science, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
AUTHOR
Marzie
Karimi
karimi.m.59@gmail.com
3
Department of Chemistry, Faculty of Science, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
AUTHOR
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b) Karimi A R., Dalirnasab Z., Karimi M., Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-ylarenes under Solvent-Free Conditions, Synthesis., 46: 917-922(2014).
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55
[51] Karimi A R., Eslami C., Mono- and Bis-2-amino-4H-pyrans: Alum Catalyzed Three- or Pseudo Five-Component Reaction of 4-Hydroxycoumarin, Malononitrile and Aldehydes, Lett. Org. Chem., 8: 150-154(2011)
56
[52] Peng Z G., Hidajat K., Uddin M S., Adsorption of bovine serum albumin on nanosized magnetic particles, J. Colloid Interf. Sci., 271: 277-283(2004).
57
[53] Chen F H., Gao Q., Ni J Z., The grafting and release behavior of doxorubincin from Fe3O4@SiO2 core–shell structure nanoparticles via an acid cleaving amide bond: the potential for magnetic targeting drug delivery, Nanotechnology, 19: 165103-165111(2008).
58
[54] Ghosh S., Badruddoza A Z M., Uddin M S., Hidajat K., Adsorption of chiral aromatic amino acids onto carboxymethyl -β-cyclodextrin bonded Fe3O4/SiO2 core–shell nanoparticles, J. Colloid Interf. Sci., 354: 483-492(2011).
59
[55] Karimi A R., Davood Abadi R., Dalirnasab Z., Synthesis of mono- and bis-spiro-2-amino-4H-pyrans catalyzed by S-alkyl O-hydrogen sulfothioate functionalized silica-coated magnetic nanoparticles under ultrasound irradiation, Res Chem Intermed., 41: 7427–7435(2015).
60
[56] Karimi A R., Sedaghatpour F., Novel Mono-and Bis(spiro-2-amino-4H-pyrans): Alum-catalyzed Reaction of 4-Hydroxy cumarin and Malononitrile with Isatins, Quinones or Ninhydrin, SYNTHESIS, 10:1731-1735 (2010).
61
[57] Karimi A.R., Sourinia M., Dalirnasab Z., Karimi M., Silica Sulfuric Acid Magnetic Nanoparticle: an Efficient and Ecofriendly Catalyst for Synthesis of Spiro[2-amino-4H-pyran-oxindole]s, Can. J. Chem, 93: 546–549 (2015).
62
[58] Safaieea M., Zolfigol M A., Afsharnadery F., Baghery S., Synthesis of a Novel Dendrimer Core of oxo-Vanadium Phthalocyanine Magnetic Nano Particles: as an Efficient Catalyst for the Synthesis of 3,4-Dihydropyrano[c]chromenes Derivatives under Green Condition, RSC Advances, 00: 1-11 (2013).
63
[59] Zolfigol M A., Safaiee M., Bahrami-Nejad N., Correction: Dendrimeric Magnetic Nanoparticle Cores with Co-phthalocyanine Tags and Their Application in the Synthesis of tetrahydrobenzo[b]pyran Derivatives, New J. Chem, 40, 8158-8160 (2016).
64
ORIGINAL_ARTICLE
Polyester/SiO2 Nanocomposites: Gas Permeation, Mechanical, Thermal and Morphological Study of Membranes
Using of nanocomposite membranes composed of polymer and inorganic nanoparticles is a novel method to enhance gas separation performance. In this study, membranes were fabricated from polyester (PE) containing silica (SiO2) nanoparticles and gas permeation properties of the resulting membranes were investigated. Morphology of the membranes, SiO2 distribution and aggregates were observed by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) analysis. Furthermore, thermal stability, the residual solvent in the membrane film, and structural ruination of membranes were analyzed by Thermo Gravimetric Analysis (TGA). The effects of SiO2 nanoparticles on the glass transition temperature (Tg) of the prepared nanocomposites were studied by Differential Scanning Calorimetry (DSC). The results obtained from gas permeation experiments with a constant pressure setup showed that adding SiO2 nanoparticles to the polymeric membrane structure increased the permeability of the membranes.
https://ijcce.ac.ir/article_37780_e355d567f7beec88b9acbf84ee437dcd.pdf
2020-04-01
33
47
10.30492/ijcce.2020.37780
polyester
Nanocomposite
silica
thermal stability
Gas permeation
Hashem
Ahmadizadegan
h.ahmadizadegan.2005@gmail.com
1
Department of Chemistry, Darab Branch, Islamic Azad University, 7481783143-196, Darab, I.R. IRAN
LEAD_AUTHOR
[1] Shao L., Low B.T., Chung T.S., Greenberg A.R., Polymeric Membranes for the Hydrogen Economy: Contemporary Approaches and Prospects for the Future, J. Membr. Sci. 327: 18-31 (2009).
1
[2] Ahmadizadegan H., Esmaielzadeh S., Ranjbar M., Improving the Proton Conductivity and
2
Antibacterial Properties of Sulfonated Polybenzimidazole/ZnO/Cellulose with Surface Functionalized Cellulose/ZnO Bionanocomposites. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37: 27-42 (2018).
3
[3] Salimi M., Pirouzfar V.,Kianfar E., Enhanced Gas Transport Properties in Silica Nanoparticle Filler-Polystyrene Nanocomposite Membranes, Colloid Polym Sci 295: 215–226 (2017).
4
[4] Le Baron P.C., Wang Z., Pinnavala T.J., Polymer Layered Silicate Nanocomposites an Overview Appl.Clay.Sci, 15: 11‐29 (1999).
5
[5] Moqadam S., Salami Kalajahi M., Mahdavian M., Synthesis and Characterization of Sunflower Oil-Based Polysulfide Polymer/Cloisite 30B Nanocomposites. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37: 185-192 (2018).
6
[6] Jing L., Wang W.W., Wel X., Wu D., Jin R., Effects of Water on the Preparation, Morphology and Properties of Polyimide and Silica Nano Composite Films Prepared by Sol‐Gel Process, J. Appl Polym. Sci., 104: 1579-1586, (2007).
7
[7] Ghorpade R.V., Rajan C.R., Chavan N.N., Ponrathnam S., Synthesis of Novel Silica-Polyimide Nanocomposite Films Using Aromatic-Amino Modified Silica Nanoparticles: Mechanical, Thermal and Morphological Investigations, eXPRESS Polymer Letters.9: 469–479 (2015).
8
[8] Chitra B., Sathish K., K. Sonication Effects on Stability and Thermal Properties of Silica- Paraflu Based Nanofluids. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36: 153-159
9
[9] Timur, M., Demetgül, C. Synthesis and Metal Ion Uptake Studies of Silica Gel-Immobilized Schiff Base Derivatives and Catalytic Behaviors of their Cu(II) Complexes. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36: 111-122 (2017).
10
[10] Kawasumi M, Masegawa N K, Ato M ,Uskd A and Okada A, Preparation and Mechanical Properties of Poly Propylene Hybrids, Macromolecules, 30: 6333‐6338 (1997).
11
[11] Ahmadizadegan H., Esmaielzadeh S., Fabrication and Characterization of Novel Polyester Thin‐Film Nanocomposite Membranes Achieved by Functionalized SiO2 Nanoparticles for Gas Separation, Polym Eng Sci., 59: 237-247 (2019).
12
[12] Ahmadizadegan H., Esmaielzadeh S., Novel polyester/SiO2 Nanocomposite Membranes: Synthesis, Properties and Morphological Studies, Solid State Sciences, 80: 81-91 (2018).
13
[13] Hu Q., Marand E., Dhingra S., Fritsch D., Wen J., Wilkes G. Poly(amide-imide)/TiO2 Nano-Composite Gas Separation Membranes: Fabrication and Characterization, J. Membr. Sci, 135: 65-79 (1997).
14
[14] Ahmadizadegan H., Synthesis and Gas Transport Properties of Novel Functional Polyimide/ZnO Nanocomposite thin Film Membranes, RSC Adv., 6: 106778-106789 (2016).
15
[15] Li T., Liu J., Zhao Sh., Chen Zh., Huang H., Guo R., Chen Y., Microporous Polyimides Containing Bulky Tetra- O -Isopropyl and Naphthalene Groups for Gas Separation Membranes, Journal of Membrane Science, 585: 282-288 (2019).
16
[16] Ahmadizadegan H., Esmaielzadeh Sh., Ranjbar M., Marzban Z., Ghavas F., Synthesis and Characterization of Polyester Bionanocomposite Membrane With Ultrasonic Irradiation Process For Gas Permeation and Antibacterial Activity, Ultrason. Sonochem. 41: 538–550 (2018).
17
[17] Ahmadizadegan H., Khajavian R., Novel Functional Aromatic Polyimides and Polyimide/Titania Nanocomposite Thin Films for Gas Separation: Preparation and Structural Characterization, J. Iran. Chem. Soc. 14: 777–789 (2017).
18
[18] Yuanliang Zhao; Xiaowen Qi; Yu Dong; Jian Ma; Qinglong Zhang; Laizhou Song; Yulin Yang; Qingxiang Yang, Mechanical, Thermal and Tribological Properties of Polyimide/Nano-SiO2 Composites Synthesized Using an In-Situ Polymerization, Tribology International 103: 599-608 (2016).
19
[19] Toiserkani H., Polyimide/Nano-Tio2 Hybrid Films Having Benzoxazole Pendentgroups: in Situ Sol–Gel Preparation and Evaluation of Properties, Progress in Organic Coatings 88: 17–22 (2015).
20
[20] Seyedjamali H., Pirisedigh A., Synthesis of Well-Dispersed Polyimide/TiO2 Nanohybrid Films Using a Pyridine-Containing Aromatic Diamine, Polym. Bull. 68: 299–308 (2012).
21
[21] Chen B., Chiu T., Tsay S., Synthesis and Characterization of Polyimide/Silica Hybrid Nanocomposites, J. Appl. Polym. Sci. 94: 382 (2004).
22
[22] Zu L., Li R., Jin L., Lian H., Liu Y., Cui X., Preparation and Characterization of Polypropylene/Silica Composite Particle with Interpenetrating Network Via Hot Emulsion Sol–Gel Approach, Progress in Natural Science: Materials International 24: 42-49 (2014).
23
[23] Kong Y., Du H., Yang J., Shi D., Wang Y., Zhang Y., Xin W., Study on Polyimide/TiO2 Nanocomposite Membranes for Gas Separation, Desalination, 146: 49–55 (2002).
24
[24] Ahmadizadegan H., Esmaielzadeh S., Gas Transport Membranes Based on Novel Optically Active Polyester/Cellulose/Zno Bionanocomposite Membranes, J Iran Chem Soc 15: 799–811 (2018).
25
[25] Tena A., Fernández A.M., Viuda M., Palacio L., Prádanos P., Lozano A.E., Abajo J., Hernández A., Advances In The Design of Co-Poly(Ether-Imide) Membranes for CO2 Separations. Influence of Aromatic Rigidity on Crystallinity, Phase Segregation and Gas Transport, Eur. Polym. J. 62:130-138 (2015).
26
[26] Lua A.C., Shen Y., Preparation and Characterization of Polyimide–Silica Composite Membranes and Their Derived Carbon–Silica Composite Membranes for Gas Separation, Chem. Eng. J. 220: 441–451 (2013).
27
ORIGINAL_ARTICLE
Structural, Optical and Magnetic Feature of Core-Shell Nanostructured Fe3O4@GO in Photocatalytic Activity
In this paper, structural, magnetic, optical, and photocatalytic properties of core-shell structure Fe3O4@GO nanoparticles have been compared with Fe3O4 nanoparticles in the degradation of methyl blue and methyl orange. For this purpose, GO nanosheets were wrapped around the APTMS-Fe3O4 nanoparticles and then characterized using X-ray Diffraction, field emission scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometer, UV-visible, and Fourier transform infrared spectroscopy. The results show the core-shell nanostructured Fe3O4@GO is formed. As an application for the synthesized structure, degradation of methyl blue and methyl orange as heavy-mass organic pollutants has been measured. While the saturation magnetization of Fe3O4@GO is lower than Fe3O4, but shows better efficiency in the degradation of methyl blue and methyl orange. The obtained catalysts can be quickly separated from the solution under an external magnetic field because of their considerable Ms values, which will be beneficial for their reuse and boosting the overall water treatment efficiency in practical applications.
https://ijcce.ac.ir/article_34296_d2846d3e790d3b8c9c20d6107e2ee748.pdf
2020-04-01
49
58
10.30492/ijcce.2020.34296
Graphene oxide
Core-shell structure
Magnetic materials
Degradation of methyl blue and methyl orange
Amir
Abharya
abharya.a@gmail.com
1
School of Physics, Damghan University (DU), Damghan, I.R. Iran
AUTHOR
Ahmad
Gholizadeh
gholizadeh@du.ac.ir
2
School of Physics, Damghan University (DU), Damghan, I.R. Iran
LEAD_AUTHOR
[1] Gholizadeh A., A Comparative Study of Physical Properties in Fe3O4 Nanoparticles Prepared by Coprecipitation and Citrate Methods, Journal of the American Ceramic Society, 100(8): 3577-3588 (2017).
1
[2] Gholizadeh A., Jafari E., Effects of Sintering Atmosphere and Temperature on Structural and Magnetic Properties of Ni-Cu-Zn ferrite nano-Particles: Magnetic Enhancement by a Reducing Atmosphere, J. Magn. Magn. Mater., 422: 328–36 (2017).
2
[3] Gholizadeh A., A Comparative Study of the Physical Properties of Cu-Zn Ferrites Annealed under Different Atmospheres and Temperatures: Magnetic Enhancement of Cu0.5Zn0.5Fe2O4 Nanoparticles
3
by a Reducing Atmosphere, Journal of Magnetism and Magnetic Materials, 452: 389–397 (2018).
4
[4] Shamgani N., Gholizadeh A., Structural, Magnetic and Elastic Properties of Mn0.3−xMgxCu0.2Zn0.5Fe3O4 Nanoparticles, Ceramics International, 45: 239–246 (2019).
5
[5] Pei S., Cheng H.-M., The Reduction of Graphene Oxide, Carbon, 50: 3210–3228 (2012).
6
[6] Vinayan B.P., Nagar R., Raman V., Rajalakshmi N., Dhathathreyan K.S., Ramaprabhu S., Synthesis of Graphene-Multiwalled Carbon Nanotubes Hybrid Nanostructure by Strengthened Electrostatic Interaction and its Lithium Ion Battery Application, J. Mater. Chem., 22: 9949 (2012).
7
[7] Yang X., Chen W., Huang J., Zhou Y., Zhu Y., Li Ch., Rapid Degradation of Methylene Blue in a Novel Heterogeneous Fe3O4@rGO@TiO2-Catalyzed Photo-Fenton System, Sci. Rep., 5: 10632 (2015).
8
[8] Wei H., Yang W., Xi Q., Chen X., Preparation of Fe3O4@graphene Oxide Core–shell Magnetic Particles for Use in Protein Adsorption, Materials Letters, 82: 224–226 (2012).
9
[9] Ouyang K., Zhu Ch., Zhao Y., Wang L., Xie Sh., Wang Q., Adsorption Mechanism of Magnetically Separable Fe3O4/Graphene Oxide Hybrids, Applied Surface Science, 355: 562–569 (2015).
10
[10] He F., Fan J., Ma D., Zhang L., Leung Ch., Chan H.L., The Attachment of Fe3O4 Nanoparticles to Graphene Oxide by Covalent Bonding, Carbon, 48: 3139 –3144 (2010).
11
[11] Li Y., Chu J., Qi J., Li X., An Easy and Novel Approach for the Decoration of Graphene Oxide
12
by Fe3O4 Nanoparticles, Applied Surface Science, 257: 6059-6062 (2011).
13
[12] Yu L., Chen J., Liang Zh., Xu W., Chen L., Ye D., Degradation of Phenol Using Fe3O4-GO Nanocomposite as a Heterogeneous Photo-Fenton Catalyst, Separation and Purification Technology, 171: 80–87 (2016).
14
[13] Yousefi H., Gholizadeh A., Mirbeig Sabzevari Z., Malekzadeh A., Structural Features of La0.55Ca0.45A0.50Co0.50O3 (A=Mg, Mn) Nanoparticles Over Photo-Degradation of Methyl Blue, J. Nanoanalysis, 4(4): 324-333 (2017).
15
[14] Soleimani F., Salehi M., Gholizadeh A., Hydrothermal Synthesis, Structural and Catalytic Studies of CuBi2O4 Nanoparticles, J. Nanoanalysis, 4(3): 239-246 (2017).
16
[15] Gholizadeh A., Malekzadeh A, Pourarian F., Rapid And Efficient Synthesis of Reduced Graphene Oxide Nano-Sheets Using CO Ambient Atmosphere as a Reducing Agent, Journal of Materials Science: Materials in Electronics, 29(22): 19402-19412 (2018).
17
[16] Gholizadeh A., La1-xCaxCo1-yMgyO3 Nano-Perovskites as CO oxidation catalysts: structural and catalytic properties, J. Am. Ceram. Soc., 100: 813 (2017).
18
[17] Mahmoudi S., Gholizadeh A., Effect of Non-Magnetic Ions Substitution on the Structure
19
and Magnetic Properties of Y3-xSrxFe5-xZrxO12 Nanoparticles, Journal of Magnetism and Magnetic Materials, 456: 46–55 (2018).
20
[18] Gholizadeh A., Tajabor N., Influence of N2- and Ar-Ambient Annealing on the Physical Properties of SnO2:Co Transparent Conducting Films, Mater. Sci. Semicond. Process., 13: 162-166 (2010).
21
[19] Soleimani F., Salehi M., Ahmad Gholizadeh, Synthesize and Characterization of Ni0.5Cu0.5Cr2O4 Nanostructure for Discoloration of Aniline Dye under Visible Light from Wastewater, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 39(2): 11-19 (2020).
22
[20] Gholizadeh A., The Effects of A/B-Site Substitution on Structural, Redox and Catalytic Properties of Lanthanum Ferrite Nanoparticles, Journal of Materials Research and Technology, https://doi.org/10.1016/j.jmrt.2017.12.006.
23
[21] Gholizadeh A., Ganjehie S., Ketabi S.A., Microstructure and Swelling Behaviour of Poly (Acrylamide-co-Acrylic Acid) Based Nanocomposite Superabsorbent Hydrogels, J. Nanoanalysis, 5(3): 195-201 (2018).
24
[22] Luo X, Liu S, Zhou J, Zhang L., In Situ Synthesis of Fe3O4/Cellulose Microspheres with Magnetic-Induced Protein Delivery, J. Mater. Chem., 19: 3538–3545 (2009).
25
[23] Ghiasi M., Malekzadeh A., Solar Photocatalytic Degradation of Methyl Orange over La0.7Sr0.3MnO3 Nano-Perovskite, Separation and Purification Technology, 134: 12–19 (2014).
26
ORIGINAL_ARTICLE
Polyethylene/Clay/Graphite Nanocomposites as Potential Materials for Preparation of Reinforced Conductive Natural Gas Transfer Pipes
A series of high-density polyethylene/Cloisite 20A/graphite nanocomposites were prepared via melt blending for the production of polymeric pipes for natural gas transfer. The microstructural, mechanical, thermal, electrical and barrier properties of prepared nanocomposites were investigated. An intercalated morphology was observed for prepared nanocomposites. Improved mechanical properties e.g. over 148 % increase in Young’s modulus were observed by incorporating the nanoparticles into the polyethylene matrix. The thermal analysis showed that the melting point of polyethylene was slightly increased by incorporating both fillers, i.e. Cloisite 20A and graphite in it, and the crystallinity was depended on the type of filler. The results showed that the MFI values decreased by incorporating the fillers into the polyethylene matrix and further decreases were observed by increasing the contents of the filler. It was also found that a considerable amount of electrical conductivity is created in graphite loaded nanocomposites. The natural gas permeability investigations revealed of more than 51 % decrease in the permeability by incorporating 5 wt.% of Cloisite 20A to the polyethylene. It was concluded that the prepared nanocomposites due to their enhanced mechanical, thermal and barrier properties along with the conductive nature are excellent materials to be used in the production of polymeric pipes in natural gas distribution and transportation networks.
https://ijcce.ac.ir/article_33964_3b631997dd43ac25c0152aaa1b422add.pdf
2020-04-01
59
68
10.30492/ijcce.2020.33964
Nanocomposites
Polyethylene
Clay
Graphite
Natural gas pipeline
Sariyeh
Parmoor
sarparmoor@uut.ac.ir
1
Faculty of Chemical Engineering, Urmia University of Technology, Urmia, I.R. IRAN
AUTHOR
Mohammad
Sirousazar
m.sirousazar@uut.ac.ir
2
Faculty of Chemical Engineering, Urmia University of Technology, Urmia, I.R. IRAN
LEAD_AUTHOR
Farshad
Kheiri
farkheiri@uut.ac.ir
3
Faculty of Chemical Engineering, Urmia University of Technology, Urmia, I.R. IRAN
AUTHOR
Mehrdad
Kokabi
mehrir@modares.ac.ir
4
Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
AUTHOR
[1] Samimi A., Zarinabadi S., Application Polyurethane as Coating in Oil and Gas Pipelines, Int. J. Sci. Eng. Invest., 1: 43-45 (2012).
1
[2] Samimi V., Zarinabadi S., An Analysis of Polyethylene Coating Corrosion in Oil and Gas Pipelines, J. Am. Sci., 7: 1032-1036 (2011).
2
[3] Kiass N., Khelif R., Boulanouar L., Chaoui K., Experimental Approach to Mechanical Property Variability Through a High-Density Polyethylene Gas Pipe Wall, J. Appl. Polym. Sci., 97: 272-281 (2005).
3
[4] Laney P., “Use of Composite Pipe Materials in the Transportation of Natural Gas”, Idaho National Engineering and Environmental Laboratory Bechtel BWXT Idaho, LLC (2002).
4
[5] Pusz A., Michalik K., Fractographic Study of High-Density Polyethylene Gas Pipe Following Small Scale Steady State Test, J. Achiev. Mater. Manuf. Eng., 38: 131-138 (2010).
5
[6] Hamouda H.B.H., Simoes-betbeder M., Grillon F., Blouet P., Billon N., Piques R., Creep Damage Mechanisms in Polyethylene Gas Pipes, Polymer, 42: 5425-5437 (2001).
6
[7] Rofooei F.R., Jalali H.H., Attari N.K.A., Kenarangi H., Samadian M., Parametric Study of Buried Steel
7
and High Density Polyethylene Gas Pipelines due to Oblique-Reverse Faulting, Can. J. Civ. Eng., 42: 178-189 (2015).
8
[8] Talhi F.Z., Benaniba M.T., Belhaneche-Bensemra N., Massardier V., Comparison of Material Properties
9
in Butt Welds of Used and Unused Polyethylene Pipes for Natural Gas Distribution, J. Polym. Eng., 37: 279-285 (2017).
10
[9] Gueugnaut D., Tessier M., Bouaffre R., Lopitaux A., Ultrasonic Phased Array Inspection of Electrofused Joints Implemented in Polyethylene Gas Piping Systems, J. Mater. Sci. Eng. A., 7: 68-81 (2017).
11
[10] Sarikanat M., Sever K., Erbay E., Guner F., Tavman I., Turgut A., Seki Y., Qzdemir I., Prepation and Mechanical Properties of Graphite Filled HDPE Nanocomposites, Arch. Mater. Sci. Eng., 50:120-124 (2011).
12
[11] Bafna A.A., “Polyethylene-clay Nanocomposites: Processing-Structure-Property Relationship”, PhD Thesis, University of Cincinnati, USA, (2004).
13
[12] Keith J.M., King J.A., Barton R.L., Electrical Conductivity Modeling of Carbon-Filled Liquid-Crystalline Polymer Composites, J. Appl. Polym. Sci., 102: 3293-3300 (2006).
14
[13] Ma P.C., Liu M. Y., Zhang H., Wang S.Q., Wang R., Wang K., Wong Y.K., Tang B.Z., Hong S.H.,
15
Paik K. W., Kim J.K., Enhanced Electrical Conductivity of Nanocomposites Containing Hybrid Fillers of Carbon Nanotubes and Carbon Black, Appl. Mater. Interfaces, 1:1090-1096 (2009).
16
[14] Osman M.A., Rupp J.E.P., Suter U.W., Gas Permeation Properties of Polyethylene-Layered Silicate Nanocomposites, J. Mater. Chem., 15: 1298-1304 (2005).
17
[15] Paydayesh A., Kokabi M., Highly Filled Organoclay/Phenolic Resin Nanocomposite as an Ablative Heat Shield Material, Iran. Polym. J., 24: 389-397 (2015).
18
[16] Nuhiji B., Attard D., Deveth A., Bungur J., Fox B., The Influence of Processing Techniques on the Matrix Distribution and Filtration of Clay in a Fibre Reinforced Nanocomposite, Compos. Part B., 84: 1-8 (2016).
19
[17] Mansoori Y., Roojaei K., Zamanloo M.R., Polymer-Clay Nanocomposites via Chemical Grafting of Polyacrylonitrile onto Cloisite 20A, Bulletin of Mater. Sci., 35: 1063-1070 (2012).
20
[18] Mansoori Y., Hemmati S., Eghbali P., Zamanloo M.R., Imanzadeh, Gh., Nanocomposite Materials Based on Isosorbide Methacrylate/Cloisite 20A, Polym. Inter., 62: 280-288 (2013).
21
[19] Mansoori Y., Masooleh T.M., Polyimide/Organo-Montmorillonite Nanocomposites: A Comparative Study of the Organoclays Modified with Aromatic Diamines, Polym. Compos., 36: 613-622 (2015).
22
[20] Mansoori Y., Mohsenzadeh R., Novel Polyamide/Layered Silicate Nanocomposites with Improved Mechanical Properties: Thermal and Mechanical Investigation, Polym. Sci. Ser. B, 57: 759-770 (2015).
23
[21] Zhang J., Jiang D. D., Wilkie C. A., Thermal and Flame Properties of Polyethylene and Polypropylenene Nanocomposites Based on Oligomerically-Modified Clay, Polym. Degrad. Stab., 91: 298-304 (2006).
24
[22] Abadchi M.R., Jalali-Arani A., Synergistic Effects of Nano-Scale Polybutadiene Rubber Powder (PBRP) and Nanoclay on the Structure, Dynamic Mechanical and Thermal Properties of Polypropylene (PP), Iran. Polym. J., 24: 805-813 (2015).
25
[23] Sirousazar M., Kokabi M., Hassan Z.M., Bahramian A.R., Nanoporous Nanocomposite Hydrogels Composed of Polyvinyl Alcohol and Na-montmorillonite, J. Macromol. Sci. Part B Phys., 51:1583-1595 (2012).
26
[24] Mansoori Y., Atghia S.V., Zamanloo M.R., Imanzadeh Gh., Sirousazar M., Polymer-Clay Nanocomposites: Free-Radical Grafting of Polyacrylamide onto Organophilic Montmorillonite, Eur. Polym. J., 46: 1844-1853 (2010).
27
[25] Mansoori Y., Atghia S.V., Shah Sanaei S., Zamanloo M.R., Imanzadeh Gh., PMMA-Clay Nanocomposite Materials: Free-Radically Grafting of PMMA onto Organophilic Montmorillonite (20A), Macromol. Res., 18: 1174-1181 (2010).
28
[26] Mansoori Y., Roojaei K., Zamanloo M.R., Imanzadeh, Gh., Polymer-Clay Nanocomposites: Chemical Grafting of Polystyrene onto Cloisite 20A, Chin. J. Polym. Sci., 30: 815-823 (2012).
29
[27] Sirousazar M., Yari M., Achachlouei B.F., Arsalani J., Mansoori Y., Polypropylene/Montmorillonite Nanocomposites for Food Packaging, e-Polymers, No. 027 (2007).
30
[28] Attaran S.A., Hassan A., Wahit M. U., Effects of ENR and OMMT on Barrier and Tensile Properties of LDPE Nanocomposite Film, Iran. Polym. J., 24: 367-378 (2015).
31
[29] Ahmadi M., Jahanmardi R., Mohammadizade M., Preparation of PMMA/MWNTs Nanocomposite Microcellular Foams by In-situ Generation of Supercritical Carbon Dioxide, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 63-72 (2016).
32
[30] Bayandori Moghaddam A., Hosseini S., Badraghi J., Banaei A., Hybrid Nanocomposite Based on CoFe2O4 Magnetic Nanoparticles and Polyaniline, Iran. J. Chem. Chem. Eng. (IJCCE), 29: 173-179 (2010).
33
[31] Zhang X., Wang J., Jia H., You S., Xiong X., Ding L., Xu Z., Multifunctional Nanocomposites Between Natural Rubber and Polyvinyl Pyrrolidone Modified Graphene, Compos. Part B., 84: 121-129 (2016).
34
[32] Parmoor S., Sirousazar M., Kheiri F., Kokabi M., Nanoclay and Cu Nanoparticles Loaded Polyethylene Nanocomposites for Natural Gas Transfer Applications, J. Macromol. Sci. Part B Phys., 55: 331-343 (2016).
35
[33] Durmus A., Woo M., Kasgoz A., Macosko C.W., Tsapatsis M., Intercalated Linear Low Density Polyethylene (LLDPE)/Clay Nanocomposites Prepared with Oxidized Polyethylene as A New Type Compatibilizer: Structural, Mechanical and Barrier Properties, Eur. Polym. J., 43: 3737-3749 (2007).
36
[34] Chmelar J., Smolna K., Haskovcova K., Podivinska K., Marsalek J., Kosek J., Equilibrium Sorption of Ethylene in Polyethylene: Experimental Study and PC-SAFT Simulations, Polymer, 59: 270-277 (2015).
37
[35] Perthue A., Bussiere P.O., Baba M., Larche J.F., Gardette J. L., Therias S., Correlation Between Water Uptake and Loss of the Insulating Properties of PE/ATH Composites Used in Cables Applications, Polym. Degrad. Stab., 127: 79-87 (2016).
38
ORIGINAL_ARTICLE
Enhanced HDN Performance of Al, Zr and Ti Modified NiW Catalysts by Using Co-Impregnation Method
The Al, Zr, and Ti modified MCM-41 materials were prepared by the post-synthesis method, and then the Ni-W species were introduced on them by using the co-impregnation method in order to obtain high-performance hydrodenitrogenation (HDN) catalysts. The activity of the catalysts was evaluated by the HDN reaction of quinoline. The optimum HDN activity was observed on the catalyst supported on the Al modified MCM-41. The high performance of the NiW/Al catalyst was due to the higher dispersion of Ni, W species, the more density of acid sites, the more appropriate nature of W species, and the lower reduction temperature of W species. Moreover, the catalysts prepared by co-impregnation method showed better performance than the catalysts prepared by the sequential impregnation method in the HDN of quinoline.
https://ijcce.ac.ir/article_37197_92da17958fbe9ef91eef1a61fe28f166.pdf
2020-04-01
69
81
10.30492/ijcce.2020.37197
Al, Zr, Ti modified MCM-41
NiW catalyst
Co-impregnation
Hydrodenitrogenation
Fang
Guo
guofang110119@163.com
1
College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong 030600, P.R. CHINA
LEAD_AUTHOR
Yi-en
Du
duyien124@163.com
2
College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong 030600, P.R. CHINA
AUTHOR
Xianjun
Niu
xjniu1984@163.com
3
College of chemistry and chemical engineering, Jinzhong University, Jinzhong 030600, P.R. CHINA
AUTHOR
Shaoqing
Guo
guosq@sxicc.ac.cn
4
College of Environment and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, P.R. CHINA
AUTHOR
Xianxian
Wei
weixianxian@tyust.edu.cn
5
College of Environment and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, P.R. CHINA
AUTHOR
Xiaoxiao
Wang
wang5203264@sina.com
6
College of Environment and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, P.R. CHINA
AUTHOR
Zegang
Qiu
qiuzegang@sxicc.ac.cn
7
College of chemistry and chemical engineering, Xi’an University of Petroleum, Xi’an 710065, P.R. CHINA
AUTHOR
Liangfu
Zhao
lfzhao@sxicc.ac.cn
8
Laboratory of Applied Catalysis and Green Chemical Engineering, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P.R. CHINA
AUTHOR
[1] Kanda Y., Temma C., Nakata, K., Kobayashi T., Sugioka M., Uemichi Y., Preparation and Performance of Noble Metal Phosphides Supported on Silica as New Hydrodesulfurization Catalysts, Appl. Catal. A: Gen., 386: 171-178 (2010).
1
[2] Yu G.L., Zhou Y.S., Wei Q., Tao X.J., Cui Q.Y., A Novel Method For Preparing Well Dispersed and Highly Sulfided Niw Hydrodenitrogenation Catalyst, Catal. Commun., 23: 48-53 (2012).
2
[3] Klimova T., Gutiérrez O., Lizama L., Amezcua J., Advantages of ZrO2- and TiO2–SBA-15 Mesostructured Supports for Hydrodesulfurization Catalysts over Pure TiO2, ZrO2 and SBA-15, Micropor. Mater., 133: 91-99 (2010).
3
[4] Gutiérrez O.Y., Ayala E., Puente I., Klimova T., Application of New ZrO2-SBA-15 Materials as Catalytic Supports: Study of Intrinsic Activity of Mo Catalysts in Deep HDS, Chem. Eng. Comm., 196: 1163-1177 (2009).
4
[5] Herrera J.M., Reyes J., Roquero P., Klimova T., New hydrotreating NiMo Catalysts Supported on MCM-41 Modified with Phosphorus, Micropor. Mater., 83: 283-291 (2005).
5
[6] Silva-Rodrigo R., Calderón-Salas C., Melo-Banda J.A., Domínguez J.M., Vázquez-Rodríguez A. Synthesis, Characterization and Comparison of Catalytic Properties of NiMo- and NiW/Ti-MCM-41 catalysts for HDS of Thiophene and HVGO, Catal. Today, 98: 123-129 (2004).
6
[7] Klimova T., Calderón M., Ramírez J., Ni and Mo Interaction with Al-Containing MCM-41 Support and Its Effect on the Catalytic Behavior in DBT Hydrodesulfurization, Appl. Catal. A: Gen., 240: 29-40 (2003).
7
[8] Rodríguez-Castellõn E., Jimenez-Lõpez A., Eliche-Quesada D., Nickel and Cobalt Promoted Tungsten and Molybdenum Sulfide Mesoporous Catalysts tor Hydrodesulfurization, Fuel, 87: 1195-1206 (2008).
8
[9] Guo F., Guo S., Wei X.X., Wang X., Xiang H., Qiu Z., Zhao L.,MCM-41 Supports Modified by Al, Zr and Ti for NiW Hydrodenitrogenation Catalysts, Catal. Lett., 144: 1584-1593 (2014).
9
[10] Salerno P., Mendioroz S., López Agudo A., Al-Pillared Montmorillonite-Based Nimo Catalysts for HDS and HDN of Gas Oil: Influence of the Method and Order of Mo And Ni Impregnation, Appl. Catal. A: Gen., 259: 17-28 (2004).
10
[11] Sardhar Basha S.J., Vijayan P., Suresh C., Santhanaraj D., Shanthi K.,Effect of Order of Impregnation of Mo and Ni on the Hydrodenitrogenation Activity of Nio-Moo3/Almcm-41 Catalyst, Ind. Eng. Chem. Res., 48: 2774-2780 (2009).
11
[12] Khder A.E.R.S., Hassan H.M.A., El-Shall M.S. Acid Catalyzed Organic Transformations by Heteropoly Tungstophosphoric Acid Supported on MCM-41, Appl. Catal. A: Gen.,411-412: 77-86 (2012).
12
[13] Carriazo D., Domingo C., Martín C., Rives V.,Pmo or PW Heteropoly Acids Supported on MCM-41 Silica Nanoparticles: Characterisation and FT-IR Study of the Adsorption of 2-Butanol, J. Solid State Chem., 181: 2046-2057 (2008).
13
[14] Méndez F.J., Llanos A., Echeverría M., Jáuregui R., Villasana Y., Díza Y., Liendo-Polanco G., Ramos-García M.A., Zoltan T., Brito J.L., Mesoporous Catalysts Based on Keggin-Type Heteropolyacids Supported on MCM-41 and Their Application in Thiophene Hydrodesulfurization, Fuel, 110: 249-258 (2013).
14
[15] Palcheva R., Spojakina A., Dimitrov L., Jiratova K., 12-Tungstophosphoric Heteropolyacid Supported
15
on Modified SBA-15 as Catalyst in HDS of Thiophene, Micropor. Mater., 122: 128-134 (2009).
16
[16] Luo Y., Hou Z., Li R., Zheng X., Rapid Synthesis of Ordered Mesoporous Silica with the Aid of Heteropoly Acids, Micropor. Mater., 109: 585-590 (2008).
17
[17] Vradman L., Landau M.V., Kantorovich D., Koltypin Y., Gedanken A., Evaluation of Metal Oxide Phase Assembling Mode Inside the Nanotubular Pores of Mesostructured Silica, Micropor. Mater., 79: 307-318 (2009).
18
[18] Kalita P., Gupta N.M., Kumar R., Synergistic Role of Acid Sites In The Ce-Enhanced Activity of Mesoporous Ce–Al-MCM-41 Catalysts in Alkylation Reactions: FTIR and TPD-Ammonia Studies, J. Catal., 245: 338-347 (2007).
19
[19] Chen H., Dai W.L., Deng J.F., Fan K., Novel Heterogeneous W-Doped MCM-41 Catalyst for Highly Selective Oxidation of Cyclopentene to Glutaraldehyde by Aqueous H2O2, Catal. Lett., 81: 131-136 (2002).
20
[20] Xiao T., Wang H., York A.P.E., Williams V.C., Green M.L.H.,Preparation of Nickel–Tungsten Bimetallic Carbide Catalysts, J. Catal., 209: 318-330 (2002).
21
[21] Tayeb K.B., Lamonier C., Lancelot C., Fournier M., Payen E., Bonduelle A., Bertoncini F., Study Of The Active Phase of Niw Hydrocracking Sulfided Catalysts Obtained from an Innovative Heteropolyanion Based Preparation, Catal. Today, 150: 207-212 (2010).
22
[22] Lei Z., Gao L., Shui H., Chen W., Wang Z., Ren S., Hydrotreatment of Heavy Oil from a Direct Coal Liquefaction Process on Sulfided Ni–W/SBA-15 Catalysts, Fuel Process. Technol.,92: 2055-2060 (2011).
23
[23] Ding L., Zheng Y., Zhang Z., Ring Z., Chen J., Hydrotreating of Light Cycle Oil Using Wni Catalysts Containing Hydrothermally and Chemically Treated Zeolite Y, Catal. Today, 125: 229-238 (2007).
24
[24] Salvatl L., Makovsky L.E., Stencel J.M., Brown F.R., Hercules D.M., Surface Spectroscopic Study of Tungsten-Alumina Catalysts Using X-Ray Photoelectron, Ion Scattering, and Raman Spectroscopies, J. Phys. Chem., 85: 3700-3707 (1981).
25
[25] Wan G., Duan A., Zhang Y., Zhao Z., Jiang G., Zhang D., Liu J., Chung K., Niw/AMBT Catalysts for the Production of Ultra-Low Sulfur Diesel, Catal. Today, 158: 521-529 (2010).
26
[26] Lizama L.Y., Klimova T.E., SBA-15 Modified with Al, Ti, or Zr as Supports for Highly Active Niw Catalysts for HDS, J. Mater. Sci., 44: 6617-6628 (2009).
27
[27] Fan Y., Bao X., Wang H., Chen C., Shi G., A Surfactant-Assisted Hydrothermal Deposition Method for Preparing Highly Dispersed W/Γ-Al2O3 Hydrodenitrogenation Catalyst, J. Catal., 245: 477-481 (2007).
28
[28] Saadatjou N., Jafari A., Sahebdelfar S., Synthesis and Characterization of Ru/Al2O3 Nanocatalyst
29
for Ammonia Synthesis, Iran. J. Chem.Chem.Eng. (IJCCE), 34(1): 1-9 (2015).
30
[29] Wei Q., Zhou Y., Wen S., Xu C., Preparation and Properties of Nickel Preimpregnated CYCTS Supports for Hydrotreating Coker Gas Oil, Catal. Today,149: 76-81 (2010).
31
ORIGINAL_ARTICLE
The Conversion Kinetics of Tincal to Boric Acid in Nitric Acid Solutions
Pure borax and various boron compounds are produced from the solutions in which tincal is dissolved with various reagents. Economically important boron compounds such as boric acid, borax, boric oxide, and refined hydrated sodium borates and perborates are produced from boron-containing ores. The production of boric acid by using nitric acid from tincal is more advantageous because it evaluates by-product NaNO3 as fertilizer production. In this study, the conversion kinetics of tincal to boric acid in nitric acid solutions were investigated by such parameters as particle size, 300-1500 µm; acid concentration,0.5-4 mol/L; solid-to-liquid ratio 0.04-0.10 g/mL; stirring speed 20.93-62.8 s-1, and reaction temperature, 30-60 oC. The conversion was found to increase with decreasing particle size and solid-to-liquid ratio and while it increased with increasing reaction temperature, acid concentration, and stirring speed. The conversion kinetics was examined using the heterogeneous and pseudo-homogeneous reaction models. The experimental results were found to be in better agreement with the correlation given in the following equation and the activation energy being 37.5 kJ/mol.
https://ijcce.ac.ir/article_37216_73eff37baf5e576805505e20bb6c126e.pdf
2020-04-01
83
90
10.30492/ijcce.2020.37216
Borax
conversion kinetics
Nitric acid
boric acid
Mehmet
Tunc
m.tunc@yyu.edu.tr
1
Department of Chemistry, Yüzüncüyıl University, Van, TURKEY
AUTHOR
Hasan
irem
hirem@yyu.edu.tr
2
Department of Chemistry, Yüzüncüyıl University, Van, TURKEY
AUTHOR
M. Muhtar
Kocakerim
mkkocakerim@yahoo.com.tr
3
Department of Chemical Engineering, Engineering Faculty, Çankırı Karatekin University, Çankırı, TURKEY
AUTHOR
Mehmet
Copur
mehmet.copur@btu.edu.tr
4
Department of Chemical Engineering, Engineering Faculty, Bursa Teknik University, Bursa, TURKEY
AUTHOR
Özkan
Küçük
okucuk74@hotmail.com
5
Department of Metallurgy and Material Engineering, Engineering Faculty, Bilecik Şeyh Edebali University, TURKEY
LEAD_AUTHOR
[1] Garret D.E., “Borates: Handbook of Deposits, Processing, Properties, and Use”, Academic Press Ltd, New York NY, (1998)
1
[2] Kemp H.P., “The Chemistry of Borates: Part I” Borax Consolidated Ltd., London, (1956)
2
[3] Sınırkaya M., Kocakerim M.M., Boncukçuoğlu R., Küçük Ö., Öncel S., Recovery of Boron from Tincal Wastes, Industrial Engineering Chemistry Research, 44 (3); 427-433 (2005)
3
[4] Celeste M., Azevedo C., Cavaleiro M.V., The Acid–Base Titration of a Very Weak Acid: Boric Acid, Journal of Chemical Education, 89(6): 767-770 (2012).
4
[5] Imamutdinova V.M., Bikchurova A. Kh., Imamutdinova V.M., Bikchurova A. Kh., Kinetics
5
of Dissolving Borates in HNO3 Solutions, Zhurnal Pikladnoi Khimii, 40 (7):1616-1618, (1967).
6
[6] Zdonovskii A.B., Imamutdinova V.M., Rate of Solution of Natural Borates in HCl Solutions, Zhurnal Pikladnoi Khimii, 36 (8): 1675-1680 (1963)
7
[7] Kononova G.N., Nozhko E.S., Nature of the Sulfuric Acid Dissolution of Magnesium Borates, Zhurnal Pikladnoi Khimii, 54(2): 397-399 (1981).
8
[8] Karazhanov N.A., The Kinetics of the Dissolution of Borates and Other Natural Salts, Zhurnal Pikladnoi Khimii, 36(12): 2642-2649 (1963).
9
[9] Imamutdinova V.M., Vladykina A.N., Rate of Decomposition Native Borates in Perchloric Acid Solutions, Zhurnal Pikladnoi Khimii, 42(5): 1172-1175 (1969).
10
[10] Zdanovskii A.B., Biktogirova L.G., Mechanism of Decomposition of Calcium Borates in H3PO4 Solutions, Zhurnal Pikladnoi Khimii, 40 (12): 2659-2663 (1967).
11
[11] Imamutdinova V.M., Abdrashitova N., Rate of Dissolution of Borates in Acetic Acid Solutions, Zhurnal Pikladnoi Khimii, 43 (2): 452-455 (1970).
12
[12] Yeşilyurt M., Determination of the Optimum Conditions for the Boric Acid Extraction from Colemanite Ore in HNO3 Solutions, Chemical Engineering and Processing, 43(10): 1189-1194 (2004).
13
[13] Gülensoy H., Kocakerim M.M., Solubility of Ulexite Mineral in CO2- Containing Water, Bulletin of The Mineral Research and Exploration, 89: 36-41 (1977)
14
[14] Gülensoy H., Kocakerim M.M., Solubility of Colemanite Mineral in CO2-Containing Water and Geological Formation of This Mineral, Bulletin of The Mineral Research and Exploration, 90: 19 (1978).
15
[15] Yapıcı S., Kocakerim M.M., Künkül A., Optimization of production of H3BO3 from ulexite, Turkish Journal of Engineering and Environmental Sciences, 18: 91-94 (1990).
16
[16] Künkül A., Yapıcı., Kocakerim M.M., Çopur M., Dissolution Kinetics of Ulexite in Ammonia Solutions Saturated with CO2, Hydrometalurgy, 44: 135-145 (1997).
17
[17] Kocakerim M.M., Alkan., Dissolution Kinetics of Colemanite in SO2-Saturated Water, Hydrometallurgy, 19: 385-392 (1988)
18
[18] Özmetin C., Kocakerim M.M., Yapıcı., Yartaşı A., Semiempirical Kinetic Model for Dissolution of Colemanite in Aqueous CH3COOH Solutions, Industrial Engineering Chemistry Research, 35 (7): 2355-2359 (1996).
19
[19] Tunç M., Yapıcı S., Kocakerim M.M., Yartaşı A., The Dissolution Kinetics of Ulexite in Sulfuric Acid Solutions, Chemical and Biochemical Engineering Quarterly, 15(4): 175-180 (2001).
20
[20] Tunç M., Kocakerim M.M., Gür A., Yartaşı A.,
21
A Semiempirical Kinetic Model for Dissolution of Ulexite in Aqueous Acetic Acid Solutions, Energy, Education, Science and Techonology, 3(1): 1-10 (1999)
22
[21] Tunç M., Gür A., Kocakerim M.M., Yartaşı A., Dissolution of Ulexite in Sulfuric Acid Solutions for High Solid-to-Liquid Ratios, Energy, Education, Science and Technology, 3(1): 32-41 (1999).
23
[22] Künkül A., Tunç M., Yapıcı S., Erşahan H., Kocakerim M.M., Dissolution of thermally dehydrated ulexite in sulfuric acid solution, Industrial Engineering Chemistry Research, 36; 4847-4851 (1997)
24
[23] Tunc M., Kocakerim M.M., Yapıcı S., Bayrakçeken S., Dissolution mechanism of ulexite in H2SO4 solution, Hydrometallurgy, 51; 359-370 (1999)
25
[24] Tunç M., Çelik C., Çolak S., Kocakerim M.M., Determination of optimum conditions for dissolution of ulexite in sulfuric acid solutions, Mineral Processing and Extractive Metallurgy, Section C, 108; 48-52 (1999)
26
[25] Tunç M., Mermerci N., Yeşilyurt M., Kocakerim, M.M., Çolak S., Dissolution kinetics of borax in acetic acid solutions, Proceedings of 3rd International boron symposium, 199-202, 02-04 November 2006 Ankara, Turkiye.
27
[26] Tunc M., Kocakerim M.M., Küçük Ö., Aluz M., Dissolution of colemanite in (NH4)2SO4 solutions, Korean Journal of Chemical Engineering, 24(1); 55-59 (2007)
28
[27] Mergen A., Demirhan M.H., Bilen M., Fabrication of boric acid and sodium sulfate from borax, Ceramic Forum International. 81(3); 37-42 (2004)
29
[28] Mergen A., Demirhan M.H., Bilen M., Gündüz M., Production of sodium sulfate as a by-product during boric acid fabrication from borax, Silicates Industrials, 69(11-12); 87-92 (2004)
30
[29] Mergen A., Demirhan M.H., Bilen M., Processing of Boric Acid from Borax by a Wet Chemical Method, Advanced Powder Technology, 14(3); 279-293 (2003)
31
[30] Nezhad B.Z., Direct Production of Crystalline Boric Acid through, Heterogeneous Reaction of Solid Borax with Propionic Acid: Operation and Simulation, The Korean Journal of Chemical Engineering, 21(5); 956-962 (2004)
32
[31] Nezhad B.Z., Monteghian M., Tavare N.S., On the confluence of dissolution, reaction and precipitation: The case of boric acid, Chemical Engineering Science, 51(11); 2547-2552 (1996)
33
[32] Levensipel O., “Chemical Reaction Engineering”, 3rd edition, Jone Wiley & Sons, Inc., New York, 566-586 (1999)
34
[33] Karagölge Z., Alkan M., Kocakerim M.M., Leaching Kinetics of colemanite by aqueous EDTA solutions, Metallurgical Transactions B, 23B; 409-413 (1992)
35
ORIGINAL_ARTICLE
Optimization and Prediction of Reaction Parameters of Plastic Pyrolysis oil Production Using Taguchi Method
Design of Experiments (DoE) is a powerful guiding tool that can help researchers to identify the main variables that affect the performance characteristics. The present paper elaborates on the optimization and prediction of reaction parameters like type of plastic, catalyst, and temperature using Taguchi’s L9 orthogonal array method with three levels and three parameters to obtain the highest yield of plastic oil. To determine the effect of each parameter, the Signal to Noise (S/N) ratio was calculated based on the experiments conducted. In this investigation, contributions of reaction parameters were analyzed by Analysis of Variance (ANOVA) using statistical software Minitab-16. Based on the investigation, the reaction parameters like type of plastic: Low-Density Polyethylene (LDPE), catalyst: Silica alumina (SA), and temperature: 500°C are optimized to get the better yield of oil. Based on the confirmatory trial, the oil yield of about 95.4%, the gas yield of about 3.4%, and solid residue as 1.2% were obtained, which is better than the normal trails.
https://ijcce.ac.ir/article_33965_7552939c5bccd5f3413e51edd94f53fc.pdf
2020-04-01
91
103
10.30492/ijcce.2020.33965
ANOVA
Orthogonal array
Plastic oil
Pyrolysis
Taguchi’s DoE
Gopinath
S
gp.nath4@gmail.com
1
Department of Mechanical Engineering, R M K College of Engineering and Technology, Puduvoyal, Tamil Nadu, 601206 INDIA
LEAD_AUTHOR
Devan
P.K..
pkdevan68@gmail.com
2
Department of Mechanical Engineering, R M K College of Engineering and Technology, Puduvoyal, Tamil Nadu, 601206 INDIA
AUTHOR
[1] Brajendra K. Sharma, Bryan R. Moser, Karl E. Vermillion, Kenneth M. Doll, Nandakishore Rajagopalan, Production, Characterization and Fuel Properties of Alternative Diesel Fuel from Pyrolysis of Waste Plastic Grocery Bags, Fuel Processing Technology, 122: 79-90 (2014).
1
[2] Kiran Raj Bukkarapu, D. Siva Gangadhar, Y. Jyothi, Prasad Kanasani, Management, Conversion, and Utilization of Waste Plastic as a Source of Sustainable Energy to Run Automotive: A Review, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects,40 (14): 1681-1692 (2018).
2
[3] Nisar J., Khan M.S., Iqbal M., Shah A., Ali G., Sayed M., Khan R.A., Shah F., Mahmood T., Thermal Decomposition Study of Polyvinyl Chloride in the Presence of Commercially Available Oxides Catalysts, Advances in Polymer Technology.); 37: 2336–2343 (2018).
3
[4] Khan M.Z.H., Sultana M., Al-Mamun M.R., Hasan M.R., Pyrolytic Waste Plastic Oil and Its Diesel Blend: Fuel Characterization, Journal of Environmental and Public Health, Article ID 7869080, 6 Pages, (2016).
4
[5] Nisar J., Khan M.A., Iqbal M., Shah A., Khan R. A., Sayed M., Mahmood T, Comparative Study of Kinetics of the Thermal Decomposition of Polypropylene Using Different Methods, Advances in Polymer Technology, 37: 1168-1175 (2018).
5
[6] Nisar J., Ali Gh., Ullah N. Ahmad Awan I., Iqbal M., Shah A., Sirajuddin, Sayed M., Mahmood T.,
6
Khan M., Pyrolysis of Waste Tire Rubber: Influence of Temperature on Pyrolysates Yield, Journal of Environmental Chemical Engineering, 6. 3469-3473 (2018).
7
[7] Nisar J., Khan M.S., Khan M.A., Catalytic thermal Decomposition of Polyethylene Determined by Thermogravimetric Treatment, Journal of the Chemical Society of Pakistan, 36(5): 829-836 (2014).
8
[8] Kyong-Hwan Lee, Thermal and Catalytic Degradation of Pyrolytic Oil from Pyrolysis of Municipal Plastic Wastes, Journal of Analytical and Applied Pyrolysis, 85(1–2): 372-379 (2009)
9
[9] Viswanath K. Kaimal, P. Vijayabalan, A Study on Synthesis of Energy Fuel from Waste Plastic and Assessment of its Potential as an Alternative Fuel for Diesel Engines, Waste Management, 51: 91-96 (2016)
10
[10] Chuan Ma, Jie Yu, Ben Wang, Zijian Song, Jun Xiang, Song Hu, Sheng Su, Lushi Sun, Chemical Recycling of Brominated Flame Retarded Plastics from e-Waste for Clean Fuels Production: A Review, Renewable and Sustainable Energy Reviews, 61: 433-450 (2016)
11
[11] Shafferina Dayana Anuar Sharuddin, Faisal Abnisa, Wan Mohd Ashri Wan Daud, Mohamed Kheireddine Aroua, A Review on Pyrolysis of Plastic Wastes, Energy Conversion and Management, 115: 308-326 (2016)
12
[12] Probir Kumar Bose, Madhujit Deb, Rahul Banerjee, Arindam Majumder, Multi Objective Optimization of Performance Parameters of a Single Cylinder Diesel Engine Running with Hydrogen Using a Taguchi-fuzzy Based Approach, Energy, 63: 375-386, (2013)
13
[13] Mustafa Kemal Balki, Cenk Sayin, Murat Sarıkaya, Optimization of the Operating Parameters Based on Taguchi Method in an SI Engine used Pure Gasoline, Ethanol and Methanol, Fuel, 180: 630-637 (2016).
14
[14] Senthilkumar N., Tamizharasan T., Effect of Tool geometry in Turning AISI 1045 steel: Experimental Investigation and FEM Analysis, Arabian Journal for Science and Engineering, 39(6): 4963-4975 (2014).
15
[15] Blazso M. Composition of Liquid Fuels Derived from the Pyrolysis of Plastics. In: Scheirs J, Kaminsky W, (Editors), “Feedstock Recycling and Pyrolysis of Waste Plastics: Converting Waste Plastics into Diesel and other Fuels”, Hungary: John Wiley & Sons Inc., 315-342 (2006).
16
[16] Jasmin Shah, Rasul Jan M., Fazal Mabood, Catalytic Pyrolysis of Waste Tyre Rubber into Hydrocarbons Via Base Catalysts, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 27(2): 103-109 (2008).
17
[17] Buekens A.G., Huang H., Catalytic Plastics Cracking for Recovery of Gasoline-Range Hydrocarbons from Municipal Plastic Wastes, Resources, Conservation and Recycling, 23(3): 163-181 (1998).
18
[18] Imtiaz Ahmad, M. Ismail Khan, Hizbullah Khan, M. Ishaq, Razia Tariq, Kashif Gul & Waqas Ahmad Pyrolysis Study of Polypropylene and Polyethylene Into Premium Oil Products, International Journal of Green Energy, 12 (7): 663-671 (2015)
19
[19] Achyut K. Panda, R.K. Singh, D.K. Mishra, Thermolysis of Waste Plastics to Liquid Fuel: A Suitable Method for Plastic Waste Management and Manufacture of Value Added Products—A World Prospective, Renewable and Sustainable Energy Reviews, 14(1): 233-248 (2010)
20
[20] Sasa V. Papuga, Petar M. Gvero, Ljiljana M. Vukic, Temperature and Time Influence on the Waste Plastics Pyrolysis in the Fixed Bed Reactor, Thermal Science, 20(2): 731-741, (2016),
21
[21] Rinku Verma, K.S. Vinoda, M. Papireddy, A.N.S. Gowda, Toxic Pollutants from Plastic Waste-
22
A Review, Procedia Environmental Sciences, 35: 701-708, (2016)
23
[22] Karabas, Hülya, Biodiesel Production from Crude Acorn (Quercus Frainetto L.) Kernel Oil: an Optimisation Process Using the Taguchi Method. Renewable Energy, 53: 384-388 (2013)
24
[23] Senthilkumar N., Tamizharasan T., Experimental Investigation of Cutting Zone Temperature and Flank Wear Correlation in Turning AISI 1045 Steel with Different Tool Geometries, Indian Journal of Engineering & Materials Sciences, 21(2): 139-148 (2014).
25
[24] Laesecke J., Ellis N., Kirchen P., Production, Analysis and Combustion Characterization of Biomass Fast Pyrolysis Oil – Biodiesel Blends for Use in Diesel Engines, Fuel, 199: 346-357 (2017)
26
[25] Shafferina Dayana Anuar Sharuddin, Faisal Abnisa, Wan Mohd Ashri Wan Daud, Mohamed Kheireddine Aroua, A Review on Pyrolysis of Plastic Wastes, Energy Conversion and Management, 115: 308-326, (2016).
27
ORIGINAL_ARTICLE
Ultrasonic Assisted Synthesis, Characterization and Bioactivity Assessment of Novel Piperonal Based Schiff Base and Its Metal Complexes
A novel Schiff base was synthesized by the reaction of piperonal and anthranilic acid, which was further utilized in the synthesis of five novel complexes by reaction with different metal salts ultrasonically. Time for the reaction was greatly reduced through ultrasound irradiations and the yield of reactions was also high as compared to the conventional methods using reflux conditions. The synthesized Schiff base and its metal complexes were characterized by spectroscopic techniques like UV-Visible, IR, and 1H NMR. The synthesized compounds were tested for their antibacterial and antioxidant activity. Good results were obtained in the case of antibacterial activities.
https://ijcce.ac.ir/article_33369_4aa25fef443d8e30fcaac77152482155.pdf
2020-04-01
105
111
10.30492/ijcce.2020.33369
Schiff Base
Antibacterial
Anti-oxidant
Anthranilic acid
Obaid-Ur-Rahman
Abid
obaid_chem@yahoo.com
1
Department of Chemistry, Hazara University Mansehra, PAKISTAN
LEAD_AUTHOR
Aziz
Ahmad
azizvishal@gmail.com
2
Department of Chemistry, Hazara University Mansehra, PAKISTAN
AUTHOR
Wajid
Rehman
sono_waj@yahoo.com
3
Department of Chemistry, Hazara University Mansehra, PAKISTAN
AUTHOR
Rehmat
Zaman
rehmat_zaman@yahoo.com
4
Department of Biochemistry, Hazara University Mansehra, PAKISTAN
AUTHOR
Mohsin
Ali
mohsinali2030@gmail.com
5
Department of Chemistry, Hazara University Mansehra, PAKISTAN
AUTHOR
Sadullah
Mir
sadullah@ciit.net.pk
6
Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad 22060, PAKISTAN
AUTHOR
Muhammad
Qureshi Tauseef
tauseefqureshi@hotmail.com
7
Department of Physics, Hazara University, Mansehra, PAKISTAN
AUTHOR
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21
ORIGINAL_ARTICLE
Binuclear Nickel(II) Complex Containing 6-Methyl-2,2'-bipyridine and Chloride Ligands: Synthesis, Characterization, Thermal Analyses, and Crystal Structure Determination
A new binuclear complex of [{NiCl(6-mbipy)}2(μ-Cl)2] (1) was prepared from the reaction of NiCl2.6H2O and 6-methyl-2,2'-bipyridine (6-mbipy) in a mixture of methanol and acetonitrile. Suitable crystals of 1 for X-ray diffraction measurement were obtained by slow evaporation of the resulted green solution at room temperature. Complex 1 was characterized by spectral methods (IR, UV–Vis, and luminescence), elemental analysis (CHN), and single-crystal X-ray diffraction. The structure of 1 is centrosymmetric binuclear complex and each Ni(II) cation is five-coordinated in a slightly distorted square-pyramidal configuration. In this binuclear complex, the Ni…Ni distance is 3.533(1)Å. Furthermore, the luminescence emission of the title complex was blue-shifted and is stronger than that of free 6-methyl-2,2'-bipyridine ligand. Thermal stabilities of this complex was also studied by thermogravimetric analysis.
https://ijcce.ac.ir/article_33338_1463eb75eabbe08d80e520d557184109.pdf
2020-04-01
113
122
10.30492/ijcce.2020.33338
Crystal structure
Nickel(II) complex
6-Methyl-2,2'-bipyridine
Luminescence spectroscopy
Thermogravimetric analysis
Vahid
Amani
v_amani2002@yahoo.com
1
Department of Chemistry, Farhangian University, Tehran, I.R. IRAN
LEAD_AUTHOR
Maryam
Zakeri
maryam_zakeri@ymail.com
2
Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
Roya
Ahmadi
roya_ahmadi_chem@yahoo.com
3
Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
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2
[3] Huang C., Zeng Y., Flisak Z., Zhao Z., Liang T., Sun W.H., Tailoring Polymers Through Interplay
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of Ligands within Precatalysts: 8-(Nitro/benzhydryl-arylimino)-7,7- dimethyl -5,6- dihydroquinolylnickel Halides in Ethylene Polymerization, J. Polym. Sci. Part A:Polym. Chem., 55(12): 2071-2083 (2017).
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[(phen)2Cu(μ-tda)Cu(phen)](ClO4)2.1.5H2O. Iran. J. Chem. Chem. Eng. (IJCCE), 33(4): 1-13
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of a Novel di-μ-chlorobis [chloro(2,9-dimethyl-1,10-phenanthroline) nickel(II)] Complex: Synthesis,
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and Spectral and Thermal Studies, Res. Chem. Intermed., 39(9): 4011-4020 (2013).
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59
ORIGINAL_ARTICLE
Characterization of Microbubble-Based Drilling Fluids: Investigating the Role of Surfactants and Polymers
Colloidal Gas Aphrons (CGA), consist of gas bubbles with diameters ranging from 10 to 100 micron, surrounded by a thin aqueous surfactant film. This fluid combines certain surfactants and polymers to create the systems of microbubbles. The function of surfactant in CGAs is to produce the surface tension to contain the aphrons. Also, a biopolymer needs to be considered in the formulation as a viscosifier as well as a stabilizer. The aphron-laden fluid appears to be particularly well suited for drilling through depleted zones. The unique feature of aphron based fluids is to form a solid free, tough, and elastic internal bridge in pore networks or fractures to minimize deep invasion using air microbubbles. This microenvironment seal readily cleans up with reservoir flow back as production is initiated, thereby reducing the cost associated with stimulation processes. This paper presents a comprehensive, comparative study of rheological behavior and filtration properties of CGA based drilling fluids with various concentrations of polymer and surfactant. Laboratory evaluations showed that the CGA based fluid is one of the ideal engineering materials which can control and kill the loss circulation, save cost and increase productivity in which rheological characteristics and filtration properties of them are greatly influenced by the level of polymer and surfactant concentration.
https://ijcce.ac.ir/article_39790_2cf04102d804dc2e3375c1f28b6cf25e.pdf
2020-04-01
123
131
10.30492/ijcce.2020.39790
Colloidal gas aphron
Microbubble
Shear-thinning
biopolymer
rheology
microscopy
Hamid Reza
Poorabbasi
hamidreza.poorabbasi@modares.ac.ir
1
Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
LEAD_AUTHOR
Mehrdad
Manteghian
manteghi@modares.ac.ir
2
Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
AUTHOR
Hormoz
Ghalavand
ghalavand.h.nioc@gmail.com
3
Exploration Directory, National Iranian Oil Company, Tehran, I.R. IRAN
AUTHOR
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[2] Lye G.J., Stuckey D.C., Structure and Stability of Colloidal Liquid Aphrons, Colloids and Surfaces,
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A: Physicochemical and Engineering Aspects, 131: 119-136 (1998).
3
[3] Deng T., Dai Y., Wang J., A New Kind of Dispersion—Colloidal Emulsion Aphrons, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 266: 97-105 (2005).
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[4] Brookey T., " Micro-Bubbles: New Aphron Drill-In Fluid Technique Reduces Formation Damage in Horizontal Wells”, in: SPE Formation Damage Control Conference, Lafayette, Louisiana, (1998).
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[5] Ivan C.D., Quintana J.L., Blake L.D., “Aphron-Base Drilling Fluid: Evolving Technologies for Lost Circulation Control”, in: SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, (2001).
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[6] Ramirez F., Greaves R., Montilva J., “Experience Using Microbubbles-Aphron Drilling Fluid in Mature Reservoirs of Lake Maracaibo”, in: International Symposium and Exhibition on Formation Damage Control, Lafayette, Louisiana, (2002).
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[8] White C., Adrian P., Ivan C., Maikranz S., Nouris R., “Aphron-Based Drilling Fluid: Novel Technology for Drilling Depleted Formations in the North Sea”, in: SPE/IADC Drilling Conference, Amsterdam, Netherlands, (2003).
9
[9] Gregoire M., Hilbig N., Stansbury M., Al-Yemeni S., “Drilling Fractured Granite in Yemen with Solids-Free Aphron Fluid”, in: IADC World Drilling, Rome, (2005).
10
[10] Ivan C., Growcock F., Friedheim J., “Chemical and Physical Characterization of Aphron-Based Drilling Fluids”, in: SPE Annual Technical Conference and Exhibition, San Antonio, Texas, (2002).
11
[11] Growcock F., Belkin A., Fosdick M., Irving M., O'Connor B., Brookey T., “Recent Advances
12
in Aphron Drilling Fluids”, in: IADC/SPE Drilling Conference, Miami, Florida, USA, (2006).
13
[12] Growcock F., “Enhanced Wellbore Stabilization and Reservoir Productivity with Aphron Drilling Fluid Technology”, Final Report, DPE Award Number DEFC26- 03NT42000, in, (2005).
14
[13] Bjorndalen N., Kuru E., Physico-Chemical Characterization of Aphron-Based Drilling Fluids, Journal of Canadian Petroleum Technology, 47:43-49 (2008).
15
[14] Spinelli L.S., Neto G.R., Freire L.F.A., Monteiro V., Lomba R., Michel R., Lucas E., Synthetic-Based Aphrons: Correlation between Properties and Filtrate Reduction Performance, Colloids and Surface,s
16
A: Physicochemical and Engineering Aspects, 353: 57-63 (2010).
17
[15] Arabloo M., Pordel Shahri M., Zamani M., “Preparation and Characterization of Colloidal Gas Aphron based Drilling Fluids Using a Plant-based Surfactant”, in: SPE Saudi Arabia Section Technical Symposium and Exhibition, Al-Khobar, Saudi Arabia, (2012).
18
[16] Tehrani A., Behaviour of Suspensions and Emulsions in Drilling Fluids, Annual Transactions-Nordic Rheology Society, 15: 17-28(2007).
19
[17] Weir I., Bailey W., A Statistical Study of Rheological Models for Drilling Fluids, SPE Journal, 1: 473-486 (1996).
20
[18] Davison J., Clary S., Saasen A., Allouche M., Bodin D., Nguyen V.A., “Rheology of Various Drilling Fluid Systems under Deepwater Drilling Conditions and the Importance of Accurate Predictions of Downhole Fluid Hydraulics”, in: SPE Annual Technical Conference and Exhibition, Houston, Texas, (1999).
21
[19] Navarrete R.C., Dearing H.L., Constien V.G., Marsaglia K.M., Seheult J.M., Rodgers P.E., Experiments in Fluid Loss and Formation Damage with Xanthan-Based Fluids While Drilling, in: IADC/SPE Asia Pacific Drilling Technology, Kuala Lumpur, Malaysia, (2000).
22
[20] Caenn R., Chillingar G.V., Drilling Fluids: State of the Art, Journal of Petroleum Science and Engineering, 14: 221-230 (1996).
23
[21] M'Bodj O., Ariguib N.K., Ayadi M.T., Magnin A., Plastic and Elastic Properties of the Systems Interstratified Clay–Water–Electrolyte–Xanthan, Journal of Colloid and Interface Science, 273:
24
675-684 (2004).
25
[22] Salamone J.C., Clough S.B., Jamison D.E., Reid K.I.G., Salamone A.B., Xanthan Gum-a Lyotropic, Liquid Crystalline Polymer and Its Properties as a Suspending Agent, SPE Journal, 22 (1982).
26
[23] Arabloo M., Shahri M.P., Zamani M., Characterization of Colloidal Gas Aphron-Fluids Produced from a New Plant-Based Surfactant, Journal of Dispersion Science and Technology, 34: 669-678 (2012).
27
ORIGINAL_ARTICLE
Promotion of the Cupellation Method for Accurate Determination of Gold Alloy’s Karat Containing Platinum-Group Metals
The main standard method for gold karat determination is the cupellation method. However, this method is not sufficiently accurate to determine gold karat in the presence of insoluble Platinum–Group Metals (PGMs), such as Ir, Ru, and Rh. In this study, for the first time, a complementary method that can be used coupled with the reference cupellation method is presented for the highly accurate determination of gold karat containing PGMs. According to this method, gold metal was separated from the PGMs by dissolving parted cornets in aqua regia and then, its selective precipitation using an aqueous solution of SO2 gas as a reducing agent. The gold amount in alloys containing PGMs was determined using the suggested strategy with an excellent recovery, high accuracy (average relative error=0.12%) and precision (SD=0.6 for n=3). The optimized volume of aqueous SO2 solution was 35 mL that provides a gold recovery as high as 99.7% with enough big grain size and high purity (999.0‰). The proposed strategy was successfully used to determine the gold amount in secondary gold jewelry containing Ir, Rh, and Ru (a gold recovery of 99.9% with a relative error of 0.07 was obtained). The obtained karat was comparable with the other methods. Accordingly, the proposed method will be a promising simple and available assay for gold alloys containing PGMs, which could be used routinely in most cupellation labs all over the world.
https://ijcce.ac.ir/article_33689_d537299fd2753d79392206dc9d390a46.pdf
2020-04-01
133
143
10.30492/ijcce.2020.33689
Cupellation method
Platinum-group metals
Gold karat
Gold alloys
Farahnaz
Rejali
isiri.tc174@gmail.com
1
Department of Chemistry, Isfahan University of Technology, Isfahan, I.R. IRAN
AUTHOR
Behzad
Rezaei
rezaei@cc.iut.ac.ir
2
Department of Chemistry, Isfahan University of Technology, Isfahan, I.R. IRAN
LEAD_AUTHOR
[1] Kloos D., Analysis of Gold Karat Alloys Using Proportional Counter Based Micro-EDXRF, [in] Proceedings of the Proceedings of the 24 th International Precious Metal Conference, (2000).
1
[2] ISO 11426:2014, Jewellery-Determination of Gold in Gold Jewellery Alloys-Cupellation Method (Fire Assay), ISO (2019).
2
[3] Haffty J., Riley L. B., Goss W. D., "Manual on Fire Assaying And Determination of the Noble Metals
3
in Geological Materials", Edited, United States Government Printing Office, Washington (1977).
4
[4] Raykhtsaum G., "Platinum Alloys", [in] Proceedings of the The Santa Fe Symposium on Jewelry Manufacturing Technology, 489-503 (2012).
5
[5] Maerz J., Platinum alloys: "Features and Benefits", [in] Proceedings of the The Santa Fe Symposium
6
on Jewelry Manufacturing Technology, 303-312 (2005).
7
[6] Raw P., "The Assaying and Refining of Gold, a Guide for the Gold Jewellery Producer", Edited, (1997).
8
[7] Corti B., "Assaying of Gold Jewelry-Ancient and Modern", [in] Proceedings of the The Santa Fe Symposium on Jewelry Manufacturing Technology, 49-70, (2001).
9
[8] Stankiewicz W., Bolibrzuch B. Marczak M., Gold and Gold Alloy Reference Materials tor XRF Analysis, Gold Bull., 31(4):119-125 (1998).
10
[9] ISO11596, Jewellery - Sampling of Precious Metal Alloys for and in Jewellery and Associated Products, (2008).
11
[10] Beamish F. E., "The Analytical Chemistry of the Noble Metals", Edited, Elsevier, (2013).
12
[11] Ott D., Raub C.J., Grain Sze of Gold and Gold Alloys, Gold Bull., 14(2): 69-74 (1981).
13
[12] McIntosh K.S., "The Systems Engineering of Automated Fire Assay Laboratories for the Analysis of the Precious Metals", University of Stellenbosch, South Africa, (2004).
14
[13] Rao C. Reddi G., Platinum Group Metals (PGM); Occurrence, Use and Recent Trends in their Determination, TrAC, Trends Anal. Chem., 19(9): 565-586 (2000).
15
[14] Syed S., Recovery of Gold from Secondary Sources—A Review, Hydrometallurgy, 115 (2012).
16
[15] Corti C.W., "Recovery and Refining of Gold Jewellery Scraps and Wastes", [in] Proceedings of the The Santa Fe Symposium on Jewelry Manufacturing Technology, 1-20 (2002).
17
[16] Beamish F., Russell J. Seath J., The Determination of Gold, Industrial & Engineering Chemistry Analytical Edition, 9(4) (1937).
18
ORIGINAL_ARTICLE
Activity Coefficients of NaClO4 in (PEG 4000 + H2O) Mixtures at (288.15, 298.15 and 308.15) K
The cell potential of the cell containing two ion-selective electrodes (ISE), Na-ISE | NaClO4 (m), PEG 4000 (Y), H2O (100-Y) | ClO4-ISE has been measured at temperatures of (288.15, 298.15, and 308.15) K as a function of the weight percentage Y of PEG 4000 in a mixed solvent at a 1 Mpa and the standard state for measured activity coefficients will be a solution of the salt in pure water. Y was varied between (0 and 25) wt.% in five-unit steps and the molality of the electrolyte (m) was between 0.05 mol kg-1 and almost saturation. The values of the standard cell potential were calculated using routine methods of extrapolation together with extended Debye-Hückel and Pitzer equations. The results obtained produced good internal consistency for all the temperatures studied. Once the standard electromotive force was determined, the mean ionic activity coefficients for NaClO4, the Gibbs energy of transfer from the water to the PEG 4000-water mixture, and the primary NaCl hydration number were calculated.
https://ijcce.ac.ir/article_33284_bfffe32d36496b028ae544900c1936e4.pdf
2020-04-01
145
157
10.30492/ijcce.2020.33284
NaClO4
PEG 4000
cell potential
Ion-selective electrode
Activity Coefficient
Jaime W.
Morales
jaime.morales@pucv.cl
1
Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, CHILE
LEAD_AUTHOR
Hector R.
Galleguillos
hector.galleguillos@uantof.cl
2
Departamento de Ingeniería Química y Procesos de Minerales, CICITEM, Universidad de Antofagasta, CHILE
AUTHOR
Felipe
Hernández-Luisc
ffhelu@ull.edu.es
3
Departamento de Química, Facultad de Ciencias, Universidad de La Laguna, Tenerife, Islas Canarias, ESPAÑA
AUTHOR
Raquel
Rodríguez-Raposoc
rrraposo@ull.edu.es
4
Departamento de Química, Facultad de Ciencias, Universidad de La Laguna, Tenerife, Islas Canarias, ESPAÑA
AUTHOR
[1] Willauer H.D., Huddleston J.G., Rogers R.D., Solute Partitioning in Aqueous Biphasic Systems Composed of Polyethylene Glycol and Salt: The Partitioning of Small Neutral Organic Species. Ind. Eng. Chem. Res. 41(7): 1892-1904, (2002).
1
[2] Rogers R.D., Eiteman M.A., “Aqueous Biphasic Separations: Biomolecules to Metal Ions”, Plenum Press, New York, (1995).
2
[3]Sadeghi R., Ziamajidi F., Water Activities of Ternary Mixtures of Poly(ethylene glycol), NaCl and Water over the Temperature Range of 293.15 K to 313.15 K, J. Chem. Thermodyn. 38(11): 1335-1343, (2006).
3
[4] Jayapal M., Regupathi I., Murugesan T., Liquid−Liquid Equilibrium of Poly(ethylene glycol) 2000 + Potassium Citrate + Water at (25, 35, and 45) °C, J. Chem. Eng. Data. 52(1): 56-59, (2007).
4
[5] Perumalsamy M., Bathmalakshmi A., Murugesan T., Experiment and Correlation of Liquid−Liquid Equilibria of an Aqueous Salt Polymer System Containing PEG6000 + Sodium Citrate. J. Chem. Eng. Data. 52(4): 1186-1188, (2007).
5
[6] Moura de Oliveira R., Reis Coimbra J.S., Minim L.A., Mendes L-H., Ferreira M.P., Liquid–Liquid Equilibria of Biphasic Systems Composed of Sodium Citrate + Polyethylene(glycol) 1500 or 4000 at Different Temperatures. J. Chem. Eng. Data. 53(4): 895-899 (2008).
6
[7] Pellegrini L., Fernández C., Picó G., Nerli V., Liquid–Liquid Equilibrium Phase Diagrams of Polyethyleneglycol + Sodium Tartrate + Water Two-Phase Systems. J. Chem. Eng. Data. 53(5): 1175-1178, (2008).
7
[8] Alves J.G., Brenneisen J., Ninni L., Meirelles A.J., Maurer G., Aqueous Two-Phase Systems of Poly(ethylene glycol) and Sodium Citrate: Experimental Results and Modeling. J. Chem. Eng. Data. 53(7): 1587-1594, (2008).
8
[9]Zafarani-Moattar M.T., Hamzehzadeh S., Hosseinzadeh S., Phase Diagrams for Liquid-Liquid Equilibrium of Ternary Poly(Ethylene Glycol) + Di-Sodium Tartrate Aqueous System and Vapor-Liquid Equilibrium of Constituting Binary Aqueous Systems at T=(298.15, 308.15, and 318.15)K. Experiment and Correlation. Fluid Phase Equilib. 268(1-2): 142-152, (2008).
9
[10] Mohsen-Nia M., Rasa H., Modarress H., Liquid-Liquid Equilibria for the Poly(Ethylene Glicol) + Water + Copper Sulfate System at Different Temperatures, J. Chem. Eng. Data, 53(4):946-949 (2008).
10
[11] Moura de Oliveira R., dos Reis Coimbra J.S., Francisco K.R., Minim L.A., Mendes L.H., Marques J.A., Liquid−Liquid Equilibrium of Aqueous Two-Phase Systems Containing Poly(ethylene) Glycol 4000 and Zinc Sulfate at Different Temperatures, J. Chem. Eng. Data. 53(4): 919-922, (2008).
11
[12] Martins J.P., Carvalho C.P., da Silva L.H.M., Coimbra J.S.R., da Silva M.C.H., Rodrigues G.D., Minim L.A., Liquid-Liquid Equilibria of an Aqueous Two-Phase System Containing Poly(Ethylene) Glicol 1500 and Sulfate Salts at Different Temperatures. J. Chem. Eng. Data., 53(1):238-241, (2008).
12
[13] Amaresh S.P., Murugesan S., Regupathi I., Murugesan T., Liquid-Liquid Equilibrium of Poly(Ethylene Glycol) 4000 + Diammonium Hydrogen Phosphate + Water at Different Temperatures,
13
J. Chem. Eng. Data., 53(7): 1574-1578 (2008).
14
[14] Graber T.A., Medina H., Galleguillos H.R., Taboada M.E., Phase Equilibrium and Partition of Iodide in an Aqueous Biphasic System Formed by (NH4)2SO4 + PEG + H2O at 25 °C, J. Chem. Eng. Data, 52(4):1262-1267, (2007).
15
[15]Yankov D.S., Martin J.P., Yordanov B.Y., Stateva R.P., Influence of Lactic Acid on the Formation of Aqueous Two-Phase Systems Containing Poly(ethylene glycol) and Phosphates, J. Chem. Eng. Data, 53(6): 1309-1315, (2008).
16
[16] Silvério S.C., Madeira P.P., Rodríguez O., Teixeira J.A., Macedo E.,A., ΔG(CH2) in PEG−Salt and Ucon−Salt Aqueous Two-Phase Systems, J. Chem. Eng. Data, 53(7): 1622-1625 (2008).
17
[17]Castro B.D., Aznar M., Liquid-Liquid Equilibrium of Water + PEG 8000 + Magnesium Sulfate or Sodium Sulfate Aqueous Two-Phase Systems at 35°C: Experimental Determination and Thermodynamic Modeling, Braz. J. Chem. Eng., 22(3): 463-470 (2005).
18
[18] Graber T.A., Taboada M.E., Cartón A., Bolado S., Liquid−Liquid Equilibrium of the Poly(ethylene glycol) + Sodium Nitrate + Water System at 298.15 K, J. Chem. Eng. Data, 45(2): 182-269 (2000).
19
[19] Silva R.M., Minim L.A., Coimbra J.S., Garcia E.E., da Silva L.H., Rodriguez V.P., Density, Electrical Conductivity, Kinematic Viscosity, and Refractive Index of Binary Mixtures Containing Poly(ethylene glycol) 4000, Lithium Sulfate, and Water at Different Temperatures. J. Chem. Eng. Data, 52(5): 1567-1570 (2007).
20
[20] Sadeghi R.A., A Modified Wilson Model for the Calculation of Vapour + Liquid Equilibrium of Aqueous Polymer + Salt Solutions, J. Chem. Thermodyn., 37(4): 323-329 (2005).
21
[21] Morales J.W., Galleguillos H.R., Taboada M.E., Hernández-Luis F., Activity Coefficients of NaCl en PEG 4000 + Wáter Mixtrures at 288.15, 298.15 and 308.15 K, Fluid Phase Equilib., 281(2):120-126 (2009).
22
[22] Hernández-Luis F., Rodriguez-Raposo R., Galleguillos H.R., Morales J.W., Activity Coefficients of KCl in PEG 4000 + Water mixtures at 288.15, 298.15 and 308.15 K, Fluid Phase Equilib. 295(2): 163-171 (2010).
23
[23] Morales J.W., Galleguillos H.R., Hernández-Luis F., Activity coefficients of LiCl in (PEG4000 + Wáter) at T = (288.15, 298.25, and 308.15) K, J.Chem. Thermodyn., 42(10): 1255-1260 (2010).
24
[24] Hernández-Luis F., Morales J.W., Graber T.A., Galleguillos, H. R. Activity coefficients of NaNO3 in Poly(ethylene glycol) 4000 + Water Mixtures at (288.15, 298.15, and 308.15) K, J. Chem. Eng. Data. 55(9): 4082-4087, (2010).
25
[25] Morales J.W., Galleguillos H.R., Hernández-Luis F., Activity Coefficients of NaBF4 in PEG4000 + Water Mixtures at (288.15, 298.15, and 308.15) K, J. Chem. Eng. Data, 57(2): 500-506, (2012).
26
[26] Morales J.W., Galleguillos H.R., Hernández-Luis F., Rodriguez-Raposo R., Activity Coefficients of NaClO4 in Aqueous Solution, J. Chem. Eng. Data, 56(8): 3449-3453 (2011).
27
[27] Hernández-Luis F., Amado-González E., Esteso M.A., Activity Coefficients of NaCl in Trehalose−Water and Maltose−Water Mixtures at 298.15 K. Carbohydr. Res., 338(13):1415-1424, (2003).
28
[28] Hernández-Luis F., Vázquez M.V., Esteso M.A., Activity Coefficients for Naf In Methanol-Water and Ethanol-Water Mixtures At 25 °C, J. Mol. Liq. 108(1-3): 283-301, (2003).
29
[29] Hernández-Luis F., Grandoso D., Lemus M., Activity Coefficients of NaCl in Fructose + Water at 298.15 K, J. Chem. Eng. Data. 49(3): 668-674, (2004).
30
[30] Hernández-Luis F., Galleguillos H.R., Vázquez M.V., Activity Coefficients of NaF in (Glucose + Water) and (Sucrose + Water) Mixtures at 298.15 K, J. Chem. Thermodyn. 36(11): 957-964, (2004).
31
[31]Hernández-Luis F., Galleguillos H.R., Esteso M.A., Activity Coefficients of Naf in Aqueous Mixtures with Ɛ-Increasing Co-Solvent: Formamide–Water Mixtures at 298.15 K, Fluid Phase Equilib., 227(2):245-253, (2005).
32
[32] Hernández-Luis F., Galleguillos H.R., Graber T.A., Taboada M.E., Activity Coefficients of LiCl in Ethanol-Water Mixtures at 298.15 K, Industrial & Engineering Chemistry Research, 47(6): 2056-2062 (2008).
33
[33] Hernández-Luis F., Galleguillos H.R., Fernández-Mérida L., González-Díaz O., Activity Coefficients of Nacl in Aqueous Mixtures with Ɛ-Increasing Co-Solvent: Formamide–Water Mixtures at 298.15 K, Fluid Phase Equilibria, 275(2): 116-126 (2009).
34
[34] Hamer W.J., Wu Y.C., Osmotic Coefficients and Mean Activity Coefficients of Uni‐Univalent Electrolytes in Water At 25° C, Journal of Physical and Chemical Reference Data, 1(4):1047-1099(1972).
35
[35] Pitzer K. S., “Ion Interaction Approach: Theory and Data Correlation. In Activity Coefficients in Electrolyte Solutions”, Pitzer, K. S. (Ed.), CRC Press, Boca Raton, Florida, (1991).
36
[36] Martell A.E., Smith R.M., “Critical Stability Constants”, Plenum Press. New York, (1974).
37
[37] Delahay, P., “Double Layer and Electrode Kinetics”, John Wiley Sons, Inc., New York, (1965).
38
[38] Goodisman J., “Electrochemistry: Theoretical Foundations”, John Wiley Sons, Inc., New York, (1987).
39
[39] Skoog D.A., Holler F.J., Nieman T.A., “Principles of Instrumental Analysis”, Saunders College Publishing: Philadelphia, (1992).
40
[40] Hitchcock D.I., The Extrapolation of Electromotive Force Measurements to Unit Ionic Activity, Journal of the American Chemical Society, 50(8): 2076-2079 (1928).
41
[41] Robinson R.A., Stokes R.H., “Electrolyte Solutions”, Dover Publications, Inc., Mineola, New York, (2002).
42
[42] Krestov G.A., “Thermodynamics of Salvation: Solution and Dissolution; Ions and Solvents; Structure and Energetics”; Ellis Horwood Limited: Chichester, (1991).
43
[43] Bjerrum N., “Untersuchungen Über Ionenassoziation, VII”, Det. Kgl. Danske Videnskab Selsk 7: 1-48, Køenhavn (1926
44
ORIGINAL_ARTICLE
Microwave Assisted Appraisal of Neem Bark Based Tannin Natural Dye and its Application onto Bio-mordanted Cotton Fabric
The current study is aimed to utilize the microwave for isolation of colorant from neem bark and its application onto chemical & bio-mordanted cotton fabric. For the purpose, aqueous, acid and organic media have been employed to isolate the colorant and to make its application onto surface modified and bio-mordanted cotton fabric followed by microwave treatment up to 6min. It is found that using optimum extraction and dyeing conditions, acceptable fastness properties have been rated when 9% of Al & Fe, 7% of tannic acid as pre chemical, 7% of acacia, 9% of henna, 7% of pomegranate & 5% of turmeric extract as pre bio mordants. Similarly, 5% of Al, 9% of T.A, 7% of pomegranate, and turmeric extract as post-mordants have been employed. It is recommended that isolation of colorant & dyeing under MW treatment has not only improved the natural dyeing process but also the addition of herbal-based bio-mordants have made the dyeing process more sustainable & ayurvedic. So it is concluded that microwave treatment has not only explored the coloring potential of neem bark but also made possible use of bio-mordants for making process more green with excellent color characteristics under reduced optimal conditions.
https://ijcce.ac.ir/article_34225_e4ba1feb10bb2219b395be7e7383f38a.pdf
2020-04-01
159
170
10.30492/ijcce.2020.34225
Bio-Mordant
Cotton
Microwave Radiation
Neem Bark
Tannin
Shahid
Adeel
shahidadeel@gcuf.edu.pk
1
Department of Applied Chemistry, Government College University Faisalabad, Faisalabad 38000, PAKISTAN
AUTHOR
Fazal-Ur
Rehman
furminhas@gcuf.edu.pk
2
Department of Applied Chemistry, Government College University Faisalabad, Faisalabad 38000, PAKISTAN
LEAD_AUTHOR
Muhammad
Kaleem Khosa
mkhosapk@yahoo.com
3
Department of Chemistry, Government College University Faisalabad, 38000, PAKISTAN
AUTHOR
Tahira
Anum
tahiraanum6@gmail.com
4
Department of Chemistry, Government College University Faisalabad, 38000, PAKISTAN
AUTHOR
Muhammad
Shahid
mshahiduaf@yahoo.com
5
Department of Biochemistry, University of Agriculture Faisalabad 38000, PAKISTAN
AUTHOR
Khalid
Mahmood Zia
drkmzia@gcuf.edu.pk
6
Department of Chemistry, Government College University Faisalabad, 38000, PAKISTAN
AUTHOR
Mohammad
Zuber
mohammadzuber@gmail.com
7
The University of Lahore, Lahore Punjab, PAKISTAN
AUTHOR
[1] Haddar W., Baaka N., Meksi N., Elksibi I., Mhenni M.F., Optimization of an Ecofriendly Dyeing Process Using the Wastewater of the Olive Oil Industry as Natural Dyes for Acrylic Fibers, J. Clean. Prod., 66: 546-554 (2014a).
1
[2] Mongkholrattanasit R., Saiwan C., Rungruangkitkrai N., Punrattanasin N., Sriharuksa K., Klaichoi C., Nakpathom M., Eco-Dyeing of Silk Fabric with Garcinia dulcis (Roxb.) Kurz Bark as a Source of Natural Dye by Using the Padding Technique, J. Nat. Fiber., 13(1): 65-76 (2016).
2
[3] Samanta A.K., Agarwal P., Datta S., Studies on Color Interaction Parameters and Color Fastness Properties for Dyeing of Cotton Fabrics with Binary Mixtures of Jackfruit Wood and Other Natural Dyes, J. Nat. Fiber., 6(2): 171-190 (2009).
3
[4] Mansour R., Ezzili B., Farouk M., The Use of Response Surface Method to Optimize the Extraction of Natural Dye from Winery Waste in Textile Dyeing, J. Text. I., 108(4): 528-537 (2017).
4
[5] Khan M.A., Islam S., Mohammad F., Extraction of Natural Dye from Walnut Bark and its Dyeing Properties on Wool Yarn, J. Nat. Fiber., 13(4): 458-469 (2016).
5
[6] Bukhari M.N., Islam S., Shabbir M., Rather L.J., Shahid M., Khan M.A., Mohammad F., Effect of Binary and Ternary Combination of Metal Salt Mordants on Dyeing and Fastness Properties of Natural Protein Fiber with Juglans regia L. Dye, J. Nat. Fiber., 14(4): 519-529 (2017).
6
[7] Haddar W., Elksibi I., Meksi N., Mhenni M.F., Valorization of the Leaves of Fennel (Foeniculum vulgare) as Natural Dyes Fixed on Modified Cotton: A Dyeing Process Optimization Based on a Response Surface Methodology, Ind. Crop Prod., 52: 588-596 (2014b).
7
[8] Ibrahim N.A., El-Gamal A.R., Gouda M., Mahrous F., A New Approach for Natural Dyeing and Functional Finishing of Cotton Cellulose, Carbohyd. Polym., 82(4): 1205-1211 (2010).
8
[9] Jose S., Gurumallesh P.H., Ammayappan L., Eco-Friendly Dyeing of Silk and Cotton Textiles Using Combination of Three Natural Colorants, J. Nat. Fiber., 14(1): 40-49 (2017).
9
[10] Haji A., Qavamnia S.S., Response Surface Methodology Optimized Dyeing of Wool with Cumin Seeds Extract Improved with Plasma Treatment, Fiber. Polym., 16(1): 46-53 (2015).
10
[11] Mohsin M., Farooq A., Ashraf U., Ashraf M.A., Abbas N., Sarwar N., Performance Enhancement of Natural Dyes Extracted from Acacia Bark Using Eco-friendly Cross-linker for Cotton, J. Nat. Fiber., 13(3): 374-381 (2016).
11
[12] Shabbir M., Rather L.J., Bukhari M.N., Shahid M., Khan M.A., Mohammad F., An Eco-friendly Dyeing of Woolen Yarn by Terminalia chebula Extract with Evaluations of Kinetic and Adsorption Characteristics, J. Adv Res., 7(3): 473-482 (2016).
12
[13] Adeel S., Rafi S., Mustaan M.A., Salman M., Ghaffar A., Animal Based Natural Dyes: A Short Review, Handbook of Renewable Materials for Coloration and Finishing, John Wiley & Sons- Scrivener Publishing LLC, USA, 43-74 (2018a).
13
[14] Haddar W., Ben Ticha M., Meksi N., Guesmi A., Application of Anthocyanins as Natural Dye Extracted from Brassica oleracea L. var. capitata f. rubra: Dyeing Studies of Wool and Silk Fibers, Nat. Prod. Res., 32(2): 141-148 (2018).
14
[15] Haji A., Mehrizi M.K., Sharifzadeh J., Dyeing of Wool with Aqueous Extract of Cotton Pods Improved by Plasma Treatment and Chitosan: Optimization Using Response Surface Methodology, Fiber. Polym., 17(9): 1480-1488 (2016).
15
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Using Polyvinyl Alcohol, part-II: Colorfastness Properties, Carbohyd. Polym., 87(4): 2439-2446 (2012).
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on Color Properties of Wool Fabric Dyed with Shrimp Shell Extract, J. Text. I., 107(10): 1314-1321 (2016).
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and Dendrimer: Effects on Dyeing with Cochineal, Int. J. Biolo. Macromol., 107: 642-653 (2017).
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41
[38] Patil N.N., Shukla S.R., Degradation of Using Microwave and Conventional Heating, J. Water Process Eng.,7:314-327 (2015).
42
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[42] Adeel S., Zia K.M., Abdullah M., Rehman F.U., Salman M., Zuber M., Ultrasonic Assisted Improved Extraction and Dyeing of Mordanted Silk Fabric Using Neem Bark as Source of Natural Colourant, Nat. Prod. Res., 33(14): 2060-2072 (2019).
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[44] Malviya N., Mahajan S., Phyto Chemical Screening of Bark of Some Important Trees of College Campus with Special Reference to Tannin, Glycoside and Their Medicinal Properties, Int. Res. J. Environ. Sci.,2(11): 13-17 (2013).
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[45] Adeel S., Zuber M., Rehman F.U., Zia K.M., Microwave-Assisted Extraction and Dyeing of Chemical And Bio-Mordanted Cotton Fabric Using Harmal Seeds as a Source of Natural Dye, Environ. Sci. Pollut. Res., 25(11): 11100-11110 (2018e).
49
[46] Islam S., Rather L.J., Shabbir M., Sheikh, J., Bukhari, M.N., Khan, M.A., Mohammad F., Exploiting the Potential of Polyphenolic Biomordants in Environmentally Friendly Coloration of Wool with Natural Dye From Butea Monosperma Flower Extract, J. Nat. Fibers., 16(4): 512-523 (2019).
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[47] Shabbir M., Rather L.J., Bukhari M.N., Islam S.U., Khan M.A., Mohammad F., First-Time Application of Bio-Mordants In Conjunction with The Alkanna Tinctoria Root Extract for Eco-Friendly Wool Dyeing, J. Nat. Fiber., 16(6): 846-856 (2019).
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[48] Rather L.J., Khan M.A., Mohammad F., Biomordanting Potential of Acacia nilotica (Babul) in Conjunction With Kerria Lacca and Rheum Emodi Natural Dyes, J. Nat. Fiber., 16(2): 275-286 (2019).
52
ORIGINAL_ARTICLE
N, S-Codoped TiO2/Fe2O3 Heterostructure Assemblies for Electrochemical Degradation of Crystal Violet Dye
In contemporary research, “Heterostructure” assemblies play an important role in energy conversion systems, wherein the composite assemblies facilitate faster charge carrier transport across the material interfaces. The improved/enhanced efficiency metrics in these systems (electro/photo-electrochemical processes/devices) is due to synergistic interaction and synchronized charge transport across material interfaces. Herein, we report Type-I Heterostructure consists of N, S doped TiO2, and Fe2O3 for electrochemical crystal violet dye degradation studies. Synthesized N-S codoped TiO2/Fe2O3 composite heterostructured assemblies were fabricated on Titanium (Ti) substrate and used for electrochemical analysis. Complete decolorization was achieved with all the fabricated electrodes and a higher rate of degradation was achieved with the composite electrode (Ti/TiO2/Fe2O3) in comparison to individual electrodes (bare Ti, Ti/TiO2, Ti/Fe2O3). Further, a probabilistic mechanism of degradation is proposed in support of the hypothesis. The outcomes of the present work will have a profound effect on doped semiconductor heterostructure assemblies in the degradation of complex dye molecules of industrial outlets.
https://ijcce.ac.ir/article_33368_f71d4b1d32a087c7430989add161f8e6.pdf
2020-04-01
171
180
10.30492/ijcce.2020.33368
Type-I Heterostructure
TiO2
Fe2O3
Crystal violet dye
Pooja Sree
Palukuru
ppoojasree@gmail.com
1
Department of Chemical Engineering, JNTUA College of Engineering, Ananthapuramu, INDIA
AUTHOR
Vishnu
Devangam A
vishnu.devangam@gmail.com
2
Department of Chemical Engineering, JNTUA College of Engineering, Ananthapuramu, INDIA
AUTHOR
Dilip Kumar
Behara
dileepbh.chemengg@jntua.ac.in
3
Department of Chemical Engineering, JNTUA College of Engineering, Ananthapuramu, INDIA
LEAD_AUTHOR
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for Electrochemical Degradation of AR 73, Chemosphere, 173: 425-434 (2017).
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by Photocatalytic Water Splitting Using N-Doped TiO2 Film, Appl. Surf. Sci., 283: 188-192 (2013).
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[33] Randeniya L.K., Murphy A.B., Plumb I.C., A Study of S-Doped TiO2 for Photoelectrochemical Hydrogen Generation from Water, J. Mater. Sci., 43(4): 1389-1399 (2008).
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[34] Ivanov S., Barylyak A., Besaha K., Bund A., Bobitski Y., Wojnarowska-Nowak R., Yaremchuk I., Kus-Liśkiewicz M., Synthesis, Characterization, and Photocatalytic Properties of Sulfur-and Carbon-Codoped TiO2 Nanoparticles, Nanoscale Res. Lett., 11(1): 140 (2016).
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Α-Fe2O3 Nanoparticles, J. Environ. Chem. Eng., 2(4): 1956-1968 (2014).
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45
ORIGINAL_ARTICLE
Investigation of Affecting Parameters on the Adsorption of Lead (II) from Aqueous Solutions on Henna Powdered Leaves
In the present study, the removal of lead (II) ions from aqueous solutions was investigated by powdered Henna. Henna is a herbal material that can dramatically adsorb metal ions. Adsorption experiments were carried out in a batch system at room temperature. Then, the equilibrium concentration of each sample was analyzed by atomic adsorption device. The effects of various parameters such as time, initial concentration, adsorbent amount, and pH were investigated. pH, initial concentration, and adsorbent amount showed sharp effects on the adsorption rate. The effect of time on the process was not considerable, as well. The optimum operating conditions were found at pH of 4.78, time of 49.47 min, lead (II) initial concentration of 93.5 mg/L, and adsorbent amount of 1 g led to 97.8% removal of lead (II). Furthermore, Langmuir and Freundlich adsorption isotherms were investigated for the lead (II) adsorption process on Henna. The results showed that Langmuir's isotherm model is more suitable for this process (R2=0.947).
https://ijcce.ac.ir/article_34019_7e87e3fb2f4e196dbedf6d19b72a1977.pdf
2020-04-01
181
189
10.30492/ijcce.2020.34019
Adsorption
Biomass
Henna leaves
Optimization
Pb(II)
Reza
Davarnejad
r-davarnejad@araku.ac.ir
1
Department of Chemical Engineering, Faculty of Engineering, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
LEAD_AUTHOR
Amir
Shoaie
amirshoaee0084@gmail.com
2
Department of Chemical Engineering, Islamic Azad University, Farahan Branch, Farahan, I.R. IRAN
AUTHOR
Zahra
Karimi Dastnayi
baharkarimi70@yahoo.com
3
Department of Chemical Engineering, Faculty of Engineering, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
AUTHOR
Mahboubeh
Chehreh
mahboubechehre107@gmail.com
4
Department of Chemical Engineering, Faculty of Engineering, Arak University, P.O. Box 38156-8-8349 Arak, I.R. IRAN
AUTHOR
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by Cone Biomass of Pinus Sylvestris, Desalination, 154(3): 233-238 (2003).
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for Adsorption of Lead onto Valonia Tannin Resin, Chem. Eng. J., 143(1): 32-42 (2008).
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with Montmorillonite for Removal of Lead and Copper Ions from Aqueous Solutions, Process Saf. Environ. Prot. 109: 97-105 (2017).
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[12] Oliveira E.A., Montanher S.F., Andrade A.D., Nobrega J.A., Rollemberg M.C., Equilibrium Studies for the Sorption of Chromium and Nickel from Aqueous Solutions Using Raw Rice Bran, Process Biochem.40: 3485–3490 (2005).
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[13] Mittal A., Mittal J., Kurup L., Adsorption Isotherms, Kinetics and Column Operations for the Removal
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of Hazardous Dye, Tartrazine from Aqueous Solutions Using Waste Materials-Bottom Ash and De-Oiled Soya, as Adsorbents, J. Hazard. Mat., B136: 567-578 (2006).
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18
[15] Zheng W., Li X.M., Yang Q., Zeng G.M., Shen X.X., Zhang Y., Liu J.J., Adsorption of Cd(II) and Cu(II) from Aqueous Solution by Carbonate Hydroxylapatite Derived from Eggshell Waste,
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J. Hazard. Mat. 147: 534-539 (2007).
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28
[24] Lee S-Y., Choi H-J., Persimmon Leaf Bio-Waste for Adsorptive Removal of Heavy Metals from Aqueous Solution, J. Environ. Manage. 209: 382–392 (2018).
29
[25] Georgescu A-M., Nardou F., Zichil V., Nistor A.I., Applied Clay Science Adsorption of Lead (II) Ions from Aqueous Solutions onto Cr-Pillared Clays, Appl. Clay Sci. 152: 44-50 (2018).
30
[26] Ghosh A., Das P., Sinha K., Modeling of Biosorption of Cu (II) by Alkali-Modified Spent Tea Leaves Using Response Surface Methodology (RSM) and Artificial Neural Network (ANN), Applied Water Sci. 5(2): 191–199 (2015).
31
[27] Deepa C.N., Syed A.A., Suresha, S., Kinetic and Isothermal Studies on the Removal of Copper (ii) from Aqueous Solution by Araucaria Cookii: Response Surface Methodology for the Optimization, Int. J. Recent Scientific Res., 5(4): 820–827 (2014).
32
[28] Krishna D., Sree R.P., Response Surface Modeling and Optimization of Cu (II) Removal from Waste Water Using Borasus Flabellifer Coir Powder, Int. J. Appl. Sci. Eng. 12(3): 157–167 (2014).
33
[29] Kumar P.S., Gayathri R., Arunkumar R.P., Adsorption of Fe (III) Ions from Aqueous Solution by Bengal Gram Husk Powder: Equilibrium Isotherms and Kinetic Approach, Electron. J. Environ. Agric. Food Chem. 9(6): 1047-1058 (2010).
34
[30] Liu B., Lv X., Meng X., Yu G., Wang D., Removal of Pb(II) from Aqueous Solution Using Dithiocarbamate Modifiedchitosan Beads with Pb(II) as Imprinted Ions, Chemical Eng. J., 220: 412-419 (2013).
35
[31] Zhou L., Adsorption: Progress in Fundamental and Application Research, "4th Pacific Basin Conference on Adsorption Science and Technology", May 22-26, Tianjin, China (2006).
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[32] Davarnejad R., Panahi P., Cu(II) and Ni(II) Removal from Aqueous Solutions by Adsorption on Henna and Optimization of Effective Parameters by Using the Response Surface Methodology, J. Ind. and Eng. Chemistry, 33: 270-275 (2016).
37
[33] Davarnejad R., Panahi P., Cu (II) Removal from Aqueous Wastewaters by Adsorption on the Modified Henna with Fe3O4 Nanoparticles Using Response Surface Methodology, J. Sep. and Pur. Technol. 158: 286-292 (2016).
38
[34] Davarnejad R., Karimi Dastnayi Z., Cd (II) Removal from Aqueous Solutions By Adsorption on Henna and Henna with Chitosan Microparticles Using Response Surface Methodology, Iran. J. Chem. Chem. Eng. (IJCCE), 38 (3): 267-281 (2019).
39
[35] Davarnejad R., Karimi Dastnayi Z., Kennedy J.F., Cr(VI) Adsorption on the Blends of Henna with Chitosan Microparticles: Experimental and Statistical Analysis, Int. J. Biological Macromolecules, 116: 281-288 (2018).
40
[36] Shoaei A., "Lead (II) Removal from Aqueous Solutions Using Henna Plant" MSc. Thesis, Islamic Azad University, Farahan Branch, Farahan, Iran (2016).
41
[37] Öztürk A., Removal of Nickel from Aqueous Solution by the Bacterium Bacillus Thuringiensis,
42
J. Hazard. Mater. 147(1–2): 518–523 (2007).
43
[38] Larous S., Meniai A.-H., Bencheikh Lehocine M., Experimental Study of The Removal of Copper From Aqueous Solutions by Adsorption Using Sawdust, Desalination 185 (1-3): 483-490 (2005).
44
[39] Chubar N., Carvalho J.R., Correia M.J.N., Cork Biomass as Biosorbent for Cu(II), Zn(II) And Ni(II), Colloids And Surf. A, 230 (1-3): 57-65 (2003).
45
[40] Junxia Y., Tong M., Xiaomei S., Buhai L., A Simple Method to Prepare Poly (Amic Acid)-Modified Biomass for Enhancement of Lead and Cadmium Adsorption, Biochem. Eng. J. 33(2): 126–133 (2007).
46
[41] Nadeem R., Hanif M.A., Shaheen F., Perveen S., Zafar M.N., Iqbal T., Physical and Chemical Modification of Distillery Sludge for Pb (II) Biosorption, J. Hazard. Mater. 150(2): 335–342 (2008).
47
[42] Chowdhury S., Saha P., Sea Shell Powder as a New Adsorbent to Remove Basic Green 4 (Malachite Green) from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies, Chem. Eng. J. 164(1): 168–177 (2010).
48
[43] El-Ashtoukhy E-S.Z., Amin N.K., Abdelwahab O., Removal of Lead (II) and Copper (II) from Aqueous Solution Using Pomegranate Peel as a New Adsorbent, Desalination, 223(1–3): 162–173 (2008).
49
[44] Saeed A., Akhter M.W., Iqbal M., Removal and Recovery Of Heavy Metals From Aqueous Solution Using Papaya Wood as a New Biosorbent, Sep. Purif. Technol. 45(1): 25–31 (2005).
50
[45] Kumar K.V., Comparative Analysis of Linear and Non-Linear Method of Estimating the Sorption Isotherm Parameters for Malachite Green onto Activated Carbon, J. Hazard. Mater. 136(2): 197–202 (2006).
51
ORIGINAL_ARTICLE
Green Removal of Toxic Th(IV) by Amino-Functionalized Mesoporous TiO2-SiO2 Nanocomposite
Mesoporous TiO2-SiO2 nanocomposite (TS) was synthesized via sol-gel method and Amino-functionalized using 3-(aminopropyl) triethoxysilane. prepared amino-functionalized TiO2-SiO2 (NH2TS) was evaluated for eliminating radioactive Th(IV) ion in comparison with (TS). The prepared nanocomposites were characterized using FT-IR, XRD, DSC-TGA, SEM, EDS, BET, and BJH analyses. DSC and TGA analyses revealed that the total organic content of the NH2TS was at about 4%. According to the XRD patterns, synthesized nanocomposites exhibited only the crystalline anatase phase, and the sizes of the anatase crystallites in the prepared TS and NH2TS calculated to be 10.4 and 14.1nm, respectively. Moreover, the pore diameters of TS and NH2TS estimated to be 4.65 and 3.632 nm according to their BJH plot. The kinetic data of Th(IV) uptake process on both of two nanocomposites corresponded well to the pseudo-second-order equation. Adsorption thermodynamic parameters including the standard enthalpy, entropy, and Gibbs free energy revealed that the ion exchange reactions on both of NH2TS and TS nanocomposites were endothermic and spontaneous processes. The results indicated that NH2TS exhibited higher adsorption affinity toward Th(IV) compared to TS. Moreover, based on the Langmuir model, the maximum adsorption capacity of NH2TS nanocomposite towards the Th (IV) was found to be 1000 mg/g.
https://ijcce.ac.ir/article_33686_884dc76a8e7b75078784bdba2ac01efe.pdf
2020-04-01
191
202
10.30492/ijcce.2020.33686
TiO2-SiO2
amino-functionalization
Th (IV) ion removal
Nanocomposite
Gibbs free energy
Simin
Janitabar Darzi
sjanitabar@aeoi.org.ir
1
Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, P.O. Box 14395-836 Tehran, I.R. IRAN
LEAD_AUTHOR
Shahrzad
Abdolmohammadi
s.abdolmohamadi@iauet.ac.ir
2
Department of Chemistry, East Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
Mohammad Hossein
Latifi
mohammadhoseynlatifi@yahoo.com
3
Department of Chemistry, East Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
[1] Nilchi A., Shariati Dehaghan T., Rasouli Garmarodi S., Kinetics, Isotherm and Thermodynamics for Uranium and Thorium Ions Adsorption from Aqueous Solutions by Crystalline Tin Oxide Nanoparticles, Desalination, 321: 67–71 (2013).
1
[2] Thorium Dioxide [3] Youngju J., Seok K., Soo-Jin P., Ji Man K., Application of Polymer-modified Nanoporous Silica to Adsorbents of Uranyl Ions, Colloi. Surf. A., 313–314:162–166 (2008).
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3
[5] Shao D.D., Jiang Z.Q., Wang X.K., Li J.X., Meng Y.D., Plasma induced Grafting Carboxymethyl Cellulose on Multiwalled Carbon Nanotubes for the Removal of UO22+ from Aqueous Solution, J. Phys. Chem. B., 113: 860–864 (2009).
4
[6] Yang X., Li J.X., Wen T., Ren X.M., Huang Y.S., Wang X.K., Adsorption of Naphthalene and Its Derivatives on Magnetic Graphene Composites and the Mechanism Investigation, Colloid. Surf. A., 422:118–125 (2013).
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[7] Li J.X., Guo Z.Q., Zhang S.W., Wang X.K., Enrich and Seal Radionuclides in Magnetic Agarose Microspheres, Chem. Eng. J., 172: 892–897 (2011).
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[9] Huang S.H., Chen D. H., Rapid Removal of Heavy Metal Cations and Anions from Aqueous Solutions by an Amino-Functionalized Magnetic Nano-Adsorbent, J. Hazard. Mater., 163: 174-179 (2009).
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[10] Mahdavian A.R., Mirrahimi M.A.S., Efficient Separation of Heavy Metal Cations by Anchoring Polyacrylic Acid on Superparamagnetic Magnetite Nanoparticles Through Surface Modification, Chem. Eng. J., 159: 264-271 (2010).
9
[11] Xu P., Zeng G.M., Huang D.L., Feng C.L., Hu S., Zhao M.H., Lai C., Wei Z., Huang C., Xie G.X., Liu Z.F., Use of Iron Oxide Nanomaterials in Wastewater Treatment., Sci. Total. Environ., 424: 1-10 (2012).
10
[12] Nilchi A., Rasouli Garmarodi S., Janitabar Darzi S., Adsorption Behavior of Nano Sized Sol-Gel Derived TiO2-SiO2 Binary Oxide in Removing Pb2+ Metal Ions, Separ. Sci. Technol., 45: 801–808 (2010).
11
[13] Nilchi A., Janitabar Darzi S., Mahjoub A.R., Rasouli Garmarodi S., New TiO2/SiO2 Nanocomposites-Phase Transformations and Photocatalytic Studies, Colloid. Surf. A., 361: 25–30 (2010).
12
[14] Peshev P., Stambolova I., Vassilev S., Stefanov P., Blaskov V., Starbova K., Starbov N., pyrolysis Deposition of Nanostructured Zirconia Thin Films, Mater. Sci. Eng. B., 97:106–110 (2003).
13
[15] Marcoux L., Florek J., Kleitz F., Critical assessment of the Base Catalysis Properties of Amino-Functionalized Mesoporous Polymer-SBA-15 Nanocomposites, App. Catal. A. Gen., 504:493-503 (2015).
14
[16] Guillet-Nicolas R., Marcoux L., Kleitz F., Insights into Pore Surface Modification of Mesoporous Polymer–Silica Composites: Introduction of Reactive Amines, New. J. Chem., 34:355–366 (2010).
15
[17] Zelenak V., Halamova D., Gaberova L., Bloch E., Llewellyn P., Amine-Modified SBA-12 Mesoporous Silica for Carbon Dioxide Capture: Effect of Amine Basicity on Sorption Properties, Micropor. Mesopor. Mat., 116:358–364 (2008).
16
[18] Song B.Y., Eom Y., Lee T.G., Removal and Recovery of Mercury from Aqueous Solution Using Magnetic Silica Nanocomposites, Appl. Surf. Sci., 257:4754–4759 (2011).
17
[19] Idris S.A., Harvey S.R., Gibson L.T., Selective Extraction of Mercury (II) from Water Samples Using Mercapto Functionalised-MCM-41 and Regeneration of the Sorbent Using Microwave Digestion, J. Hazard. Mater., 193: 171-176 (2011).
18
[20] Mureseanu M., Reiss A., Stefanescu I., David E., Parvulescu V., Renard G., Hulea V., Modified SBA-15 Mesoporous Silica for Heavy Metal Ions Remediation, Chemosphere, 73:1499–1504 (2008).
19
[21] Manzano M., Aina V., Arean C.O., Balas F., Cauda V., Colilla M., Delgado M.R., Vallet-Reg M.,
20
Studies on MCM-41 Mesoporous silica for Drug Delivery: Effect of Particle Morphology and Amine Functionalization, Chem. Eng. J., 137:30–37 (2008).
21
[22] Liu H, Zhang L, Seaton N.A. Analysis of Sorption Hysteresis in Mesoporous Solids Using a Pore Network Model, J. Colloid. Interf. Sci., 156: 285-293 (1993).
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[23] Kruk M., Jaroniec M., Sayari A., Application of Large Pore MCM-41 Molecular Sieves To Improve Pore Size Analysis Using Nitrogen Adsorption Measurements, Langmuir., 13:6267-6273 (1997).
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[24] Kruk M., Jaroniec M., Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials, Chem Mater., 13:3169–3183 (2001).
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[25] Li W.J., Tao Z.Y., Comparative Study on Th(IV) Sorption on Alumina and Silica from Aqueous Solutions,
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J. Radioanal. Nucl. Chem., 254:187–192 (2002).
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[26] Sharma P., Tomar R., Sorption Behaviour of Nanocrystalline MOR Type Zeolite for Th(IV) and Eu(III) Removal from Aqueous Waste by Batch Treatment, J. Colloid. Interf. Sci., 362:144–156 (2011).
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[27] Anirudhan T.S., Sreekumari S.S., Adsorptive Removal of Heavy Metal Ions from Industrial Effluents Using Activated Carbon Derived from Waste Coconut Buttons, J. Environ. Sci., 23: 1989–1998 (2011).
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[29] Martins R.J.E., Pardo R., Boaventura R.A.R., Cadmium(II) and Zinc(II) Adsorption by the Aquatic Moss Fontinalis Antipyretica: Effect of Temperature, pH and Water Hardness, Water. Res., 38:693-699 (2004).
30
[30] Echeverria J.C., Zarranz I., Estella J., Garrido J.J., Simultaneous Effect of pH, Temperature, Ionic Strength, and Initial Concentration on the Retention of Lead on Illite, Appl. Clay. Sci., 30: 103-115 (2005).
31
[31] Sharma P., Tomar R., Synthesis and Application of an Analogue of Mesolite for the Removal of Uranium(VI), Thorium(IV), and Europium(III) From Aqueous Waste, Micropor. Mesopor. Mater., 116: 641-652 (2008).
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[32] Anirudhan T.S., Jalajamony S., Ethyl Thiosemicarbazide Intercalated Organophilic Calcined Hydrotalcite as a Potential Sorbent for the Removal of Uranium (VI) and Thorium (IV) Ions from Aqueous Solutions, J. Environ. Sci., 25: 717–725 (2013).
33
[33] Cortes-Martínez R., Olguin M.T., Solache-Rios M., Cesium Sorption by Clinoptilolite-Rich Tuffs
34
in Batch and Fixed-Bed Systems, Desalination., 258: 164–170 (2010).
35
[34] Nilchi A., Rasouli Garmarodi S., Janitabar Darzi S., Removal of Arsenic from Aqueous Solutions
36
by an Adsorption Process with Titania–Silica Binary Oxide Nanoparticle Loaded Polyacrylonitrile Polymer,
37
J. Appl. Polym. Sci., 119: 3495–3503 (2011).
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[35] Wu L., Ye Y., Liu F., Tan C., Liu H., Wang S., Wang J., Yi W., Wu W., Organo-Bentonite-Fe3O4 Poly (Sodium Acrylate) Magnetic Superabsorbent Nanocomposite: Synthesis, Characterization, and Thorium(IV) Adsorption, Appl. Clay. Sci., 83–84: 405–414 (2013).
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[36] Da Costa A.C.A., Leite S.G.F., Metals Biosorption by Sodium Alginate Immobilized Chlorella Homosphaera Cells, Biotechnol. Lett., 13: 559–562 (1991).
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[37] Abbasizadeh S., Keshtkar A.R., Mousavian M.A., Preparation of a Novel Electrospun Polyvinyl Alcohol/Titanium Oxide Nanofiber Adsorbent Modified with Mercapto Groups for Uranium(VI) and Thorium(IV) Removal from Aqueous Solution, Chem. Eng. J., 220:161–171 (2013).
41
[38] Ahmadi S.J., Akbari N., Shiri-Yekta Z., Mashhadizadeh M.H., Hosseinpour M., Removal
42
of Strontium Ions from Nuclear Waste Using Synthesized Mno2-Zro2 Nano-Composite by Hydrothermal Method in Supercritical Condition, Korean. J. Chem. Eng., 32: 478-485 (2014).
43
[39] Wu Y., Kim S.Y., Tozawa D., Ito T., Tada T., Hitomi K., Kuraoka E., Yamazaki H., Ishii K., Equilibrium and Kinetic Studies of Selective Adsorption and Separation for Strontium Using Dtbu- CH18C6 Loaded Resin, J. Nucl.Sci. Technol., 49:320-327 (2012).
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[40] Humelnicu D., Blegescu C., Ganju D., Removal of Uranium(VI) and Thorium(IV) Ions from Aqueous Solutions by Functionalized Silica: Kinetic and Thermodynamic Studies, J. Radioanal. Nucl. Chem., 299:1183–1190 (2014).
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[41] Khazaei Y., Faghihian H., Kamali M., Removal of Thorium from Aqueous Solutions by Sodium Clinoptilolite, J. Radioanal. Nucl. Chem., 289:529-536 (2011).
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[42] Savva I., Efstathiou M., Krasia-Christoforou T., Pashalidis I., Adsorptive Removal of U(VI) and Th(IV) from Aqueous Solutions Using Polymer-Based Electrospun PEO/PLLA Fibrous Membranes. J. Radioanal. Nucl. Chem., 298:1991-1997 (2013).
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[43] Gok C., Turkozu D.A., Aytas S., Removal of Th(IV) Ions from Aqueous Solution Using Bi-Functionalized Algae-Yeast Biosorbent, J. Radioanal. Nucl. Chem., 287(2): 533–541 (2011).
48
[44] Akkaya R., Ulusoy U., Adsorptive Features of Chitosan Entrapped in Polyacrylamide Hydrogel
49
for Pb2+, UO22+, and Th4+., J. Hazard. Mater., 151(2–3): 380–388 (2008).
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[45] Maheri K., Chudasam U., Studies on Kinetics, Thermodynamics and Sorption Characteristics
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of an Inorganic Ion Exchanger—Titanium Phosphate Towards Pb(II), Bi(III) And Th(IV), J. Indian. Inst. Sci., 86(5): 515-525 (2006).
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[46] Yu S.M., Chen C.L., Chang P.P., Wang T.T., Lu S.S., Wang X.K., Adsorption of Th(IV) Onto Al-Pillared Rectorite: Effect of Ph, Ionic Strength, Temperature, Soil Humic Acid and Fulvic Acid, Appl. Clay Sci., 38(3–4): 219-226 (2008).
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[47] Chen C.L., Li X.L., Zhao D.L., Tan X.L., Wang X.K., Adsorption Kinetic, Thermodynamic and Desorption Studies of Th(IV) On Oxidized Multi-Wall Carbon Nanotubes, Colloid. Surf. A-Physicochem. Eng. Aspects, 302 (1-3): 449–454 (2007).
54
ORIGINAL_ARTICLE
Quantification of Sterol Contents in Almond (PrunusamygdalusL.) Oils
In this study, the sterol contents of almond kernel oils collected from naturally growing almond trees in Mersin province were determined. Generally, the sterol contents of almond oil samples varied depending on almond types. The major sterols in almond oils wereß-sitosterol, 5-avenasterol and campesterol, followed by 5,24-stigmastadienol, stigmasterol, sitostanol, and cholesterol. While β-sitosterol contents of almond oils varied between 1986 mg/kg (T26) and 3908 mg/kg (T16), 5-avenasterol contents of almond oils samples were in the range between 215.9 mg/kg (T31) and 581.7 mg/kg (T16). In addition, campesterol contents of oils were found from 75.8 mg/kg (T31) to 172.3 mg/kg (T16). Interestingly, all sterol contents (except cholesterol, brassicasterol and 7-campesterol) of T16 almond oil were found higher than those of the other almond types. The current study showed that almond kernels of the investigated almond types from Turkey are potential sources of valuable oil which might be used as edible oil or industrial applications.
https://ijcce.ac.ir/article_33367_4020b98f246a21aa14528cb0ac9940ae.pdf
2020-04-01
203
206
10.30492/ijcce.2020.33367
Almond
type
kernel oil
sterol
GC and GC-MS
Bertrand
Matthäus
bertrand.matthaeus@mri.bund.de
1
Max Rubner-Institut (MRI) Federal Research Institute for Nutrition and Food, Department for Safety and Quality for Cereals Schützenberg 12 D-32756 Detmold, GERMANY
AUTHOR
Mehmet Musa
Özcan
mozcan@selcuk.edu.tr
2
Department of Food Engineering, Faculty of Agricultural, Selcuk University, 42031 Konya, TURKEY
LEAD_AUTHOR
[1] Moayedi A., Rezaei K., Moini S., Keshavarz B., Chemical Composition of Oils from Several Wild Almond Species, J. Am. Oil Chem. Soc., 88:503-508 (2011).
1
[2] Izaddost M., Imani A., Piri S., Bagiri A.M., Oil Content, Major Fatty Acids Composition, α-Tocopherol and Nut Characteristics of Almond at Time of Harvest, J.BasicallyAppl Sc. Res., 3: 201-205 (2013).
2
[3] Miraliakbari H., Shahidi F., Antioxidant Activity of Minör Components of Tree Nut Oils, Food Chem.111:421-427 (2008).
3
[4] Kamal-Eldin A., Moreau R.A., Tree nut Oils. In: “Gourmet and Health-Promoting Special Oils”, Kamal-Eldin A., Moreau R.A., (Eds.), p.587, AOCS Press, Urbana, Ill, USA, (2009).
4
[5] Aşkın M.A., Balta M.F., Tekintaş F.E., Kazankaya A., Balta F., Fatty Acid Composition Affected by Kernel Weight in Almond (Prunusdulcis (Mill.) D.A. Webb.) Genetic Resources. J. Food Comp. Analysis, 20:7-12 (2007).
5
[6] Matthäus B., Özcan M.M., Al Juhaimi F., Adiamo O.Q., Alsawmahi O.N., Ghafoor K., Babiker E.E., Effect of the Harvest time on Oil Yield, Fatty Acid, Tocopherol and Sterol Contents of Developing Almond and Walnut kernels. J. Oleo Sci., 67(1): 39-45 (2018).
6
[7] Fernandes G.D., Gómez-Coca R.B., CarmenPérez-Camino M., Moreda W., Barrera-Arellano D., Chemical Characterization of Major and Minor Compounds of Nut Oils: Almond, Hazelnut, and Pecan Nut. J. Chem., 1:11 (2017).
7
[8] Özcan M.M., Ünver A., Erkan E., Arslan D., Characteristics of some Almond Kernel and Oils, Sci. Hort., 127:330-333 (2011).
8
[9] Normén L., Frohlich J, Trautwein E., Role of Plant Sterols in Cholesterol Lowering. In: Dutta P C. (Ed.), “Phytosterols as Functional Food Components and Nutraceuticals”, Marcel Dekker, Inc., Newyork, pp. 243-315 (2004).
9
[10] Dulf F.V., Unguresan M-L., Vodnar D.C., Socaciu C., Free and Esterified Sterol Distribution in Four Romanian Vegetable Oil, Not. Bot. Hort. Agrobot. Cluj, 38 (2): 91-97 (2010).
10
[11] Matthäus B.,Özcan M.M., Quantitation of Fatty Acids, Sterols, and Tocopherolsin Turpentine (Pistaciaterebinthus Chia) Growing wild in Turkey, J. Agric. Food Chem., 54(20):7 667-7671 (2006).
11
[12] Püskülcü H.,Ikiz F., “Introduction to Statistic”, p 333. Bilgehan Presss: Bornova, Izmir, Turkey
12
(1989) [in Turkish].
13
[13] Savage P., McNeil D. L., Dutta P. C., Lipid Composition and Oxidative Stability of Oils in Hazelnuts (Corylus ellana L.) Grown in New Zealand, J. Amer. Oil Chem. Soc., 74: 755-759 (1997).
14
[14] White P. J., Armstrong L. S., Effect of Selected Oat Sterols on the Determination of Heated Soybean Oil, J. Amer. Oil Chem. Soc., 63: 525-529 (1986).
15
[15] Madawala S.R.P., Kochhar S.P., Dutta P.C., Lipid Components and Oxidative Status of Selected Specialty Oils, Gracas y Aceites, 63: 143-151 (2012).
16
[16] Phillips K.M., Ruggio D.M., Ashraf-Khorasani M.J., Phytosterol Composition of Nuts and Seeds Commonly Consumed in the United States, Agric. Food Chem., 53: 9436-9445 (2005).
17
[17] Johansson A.K., KuusistoP.H., Lakkso P.H., Derome K.K., Sepponen P.J., KatajistoJ.K., Geographical Variations in Seed Oils from Rubuschamaemorus and Empetrum, Phytochem., 44(8): 1421-1427 (1997).
18
[18] Soler L., Canellas J., SauraCalixto F.J., Oil Content and Fatty Acid Composition of Developing Almond Seeds, Agric. Food Chem.36:695-697 (1988).
19
[19] Matthaus B., Özcan M.M., Fatty Acid Composition, Tocopherol and Sterol Contents in Linseed (LinumusitatissimumL.) Varieties, Iran. J. Chem. Chem. Eng. (IJCCE), 36:147-152 (2017).
20
ORIGINAL_ARTICLE
Chemical Composition and Biological Activities of Essential Oil and Methanol Extract of Teucrium scordium
In this study, the chemical composition of the essential oil of Teucrium scordium was studied using capillary GC and GC/MS instruments. In addition, the antimicrobial and cytotoxic activities of the oil and methanol extract were evaluated by disc diffusion and MTT assays, respectively. Forty-three volatile components were identified from the oil of aerial parts, representing of 98.1% of total oil. The major constituents were trans-α-bergamotene (52.3%), (Z)-α-trans-bergamotol (18.1%), linalool (3.0%) and piperitenone oxide (2.9%). The best anti-bacterial activity was observed for the methanol extract against Staphylococcus epidermidis with ZI (19.0 ± 0.47) mm and also against Proteus mirabilis with MIC value of 1.25 µg/mL.Investigation of the samples on cell viability of HeLa cells showed good activity for the essential oil with an IC50 value of 5.2 µg/mL. Our results indicated that Teucrium scordium can be considered for further analyses as an effective and safe curing agent for cancer and pathogenic infection therapies.
https://ijcce.ac.ir/article_36074_f69fe338e9270b3a3be00253be6a53ed.pdf
2020-04-01
207
215
10.30492/ijcce.2020.36074
Teucrium scordium
essential oil
Antimicrobial activity
Cell viability
Parisa
Ebrahimi
p_ea97@yahoo.com
1
Medical Biotechnology Research Center, Ashkezar Branch, Islamic Azad University, Ashkezar, Yazd, I.R. IRAN
AUTHOR
Fateme
Aboee-Mehrizi
f_aboee@yahoo.com
2
Department of Medicine, Yazd Branch, Islamic Azad University, Yazd, I.R. IRAN
LEAD_AUTHOR
Mahmood
Dehghani Ashkezari
mdashkezarey@gmail.com
3
Medical Biotechnology Research Center, Ashkezar Branch, Islamic Azad University, Ashkezar, Yazd, I.R. IRAN
AUTHOR
Samaneh
Sedighi
s_sedighi90@yahoo.com
4
Medical Biotechnology Research Center, Ashkezar Branch, Islamic Azad University, Ashkezar, Yazd, I.R. IRAN
AUTHOR
Henghame
Amirian
hengame_amirian@yahoo.com
5
Department of Medicine, Yazd Branch, Islamic Azad University, Yazd, R. IRAN
AUTHOR
[1] Ferlay J., Soerjomataram I., Dikshit R., Eser S., Mathers C., Rebelo M., Parkin D.M., Forman D., Bray F., Cancer Incidence and Mortality Worldwide: Sources, Methods and Major Patterns in GLOBOCAN 2012, Int. J. Cancer,136: E359-E386 (2015).
1
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2
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3
[4] Abbas-Mohammadi M., Farimani M.M., Salehi P., Ebrahimi S.N., Sonboli A., Kelso C., Skropeta D., Acetylcholinesterase-Inhibitory Activity of Iranian Plants: Combined HPLC/Bioassay-Guided Fractionation, Molecular Networking and Docking Strategies for the Dereplication of Active Compounds, J. Pharm. Biomed. Anal.,158: 471-479 (2018).
4
[5] Subramanian R., Asmawi M.Z., Sadikun A., In vitro α-Glucosidase and α-Amylase Enzyme Inhibitory Effects of Andrographis Paniculata Extract and Andrographolide, Acta Biochim Pol,55: 391-398 (2008).
5
[6] Ozcan M., Ozkan G., The Total Phenol, Flavonol Amounts and Antiradical activity of Origanum Onites, Zeitschrift Fur Arznei-& Gewurzpflanzen,22: 184-185 (2017).
6
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7
A Review, Res. Plant Biol.,1: 1-14 (2011).
8
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9
Plants Used in Traditional Medicine for Drug Discovery, Environ. Health Perspect.,109: 69 (2001).
10
[9] Amirghofran Z., Zand F., Javidnia K., Miri R., The Cytotoxic Activity of Various Herbals Against Different Tumor Cells: An In Vitro Study, Iranian Red Crescent Med. J.,12: 260 (2010).
11
[10] Kundaković T., Milenković M., Stanojković T., Juranić Z., Lakuscaron B., Cytotoxicity and Antimicrobial Activity of Teucrium scordium L.(Lamiaceae) Extracts, Afr. J. Microbiol. Res.,5: 2692-2696 (2011).
12
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13
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14
[13] Tafrihi M., Toosi S., Minaei T., Gohari A.R., Niknam V., Arab Najafi S.M., Anticancer Properties of Teucrium persicum in PC-3 Prostate Cancer Cells, Asian Pac. J. Cancer. Prev.,15: 785-791 (2014).
15
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16
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18
[17] Javidnia K., Miri R., Composition of the Essential Oil of Teucrium orientate L. ssp. Orientate
19
from Iran, J. Essent. Oil Res.,15: 118-119 (2003).
20
[18] Mohamed A.A., Ali S.I., EL-Baz F.K., Hegazy A.K., Kord M.A., Chemical Composition of Essential Oil and In Vitro Antioxidant and Antimicrobial Activities of Crude Extracts of Commiphora myrrha Resin, Ind. Crops Prod.,57: 10-16 (2014).
21
[19] Ali N.A., Wurster M., Arnold N., Lindequist U., Wessjohan L., Chemical Composition of the Essential Oil of Teucrium yemense Deflers, Rec. Nat. Prod.,2: 25-32 (2008).
22
[20] Kovacevic N.N., Lakusic B.S., Ristic M.S., Composition of the Essential Oils of Seven Teucrium Species from Serbia and Montenegro, J. Essent. Oil Res.,13: 163-165 (2001).
23
[21] Ruiters A., Tilney P., Van Vuuren S., Viljoen A., Kamatou G., Van Wyk B.-E., The Anatomy, Ethnobotany, Antimicrobial Activity and Essential Oil Composition of Southern African Species of Teucrium (Lamiaceae), S. Afr. J. Bot., 102: 175-185 (2015).
24
[22] Cavaleiro C., Salgueiro L., Miguel M., da Cunha A.P., Analysis by Gas Chromatography–Mass Spectrometry of the Volatile Components of Teucrium lusitanicum and Teucrium algarbiensis,
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[25] Morteza‐Semnani K., Akbarzadeh M., Rostami B., The Essential Oil Composition of Teucrium chamaedrys L. from Iran, Flavour Fragr. J.,20: 544-546 (2005).
29
[26] Baher Z., Mirza M., Volatile Constituents of Teucrium flavum L. from Iran, J. Essent. Oil Res.,15: 106-107 (2003).
30
[27] Formisano C., Rigano D., Senatore F., Bruno M., Maggio A., Piozzi F., Chemical Composition of the Essential Oil of Teucrium flavum ssp. flavum from Zakynthos, Greece, Rec. Nat. Prod.,6: 306-310 (2012).
31
[28] Flamini G., Cioni P.L., Morelli I., Maccioni S., Monti G., Composition of the Essential Oil of Teucrium fruticans L. from the Maremma Regional Park (Tuscany, Italy), Flavour Fragr. J.,16: 367-369 (2001).
32
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33
[30] Ricci D., Fraternale D., Giamperi L., Bucchini A., Epifano F., Burini G., Curini M., Chemical Composition, Antimicrobial and Antioxidant Activity of the Essential Oil of Teucrium marum (Lamiaceae), J. Ethnopharmacol.,98: 195-200 (2005).
34
[31] Amiri H., Chemical Composition of Essential Oil of Teucrium orientale L. Subsp. Taylori (Boiss.) Rech. F, J. Med. Plant,7: 100-104 (2008).
35
[32] Javidnia K., Miri R., Khosravi A., Composition of the Essential Oil of Teucrium persicum Boiss. from Iran, J. Essent. Oil Res.,19: 430-432 (2007).
36
[33] Kabouche A., Kabouche Z., Ghannadi A., Sajjadi S., Analysis of the Essential Oil of Teucrium polium ssp. Aurasiacum from Algeria, J. Essent. Oil Res.,19: 44-46 (2007).
37
[34] Khani A., Heydarian M., Fumigant and Repellent Properties of Sesquiterpene-Rich Essential Oil from Teucrium polium Subsp. Capitatum (L.), Asian Pac. J. Trop. Med.,7: 956-961 (2014).
38
[35] Cozzani S., Muselli A., Desjobert J.-M., Bernardini A.-F., Tomi F., Casanova J., Chemical Composition of Essential Oil of Teucrium polium Subsp. Capitatum (L.) from Corsica, Flavour Fragr. J.,20: 436-441 (2005).
39
[36] Morteza-Semnani K., Saeedi M., Akbarzadeh M., Essential Oil Composition of Teucrium scordium L, Acta Pharm.,57: 499-504 (2007).
40
[37] Sharififar F., Mahdavi Z., Mirtajaldini M., Purhematy A., Volatile Constituents of Aerial Parts of Teucrium scordium L. from Iran, J. Essent. Oil Res.,22: 202-204 (2010).
41
[38] Maccioni S., Baldini R., Tebano M., Cioni P.L., Flamini G., Essential Oil of Teucrium scorodonia L. ssp. scorodonia from Italy, Food Chem.,104: 1393-1395 (2007).
42
[39] Djabou N., Allali H., Battesti M.-J., Tabti B., Costa J., Muselli A., Varesi L., Chemical and Genetic Differentiation of Two Mediterranean Subspecies of Teucrium scorodonia L, Phytochemistry,74: 123-132 (2012).
43
[40] Shah S.M.M., Ullah F., Shah S.M.H., Zahoor M., Sadiq A., Analysis of Chemical Constituents and Antinociceptive Potential of Essential Oil of Teucrium stocksianum Bioss Collected from the North West of Pakistan, BMC Complement. Altern. Med., 12: 244 (2012).
44
[41] Jaimand K., Rezaee M., Soltanipoor M., Mozaffarian V., Volatile Constituents of Teucrium stocksianum Boiss. ssp. stocksianum from Iran, J. Essent. Oil Res.,18: 476-477 (2006).
45
[42] Van Vuuren D.P., Bouwman A.F., Beusen A.H., Phosphorus Demand for the 1970–2100 Period:
46
A Scenario Analysis of Resource Depletion, Global Environmen. Change,20: 428-439 (2010).
47
[43] Mohammadpour Vashvaei R., Sepehri Z., Jahantigh M., Javadian F., Antimicrobial Activities of Teucrium polium Against Salmonella typhimurium, International Journal of Advanced Biological and Biomedical Research,3: 149-152 (2015).
48
ORIGINAL_ARTICLE
A Comparative Study between Different Tunisian Propolis Essential Oils and Their Antioxidant Activities
Propolis is a resinous substance collected by bees from plants with a complex and variable chemical composition. Propolis and its fractions possess multiple biological activities. This study focused on a chemical and statistical comparison between four Tunisian Propolis Essential Oils (PEO) and its antioxidant activities. Volatile oils were extracted by hydrodistillation and analyzed by GC-MS. Essential oil yield varied from 0.095% to 0.324%. A total of 59 volatile components were identified mainly dominated by sesquiterpenes and diterpenes hydrocarbons. Six major components were found in all samples collected from the four different locations α-Cedrol, Manoyl Oxide, Manool, Totarol, Tricosane, and Eicosane. The antioxidant activities of Tunisian propolis essential oils have been evaluated using two methods: β-carotene-linoleic acid bleaching and DPPH radical scavenging assays and the results were compared with the standard antioxidant (Triolox). PEO from Bizerte region presented a lower IC50 value (30.5 mg/mL) than that of the standard antioxidant Trolox (IC50 = 40.05 mg/mL) indicating high antioxidant capacity using DPPH assay but for the b-carotene-linoleic acid bleaching assay, PEO from Zouarine region had the lowest value of (IC50 = 26.5 mg/mL) compared to standard (IC50 = 31.25 mg/mL). Our findings demonstrated that Propolis Essential Oil (PEO) possess high antioxidant activities and may be suggested as a new potential source of natural antioxidant.
https://ijcce.ac.ir/article_39791_4b7d7296695531fbd8f707798d9dacde.pdf
2020-04-01
217
231
10.30492/ijcce.2020.39791
Tunisian Propolis
essential oil
GC/MS
Antioxidant Activity
α-Cedrol
Jihene
Ayari
jihneayari@yahoo.fr
1
Laboratoire Matériaux Molécules et Applications, Institut Préparatoire des Etudes Scientifiques et Techniques, IPEST, BP 51, 2070 La Marsa, TUNISIA
AUTHOR
Iness Jabri
Karoui
iness.karoui@yahoo.fr
2
Laboratoire Matériaux Molécules et Applications, Institut Préparatoire des Etudes Scientifiques et Techniques, IPEST, BP 51, 2070 La Marsa, TUNISIA
AUTHOR
Manef
Abderrabba
abderrabbamanef@gmail.com
3
Laboratoire Matériaux Molécules et Applications, Institut Préparatoire des Etudes Scientifiques et Techniques, IPEST, BP 51, 2070 La Marsa, TUNISIA
LEAD_AUTHOR
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48
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49
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50
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51
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54
ORIGINAL_ARTICLE
Encapsulation of Zataria multiflora Essential Oil in Saccharomyces cerevisiae: Sensory Evaluation and Antibacterial Activity in Commercial Soup
Nowadays rising consumer concern on the safety of synthetic chemical food preservatives is a reason for finding natural new antimicrobial agents, especially among the components of medicinal plants such as Essential Oils (EOs). However, most EOs are sensitive to oxygen, light, and temperature and can be easily degraded. Some EOs have strong taste, flavor, and affect the organoleptic characteristics of foods. Encapsulation can control these unpleasant characteristics. Using yeast cells as encapsulating agents and delivery systems for active ingredients has been widely investigated. Encapsulation in yeast cells has a wide range of advantages such as processes simplicity, commercial availability, low cost-high volume process, and needless of toxic solvents. In this study, the antibacterial activity of free and encapsulated Zataria multiflora Bioss. Essential Oil (ZEO) in Saccharomyces cerevisiae against Escherichia coli O157:H7 and Listeria monocytogenes as important foodborne pathogens were evaluated. The sensory evaluation of both forms of ZEO in a food model was also done. ZEO was successfully encapsulated into S. cerevisiae cells. Carvacrol and thymol contents in loaded yeasts were determined. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of free and loaded ZEO were studied against Escherichia coli O157:H7 and Listeria monocytogenes; their antibacterial effects in the commercial chicken soup was investigated, and their sensory attributes in the commercial soup were evaluated as well. Our results showed significant decreases in the MIC and MBC values of ZEO in culture media after encapsulation; however, the antibacterial activity of ZEO in commercial chicken soup showed no significant differences after encapsulation (P>0.05). ZEO encapsulation improves its sensory score and hence, decreases its organoleptic effects in food (P<0.01). Considering acceptable sensorial scores of loaded ZEO in yeast cells, this method can practically be applied in food systems as natural biopreservation.
https://ijcce.ac.ir/article_34020_ed1e3e037dcff0868252f7ebac695032.pdf
2020-04-01
233
242
10.30492/ijcce.2020.34020
Zataria multiflora Bioss
essential oil
Saccharomyces cerevisiae
encapsulation
Escherichia coli O157:H7
Listeria monocytogenes
Maryam
Nakhaee Moghadam
mn.moghadam@gmail.com
1
Department of Food Hygiene, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
Jebrail
Movaffagh
movaffaghj@mums.ac.ir
2
Targeted Drug Delivery Research Center, Pharmaceutical Technology Institute, Mashhad University of Medical Sciences, Mashhad, I.R. IRAN
AUTHOR
Bibi Sedighe
Fazli Bazzaz
fazlis@mums.ac.ir
3
Biotechnology Research Center, Pharmaceutical Technology Institute, Mashhad University of Medical Sciences, Mashhad, I.R. IRAN
AUTHOR
Mohammad
Azizzadeh
azizzadeh@gmail.com
4
Department of Clinical Sciences, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
Abdollah
Jamshidi
ajamshid@um.ac.ir
5
Department of Food Hygiene, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
LEAD_AUTHOR
[1] Sacchetti G., Maietti S., Muzzoli M., Scaglianti M., Manfredini S., Radice M., Bruni R., Comparative Evaluation of 11 Essential oils of Different Origin as Functional Antioxidants, Antiradicals and Antimicrobials in Foods, Food Chemistry, 91(4): 621-632 (2005).
1
[2] Viuda-Martos M., El Gendy Ael N., Sendra E., Fernandez-Lopez J., Abd El Razik K.A., Omer E.A., Perez-Alvarez J.A., Chemical Composition and Antioxidant and Anti-Listeria Activities of Essential Oils Obtained from Some Egyptian Plants, Journal of Agricultural and Food Chemistry, 58(16): 9063-9070(2010).
2
[3] Shahinfar R., khanzadi S., Hashami M., Azizzadeh M., Bostan A., The Effect of Ziziphora clinopodioides Essential Oil and Nisin on Chemical and Microbial Characteristics of Fish Burger during Refrigerated Storage, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(5): 65-75(2017).
3
[4] Nabil Qaid M.A.-H., Algabr M., Husnain R., Riyadh T., Al-Farga A., Waleed A., Hongxin W., Antibacterial Activities of the Essential Oils of Some Aromatic Medicinal Plants to Control Pathogenic Bacteria and Extend the Shelf-Life of Seafood, Turkish Journal of Fisheries and Aquatic Sciences, 17: 181-191(2017).
4
[5] Barkhori-Mehni S., Khanzadi S., Hashemi M., Azizzadeh M., The Effect of Sodium Alginate Coating Incorporated with Lactoperoxidase System and Zataria Multiflora Boiss Essential Oil on Shelf Life Extension of Rainbow Trout Fillets During Refrigeration, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 38(1): 163-172 (2018).
5
[6] Patra J.K., Baek K.H., Antibacterial Activity and Action Mechanism of the Essential Oil from Enteromorpha Linza L. Against Foodborne Pathogenic Bacteria, Molecules (Basel, Switzerland), 21(3): 388(2016).
6
[7] Wiwanitkit V., Ebrahimi khoosfi M., Safety Aspects of Local Tropical Food Production: Essential Oil Incorporation as a Safe Approach, Applied Food Biotechnology, 2(2): 3-6 (2015).
7
[8] Nasseri M., Golmohammadzadeh S., Arouiee H., Jaafari M.R., Neamati H., Antifungal Activity
8
of Zataria Multiflora Essential Oil-Loaded Solid Lipid Nanoparticles in-Vitro Condition, Iranian Journal of Basic Medical Sciences, 19(11): 1231-1237(2016).
9
[9] Mazhar S.F., Aliakbari F., Karami-Osboo R., Morshedi D., Shariati P., Farajzadeh D., Inhibitory Effects of Several Essential Oils towards Salmonella typhimurium, Salmonella paratyphi A and Salmonella paratyphi B, Applied Food Biotechnology, 1(1): 10- (2014).
10
[10] Zengin H., Baysal A.H., Antibacterial and Antioxidant Activity of Essential Oil Terpenes Against Pathogenic and Spoilage-Forming Bacteria and Cell Structure-Activity Relationships Evaluated by SEM Microscopy, Molecules (Basel, Switzerland), 19(11): 17773-98(2014).
11
[11] Tajik H., Aminzare M., Mounesi Raad T., Hashemi M., Hassanzad Azar H., Raeisi M., Naghili H., Effect of Zataria multiflora Boiss Essential Oil and Grape Seed Extract on the Shelf Life of Raw Buffalo Patty and Fate of Inoculated Listeria monocytogenes, Journal of Food Processing and Preservation, 39(6): 3005-3013(2015).
12
[12] Shafiee A., Javidnia K., Tabatabai M., Volatile Constituents and Antimicrobial Activity of Zataria Multiflora, Population Iran, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 18(1): 1-5(1999).
13
[13] Khatibi S.A., Misaghi A., Moosavy M.-H., Amoabediny G., Basti A.A., Effect of Preparation Methods on the Properties of Zataria Multiflora Boiss. Essential oil loaded Nanoliposomes: Characterization of Size, Encapsulation Efficiency and Stability, Pharm Sci., 20 (4): 141-148(2015).
14
[14] Sultanbawa, Y., Plant Antimicrobials in Food Applications: Minireview, in: A. Méndez-Vilas (Ed.) "Science Against Microbial Pathogens: Communicating Current Research and Technological Advances". Formatex Research Center, Badajoz, Spain. pp. 1084-1093 (2011).
15
[15] Khosravi‐Darani K., Khoosfi Mahin E., Hosseini H., Encapsulation of Zataria multiflora Boiss.
16
Essential Oil in Liposome: Antibacterial Activity Against E. Coli O157:H7 in Broth Media and Minced Beef, Journal of Food Safety, 36(4): 515-523(2016).
17
[16] Hosseini, S.M., Hosseini, H., Mohammadifar, M.A., Mortazavian, A.M., Mohammadi, A., Khosravi-Darani, K., Shojaee-Aliabadi, S., Dehghan, S., Khaksar R., Incorporation of Essential Oil in Alginate Microparticles by Multiple Emulsion/Ionic Gelation Process, International Journal of Biological Macromolecules, 62: 582-588(2013).
18
[17] Fang Z., Bhandari B., Encapsulation of Polyphenols – A Review, Trends in Food Science & Technology, 21(10): 510-523(2010).
19
[18] Paramera E.I., Karathanos V.T., Konteles S.J., Chapter 23 - Yeast Cells and Yeast-Based Materials for Microencapsulation, "Microencapsulation in the Food Industry", Academic Press, San Diego. pp. 267-281 (2014).
20
[19] Salari R., Rajabi O., Khashyarmanesh Z., Fathi Najafi M., Fazly Bazzaz B.S., Characterization of Encapsulated Berberine in Yeast Cells of Saccharomyces Cerevisiae, Iranian journal of Pharmaceutical Research : IJPR, 14(4): 1247-56 (2015).
21
[20] Ciamponi F., Duckham C., Tirelli N., Yeast Cells as Microcapsules. Analytical Tools and Process Variables in the Encapsulation of Hydrophobes in S. Cerevisiae, Applied Microbiology and Biotechnology, 95(6): 1445-56(2012).
22
[21] Shi, G., Rao, L., Yu, H., Xiang, H., Pen, G., Long, S., Yang, C., Yeast-Cell-Based Microencapsulation of Chlorogenic Acid as a Water-Soluble Antioxidant, Journal of Food Engineering, 80(4): 1060-1067 (2007).
23
[22] Bishop J.R., Nelson G., Lamb J., Microencapsulation in Yeast Cells, Journal of Microencapsulation, 15(6) 761-73 (1998).
24
[23] Paramera E.I., Konteles S.J., Karathanos V.T., Stability and Release Properties of Curcumin Encapsulated in Saccharomyces Cerevisiae, β-Cyclodextrin and Modified Starch, Food Chemistry, 125(3): 913-922(2011).
25
[24] Behravan J., Ramezani M., Hassanzadeh M.K., Eskandari M., Kasaian J., Sabeti Z., Composition, Antimycotic and Antibacterial Activity of Ziziphora clinopodioides Lam. Essential Oil from Iran, Journal of Essential Oil Bearing Plants, 10(4): 339-345 (2007).
26
[25] Sartoratto A., Lúcia M. Machado A., Delarmelina C., Figueira G., Duarte M., Lúcia G. Rehder V., Composition and Antimicrobial Activity of Essential Oils from Aromatic Plants Used in Brazil, Braz. J. Microbiol., 35(4): 275-280(2004).
27
[26] Dini S., Dadkhah A., Fatemi F., Biological Properties of Iranian Zataria Multiflora Essential Oils: A Comparative Approach, Electronic Journal of Biology, 11(3): 57-62(2015).
28
[27] Gutierrez J., Barry-Ryan C., Bourke P., Antimicrobial Activity of Plant Essential Oils Using Food Model Media: Efficacy, Synergistic Potential and Interactions with Food Components, Food Microbiology, 26(2): 142-150 (2009).
29
[28] Aida A., Ali M.S., Behrooz M.V., Chemical Composition and Antimicrobial Effect of the Essential Oil of Zataria Multiflora Boiss Endemic in Khorasan-Iran, Asian Pacific Journal of Tropical Disease, 5(3): 181-185(2015).
30
[29] Aliakbarlu, J., Sadaghiani, S.K., Mohammadi, S., Comparative Evaluation of Antioxidant and Anti Food-Borne Bacterial Activities of Essential Oils from Some Spices Commonly Consumed in Iran, Food Science and Biotechnology, 22(6): 1487-1493(2013).
31
[30] Motevasel M., Zomorodian K., Ashraf Mansouri M.A., Farshad S.H., Haghighhat A.R., Hadaegh M.G., Takhshid M.A., The Anti-Bacterial Effects of Zataria Multiflora Extract on Common Pathogenic Gram Positive Cocci, Pathogenic Gram Negative Bacilli and Non -Pathogenic Bacteria, Afr. J. Microbiol. Res., 5(28): 4993-4996 (2011).
32
[31] Rahnama M., Razavi Rohani S., Tajik H., Khalighi-Sigaroodi F., Rezazad - Bari M., Effects of Zataria Multiflora Boiss. Essential Oil and Nisin, Alone and in Combination Against Listeria Monocytogen in BHI Broth, Journal of Medicinal Plants, 4(32): 120-131(2009).
33
[32] Eftekhar F., Zamani S., Morteza Y., Hadian J., Ebrahimi, S., Antibacterial Activity of Zataria Multiflora Boiss Essential Oil Against Extended Spectrum B-Lactamase Produced by Urinary Isolated of Klebsiella Pneumonia, Jundishapur J. Microbiol., 4: 43-49 (2011).
34
[33] Akhondzadeh Basti A., Aminzare M., Razavi Rohani S., Khanjari A., Noori N., Jebelli Javan A., Taheri Mirghaed A., Raeisi M., Naghili H., Mohammadkhan F., The Combined Effect of Lysozyme and Zataria multiflora Essential Oil on Vibrio Parahaemolyticus, Journal of Medicinal Plants, 2(50): 27-34(2014).
35
[34] Donsì F., Annunziata M., Sessa M., Ferrari G., Nanoencapsulation of Essential Oils to Enhance Their Antimicrobial Activity in Foods, LWT - Food Science and Technology, 44(9): 1908-1914(2011).
36
[35] Hadian M., Rajaei A., Mohsenifar A., Tabatabaei M., Encapsulation of Rosmarinus Officinalis Essential Oils in Chitosan-Benzoic Acid Nanogel with Enhanced Antibacterial Activity in Beef Cutlet Against Salmonella Typhimurium During Refrigerated Storage, LWT, 84: 394-401(2017).
37
[36] Khatibi S.A., Misaghi A., Moosavy M.H., AkhondzadehBasti A., Koohi M.K., Khosravi P., Haghirosadat F., Encapsulation of Zataria multiflora Bioss. Essential Oil into Nanoliposomes and in Vitro Antibacterial Activity Against Escherichia coli O157:H7, Journal of Food Processing and Preservation, 41(3): e12955(2016).
38
[37] Rajaei A., Hadian M., Mohsenifar A., Rahmani-Cherati T., Tabatabaei M., A Coating Based
39
on Clove Essential Oils Encapsulated by Chitosan-Myristic Acid Nanogel Efficiently Enhanced
40
the Shelf-Life of Beef Cutlets, Food Packaging and Shelf Life, 14: 137-145(2017).
41
[38] Fakruddin M., Hossain M.N., Ahmed M.M., Antimicrobial and Antioxidant Activities of Saccharomyces Cerevisiae IFST062013, a Potential Probiotic, BMC Complementary and Alternative Medicine, 17(1): 64- (2017).
42
[39] Younis, G., Awad, A., Dawod, R.E., Yousef, N.E., Antimicrobial Activity of Yeasts Against some Pathogenic Bacteria, Veterinary world, 10(8): 979-983(2017).
43
[40] Chamidah A., Hardoko H., Prihanto A., Antibacterial Activities of β-Glucan (laminaran) Against Gram-Negative and Gram-Positive Bacteria, AIP Conference Proceedings, 1844(1): 10.1063-1.4983422 (2017).
44
[41] Karim G., Aghazadeh Meshgi M., Karimi Ababil R., Bokaie, S., Antimicrobial Effect of Mentha Spicata And Mentha Pulegium Essential Oils in Two Storage Temperatures on the Survival of Debaryomyces Hansenii in Iranian Doogh, Applied Food Biotechnology, 3(2): 99-104 (2016).
45
[42] Ghasemi, S., Haji Seyed Javadi, N., Moradi, M., Khosravi, K., Investigation on Development of Zein Antimicrobial Edible Film and Essential Oil of Zataria Multiflora Boiss. on Sallmonella Enteritidis, Listeria Monocytogenes, Escherichia Coli and Staphylococcus Aureu, Asian Journal of Chemistry, 24 (12): 5941-5942 (2012).
46
[43] Dima C., Corina N., Cercel F., Alexe P., Sensory, Physico-Chemical and Microbiological Properties of Cooked Ham with Β-Ciclodextrin Loaded with Coriander and Pimento Essential Oils, J. Agroaliment. Proc. Technol., 20(4): 319-329(2014).
47
[44] Barroso A.K., Pierucci A.P., Freitas S.P., Torres, A.G., Rocha-Leao, M.H., Oxidative Stability and Sensory Evaluation of Microencapsulated Flaxseed Oil, Journal of Microencapsulation, 31(2): 193-201 (2014).
48
ORIGINAL_ARTICLE
Effect of 1,2,3-Trichloropropane as Tri-Functional Monomer on Thermophysical Properties of Poly(ethylene tetrasulfide)
In this study, the effect of 1,2,3-trichloropropane (TCP) as trifunctional monomer on thermophysical properties of synthesized poly(ethylene tetrasulfide) (PETS) is investigated. To this end, different amounts of TCP (0-40 mol. % of halide-containing monomer) were incorporated into the structure of polysulfide polymer via interfacial condensation polymerization. Measurement of gel, fraction showed that by the introduction of only 10 mol. % of TCP, synthesized structure is almost crosslinked. The X-Ray Diffraction (XRD) results revealed that all samples are semi-crystalline whereas the crystallinity of samples strongly depends on the amount of TCP. All samples showed a glass transition temperature (Tg) less than 0 °C followed by melting temperature (Tm). Higher amountof crosslinking monomer resulted in higher Tg while Tm and heat of fusion (ΔHm) were reduced. According to ThermoGravimetric Analysis (TGA) results, all samples exhibited a two-stage degradation process. Although, the introduction of 10 mol. % TCP into the structure of PETS resulted in lower thermal stability of obtained polymer, adding higher amounts of TCP led to the higher thermal stability of polymers.
https://ijcce.ac.ir/article_33688_19df5da0d789a5630c5b0c57f7e83e28.pdf
2020-04-01
243
249
10.30492/ijcce.2020.33688
Polysulfide
Poly(ethylene tetrasulfide)
1,2,3-trichloropropane
crosslinking
thermo-physical properties
Mina
Amangah
m_amangah@sut.ac.ir
1
Department of Polymer Engineering, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, I.R. IRAN
AUTHOR
Mehdi
Salami Kalajahi
m.salami@sut.ac.ir
2
Department of Polymer Engineering, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, I.R. IRAN
LEAD_AUTHOR
Hossein
Roghani-Mamaqani
r.mamaghani@sut.ac.ir
3
Department of Polymer Engineering, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, I.R. IRAN
LEAD_AUTHOR
[1] Zhang Y., Shao L., Dong D., Wang Y., Enhancement of Water and Organic Solvent Resistances of
1
a Waterborne Polyurethane Film by Incorporating Liquid Polysulfide, RSC Adv., 6: 17163-17171 (2016).
2
DOI: https://doi.org/10.1039/C5RA24574E.
3
[2] Zhang Y., Shao L., Liu B., Wang F., Wang Y., Effect of Molecular Weight of Liquid Polysulfide on Water and Organic Solvent Resistances of Waterborne Polyurethane/Polysulfide Copolymer, Prog. Org. Coat., 112: 219-224 (2017).
4
DOI: https://doi.org/10.1016/j.porgcoat.2017.07.010.
5
[3] Amangah M., Salami-Kalajahi M., Roghani-Mamaqani H., Nanoconfinement Effect of Graphene on Thermophysical Properties and Crystallinity of Matrix-Grafted Graphene/ Crosslinked Polysulfide Polymer Nanocomposites, Diamond Relat. Mater., 83: 177-183 (2018).
6
DOI: https://doi.org/10.1016/j.diamond.2018.02.012.
7
[4] Pirayesh A., Salami-Kalajahi M., Roghani-Mamaqani H., Dehghani E., Amine-Modified Graphene Oxide
8
as Co-Curing Agent of Epoxidized Polysulfide Prepolymer: Thermophysical and Mechanical Properties of Nanocomposites, Diamond Relat. Mater., 86: 109-116 (2018).
9
DOI: https://doi.org/10.1016/j.diamond.2018.04.025.
10
[5] Lafont U., Moreno-Belle C., van Zeijl H., van der Zwaag S., Self-Healing Thermally Conductive Adhesives, J. Intell. Mater. Syst. Struct., 25: 67-74 (2014).
11
DOI: https://doi.org/10.1177/1045389X13498314.
12
[6] Marques E. A. S., da Silva L. F. M., Banea M. D., Carbas R. J. C., Adhesive Joints for Low- and High-Temperature Use: An Overview, J. Adhes., 91: 556-585 (2015).
13
DOI: https://doi.org/10.1080/00218464.2014.943395.
14
[7] Pirayesh A., Salami-Kalajahi M., Roghani-Mamaqani H., Najafi F., Polysulfide Polymers: Synthesis, Blending, Nanocomposites and Applications, Polym. Rev., 59: 124-148 (2019).
15
DOI: https://doi.org/10.1080/15583724.2018.1492616.
16
[8] Farajpour T., Bayat Y., Keshavarz M. H., Zanjirian E., Investigating the Effect of Modifier Chain Length
17
on Insulation Properties of Polysulfide Modified Epoxy Resin, Iran. J. Chem. Chem. Eng. (IJCCE), 33: 37-44 (2014).
18
[9] Abdouss M., Farajpour T., Derakhshani M., The Effect of Epoxy-Polysulfide Copolymer Curing Methods on Mechanical-Dynamical and Morphological Properties, Iran. J. Chem. Chem. Eng. (IJCCE), 30(4): 37-44 (2011).
19
[10] Pirayesh A., Salami-Kalajahi M., Roghani-Mamaqani H., Mazloomi-Rezvani M., Synthesis and Characterization of Bis(oxiranylmethyl)Sulfanes as New Epoxide-Terminated Polysulfide Prepolymers and Their Use in Synthesis of New Amine-Cured Polysulfide Polymers, Adv. Polym. Technol., (2018).
20
DOI: https://doi.org/10.1002/adv.22117.
21
[11] Zhang Y., Peng Y., Wang Y., Li J., Li H., Zeng J., Wang J., Hwang B. J., Zhao J., High Sulfur-Containing Carbon Polysulfide Polymer as a Novel Cathode Material for Lithium-Sulfur Battery, Sci. Rep., 7: 11386 (2017).
22
DOI: https://doi.org/10.1038/s41598-017-11922-6.
23
[12] Kariminejad B., Salami-Kalajahi M., Roghani-Mamaqani H., Thermophysical Behaviour of matrix-Grafted Graphene/Poly(ethylene tetrasulphide) Nanocomposites, RSC Adv., 5: 100369-100377 (2015).
24
DOI: https://doi.org/10.1039/C5RA20254J.
25
[13] Kariminejad B., Salami-Kalajahi M., Roghani-Mamaqani H., Noparvar-Qarebagh A., Effect of Surface Chemistry of Graphene and Its Content on the Properties of Ethylene Dichloride- and Disodium Tetrasulfide-Based Polysulfide Polymer nanocomposites, Polym. Compos., 38: E515-E524 (2017).
26
DOI: https://doi.org/10.1002/pc.23857.
27
[14] Moqadam S., Salami-Kalajahi M., Halogenated Sunflower Oil as a Precursor for Synthesis of Polysulfide Polymer, e-Polymers, 16: 33-39 (2016).
28
DOI: https://doi.org/10.1515/epoly-2015-0152.
29
[15] Sheydaei M., Kalaee M. R., Allahbakhsh A., Moradi-e-Rufchahi E. O., Samar M., Moosavi G., Sedaghat N., Synthesis and Characterization of Poly(p-xylylene tetrasulfide) via Interfacial Polycondensation in the Presence of Phase Transfer Catalysts, Des. Monom. Polym., 16: 191-196 (2013).
30
DOI: https://doi.org/10.1080/15685551.2012.725213.
31
[16] Kazerouni S. S., Kalaee M., Sharif F., Mazinani S., Synthesis and Characterization of Poly(ethylene tetrasulfide)/Graphene Oxide Nanocomposites by in Situ Polymerization Method, J. Sulfur Chem., 37: 328-339 (2016).
32
DOI: https://doi.org/10.1080/17415993.2016.1139114.
33
[17] Allahbakhsh A., Sheydaei M., Mazinani S., Kalaee M., Enhanced Thermal Properties of Poly(ethylene tetrasulfide) via Expanded Graphite Incorporation by in Situ Polymerization Method, High Perform. Polym., 25: 576-583 (2013).
34
DOI: https://doi.org/10.1177/0954008313476314.
35
[18] Gao W., Bie M., Liu F., Chang P., Quan Y., Self-Healable and Reprocessable Polysulfide Sealants Prepared from Liquid Polysulfide Oligomer and Epoxy Resin, ACS Appl. Mater. Interfaces, 9: 15798-15808 (2017).
36
DOI: https://doi.org/10.1021/acsami.7b05285.
37
[19] Bandyopadhyay A., Valavala P.K., Clancy T.C., Wise K.E., Odegard G.M., Molecular Modeling of Crosslinked Epoxy Polymers: The Effect of Crosslink Density on Thermomechanical Properties, Polymer, 52: 2445-2452 (2011).
38
DOI: https://doi.org/10.1016/j.polymer.2011.03.052.
39
[20] AbdolahZadeh M., Esteves A. C. C., van der Zwaag S., Garcia S.J., Healable Dual Organic–Inorganic Crosslinked Sol–Gel Based Polymers: Crosslinking Density and Tetrasulfide Content Effect, J. Polym. Sci. Polym. Chem., 52: 1953-1961 (2014).
40
DOI: https://doi.org/10.1002/pola.27200.
41
[21] Lim J., Jung U., Joe W. T., Kim E. T., Pyun J., Char K., High Sulfur Content Polymer Nanoparticles Obtained from Interfacial Polymerization of Sodium Polysulfide and 1,2,3-Trichloropropane in Water, Macromol. Rapid Commun., 36: 1103-1107 (2015).
42
DOI: https://doi.org/10.1002/marc.201500006.
43
[22] Sheydaei M., Jabari H., Dehaghi H. A.-A., Synthesis and Characterization of Ethylene-Xylene-Based Polysulfide Block-Copolymers Using the Interfacial Polymerization Method, J. Sulfur Chem., 37: 646-655 (2016).
44
DOI: https://doi.org/10.1080/17415993.2016.1177054.
45
[23] Kalaee M., Mahdavi H., Famili M. H. N., Preparation of Synthesized Sulfide Polymer Through Phase-Transfer Catalyzed Polycondensation of Ethylene Dibromide and Sodium Tetrasulfide: Characterization, Thermal and Rheological Properties, J. Sulfur Chem., 35: 373-381 (2014).
46
DOI: https://doi.org/10.1080/17415993.2014.882336.
47
[24] Torkpur-Biglarianzadeh M., Salami-Kalajahi M., Multilayer Fluorescent Magnetic Nanoparticles
48
with Dual Thermoresponsive and pH-sensitive Polymeric Nanolayers as Anti-cancer Drug Carriers, RSC Adv., 5: 29653-29662 (2015).
49
DOI: https://doi.org/10.1039/C5RA01444A.
50
[25] Khonakdar H. A., Morshedian J., Wagenknecht U., Jafari S.H., An Investigation of Chemical crosslinking Effect on Properties of High-Density Polyethylene, Polymer, 44: 4301-4309 (2003).
51
DOI: https://doi.org/10.1016/S0032-3861(03)00363-X.
52
[26] Ungár T., Microstructural Parameters from X-Ray Diffraction Peak Broadening, Scr. Mater., 51: 777-781 (2004).
53
DOI: https://doi.org/10.1016/j.scriptamat.2004.05.007.
54
[27] Safajou-Jahankhanemlou M., Abbasi F., Salami-Kalajahi M., Synthesis and Characterization of Thermally Expandable PMMA-Based Microcapsules with Different Cross-Linking Density, Colloid Polym. Sci., 294: 1055-1064 (2016).
55
DOI: https://doi.org/10.1007/s00396-016-3862-2.
56
[28] Adelnia H., Gavgani J. N., Riazi H., Bidsorkhi H. C., Transition Behavior, Surface Characteristics and Film Formation of Functionalized Poly(methyl methacrylate-co-butyl acrylate) Particles, Prog. Org. Coat., 77: 1826-1833 (2014).
57
DOI: https://doi.org/10.1016/j.porgcoat.2014.06.009.
58
[29] Moqadam S., Salami-Kalajahi M., Mahdavian M., Synthesis and Characterization of Sunflower Oil-based Polysulfide Polymer/Cloisite 30B Nanocomposites, Iran. J. Chem. Chem. Eng. (IJCCE), 37(1): 185-192 (2018).
59
[30] Riazi H., Mohammadi N., Mohammadi H., Emulsion Copolymerization of Methyl Methacrylate/Butyl Acrylate/Iodine System to Monosize Rubbery Nanoparticles Containing Iodine and Triiodide Mixture, Ind. Eng. Chem. Res., 52: 2449-2456 (2013).
60
DOI: https://doi.org/10.1021/ie303063b.
61
[31] Haghighi A. H., Sheydaei M., Allahbakhsh A., Ghatarband M., Hosseini F.S., Thermal Performance of Poly(ethylene disulfide)/Expanded Graphite Nanocomposites, J. Therm. Anal. Calorim., 117: 525-535 (2014).
62
DOI: https://doi.org/10.1007/s10973-014-3752-0.
63
[32] Modarresi-Saryazdi S. M., Haddadi-Asl V., Salami-Kalajahi M., N,N'-Methylenebis(acrylamide)-Crosslinked Poly(acrylic acid) Particles as Doxorubicin Carriers: A Comparison between Release Behavior of Physically Loaded Drug and Conjugated Drug via Acid-Labile Hydrazone Linkage, J. Biomed. Mater. Res. A, 106: 342-348 (2018).
64
DOI: http://dx.doi.org/10.1002/jbm.a.36240.
65
[33] Levchik G.F., Si K., Levchik S.V., Camino G., Wilkie C.A., The Correlation between Cross-Linking and Thermal Stability: Cross-Linked Polystyrenes and Polymethacrylates, Polym. Degrad. Stab., 65: 395-403 (1999).
66
DOI: https://doi.org/10.1016/S0141-3910(99)00028-2.
67
ORIGINAL_ARTICLE
A New Mathematical Model for the Prediction of Internal Recirculation in Impinging Streams Reactors
A mathematical model for the prediction of internal recirculation of complex impinging stream reactors has been presented. The model constitutes a repetition of a series of ideal plug flow reactors and CSTR reactors with recirculation. The simplicity of the repeating motif allows for the derivation of an algebraic relation of the whole system using the Laplace transform. An impinging streams reactor system with one axial and two tangential inlet fluid streams was constructed and considered as a case study. The model predicts satisfactorily the complex and flow rate dependent experimental residence time distribution functions obtained employing a pulse tracer method for different total flow rates of the incoming feed. The variation of the controlling parameters with changing the total inlet flow rate is discussed. The presented model can predict complex internal recirculation streams within the impinging streams reactor system.
https://ijcce.ac.ir/article_33734_73466bae8c6e3f80b6383c680a261d32.pdf
2020-04-01
251
261
10.30492/ijcce.2020.33734
Impinging streams reactor
residence time distribution
internal recirculation
Mathematical modeling
Hoda
Safaei
hoda.safaee@yahoo.com
1
Chemical Engineering Department, Amirkabir University of Technology, Tehran, I.R. IRAN
AUTHOR
Morteza
Sohrabi
sohrabi@aut.ac.ir
2
Chemical Engineering Department, Amirkabir University of Technology, Tehran, I.R. IRAN
AUTHOR
Cavus
Falamaki
c.falamaki@aut.ac.ir
3
Chemical Engineering Department, Amirkabir University of Technology, Tehran, I.R. IRAN
LEAD_AUTHOR
Sayed Javid
Royaee
royaeesj@ripi.ir
4
Petroleum Refining Technology Development Division, Research Institute of Petroleum Industry (RIPI), Tehran, I.R. IRAN
AUTHOR
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[2] Wu Y., Xiao Y., Zhou Y., Micromixing in the Submerged Circulative Impinging Stream Reactor, Chin. J. Chem. Eng., 11(4): 420-425 (2003).
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[13] Ji L., Wu B., Chen K., Zhu J., Experimental Study and Modeling of Residence Time Distribution
13
in Impinging Stream Reactor with GDB Model, J. Ind. Eng. Chem., 16: 646-650 (2010).
14
[14] Royaee S J., Sohrabi M., Jafarikojour M., Kinetic Modeling for Phenol Degradation Using Photo-Impinging Streams Reactor, Res. Chem. Intermed., 41(9): 6409-6431 (2014).
15
[15] Wibel W., Wenka A., Brandner J. J., Dittmeyer R., Measuring and Modeling the Residence Time Distribution of Gas Flows in Multichannel Microreactors, Chem. Eng. J., 215-216: 449-460
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[16] Rajamanickam A., Balu K., Design and Development of Mathematical Model for Static Mixer, Iran. J. Chem. Chem. Eng. (IJCCE), 35(1): 109-116 (2016).
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[17] Wang X., Tian B., Wang C., Wu J., Mathematical Modelling of Residence Time Distribution
18
in Tubular Loop Reactors, Can. J. Chem. Eng., 9999: 1-8 (2016).
19
[18] Royaee S. J., Sohrabi M., Comprehensive Study on Wastewater Treatment Using Photo-Impinging Streams Reactor: Residence Time Distribution and Reactor Modelling, Ind. Eng. Chem. Res., 51: 4152-4160 (2012).
20
[19] Jafarikojour M., Mohammadi M., Sohrabi M., Royaee S.J., Evaluation and Modeling of a Newly Designed Impinging Stream Photoreactor Equipped with a TiO2 Coated Fiberglass Cloth, Roy. Soc. Chem. Adv., 5: 9019-9027 (2015).
21
[20] Jafarikojour M., Sohrabi M., Royaee S.J., Rezaei M., A New Model for Residence Time Distribution of Impinging Stream Reactors Using Descending-Sized Stirred Tank in Series, Chem. Eng. Research. Des., 109: 86-96 (2016).
22
[21] Royaee S.J., Sohrabi M., Jabari barjesteh P., Performance Evaluation of Continuous Flow Photo-Impinging Streams Cyclone Reactor for Phenol Degradation, Chem. Eng. Res. Des., 90: 1923-1929 (2012).
23
[22] Rajaie E., Sohrabi M., Application of the Monte Carlo Technique in Simulation of Flow and Modeling the Residence Time Distribution
24
in a Continuous Two Impinging Liquid–Liquid Streams Contactor, Chem. Eng. J., 143: 249–256 (2008).
25
[23] Ghasemi N., Sohrabi M., Khosravi M., Mujumdar A., Goodarzi M., CFD Simulation of Solid–Liquid Flow in a Two Impinging Streams Cyclone Reactor: Prediction of Mean Residence Time and Holdup of Solid Particles, Chem. Eng. Process., 49: 1277–1283 (2010).
26
[24] Sohrabi M., Jamshidi A. M., Application of the Continuous Two Impinging Stream Reactors
27
in Chemical Absorption, Stud. Surf. Sci. Cat., 122: 423–426 (1999).
28
[25] Sohrabi M., Ahmadi Marvast M., Application of a Continuous Two Impinging Stream Reactor
29
in Solid−Liquid Enzyme Reactions, Ind. Eng. Chem. Res., 39: 1903-1910 (2000).
30
[26] Sohrabi M., Zareikar B., Modeling of the Residence Time Distribution and Application of the Continuous Two Impinging Stream Reactor in Liquid-Liquid Reactions, Chem. Eng. Tech., 28: 61-66 (2005).
31
[27] Sohrabi M., Kaghazchi T., Yazdani F., Modelling and Application of the Continuous Impinging Stream Reactors in Liquid-Liquid Heterogeneous Reactions, Chem. Eng. Tech., 58: 363-370 (1993).
32
[28] Jafarikojour M., Sohrabi M., Royaee S. J., Rezaee M., Residence Time Distribution Analysis and Kinetic Study of Toluene Photo-Degradation Using a Continuous Immobilized Photoreactor, Roy. Soc. Chem. Adv., 4: 53097-53104 (2014).
33
[29] Sohrabi M., Jamshidi A. M., Studies on the Behaviour and Application of the Continuous Two Impinging Stream Reactors in Gas–Liquid Reactions, J. Chem. Tech. Biotech., 69: 415-420 (1997).
34
[30] Royaee S.J., Sohrabi M., Application of Photo-Impinging Streams Reactor in Degradation of Phenol in Aqueous Phase, Desalination, 253: 57–61 (2010).
35
[31] Fatourehchi N., Sohrabi M., Dabir B., Royaee S. J., Haji-Malayeri A., Application of a Novel Type Impinging Stream Reactor in Solid-Liquid Enzyme Reactions and Modeling of Residence Time Distribution Using GDB Model, Enz. Mic.Tech., 55: 14-20 (2014).
36
[32] Madadi S., Sohrabi M., Royaee S. J., Performance Evaluation of a Novel Multi-Stage Axial-Radial Impinging Flow Photo-Reactor for Degradation of p-Nitrophenol, J. Tai. Institute Chem. Eng., 55: 101-111 (2015).
37
[33] Madadi S., Sohrabi M., Royaee S.J., Photodegradation of 4-Nitrophenol Using an Impinging Streams Photoreactor Coupled with a Membrane, Chem. Eng. Process. Proc. Intens., 99: 1-9 (2016).
38
[34] Guo Q., Liang Q., Ni J., Xu S., Yu G., Yu Z., Markov Chain Model of Residence Time Distribution in a New Type Entrained-Flow Gasifier, Chem. Eng. Process. Proc. Intens., 47: 2061–2065 (2008).
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41
ORIGINAL_ARTICLE
Numerical Simulation of Micropolar Flow in a Channel under Osciatory Pressure Gradient
We numerically investigate the pulsatile flow and heat transfer of a micropolar fluid through a Darcy-Forchhmeir porous channel in the presence of wall transpiration. We use the central difference approximations for the spatial derivatives, whereas the time integration has been performed by employing the three steps explicit Runge-Kutta method to obtain the numerical solution. It is noted that the Darcy parameter tends to accelerate the fluid, whereas the Forchheimer quadratic drag parameter and the magnetic parameter would reduce the flow velocity. The effect of the steady component of the pressure gradient is to remarkably accelerate the flow whereas that of the oscillatory component is time-dependent. An increase in the Prandtl number tends to almost straighten the temperature profiles.
https://ijcce.ac.ir/article_37707_4d205a80bdd2144c868985b775aec4e1.pdf
2020-04-01
263
272
10.30492/ijcce.2020.37707
Pulsatile flow, Darcy-Forchhmeir model
Micropolar fluid
Three-step explicit R.K. method
Muhammad
Ashraf
meharashraf25@gmail.com
1
Centre for Advanced Studies in Pure and Applied Mathematics, Bahauddin Zakariya University, Multan, PAKISTAN
AUTHOR
Kashif
Ali
kashifali_381@yahoo.com
2
Department of Basic Sciences and Humanities, Muhammad Nawaz Sharif University of Engineering and Technology, Multan, PAKISTAN
AUTHOR
Muhammad
Ashraf
mashraf_mul@yahoo.com
3
Centre for Advanced Studies in Pure and Applied Mathematics, Bahauddin Zakariya University, Multan, PAKISTAN
LEAD_AUTHOR
[1] Fakour M., Vahabzadeh A., Ganji D., Hatami M., Analytical Study of Micropolar Fluid Flow and Heat Transfer in a Channel with Permeable Walls, Journal of Molecular Liquids, 204(3): 198-204 (2015).
1
[2] Mehrabian M.A., Kimiaeifar A., Golkarfard V., Akhgar A.R., Study of Chemically Reactive Flow and Heat Transfer in The Presence of a Uniform Magnetic Field, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 119-137 (2016).
2
[3] Gibanov N.S., Sheremet M. A., Pop I., Free Convection in a Trapezoidal Cavity Filled with a Micropolar Fluid, International Journal of Heat and Mass Transfer, 99: 831-838 (2016).
3
[4] Ramzan M., Farooq M., Hayat T., Chung J. D., Radiative and Joule Heating Effects in the MHD Flow of a Micropolar Fluid with Partial Slip and Convective Boundary Condition, Journal of Molecular Liquids, 221: 394-400 (2016).
4
[5] Akhter S., Ashraf M., Ali K., MHD Flow and Heat Transfer Analysis of Micropolar Fluid Through
5
a Porous Medium between Two Stretchable Disks Using Quasi-Linearization Method, Iran. J. Chem. Chem. Eng. (IJCCE), 36(4): 155-169 (2017).
6
[6] Hsiao K. L., Micropolar Nanofluid Flow with MHD and Viscous Dissipation Effects Towards a Stretching Sheet with Multimedia Feature, International Journal of Heat and Mass Transfer, 112: 983-990 (2017)
7
[7] Habibi M. R., Amini M., Arefmanesh A., Ghasemikafrudi E., Effects of Viscosity Variations on Buoyancy-Driven Flow from a Horizontal Circular Cylinder Immersed in Al2O3-Water Nanofluid, Iran. J. Chem. Chem. Eng. (IJCCE), 38(1): 213-232 (2019)
8
[8]. Abdulaziz O., N. F M Noor N. F. M.,Hashim I., Homotopy Analysis Method for Fully Developed MHD Micropolar Fluid Flow between Vertical Porous Plates, Int. J. for Num Meth. Engin., 78(7): 817-827 (2009).
9
[9] Noor N.F.M., Haq R.U., Nadeem S., Mixed Convection Stagnation Flow of a Micropolar Nanofluid Along a Vertically Stretching Surface with Slip Effects, Meccanica, 50(8): 2007-2022 (2015).
10
[10] Haq U.R., Noor N.F.M., Khan Z.H., Numerical Simulation of Water Based Magnetic Nanoparticles between Two Parallel Disks, Adv. Pow. Tech., 27: 1568-1575 (2016).
11
[11] Zheng L., Liu N., Niu J., Zhang X., Slip and Buoyancy Lift Effects on the Mixed Convection Flow and Radiation Heat Transfer of a Micropolar Fluid Toward Vertical Permeable Plate, J. of Por. Med., 16: 575-583 (2013).
12
[12] Hung K.Y., Hsu T.H., Lin J.W., Mixed Convection of Micropolar Fluids in a Vertical Wavy Channel Saturated with Porous Media, J. of Por. Med., 16: 1107-1118 (2013).
13
[13] Hung K.Y., Hsu T. H., Lin J.W., Transient Behavior of Micropolar Fluids Through a Porous Wavy Channel, J. of Por. Med., 17: 1-15 (2014).
14
[14] Umavathi J., Sheka M., Flow and Heat Transfer in a Porous Medium Saturated by a Micropolar Fluid between Parallel Permeable Disks, J. of Por. Med., 17: 669-684 (2014).
15
[15] Rashidi M.M., Ali M., Freidoonimehr N., Rostami B., Hossain M.A., Mixed Convective Heat Transfer
16
for MHD Viscoelastic Fluid Flow over a Porous Wedge with Thermal Radiation, Int. J. of Ther. Sci.vol. 2014(87): 136-145 (2015).
17
[16] Malik M.Y., Khan I., Hussain A., Salahuddin T., Mixed Convection Flow of MHD Eyring-Powell Nanofluid over a Stretching Sheet: A numerical Study,Amer. Inst. of Phy. AIP Adv., 5, 117118 doi: 10.1063/1.4935639, (2015).
18
[17] Abbasbandy S., Hayat T., Alsaedi A., Rashidi M. M., Numerical and Analytical Solutions for Falkner-Skan Flow of MHD Oldroyd-B Fluid, Int. J. of Num. Meth. for HFF, 24: 390-401 (2014).
19
[18] Rashidi M.M., Erfani E., Analytical Method for Solving Steady MHD Convective and Slip Flow Due to a Rotating Disk with Viscous Dissipation and Ohmic Heating, Engine. Comput., 29(6): 562-579 (2012).
20
[19] Cai J., Hu X., Xiao B., Zhou Y., Wei, W., Recent Developments on Fractal-Based Approaches to Nanofluids and Nanoparticle Aggregation, Int. J. Heat Mass Transfer, 105: 623-637 (2017).
21
[20] Khidir A.A., Sibanda P., Nanofluid Flow over a Nonlinear Stretching Sheet in Porous Media with Mhd and Viscous Dissipation Effects, J. of Por. Med., 17: 391-403 (2014).
22
[21] Khan W.A., Uddin J.M., Ismail A.I. Md., Effect of Multiple Slips and Dissipation on Boundary Layer Flow of Nanofluid Flow over a Porous Flat Plate in Porous Media, J. of Por. Med., 18: 1-14 (2015).
23
[22] Tian X., Wang P., Xu S., Wu X, Comparison Study of Different Viscous Dissipation Effects on Forced Convection Heat Transfer in a Power Law Fluid Saturated Porous Medium, J. of Por. Med., 19: 885-900 (2016).
24
[23] Azarkhalil M.S., Keyyani B., Synthesis of Silver Nanoparticles from Spent X-Ray Photographic Solution via Chemical Reduction, Iran. J. Chem. Chem. Eng. (IJCCE), 35(3): 1-8 (2016).
25
[24] Izadkhah M., Erfan-Niya H., Moradkhani H., Rheological Behavior of Water-Ethylene Glycol Based Graphene Oxide Nanofluids, Iran. J. Chem. Chem. Eng. (IJCCE), 37(5): 177-187 (2018).
26
ORIGINAL_ARTICLE
Numerical Study on Parameters Affecting the Structure of Scaffolds Prepared by Freeze-Drying Method
Freeze-drying is one of the most used methods for preparing scaffolds and is very sensitive to the material and operational parameters such as nucleation temperature, thermal properties of the mold, cooling rate, set freezing point, and slurry height. In the present study, a Finite Element Method (FEM) based code was developed to investigate the effects of such parameters and to eventually predict the microstructure of the scaffold. Similar molds and cooling conditions used in various experimental studies were simulated and compared. The achieved pattern demonstrated how different thermal condition tailored scaffold microstructure. It was shown that nucleation temperature (Tn) was an effective parameter controlling the final structure of the scaffold and influenced pore sizes with different mold materials. Simulation results also showed that by decreasing the rate of cooling, the average pore sizes increased, and a quenching solution led to a randomly distributed pattern of pore sizes. It is also achieved that by increasing the set freezing temperature as well as the height of the solution the pore sizes increased more at the top of the mold. The thermal gradient also illustrated the orientation of the pore in a mold with the thick isolated wall was considerably uniform. This framework can be used to optimize the scaffold structure or any ice templating method.
https://ijcce.ac.ir/article_37001_6a8e54d52d43ddac6923d6f133717cc3.pdf
2020-04-01
273
288
10.30492/ijcce.2020.37001
Finite element Methods
Scaffold
Freeze-drying
ice
crystal size
Mahdi
Madelatparvar
mahdi_mp@yahoo.com
1
Faculty of Polymer Engineering, Sahand University of Technology, Tabriz, I.R. IRAN
AUTHOR
Mahdi
Salami Hosseini
salami@sut.ac.ir
2
Faculty of Polymer Engineering, Sahand University of Technology, Tabriz, I.R. IRAN
LEAD_AUTHOR
Farhang
Abbasi
f.abbasi@sut.ac.ir
3
Faculty of Polymer Engineering, Sahand University of Technology, Tabriz, I.R. IRAN
AUTHOR
[1] Chung H.J., Park T.G., Surface Engineered and Drug Releasing Pre-Fabricated Scaffolds for Tissue Engineering. Advanced Drug Delivery Reviews, 59(4): 249-262 (2007).
1
[2] O'Brien F.J., Biomaterials & Scaffolds for Tissue Engineering. Materials Today, 14 (3): 88-95 (2011).
2
[3] O’Brien F.J., Harley B.A., Yannas I.V., Gibson L., Influence of Freezing Rate on Pore Structure
3
in Freeze-Dried Collagen-GAG Scaffolds, Biomaterials, 25 (6), 1077-1086 (2004).
4
[4] Madaghiele M., Sannino A., Yannas I.V., Spector M., Collagen‐Based Matrices with Axially Oriented Pores, Journal of Biomedical Materials Research Part A, 85 (3): 757-767 (2008).
5
[5] Alizadeh M., Abbasi F., Khoshfetrat A., Ghaleh H., Microstructure and Characteristic Properties of Gelatin/Chitosan Scaffold Prepared by a Combined Freeze-Drying/Leaching Method, Materials Science and Engineering: C, 33(7): 3958-3967 (2013).
6
[6] Davidenko N., Gibb T., Schuster C., Best S.M., Campbell J., Watson C., Cameron R.E., Biomimetic Collagen Scaffolds with Anisotropic Pore Architecture, Acta Biomaterialia, 8 (2): 667-676 (2012).
7
[7] Haugh M.G., Murphy C.M., O'Brien F.J., Novel Freeze-Drying Methods to Produce a Range of Collagen–Glycosaminoglycan Scaffolds with Tailored Mean Pore Sizes, Tissue Engineering Part C: Methods, 16 (5): 887-894 (2009).
8
[8] Yuan N.-Y., Lin Y.-A., Ho M.-H., Wang D.-M., Lai J.-Y., Hsieh H.-J., Effects of the Cooling mode on the Structure and Strength of Porous Scaffolds Made of Chitosan, Alginate, and Carboxymethyl Cellulose by the Freeze-Gelation Method, Carbohydrate Polymers, 78 (2): 349-356 (2009).
9
[9] Tanthapanichakoon W., Tamon H., Nakagawa K., Charinpanitkul T., Synthesis of Porous Materials
10
and Their Microstructural Control through Ice Templating. Engineering Journal, 17 (3): 1-8 (2013).
11
[10] Moore M.J., Friedman J.A., Lewellyn E.B., Mantila S.M., Krych A.J., Ameenuddin S., Knight A.M., Lu L., Currier B.L., Spinner R.J., Multiple-Channel Scaffolds to Promote Spinal Cord Axon Regeneration, Biomaterials, 27 (3): 419-429 (2006).
12
[11] Yannas I., Burke J., Orgill D., Skrabut E., Wound Tissue can Utilize a Polymeric Template to Synthesize a Functional Extension of Skin, Science, 215 (4529): 174-176 (1982).
13
[12] Lee S.Y., Oh J.H., Kim J.C., Kim Y.H., Kim S.H., Choi J.W., In vivo Conjunctival Reconstruction Using Modified PLGA Grafts for Decreased Scar Formation and Contraction, Biomaterials, 24(27): 5049-5059 (2003).
14
[13] Murphy C.M., Haugh M.G., O'Brien, F.J., The Effect of Mean Pore Size on Cell Attachment, Proliferation and Migration in Collagen–Glycosaminoglycan Scaffolds for Bone Tissue Engineering. Biomaterials, 31 (3): 461-466 (2010).
15
[14] Berry C.C., Campbell G., Spadiccino A., Robertson M., Curtis A.S., The Influence of Microscale Topography on Fibroblast Attachment and Motility, Biomaterials, 25(26): 5781-5788 (2004).
16
[15] Woinet B., Andrieu J., Laurent M., Min S., Experimental and Theoretical Study of Model Food Freezing. Part II. Characterization and Modelling of the Ice Crystal Size, Journal of Food Engineering, 35(4): 395-407 (1998).
17
16] Pawelec K., Husmann A., Best S.M., Cameron R.E., Understanding Anisotropy and Architecture in Ice-Templated Biopolymer Scaffolds, Materials Science and Engineering: C, (2014).
18
[17] Pawelec K., Husmann A., Best S.M., Cameron R.E., A Design protocol for tailoring ice-templated scaffold Structure, Journal of the Royal Society Interface, 11(92): 20130958 (2014).
19
[18] Kiani H., Sun D.-W., Water Crystallization and Its Importance to Freezing of Foods: A Review, Trends in Food Science & Technology, 22(8): 407-426 (2011).
20
[19] Lunardini, V.J., “Heat Transfer with Freezing and Thawing”, Elsevier: (1991).
21
[20] Moore E.B., Molinero V., Structural Transformation in Supercooled Water Controls the Crystallization Rate of Ice, Nature, 479(7374): 506-508 (2011).
22
[21] Nakagawa K., Hottot A., Vessot S., Andrieu J., Modeling of Freezing Step during Freeze‐Drying of Drugs in Vials, AIChE Journal, 53(5): 1362-1372 (2007).
23
[22] Saatchi, A., Seddiqi, H., Amoabediny, G., Helder, M.N., Zandieh-Doulabi, B., Klein-Nulend, J., Computational Fluid Dynamics in 3D-Printed Scaffolds with Different Strand-Orientation in Perfusion Bioreactors. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), - (2019). [in Press]
24
[23] Muzzio C.R., Dini N.G., Simulation of Freezing Step in Vial Lyophilization Using Finite Element Method, Computers & Chemical Engineering, 35 (11): 2274-2283 (2011).
25
[24] Nakagawa, K., Thongprachan, N., Charinpanitkul, T., Tanthapanichakoon, W., Ice Crystal Formation
26
in the Carbon Nanotube Suspension: A Modelling Approach, Chemical Engineering Science, 65 (4): 1438-1451 (2010).
27
[25] Quintero Ortega I.s.A., Mota-Morales J.D., Elizalde Peña E.A., Zárate-Triviño D.G., De Santiago Y.A., Ortiz A., García Gaitan B., Sanchez I.C., Luna-Bárcenas G., Cryogenic Process to Elaborate
28
Poly (ethylene glycol) Scaffolds. Experimental and Simulation Studies. Industrial & Engineering Chemistry Research, 52 (2): 706-715 (2012).
29
[26] Chan K., Liang W., Francis W., Nicolella D., A Multiscale Modeling Approach to Scaffold Design and Property Prediction, Journal of the Mechanical Behavior of Biomedical Materials, 3(8): 584-593 (2010).
30
[27] Hollister S., Maddox R., Taboas J., Optimal Design and Fabrication of Scaffolds to Mimic Tissue Properties and Satisfy Biological Constraints, Biomaterials, 23(20): 4095-4103 (2002).
31
[28] Mehdizadeh H., Sumo S., Bayrak E.S., Brey E.M., Cinar A., Three-dimensional Modeling of Angiogenesis in Porous Biomaterial Scaffolds, Biomaterials, 34 (12): 2875-2887 (2013).
32
[29] Yu P., Lee T.S., Zeng Y., Low H.T., Fluid Dynamics and Oxygen Transport in a Micro-Bioreactor
33
with a Tissue Engineering Scaffold, International Journal of Heat and Mass Transfer, 52 (1): 316-327 (2009).
34
[30] Youssef K., Mack J., Iruela‐Arispe M., Bouchard L.S., Macro‐Scale Topology Optimization for Controlling Internal Shear Stress in a Porous Scaffold Bioreactor, Biotechnology and Bioengineering, 109(7): 1844-1854 (2012).
35
[31] Kamalipour M., AliMousavi Dehghani S.A., Naseri A., Abbasi S., Distinguishing Anhydrate
36
and Gypsum Scale in Mixing Incompatible Surface and Ground Waters During Water Injection
37
Process, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(1): 231-240
38
[32] Jamshidi S., Bozorgmehry Boozarjomehry R., Pishvaie S.M.R., An Irregular Lattice Pore Network Model Construction Algorithm, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 29(1): 61-70 (2010).
39
[33] Ghaleh H., Abbasi F., Alizadeh M., Khoshfetrat A.B., Mimicking the Quasi-Random Assembly of Protein Fibers in the Dermis by Freeze-Drying Method, Materials Science and Engineering: C, 49: 807-815 (2015).
40
[34] Williams T.L., “An Experimental Investigation of Natural Convection Heat Transfer in a Refrigerator During Closed Door Conditions”; Air Conditioning and Refrigeration Center. College of Engineering, University of Illinois at Urbana-Champaign (1994).
41
[35] Shultz, M.J., Bisson, P.J., Brumberg, A., Best Face Forward: Crystal-Face Competition at the Ice-Water Interface, The Journal of Physical Chemistry B, 118(28): 7972–7980 (2014).
42
[36] Swope W.C., Andersen H.C., Berens P.H., Wilson K.R., A Computer Simulation Method for the Calculation of Equilibrium Constants for the Formation of Physical Clusters of Molecules: Application To Small Water Clusters, The Journal of Chemical Physics, 76(1): 637-649 (1982).
43
ORIGINAL_ARTICLE
Studies on the Influence of Various Metabolic Uncouplers on the Biodegradation Rate of Toluene in a Biofilm Bio-Filter Reactor
Biological inhibition of air pollution has vast advantages over physicochemical methods. One of the biggest challenges faced by researchers with traditional bio-filter in controlling Volatile Organic Compounds (VOCs) such as Benzene, Toluene, Ethylbenzene and Xylene (BTEX) is, low degradation rate (elimination capacity) and accumulation of very high biomass. The use of metabolic uncouplers involves uncoupling electron transport from oxidative phosphorylation reactions and thereby ATP production is less efficient, leads to more substrate utilization. So, this research is aimed to study the influence of different metabolic uncouplers on the biodegradation rate of toluene in a biofilm bio-filter reactor. The bio-filter reactor with Pseudomonas putida MTCC 10617 as biofilm in the presence of five different metabolic uncouplers such as Pentachlorophenol (PCP), 2, 4-Dinitrophenol (DNP), 2, 4, 6-Trichlorophenol (TCP), Benzoic Acid (BA) and Malonic Acid (MA) were studied. Results showed that only PCP and TCP increased the Surface Elimination Capacity (SEC) by 87% and 38% respectively. From the SEM analysis, larger and wider air interface cavities were observed in the biofilm subjected to PCP than TCP exposed biofilm. This infers the higher mass transfer in biofilm exposed to PCP.
https://ijcce.ac.ir/article_43271_894c16de89f371a566dca4964fdaf412.pdf
2020-04-01
289
297
10.30492/ijcce.2020.43271
biofilm
Bioreactor
metabolic uncoupler
surface elimination capacity
Suganya
Baskaran
suganyab@svce.ac.in
1
Department of Chemical Engineering, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur, Tamilnadu-602117, INDIA
AUTHOR
Swaminathan
Detchanamurthy
swamibiochem@gmail.com
2
Department of Chemical Engineering, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur, Tamilnadu-602117, INDIA
LEAD_AUTHOR
[1] Detchanamurthy S., Gostomski P.A., Biofiltration for Treating Vocs: an Overview, Reviews in Environmental Science and Bio/Technology, 11(3): 231-241 (2012).
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[2] Leson G., Winer A.M., Biofiltration: an Innovative Air Pollution Control Technology for VOC Emissions, Journal of the Air & Waste Management Association, 41(8): 1045-1054 (1991).
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[3] Detchanamurthy S., Gostomski P.A., Metabolic Uncouplers in Environmental Research: a Critical Review, Reviews in Chemical Engineering, 28(4-6): 309-317 (2012).
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[4] Low E.W., Chase H.A., The Use of Chemical Uncouplers for Reducing Biomass Production During Biodegradation, Water Science and Technology, 37(4-5): 399-402 (1998).
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[5] Hiraishi A., Kawagishi T., Effects of Chemical Uncouplers on Microbial Biomass Production, Metabolic Activity, and Community Structure in an Activated Sludge System, Microbes and Environments, 17(4):197-204 (2002).
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[6] Del Castilla T., Ramos J.L., Simultaneous Catabolite Repression between Glucose and Toluene Metabolism in Pseudomonas Putida is Channelled Through Different Signalling Pathways, Journal of Bacteriology, 189(18):6602-6610 (2007).
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[7] Weinbach E.C., Garbus J., The Interaction of Uncoupling Phenols with Mitochondria and with Mitochondrial Protein, Journal of Biological Chemistry, 240(4): 1811-1819 (1965).
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[8] Stockdale M., Selwyn M.J., Effects of Ring Substituents on the Activity of Phenols as Inhibitors and Uncouplers of Mitochondrial Respiration, The FEBS Journal, 21(4): 565-574 (1971).
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[9] Zheng G., Li M., Wang L., Chen Z., Qian Y., Zhou Q., Feasibility of 2, 4, 6-Trichlorophenol and Malonic Acid as Metabolic Uncoupler for Sludge Reduction in the Sequence Batch Reactor for Treating Organic Wastewater, Applied Biochemistry And Biotechnology, 144(2):101-109 (2008).
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[10] Kimura N., Shinozaki Y., Suwa Y., Urushigawa Y.. Phylogenetic and Phenotypic Relationships of Microorganisms that Degrade Uncoupler Compound, 2,4-Dinitrophenol, The Journal of General And Applied Microbiolohy, 46(6): 317-322 (2000).
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[11] Achinta B, Gostomski PA., Influence of Environmental Parameters on the Carbon Balance in a Biofilter, Chemeca Proceedings, 526-533 (2014).
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[12] Detchanamurthy S., Gostomski P.A., Muralidhar A., Isolation, Characterization and Preservation of Toluene Degraders from Soil Subjected to Biofiltration Studies. Biotechnology, An Indian Journal., 10(1):18-23 (2014).
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[13] Shen Y., Stehmeier L.G., Voordouw G., Identification of Hydrocarbon-Degrading Bacteria in Soil by Reverse Sample Genome Probing, Applied and Environmental Microbiology, 64(2):637-645 (1998).
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[14] Detchanamurthy S., Gostomski P.A., Development of a Modified Differential Biofiltration Reactor with Online Sample and Carbon Dioxide Monitoring System, Asia-Pacific Journal of Chemical Engineering, 8(3): 414-424 (2013).
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[15] Detchanamurthy S., Gostomski P.A., Studies on the Influence of Different Metabolic Uncouplers on the Biodegradation of Toluene in a Differential Biofilter Reactor, Biotechnology and Bioprocess Engineering, 20(5): 915-923 (2015).
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