ORIGINAL_ARTICLE
Nano-Ceria (CeO2): An Efficient Catalyst for the Multi-Component Synthesis of a Variety of Key Medicinal Heterocyclic Compounds
This review gives an overview of the applications of ceria nanoparticles as inexpensive, efficient, reusable, and environmentally sustainable heterogeneous catalysts for the synthesis of a variety of key medicinal heterocyclic compounds with the emphasis on mechanistic aspects of the reactions. Literature has been surveyed from 2005 to 2018.
https://ijcce.ac.ir/article_33786_baceacee9e22ec4b9f1bfad5256a8bd2.pdf
2019-12-01
1
19
10.30492/ijcce.2019.33786
ceria nanoparticles
multicomponent reactions
heterocycles
catalyst
Synthesis
Sheida
Ahmadi
sh.ahmadi_ch@yahoo.com
1
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, I.R. IRAN
AUTHOR
Akram
Hosseinian
hoseinian@ut.ac.ir
2
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, I.R. IRAN
AUTHOR
Parvaneh
Delir Kheirollahi Nezhad
parvanehdalir@yahoo.com
3
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, I.R. IRAN
AUTHOR
Aazam
Monfared
dmonfared@gmail.com
4
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, I.R. IRAN
AUTHOR
Esmail
Vessally
vessally@yahoo.com
5
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Eicher T., Hauptmann S., Speicher A., “The Chemistry of Heterocycles”, Georg Thieme, Stuttgart (2003).
1
[2] Gomtsyan A., Heterocycles in Drugs and Drug Discovery, Chem. Heterocycl. Compd., 48: 7-10 (2012).
2
[3] Martins P., Jesus J., Santos S., Raposo L.R., Roma-Rodrigues, C., Baptista P.V., Fernandes, A.R., Heterocyclic Anticancer Compounds: Recent Advances and the Paradigm Shift Towards the Use of Nanomedicine''s Tool Box, Molecules, 20: 16852-16891 (2015).
3
[4] (a) Vessally E., Abdoli M., Oxime Ethers as Useful Synthons in the Synthesis of a Number of Key Medicinal Heteroaromatic Compounds, J. Iran. Chem. Soc., 13: 1235-1256 (2016);
4
(b) Babazadeh M., Soleimani-Amiri S., Vessally E., Hosseinian A., Edjlali L., Transition Metal-Catalyzed [2+ 2+ 2] Cycloaddition of Nitrogen-Linked 1, 6-Diynes: A Straightforward Route to Fused Pyrrolidine Systems, RSC Adv., 7: 43716-43736 (2017);
5
(c) Arshadi S., Vessally E., Edjlali L., Ghorbani-Kalhor E., Hosseinzadeh-Khanmiri, R., N-Propargylic β-Enaminocarbonyls: Powerful and Versatile Building Blocks in Organic Synthesis, RSC Adv., 7: 13198-13211 (2017);
6
(d) Arshadi S., Vessally E., Sobati M., Hosseinian A., Bekhradnia A., Chemical Fixation of CO2 to N-Propargylamines: A Straightforward Route to 2-Oxazolidinones, J. CO2 Util., 19: 120-129 (2017);
7
(e) Vessally E., Babazadeh M., Didehban K., Hosseinian A., Edjlali L., Intramolecular Cyclization of N-Arylpropiolamides: A New Strategy for the Synthesis of Functionalized 2-Quinolones, Cur. Org. Chem., 21: 2561-2572 (2017);
8
(f) Vessally E., Hosseinian A., Edjlali L., Ghorbani-Kalhor E., Hosseinzadeh-Khanmiri R., Intramolecular Cyclization of N-Propargyl Anilines: A New Synthetic Entry Into Highly Substituted Indoles, J. Iran. Chem. Soc., 14: 2339-2353 (2017);
9
(g) Vessally E., Hosseinian A., Edjlali L., Babazadeh M., Hosseinzadeh-Khanmiri R., New Strategy for the Synthesis of Morpholine Cores: Synthesis from N-Propargylamines, Iran. J. Chem. Chem. Eng. (IJCCE), 36: 1-13 (2017).
10
[5] (a) D''Souza D.M., Mueller T.J., Multi-Component Syntheses of Heterocycles by Transition-Metal Catalysis, Chem. Soc. Rev., 36: 1095-1108 (2007);
11
(b) Jiang B., Rajale T., Wever W., Tu S.J., Li G., Multicomponent Reactions for the Synthesis of Heterocycles, Chem. Asian J., 5: 2318-2335 (2010).
12
(c) Banerjee B., Recent Developments on Ultrasound-Assisted One-Pot Multicomponent Synthesis of Biologically Relevant Heterocycles, Ultrason Sonochem., 35: 15-35 (2017);
13
(d) Ibarra I.A., Islas-Jácome A., González-Zamora E., Synthesis of Polyheterocycles via Multicomponent Reactions, Org. Biomol. Chem., 16: 1402-1418 (2018);
14
(e) Ramazani A., Reza Kazemizadeh A., Preparation of Stabilized Phosphorus Ylides via Multicomponent Reactions and their Synthetic Applications, Curr. Org. Chem., 15: 3986-4020 (2011);
15
(f) Reza Kazemizadeh A., Ramazani A., Synthetic Applications of Passerini Reaction, Curr. Org. Chem., 16: 418-450 (2012);
16
(g) Marjani A.P., Khalafy J., Chitan M., Mahmoodi S., Microwave-Assisted Synthesis of Acridine-1,8(2H,5H)-Diones via a One-Pot, Three Component Reaction, Iran. J. Chem. Chem. Eng. (IJCCE), 36: 1-6 (2017(.
17
[6] Bhaskaruni S.V., Maddila S., Gangu K.K., Jonnalagadda S.B., A Review on Multi-Component Green Synthesis of N-Containing Heterocycles Using Mixed Oxides as Heterogeneous Catalysts, Arab. J. Chem., (2017).
18
DOI: 10.1016/j.arabjc.2017.09.016.
19
[7] (a) Vessally E., Babazadeh M., Hosseinian A., Arshadi S., Edjlali L., Nanocatalysts for Chemical Transformation of Carbon Dioxide, J. CO2 Util., 21: 491-502 (2017);
20
(b) Didehban K., Vessally E., Hosseinian A., Edjlali L., Khosroshahi E.S., Nanocatalysts for C–Se Cross-Coupling Reactions, RSC Adv., 8: 291-301 (2018);
21
(c) Visually E., Didehban K., Mohammadi R., Hosseinian A., Babazadeh M., Recent Advantages in the Metal (bulk and nano)-Catalyzed S-Arylation Reactions of Thiols with Aryl Halides in Water: A Perfect Synergy for Eco-Compatible Preparation of Aromatic Thioethers, J. Sulfur Chem., 39: 332-349 (2018);
22
d) Ramazani A., Asiabi P.A., Aghahosseini H., Gouranlou F., Review on the Synthesis and Functionalization of SiO2 Nanoparticles as Solid Supported Catalysts, Curr. Org. Chem., 21: 908-922 (2017);
23
(e) Aghahosseini H., Ramazani A., Gouranlou F., Woo J.S., Nanoreactors Technology in Green Organic Synthesis, Curr. Org. Synth., 14: 810-864 (2017);
24
(f) Nakhaei A., Davoodnia A., Yadegarian S., An Efficient Green Approach for the Synthesis of Fluoroquinolones as Potential Antibacterial Using Nano Zirconia Sulfuric Acid as Highly Efficient Recyclable Catalyst, Iran. J. Chem. Chem. Eng. (IJCCE), 37(3): 33-42 (2018).
25
(g) Kalhor M., Seyedzade Z., Ni@zeolite-Y Nano-Porous: Preparation and Application as a High Efficient Catalyst for Facile Synthesis of Quinoxaline, Pyridopyrazine and Indoloquinoxaline Derivatives, Iran. J. Chem. Chem. Eng. (IJCCE), 38(1): 27-41 (2019).
26
[8] Shirini F., Abedini M., Application of Nanocatalysts in Multi-Component Reactions, J. Nanosci. Nanotechnol., 13: 4838-4860 (2013).
27
[9] (a) Juárez R., Concepción P., Corma A., García H., Ceria Nanoparticles as Heterogeneous Catalyst for CO2 Fixation by ω-Aminoalcohols, ChemComm., 46: 4181-4183 (2010);
28
(b) Leyva-Pérez A., Cómbita-Merchán D., Cabrero-Antonino J.R., Al-Resayes S.I., Corma A., Oxyhalogenation of Activated Arenes with Nanocrystalline Ceria, ACS Catal, 3: 250-258 (2013);
29
(c) Shelkar R., Sarode S., Nagarkar J., Nano Ceria Catalyzed Synthesis of Substituted Benzimidazole, Benzothiazole, and Benzoxazole in Aqueous Media, Tetrahedron Lett, 54: 6986-6990 (2013).
30
[10] Dheer D., Singh V., Shankar R., Medicinal Attributes of 1, 2, 3-Triazoles: Current Developments, Bioorganic. Chem., 71: 30-54 (2017).
31
[11] (a) Agalave S.G., Maujan S.R., Pore V.S., Click Chemistry: 1, 2, 3‐Triazoles as Pharmacophores, Chem. Asian J., 6: 2696-2718 (2011);
32
(b) Jalani H.B., Karagöz A.Ç., Tsogoeva S.B., Synthesis of Substituted 1, 2, 3-Triazoles Via Metal-Free Click Cycloaddition Reactions and Alternative Cyclization Methods, Synthesis, 49: 29-41(2017);
33
(c) Saeidian H., Sadighian H., Abdoli M., Sahandi M., Versatile and Green Synthesis, Spectroscopic Characterizations, Crystal Structure and DFT Calculations of 1, 2, 3‒Triazole‒Based Sulfonamides, J. Mol. Struct., 1131: 73-78 (2017).
34
[12] Albadi J., Shiran J.A., Mansournezhad A., Click Synthesis of 1,4-Disubstituted-1,2,3-Triazoles Catalysed by CuO–CeO2 Nanocomposite in the Presence of Amberlite-Supported Azide, J. Chem. Sci., 126: 147-150 (2014).
35
[13] Amini M., Hassandoost R., Bagherzadeh M., Gautam S., Chae K.H. Copper Nanoparticles Supported on CeO2 as an Efficient Catalyst for Click Reactions of Azides with Alkynes, Catal. Commun., 85: 13-16 (2016).
36
[14] Bhardwaj V., Gumber D., Abbot V., Dhiman S., Sharma P., Pyrrole: A Resourceful Small Molecule in Key Medicinal Hetero-Aromatics, RSC Adv., 5: 15233-15266 (2015).
37
[15] Vessally E., A New Avenue to the Synthesis of Highly Substituted Pyrroles: Synthesis from N-Propargylamines, RSC Adv., 6: 18619-18631 (2016).
38
[16] (a) Estevez V., Villacampa M., Menendez J.C., Multicomponent Reactions for the Synthesis of Pyrroles, Chem. Soc. Rev., 39: 4402-4421 (2010);
39
(b) Estévez V., Villacampa M., Menéndez J.C., Recent Advances in the Synthesis of Pyrroles by Multicomponent Reactions, Chem. Soc. Rev., 43: 4633-4657 (2014);
40
(c) Saeidian H., Abdoli M., Salimi R., One-Pot Synthesis of Highly Substituted Pyrroles Using Nano Copper Oxide as an Effective Heterogeneous Nanocatalyst, C. R. Chim., 16: 1063-1070 (2013).
41
[17] Samai B., Sarkar S., Chall S., Rakshit S., Bhattacharya S.C., Polymer-Fabricated Synthesis of Cerium Oxide Nanoparticles and Applications as a Green Catalyst Towards Multicomponent Transformation with Size-Dependent Activity Studies, Cryst. Eng. Comm., 18: 7873-7882 (2016).
42
[18] Wang Y., Ge W., Fang Y., Ren X., Cao S., Liu G., Li M., Xu J., Wan Y., Han X., Porous CeO2 Nanorod-Catalyzed Synthesis of Poly-Substituted Imino-Pyrrolidine-Thiones, Res. Chem. Intermed., 43: 631-640 (2017).
43
[19] (a) Goetz A.E., Garg N.K., Regioselective Reactions of 3, 4-Pyridynes Enabled by the Aryne Distortion Model, Nature Chem., 5: 54-60 (2013);
44
(b) Baumann M., Baxendale I.R., An Overview of the Synthetic Routes to the Best Selling Drugs Containing 6-Membered Heterocycles, Beilstein J. Org. Chem., 9: 2265-2319 (2013).
45
[20] (a) Hill M.D., Recent Strategies for the Synthesis of Pyridine Derivatives, Chem. Eur. J., 16: 12052-12062 (2010);
46
(b) Vessally E., Hosseinian A., Edjlali L., Bekhradnia A., Esrafili M.D., New Page to Access Pyridine Derivatives: Synthesis from N-Propargylamines, RSC Adv., 6: 71662-71675 (2016).
47
[21] Gawande M.B., Bonifácio V.D., Varma R.S., Nogueira I.D., Bundaleski N., Ghumman C.A.A., Teodoro O.M., Branco P.S., Magnetically Recyclable Magnetite–Ceria (Nanocat-Fe-Ce) Nanocatalyst–Applications in Multicomponent Reactions under Benign Conditions, Green Chem., 15: 1226-1231 (2013).
48
[22] Girija D., Naik H.S.B., Sudhamani C., Kumar B.V., Cerium Oxide Nanoparticles - A Green, Reusable, and Highly Efficient Heterogeneous Catalyst for the Synthesis of Polyhydroquinolines under Solvent-Free Conditions, Arch. Appl. Sci. Res., 3: 373-382 (2011).
49
[23] Kumar P.S.V., Suresh L., Vinodkumar T., Chandramouli G., Eu2O3 Modified CeO2 Nanoparticles as a Heterogeneous Catalyst for an Efficient Green Multicomponent Synthesis of Novel Phenyldiazenyl-acridinedione-Carboxylic acid derivatives in Aqueous Medium, RSC Adv., 6: 91133-91140 (2016).
50
[24] Sharma V., Chitranshi N., Agarwal A.K., Significance and Biological Importance of Pyrimidine in the Microbial World, Int. J. Med. Chem., (2014) DOI: 10.1155/2014/202784.
51
[25] Selvam T.P., James C.R., Dniandev P.V., Valzita S.K., A Mini Review of Pyrimidine and Fused Pyrimidine Marketed Drugs, Res. Pharm., 2: 1-9 (2015).
52
[26] Gore R.P., Rajput A.P., A review on recent Progress in Multicomponent Reactions of Pyrimidine Synthesis, Drug Inv. Today, 5: 148-152 (2013).
53
[27] Sabitha G., Reddy K.B., Yadav J., Shailaja D., Sivudu K.S., Ceria/vinylpyridine Polymer Nanocomposite: an Ecofriendly Catalyst for the Synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones, Tetrahedron Lett., 46: 8221-8224 (2005).
54
[28] Biklarian H., Behbahani F.K., Fakhroueian Z., 22% Co/CeO2-ZrO2-catalyzed Synthesis of 1, 2, 3, 4-tetrahydro-2-pyrimidinones and-thiones, Lett. Org. Chem, 9:580-584 (2012).
55
[29] Albadi J., Mansournezhad A., CuO-CeO2 Nanocomposite: A Green Recyclable Catalyst for the Synthesis of 3, 4-dihydropyrimidin-2 (1H)-Ones/Thiones, Iran. J. Catal., 3, 73-77 (2013).
56
[30] Suresh L., Kumar P.S.V., Vinodkumar T., Chandramouli G., Heterogeneous Recyclable Nano-CeO2 Catalyst: Efficient and Eco-Friendly Synthesis of Novel Fused Triazolo and Tetrazolo Pyrimidine Derivatives in Aqueous Medium, RSC Adv., 6: 68788-68797 (2016).
57
[31] (a) Ballini R., Bosica G., Conforti M.L., Maggi R., Mazzacani A., Righi P., Sartori G., Three-Component Process for the Synthesis of 2-amino-2-Chromenes in Aqueous Media, Tetrahedron, 57, 1395-1398 (2001);
58
(b) Maggi R., Ballini R., Sartori G., Sartorio R., Basic Alumina Catalysed Synthesis of Substituted 2-amino-2-chromenes via Three-Component reaction, Tetrahedron Lett., 45: 2297-2299 (2004);
59
(c) Sabitha G., Bhikshapathi M., Nayak S., Srinivas R., Yadav J., Triton B Catalyzed Three‐Component, One‐Pot Synthesis of 2‐amino‐2‐chromenes at Ambient Temperature, J. Heterocycl. Chem., 48: 267-271 (2011).
60
[32] Pratap R., Ram V.J., Natural and Synthetic Chromenes, Fused Cromenes, and Versatility of Dihydrobenzo[h]chromenes in Organic Synthesis, Chem. Rev., 114: 10476-10526 (2014).
61
[33] Samantaray S., Pradhan D., Hota G., Mishra B., Catalytic Application of CeO2–CaO Nanocomposite Oxide Synthesized Using Amorphous Citrate Process Toward the Aqueous Phase One Pot Synthesis of 2-amino-2-chromenes, Chem. Eng. J, 193: 1-9 (2012).
62
[34] Albadi J., Razeghi A., Mansournezhad A., Azarian Z., CuO-CeO2 Nanocomposite Catalyzed Efficient Synthesis of Aminochromenes, JNSC, 3: 85- (2013).
63
[35] Sagar Vijay Kumar P., Suresh L., Vinodkumar T., Reddy B.M., Chandramouli G., Zirconium Doped Ceria Nanoparticles: An Efficient and Reusable Catalyst for a Green Multicomponent Synthesis of Novel Phenyldiazenyl–chromene Derivatives Using Aqueous Medium, ACS Sustain. Chem. Eng., 4: 2376-2386 (2016).
64
[36] Edayadulla N., Lee Y.R., Cerium oxide Nanoparticle-catalyzed Three-Component Protocol for the Synthesis of Highly Substituted Novel Quinoxalin-2-Amine Derivatives and 3,4-Dihydroquinoxalin-2-Amines in Water, RSC Adv., 4: 11459-11468 (2014).
65
[37] Albadi J., Mansournezhad A., Derakhshandeh Z., CuO–CeO2 Nanocomposite: a Highly Efficient Recyclable Catalyst for the Multicomponent Synthesis of 4H-benzo [b] pyran Derivatives, Chin. Chem. Lett., 24: 821-824 (2013).
66
[38] Albadi J., Mansournezhad A., Abbaszadeh H., CuO‐CeO2 Nanocomposite: A Highly Efficient Recyclable Catalyst for the Green Synthesis of 1,8‐dioxooctahydroxanthenes in Water, J. Chin. Chem. Soc., 60: 1193-1196 (2013).
67
[39] Safaei-Ghomi J., Asgari-Keirabadi M., Khojastehbakht-Koopaei B., Shahbazi-Alavi H., Multicomponent Synthesis of C-Tethered Bispyrazol-5-ols Using CeO2 Nanoparticles as an Efficient and Green Catalyst, Res. Chem. Intermed., 42, 827-837 (2016).
68
[40] Saraei-Ghomi J., Kalhor S., Shahbazi-Alavi H., Asgari-Kheirabadi M., Three-Component Synthesis of Cyclic β-aminoesters Using CeO2 Nanoparticles as an Efficient and Reusable Catalyst, Turk. J. Chem., 39, 843-849 (2015).
69
[41] Shrestha R., Sharma K., Lee Y.R., Wee Y.J., Cerium Oxide-catalyzed Multicomponent Condensation Approach to Spirooxindoles in Water, Mol. Divers., 20, 847-858 (2016).
70
ORIGINAL_ARTICLE
Green Synthesis and Characterization of Ni-Cu-Mg Ferrite Nanoparticles in the Presence of Tragacanth Gum and Study of Their Catalytic Activity in the Synthesis of Hexanitrohexaazaisowurtzitane
Here, we report the synthesis, characterization, and catalytic evaluation of Ni-Cu-Mg ferrite using tragacanth gum as biotemplate and Metals nitrate as the metal source by the sol-gel method without using any organic chemicals. The sample was characterized by powder X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Vibrating Sample Magnetometer (VSM), and Scanning Electron Microscopy (SEM). The X-Ray powder Diffraction (XRD) analysis revealed the formation of Cubic phase ferriteMNPs with an average particle size of 19 nm. The magnetic analysis revealed that the Ni-Cu-Mg ferrite nanoparticles had a ferromagnetic behavior at room temperature with a saturation magnetization of 27.85 emu/g. The catalytic activity of Ni-Cu-Mg ferrite MNPs was evaluated for the synthesis of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo [5.5.0.05,9.03,11 ] dodecane (HBIW) under ultrasonic irradiation. The catalyst could easily be recycled and reused a few times without a noticeable decrease in catalytic activity.
https://ijcce.ac.ir/article_33364_acdaa403d82026b92e54071b693ee33f.pdf
2019-12-01
21
29
10.30492/ijcce.2019.33364
Ferrites
tragacanth gum
natural Hydrogel
HBIW
ultrasonic irradiation
Saeid
Taghavi Fardood
saeidt64@gmail.com
1
Department of Chemistry, University of Zanjan, Zanjan, I.R. IRAN
AUTHOR
Behrooz
Ebadzadeh
ebadzade33@yahoo.com
2
Department of Chemistry, University of Zanjan, Zanjan, I.R. IRAN
AUTHOR
Ali
Ramazani
aliramazani@gmail.com
3
Department of Chemistry, University of Zanjan, Zanjan, I.R. IRAN
LEAD_AUTHOR
[1] Taghavi Fardood S., Ramazani A., Green Synthesis and Characterization of Copper Oxide Nanoparticles Using Coffee Powder Extract, J. Nanostruct., 6(2): 167-171 (2016).
1
[2] Saadatjou N., Jafari A., Sahebdelfar S., Synthesis and Characterization of Ru/Al2O3 Nanocatalyst for Ammonia Synthesis, Iran. J. Chem. Chem. Eng. (IJCCE), 34(1): 1-9 (2015).
2
[3] Pouretedal H.R., Basati S., Characterization and Photocatalytic Activity of ZnO, ZnS, ZnO/ZnS, CdO, CdS and CdO/CdS Nanoparticles in Mesoporous SBA-15, Iran. J. Chem. Chem. Eng. (IJCCE), 34(1): 11-19 (2015).
3
[4] Taghavi Fardood S., Ramazani A., Joo S.W., Eco-friendly Synthesis of Magnesium Oxide Nanoparticles using Arabic Gum, J. Appl. Chem. Res., 12(1): 8-15 (2018).
4
[5] Ramazani A., Taghavi Fardood S., Hosseinzadeh Z., Sadri F., Joo S.W., Green Synthesis of Magnetic Copper Ferrite Nanoparticles using Tragacanth Gum as a Biotemplate and their Catalytic Activity for the Oxidation of Alcohols, Iran. J. Catal., 7(3): 181-185 (2017).
5
[6] Alaei M., Rashidi A.M., Bakhtiari I., Preparation of High Surface Area ZrO2 Nanoparticles, Iran. J. Chem. Chem. Eng. (IJCCE), 33(2): 47-53 (2014).
6
[7] Alaei M., Mahjoub A.R., Rashidi A., Effect of WO3 Nanoparticles on Congo Red and Rhodamine B Photo Degradation, Iran. J. Chem. Chem. Eng. (IJCCE), 31(1): 23-29 (2012).
7
[8] Ramazani A., Ahmadi Y., Fattahi N., Ahankar H., Pakzad M., Aghahosseini H., Rezaei A., Taghavi Fardood S., Joo S.W., Synthesis of 1, 3, 4-Oxadiazoles from the Reaction of N-Isocyaniminotriphenylphosphorane (Nicitpp) with Cyclohexanone, a Primary Amine and an Aromatic Carboxylic Acid via Intramolecular Aza-Wittig Reaction of In-Situ Generated Iminophosphoranes, Phosphorus, Sulfur Silicon Relat. Elem., 191(7): 1057-1062 (2016).
8
[9] Taghavi Fardood S., Ramazani A., Golfar Z., Joo S.W., Green Synthesis of α-Fe2O3 (hematite) Nanoparticles using Tragacanth Gel, J. Appl. Chem. Res., 11(3): 19-27 (2017).
9
[10] Alaei M., Jalali M., Rashidi A., Simple and Economical Method for the Preparation of MgO Nanostructures with Suitable Surface Area, Iran. J. Chem. Chem. Eng. (IJCCE), 33(1): 21-28 (2014).
10
[11] Dehno Khalaji A., Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study, Iran. J. Chem. Chem. Eng. (IJCCE), 35(3): 17-20 (2016).
11
[12] Ahmadi S.H., Davar P., Manbohi A., Adsorptive Removal of Reactive Orange 122 from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent, Iran. J. Chem. Chem. Eng. (IJCCE), 35(1): 63-73 (2016).
12
[13] Moradi S., Taghavi Fardood S., Ramazani A., Green Synthesis and Characterization of Magnetic NiFe2O4@ZnO Nanocomposite and its Application for Photocatalytic Degradation of Organic Dyes, J. Mater. Sci. Mater. Electron., 29(16): 14151-14160 (2018).
13
[14] Hassanpour A., Hosseinzadeh-Khanmiri R., Ghorbanpour K., Abolhasani J., Mosaei Oskoei Y., Synthesis of 3,4-Dihydroquinoxalin-2-Amine, Diazepine-Tetrazole and Benzodiazepine-2-Carboxamide Derivatives with the Aid of H6P2W18O62/Pyridino-Fe3O4, Iran. J. Chem. Chem. Eng. (IJCCE), 35(4): 39-47 (2016).
14
[15] Bayandori Moghaddam A., Hosseini S., Badraghi J., Banaei A., Hybrid Nanocomposite Based on CoFe2O4 Magnetic Nanoparticles and Polyaniline, Iran. J. Chem. Chem Eng. (IJCCE), 29(4): 173-179 (2010).
15
[16] Ramazani A., Farshadi A., Mahyari A., Sadri F., Joo S.W., Asiabi P.A., Taghavi Fardood S., Dayyani N., Ahankar H., Synthesis of Electron-poor N-Vinylimidazole Derivatives Catalyzed by Silica Nanoparticles under Solvent-free Conditions, Int. J. Nano Dimens., 7(1): 41 (2016).
16
[17] Khashi M., Allameh S., Beyramabadi S.A., Morsali A., Dastmalchian E., Gharib A., BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives, Iran. J. Chem. Chem. Eng. (IJCCE), 36(3): 45-52 (2017).
17
[18] Lebid M., Omari M., Effects of the Solvent and Calcination Temperature on LaFeO3 Catalysts for Methanol Oxidation, Iran. J. Chem. Chem. Eng. (IJCCE), 35(3): 75-81 (2016).
18
[19] Batoo K.M., El-sadek M.-S.A., Electrical and Magnetic Transport Properties of Ni–Cu–Mg Ferrite Nanoparticles Prepared by Sol–Gel Method, J. Alloys Compd., 566: 112-119 (2013).
19
[20] Gabal M., Effect of Mg Substitution on the Magnetic Properties of NiCuZn Ferrite Nanoparticles Prepared through a Novel Method using Egg White, J. Magn. Magn. Mater., 321(19): 3144-3148 (2009).
20
[21] Shayegan Mehr E., Sorbiun M., Ramazani A., Taghavi Fardood S., Plant-Mediated Synthesis of Zinc Oxide and Copper Oxide Nanoparticles by using Ferulago Angulata (Schlecht) Boiss Extract and Comparison of their Photocatalytic Degradation of Rhodamine B (RhB) under Visible Light Irradiation, J. Mater. Sci. Mater. Electron., 29(2): 1333-1340 (2018).
21
[22] Arabian R., Ramazani A., Mohtat B., Azizkhani V., Joo S.W., Rouhani M., A Convenient and Efficient Protocol for the Synthesis of HBIW Catalyzed by Silica Nanoparticles under Ultrasound Irradiation, J. Energ. Mater., 32(4): 300-305 (2014).
22
[23] Maksimowski P., Gołofit T., Tomaszewski W., Palladium Catalyst in the HBIW Hydrodebenzylation Reaction. Deactivation and Spent Catalyst Regeneration Procedure, Cent. Eur. J. Energetic Mater., 13(2): 333-348 (2016).
23
[24] Nielsen A.T., Chafin A.P., Christian S.L., Moore D.W., Nadler M.P., Nissan R.A., Vanderah D.J., Gilardi R.D., George C.F., Flippen-Anderson J.L., Synthesis of Polyazapolycyclic Caged Polynitramines, Tetrahedron, 54(39): 11793-11812 (1998).
24
[25] Bellamy A.J., Reductive Debenzylation of Hexabenzylhexaazaisowurtzitane, Tetrahedron, 51(16): 4711-4722 (1995).
25
[26] Bayat Y., Ebrahimi H., Fotouhi-Far F., Optimization of Reductive Debenzylation of Hexabenzylhexaazaisowurtzitane (the Key Step for Synthesis of HNIW) using Response Surface Methodology, Org. Process Res. Dev., 16(11): 1733-1738 (2012).
26
[27] Qiu W., Chen S., Yu Y., The Crystal Structure of Hexabenzoylhexaazaisowurtzitane, J. Chem. Crystallogr., 28(8): 593-596 (1998).
27
[28] Crampton M.R., Hamid J., Millar R., Ferguson G., Studies of the Synthesis, Protonation and Decomposition of 2, 4, 6, 8, 10, 12-Hexabenzyl-2, 4, 6, 8, 10, 12-Hexaazatetracyclo [5.5. 0.05, 9.03, 11] Dodecane (HBIW), J. Chem. Soc., Perkin Trans. 2, 2(5): 923-929 (1993).
28
[29] Taghavi Fardood S., Golfar Z., Ramazani A., Novel Sol–Gel Synthesis and Characterization of Superparamagnetic Magnesium Ferrite Nanoparticles using Tragacanth Gum as a Magnetically Separable Photocatalyst for Degradation of Reactive Blue 21 Dye and Kinetic Study, J. Mater. Sci. Mater. Electron., 28(22): 17002–17008 (2017).
29
[30] Zohuriaan M., Shokrolahi F., Thermal Studies on Natural and Modified Gums, Polym. Test., 23(5): 575-579 (2004).
30
[31] Ou Y., Jia H., Xu Y., Chen B., Fan G., Liu L., Zheng F., Pan Z., Wang C., Synthesis and Crystal Structure of β-Hexanitrohexaazaisowurtzitane, Sci. China, Ser. B, Chem., 42(2): 217-224 (1999).
31
[32] Waldron R., Infrared Spectra of Ferrites, Phys. Rev., 99(6): 1727-1735 (1955).
32
[33] Sorbiun M., Shayegan Mehr E., Ramazani A., Taghavi Fardood S., Biosynthesis of Ag, ZnO and Bimetallic Ag/ZnO Alloy Nanoparticles by Aqueous Extract of Oak Fruit Hull (Jaft) and Investigation of Photocatalytic Activity of ZnO and Bimetallic Ag/ZnO for Degradation of Basic Violet 3 Dye, J. Mater. Sci. Mater. Electron., 29(4): 2806-2814 (2018).
33
[34] Azizkhani V., Montazeri F., Molashahi E., Ramazani A., Magnetically Recyclable CuFe2O4 Nanoparticles as an Efficient and Reusable Catalyst for the Green Synthesis of 2, 4, 6, 8, 10, 12-Hexabenzyl-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane as CL-20 Explosive Precursor, J. Energ. Mater., 35(3): 314-320 (2017).
34
[35] Shokrollahi S., Ramazani A., Tabatabaei Rezaei S.J., Mashhadi Malekzadeh A., Azimzadeh Asiabi P., Joo S.W., Citric acid as an Efficient and Green Catalyst for the Synthesis of Hexabenzylhexaazaisowurtzitane (HBIW), Iran. J. Catal., 6(1): 65-68 (2016).
35
[36] Jefimczyk J., Antczak A., Maksimowski P., Studies on Synthesis of Hexabenzylhexaazaisowurtzitane (HBIW) in the Menthol-Sulfuric Acid System, Przem. Chem., 87(3): 296-299 (2008).
36
[37] Gołofit T., Maksimowski P., Szwarc P., Cegłowski T., Jefimczyk J., Scale-Up Synthesis of HBIW, an Intermediate in CL-20 Synthesis, Org. Process Res. Dev., 21(7): 987-991 (2017).
37
[38] Bayat Y., Hajighasemali F., An Efficient and Facile Synthesis of CL‐20 from TADNO using HNO3/N2O5 and Optimization of Reaction Parameters by Taguchi Method, Propellants, Explosives, Pyrotechnics, 41(5): 893-898 (2016).
38
ORIGINAL_ARTICLE
Synthesis and Characterization of Silver and Gold Nano-Structures on Chitosan-Porous Anodic Alumina Nano-Composite
This study was designed to probe the fabrication of unique silver and gold nano-structures engaging a self-designed chitosan-porous anodic alumina nano-composite as a template. Porous anodic alumina has been manufactured by di-step aluminum anodization in an oxalic acid electrolytic bath. The surface properties of porous anodic alumina were reinforced by chitosan neutralized in sodium hydroxide. Multifarious nano-morphologies of silver, as well as gold nanostructures, were observed. Furthermore, the long chitosan biopolymer chains were degraded by γ-irradiations and the same procedure was employed for modification of porous anodic alumina with γ-degraded chitosan. The morphologies of fabricated silver and gold nanostructures were investigated by scanning electron microscopy, while their composition was evaluated with the help of energy-dispersive X-ray spectroscopy. X-ray diffraction study exposed the face-centered cubic phase for both silver and gold nanostructures. Reflection mode UV-Vis spectroscopy was used to ascertain reflection grooves in the absorption range of silver and gold nanostructures respectively. The technique does not involve any harmful reagent and shows different selectivity than methods in general practice. The achieved results apprised that the fabricated nanostructures offer the advantages of biocompatibility and eco-friendliness for numerous biomedical uses.
https://ijcce.ac.ir/article_32438_2bb9ff7af8b953a0b21593624475e91a.pdf
2019-12-01
31
44
10.30492/ijcce.2019.32438
Porous anodic alumina
Di-step aluminum anodization
Chitosan
Nano-composite
Gold and silver nano-structures
Somia
Qayyum
somiaqayyum23@gmail.com
1
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
Mazhar
Mehmood
mazhar@pieas.edu.pk
2
Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Nilore, Islamabad-45650, PAKISTAN
AUTHOR
Muhammad Aslam
Mirza
muhammadaslammirzachem@gmail.com
3
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
LEAD_AUTHOR
Sumaira
Ashraf
4
Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Nilore, Islamabad-45650, PAKISTAN
AUTHOR
Zahoor
Ahmed
zahoorbuct@hotmail.com
5
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
Tauseef
Tanvir
6
Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Nilore, Islamabad-45650, PAKISTAN
AUTHOR
Muhammad Aziz
Choudhary
azizch@yahoo.com
7
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
Masood
Iqbal
umairulhassan05@gmail.com
8
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
Faria
Nisar
asharebkhan1@gmail.com
9
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
Zaib un
Nisa
10
Department of Chemistry, Mirpur University of Science and Technology (MUST), Mirpur, AJ&K-10250, PAKISTAN
AUTHOR
[1] Masuda H., Matsui Y., Yotsuya M., Matsumoto F., Nishio K., Fabrication of Highly Ordered Anodic Porous Alumina Using Self-organized Polystyrene Particle Array, Chem. Lett., 33(5):584-585 (2004).
1
[2] Lee J., Nigo S., Nakano Y., Kato S., Kitazawa H., Kido G., Structural Analysis of Anodic Porous Alumina Used for Resistive Random Access Memory, Sci. Technol. Adv. Mater., 11(2):025002-025006 (2010).
2
[3] Rauf A., Mehmood M., Rasheed M.A., Aslam M., The Effects of Electro-polishing on the Nano-channel Ordering of the Porous Anodic Alumina Prepared in Oxalic Acid. J. Solid State Electr., 13(2): 321-332 (2009).
3
[4] Sulka G.D., Brzozka A., Zaraska L., Jaskula M., Through-hole Membranes of Nano-porous Alumina Formed by Anodizing in Oxalic Acid and their Applications in Fabrication of Nanowire Arrays. Electrochim. Acta., 55(14): 4368-4376 (2010).
4
[5] Mutalib A., Losic D., Voelcker N.H., Nano-porous Anodic Aluminum Oxide: Advances in Surface Engineering and Emerging Applications, Prog. Mater. Sci., 58(5):636-704 (2013).
5
[6] Santos A., Kumeria T., Losic D., Nano-porous Anodic Alumina: A Versatile Platform for Optical Biosensors, Materials, 7(6): 4297-4320 (2014).
6
[7] Borrull J.F., Pallares J., Macias G., Marsal L.F., Nanostructural Engineering of Nanoporous Anodic Alumina for Biosensing Applications, Materials, 7(7): 225-5253 (2014).
7
[8] Sriram G., Patil P., Bhat M.P., Hegde R.M., Ajeya K.V., Udachyan I., Bhavya M.B., Gatti M.G., Uthappa U.T., Neelgund G.M., Jung H.Y., Current Trends in Nanoporous Anodized Alumina Platforms for Biosensing Applications, J. Nanomater., 2016(2): 2-26 (2016).
8
[9] Yanagishita T., Kato A., Masuda H., Preparation of Ideally Ordered Through-hole Anodic Porous Alumina Membranes by Two-layer Anodization, Jpn. J. Appl. Phys., 56(3): 035202-035204 (2017).
9
[10] Chatterjee S., Sarkar J., Mallick A.B., Roy D., Deb P., Effect of Anodizing Medium on the Morphology and Photoluminescent Property of Porous Alumina Film, J. Eng. Tech., 4(2): 59-62 (2017).
10
[11] Roslyakov I.V., Elena O.G., Kirill S.N., Role of Electrode Reaction Kinetics in Self-ordering of Porous Anodic Alumina, Electrochim. Acta., 241: 362-369 (2017).
11
[12] Mezni A., Altalhi T., Saber N.B., Aldalbahi A., Boulehmi S., Santos A., Losic D., Size and Shape-Controlled Synthesis of Well-organised Carbon Nanotubes Using Nanoporous Anodic Alumina with Different Pore Diameters, J. Colloid Interf. Sci., 491: 375-389 (2017).
12
[13] Zhang Q., Li Y., Xu D., Gu Z., Preparation of Silver Nanowire Arrays in Anodic Aluminum Oxide Templates, J. Mater. Sci. Lett., 20(10): 925-927 (2001).
13
[14] Nielsch K., Muller F., Li A.P., Gosele U., Uniform Nickel Deposition into Ordered Alumina Pores by Pulsed Electrodeposition, Adv. Mater., 12(8): 582-586 (2000).
14
[15] Krolla M., Blaua W.J., Grandjeanb D., Benfieldb R.E., Luisc F., Paulusc P.M., De-Jongh L.J., Magnetic Properties of Ferromagnetic Nanowires Embedded in Nanoporous Alumina Membranes, J. Magn. Magn. Mater., 249(1-2): 241-245 (2002).
15
[16] Xu C.L., Li H., Zhao G.Y., Li H.L., Electrodeposition of Ferromagnetic Nanowire Arrays on AAO/Ti/Si Substrate for Ultrahigh-density Magnetic Storage Devices, Mater. Lett., 60(19): 2335-2338 (2006).
16
[17] Huczko A., Template-Based Synthesis of Nanomaterials, Appl. Phys. A., 70(4): 365-376 (2000).
17
[18] Shi W., Shen Y., Ge D., Xue M., Cao H., Huang S., Wang J., Zhang G., Zhang F., Functionalized Anodic Aluminum Oxide (AAO) Membranes for Affinity Protein Separation, J. Membrane Sci., 325(2): 801-808 (2008).
18
[19] Ding Y., Zhang P., Qub Y., Jiang Y., Huang J., Yan W., Liu G., AFM Characterization and Electrochemical Property of Ag Nanowires by Modified AAO Template Method, J. Alloy Compd., 466(1-2): 479-482 (2008).
19
[20] Hanaoka T.A., Heilmann A., Kroll M., Kormann H.P., Sawitowski T., Schmid G., Jutzi P., Klipp A., Kreibig U., Neuendorf R., Alumina Membranes—Templates for Novel Nanocomposites, Appl. Organomet. Chem., 12(5):367-373 (1998).
20
[21] Noyan A.A., Leontiev A.P., Yakovlev M.V., Roslyakov I.V., Tsirlina G.A., Napolskii K.S., Electrochemical Growth of Nanowires in Anodic Alumina Templates: The Role of Pore Branching, Electrochim. Acta., 226(1): 60-68 (2017).
21
[22] Chik H., Xu J., Nanometric Superlattices: Non-lithographic Fabrication, Materials, and Prospects, Mater. Sci. Eng., R., 43(4):103-138 (2004).
22
[23] Shingubara S., Okino O., Murakami Y., Sakaue H., Takahaqi T., Fabrication of Nanohole Array on Si Using Self-organized Porous Alumina Mask, J. Vac. Sci. Technol. B., 19(5): 1901-1904 (2001).
23
[24] Thorat S., Diaspro A., Scarpellini A., Povia M., Salerno M., Comparative Study of Loading of Anodic Porous Alumina with Silver Nanoparticles Using Different Methods, Mater., 6(1): 206-216 (2013).
24
[25] Forrer P., Schlottig F., Siegenthaler H., Textor M., Electrochemical Preparation and Surface Properties of Gold Nanowire Arrays Formed by the Template Technique, J. Appl. Electrochem., 30(5):533-541 (2000).
25
[26] Sulka G.D., Brzozka A., Liu L., Fabrication of Diameter-Modulated and Ultrathin Porous Nanowires in Anodic Aluminum Oxide Templates, Electrochim. Acta., 56(14): 4972-4979 (2011).
26
[27] Park H., Kim T.H., Kang S.W., Jeong S.H., Nanoscale Reaction Vessels: Highly Ordered Nanocrystal Arrays Inside Porous Anodic Alumina Nanowells, Int. J. Electrochem. Sci., 10(10): 8447 – 8453 (2015).
27
[28] Choi J., Sauer G., Nielsch K., Wehrspohn R.B., Gosele U., Hexagonally Arranged Monodisperse Silver Nano-wires with Adjustable Diameter and High Aspect Ratio, Chem. Mater., 15(3):776-779 (2003).
28
[29] Yang R., Sui C., Gong J., Qu L., Silver Nanowires Prepared by Modified AAO Template Method, Mater. Lett., 61(3): 900-903(2007).
29
[30] Narayan R.J., Aggarwal R., Wei W., Jin C., Monteiro-Riviere N.A., Crombez R., Mechanical and Biological Properties of Nanoporous Carbon Membranes, Biomed. Mater., 3(3): 034107 (2008).
30
[31] Lee S.B., Mitchell D.T., Trofin L., Nevanen T.K., Soderlund H., Martin C.R., Antibody-Based Bionanotube Membranes for Enantiomeric Drug Separations, Sci., 296(5576): 2198-2200 (2002).
31
[32] Winkler B., Modification of the Surface Characteristics of Anodic Alumina Membranes Using Sol–gel Precursor Chemistry, J. Membrane Sci., 226(1-2):75-84 (2003).
32
[33] Skoog S.A., Bayati M.R., Petrochenko P.E., Stafslien S., Daniels J., Cilz N., Antibacterial Activity of Zinc Oxide Coated Nanoporous Alumina, Mater. Sci. Eng. B., 177(12): 992-998 (2012).
33
[34] Kovtyukhova N.I., Mallouk T.E., Mayer T.S., Templated Surface Sol-gel Synthesis of SiO2 Nanotubes and SiO2 Insulated Metal Nanowires, Adv. Mater., 15(10): 780-785 (2003).
34
[35] Cameron M.A., Gartland I.P., Smith J.A., Diaz S.F., George S.M., Atomic Layer Deposition of SiO2 and TiO2 in Alumina Tubular Membranes: Pore Reduction and Effect of Surface Species on Gas Transport, Langmuir, 16(19): 7435-7444 (2000).
35
[36] Vajandar S.K., Xu D., Markov D.A., Wikswo J.P., Hofmeister W., Li D., SiO2 Coated Porous Anodic Alumina Membranes for High Flow Rate Electroosmotic Pumping, Nanotechnology, 18(27): 275705 (2007).
36
[37] Matsumoto F., Nishio K., Masuda H., Flow-through-type DNA Array Based on Ideally Ordered Anodic Porous Alumina Substrate, Adv. Mater., 16(23-24): 2105-2108 (2007).
37
[38] Milka P., Krest I., Keusgen M., Immobilization of Alliinase on Porous Aluminum Oxide, Biotechnol. Bioeng., 69(3): 344-348 (2000).
38
[39] ter Maat J., Regeling R., Ingham C.J., Weijers C.A., Giesbers M., de Vos W.M., Zuilhof H.. Organic Modification and Subsequent Biofunctionalization of Porous Anodic Alumina Using Terminal Alkynes. Langmuir, 27(22): 13606-13617 (2011).
39
[40] Aramesh M., Fox K., Lau D.W.M., Fang J.H., Ostrikov K., Prawer S., Cervenka J., Multifunctional Three Dimensional Nanodiamond Nanoporous Alumina Nanoarchitectures, Carbon, 75: 452- 464 (2014).
40
[41] Skoog S.A., Sumant A.V., Monteiro-Riviere N.A., Narayan R.J., Ultrananocrystalline Diamond-Coated Microporous Silicon Nitride Membranes for Medical Implant Applications, JOM, 64(4): 520-525 (2012).
41
[42] Karan S., Samitsu S., Peng X., Kurashima K., Ichinose I., Ultrafast Viscous Permeation of Organic Solvents Through Diamond Like Carbon Nanosheets, Sci., 335(6067): 444-447 (2012).
42
[43] Popat K.C., Mor G., Grimes C.A., Desai T.A., Surface Modification of Nanoporous Alumina Surfaces with Poly(ethylene glycol), Langmuir, 20(19): 8035-8041 (2004).
43
[44] Lee S.W., Shang H., Haasch R.T., Petrova V., Lee G.U., Transport and Functional Behaviour of Poly(ethylene glycol) Modified Nanoporous Alumina Membranes, Nanotechnology, 16(8): 1335-1340 (2005).
44
[45] Simovic S., Losic D., Vasilev K., Controlled Drug Release from Porous Materials by Plasma Polymer Deposition, Chem. Commun., 46(8): 1317-1319 (2010).
45
[46] Aw M.S., Simovic S., Addai-Mensah J., Losic D., Polymeric Micelles in Porous and Nanotubular Implants as a New System for Extended Delivery of Poorly Soluble Drugs, J. Mater. Chem., 21(20): 7082-7089 (2011).
46
[47] Bruening M.L., Dotzauer D.M., Jain P., Ouyang L., Baker G.L., Creation of Functional Membranes Using Polyelectrolyte Multilayers and Polymer Brushes, Langmuir, 24(15): 7663-7673 (2008).
47
[48] Nagale M., Kim B.Y., Bruening M.L., Ultrathin, Hyperbranched Poly(Acrylic Acid) Membranes on Porous Alumina Supports, J. Am. Chem. Soc., 122(47): 11670-11678 (2000).
48
[49] Pearce M.E., Jessica B., Melanko, Salem A.K., Multifunctional Nanorods for Biomedical Applications, Pharm. Res., 24(12): 2335-2352 (2007).
49
[50] Wei J., Xue D., Xu Y., Photoabsorption Characterization and Magnetic Property of Multiferroic BiFeO3 Nanotubes Synthesized bya Facile Sol–gel Template Process, Scripta Mater., 58(1): 45-48 (2008).
50
[51] Naghizadeh A., Ghafouri M., Synthesis and Performance Evaluation of Chitosan Prepared from Persian Gulf Shrimp Shell in Removal of Reactive Blue 29 Dye from Aqueous Solution (Isotherm, Thermodynamic and Kinetic Study). Iran. J. Chem. Chem. Eng. (IJCCE), 36(3): 25-36 (2017).
51
[52] Kumar M.N.V.R., A Review of Chitin and Chitosan Applications, React. Funct. Polym., 46(1): 1-27 (2000).
52
[53] Lee M., Chen B.Y., Den W., Chitosan as a Natural Polymer for Heterogeneous Catalysts Support: A Short Review on its Applications, Appl. Sci., 5(4): 1272-1283 (2015).
53
[54] Austin P.R., Brine C.J., Castle J.E., Zikakis J.P., Chitin: New facets of research. Sci., 212(4496):749-753 (1981).
54
[55] Raoufi M., Aslankoohi N., Mollenhauer C., Boehm H., Spatz J.P., Bruggemann D., Template-Assisted Extrusion of Biopolymer Nanofibers Under Physiological Conditions, Integr. Biol-UK, 8: 1059-1066 (2016).
55
[56] Berger J., Reist M., Mayer J.M., Felt O., Gurny R., Structure and Interactions in Chitosan Hydrogels Formed by Complexation or Aggregation for Biomedical Applications, Eur. J. Pharm. Biopharm., 57 (1): 35-52 (2004).
56
[57] Mohanasrinivasan V., Mishra M., Paliwal J.S., Singh S.K., Selvarajan E., Suganthi V., Devi C.S., Studies on Heavy Metal Removal Efficiency and Antibacterial Activity of Chitosan Prepared from Shrimp Shell Waste, 3 Biotech., 4(2): 167-175 (2014).
57
[58] Huang H., Yuan Q., Yang X., Morphology Study of Gold–Chitosan Nanocomposites, J. Colloid Interf. Sci., 282(1):26-31(2005).
58
[59] Wang M., Qiang J., Fang Y., Hu D., Cui Y., Fu X., Preparation and Properties of Chitosan‐Poly (N‐isopropylacrylamide) Semi‐IPN Hydrogels, J. Polym. Sci. Pol. Chem., 38(3): 474-481 (2000).
59
[60] Wang B., Chen K., Jiang S., Reincke F.O., Tong W., Wang D., Gao C., Chitosan-Mediated Synthesis of Gold Nanoparticles on Patterned Poly (dimethylsiloxane) Surfaces, Biomacromolecules., 7(4):1203-1209 (2006).
60
[61] Sun L., Yuan Z., Gong W., Zhang L., Xu Z., Su G., Han D., The Mechanism Study of Trace Cr (VI) Removal from Water Using Fe 0 Nanorods Modified with Chitosan in Porous Anodic Alumina, Appl. Surf. Sci., 328(15): 606-613 (2015).
61
[62] Shi W., Shen Y., Ge D., Xue M., Cao H., Huang S., Wang J., Zhang G., Zhang F., Functionalized Anodic Aluminum Oxide (AAO) Membranes for Affinity Protein Separation, J. Membrane Sci., 325(2): 801-808 (2008).
62
[63] Mehmood M., Rauf A., Rasheed M.A, Saeed S., Akhter J.I., Ahmad J., Aslam M., Preparation of Transparent Anodic Alumina with Ordered Nanochannels by Through-thickness Anodic Oxidation of Aluminum Sheet, Mater. Chem. Phys., 104(2-3): 306-311 (2007).
63
[64] Huang Y., Yu H., Guo L., Huang Q., Structure and Self-Assembly Properties of a New Chitosan-Based Amphiphile, J. Phys. Chem. B., 114(23):7719-7726 (2010).
64
[65] Tahtat D., Uzun C., Mahlous M., Güven O., Beneficial Effect of Gamma Irradiation on the N-Deacetylation of Chitin to Form Chitosan, Nucl. Instrum. Methods Phys. Res., Sect. B, 265(1): 425-428 (2007).
65
[66] Zainol I., Akil H.M., Mastor A., Effect of γ-irradiation on the Physical and Mechanical Properties of Chitosan Powder, Mater. Sci. Eng., C, 29(1): 292-297 (2009).
66
[67] Baroudi A., García-Payo C., Khayet M., Structural, Mechanical, and Transport Properties of Electron Beam-irradiated Chitosan Membranes at Different Doses, Polymers, 10(2): 117-140 (2018).
67
[68] Nho Y.C., Park S.E., Kim H.I., Hwang T.S., Retracted: Oral Delivery of Insulin Using pH-Sensitive Hydrogels Based on Polyvinyl Alcohol Grafted with Acrylic Acid/Methacrylic Acid by Radiation, Nucl. Instrum. Methods Phys. Res., Sect. B, 236(1-4): 283-288 (2005).
68
[69] Islam A., Yasin T., Rehman I.U., Synthesis osf Hybrid Polymer Networks of Irradiated Chitosan/Poly (vinyl alcohol) for Biomedical Applications, Radiat. Phys. Chem., 96: 115- 119 (2014).
69
[70] Wasikiewicz J.M., Yoshii F., Nagasawa N., Wach R.A., Mitomo H., Degradation of Chitosan and Sodium Alginate by Gamma Radiation, Sonochemical and Ultraviolet Methods, Radiat. Phys. Chem., 73(5): 287-295 (2005).
70
[71] Dubey K.A., Bhardwaj Y.K., Chaudhari C.V., Kumar V., Goel N.K., Sabharwal S., Radiation Processed Ethylene Vinyl Acetate-Multiple Walled Carbon Nanotube Nano-Composites: Effect of MWNT Addition on the Gel Content and Crosslinking Density, Express Polym. Lett., 3(8): 492-500 (2009).
71
[72] Lundvall O., Gulppi M., Paez M.A., Gonzalez E., Zagal J.H., Pavez J., Thompson G. E., Copper Modified Chitosan for Protection of AA-2024, Surf. Coat. Tech., 201(12): 5973-5978 (2007).
72
[73] Huang H., Yuan Q., Yang X., Preparation and Characterization of Metal–chitosan Nanocomposites, Colloids Surfaces B., 39(1-2): 31-37 (2004).
73
[74] Kumirska J., Czerwicka M., Kaczyński Z., Bychowska A., Brzozowski K., Thöming J., Stepnowski P., Application of Spectroscopic Methods for Structural Analysis of Chitin and Chitosan, Mar. Drugs, 8(5): 1567-1636 (2010).
74
[75] Zhang Y., Xue C., Xue Y., Gao R., Zhang X., Determination of the Degree of Deacetylation of Chitin and Chitosan by X-ray Powder Diffraction, Carbohyd. Res., 340(11): 1914-1917 (2005).
75
[76] Ngah, W.S.W., Teong L.C., Hanafiah M.A.K.M., Adsorption of Dyes and Heavy Metal Ions by Chitosan Composites: A Review, Carbohyd. Polym., 83(4): 1446-1456 (2011).
76
[77] Paramelle D., Sadovoy A., Gorelik S., Free P., Hobley J., Fernig D.G., A Rapid Method to Estimate the Concentration of Citrate Capped Silver Nanoparticles from UV-Visible Light Spectra, Analyst, 139(19): 4855-4861 (2014).
77
[78] Zuber A., Purdey M., Schartner E., Forbes C., Hoek B.V.D., Giles D., Abell A., Monro T., Heidepriem H.E., Detection of Gold Nanoparticles with Different Sizes Using Absorption and Fluorescence Based Method, Sensor Actuat., B Chem., 227: 117-127 (2016).
78
[79] Rahman S., Size and Concentration Analysis of Gold Nanoparticles with Ultraviolet-Visible Spectroscopy, Undergraduate J. Math. Modeling: One + Two (UJMM), 7(1): 2 (2016).
79
[80] Dharma J., Pisal A., Shelton C.T., Simple Method of Measuring the Band Gap Energy Value of TiO2 in the Powder form using a UV/Vis/NIR Spectrometer, Application Note, (2009).
80
[81] Budhiraja N., Sharma A., Dahiya S., Parmar R., Vidyadharan V., Synthesis and Optical Characteristics of Silver Nanoparticles on Different Substrates, Int. Lett. Chem. Phys. Astron., 14: 80-88 (2013).
81
ORIGINAL_ARTICLE
Synthesis of Zinc-Sulfate Nano Particles and Detection of Their Induction Time, Nucleation Rate and Interfacial Tension
The production of zinc sulfate is important both medically and agriculturally. If zinc sulfate is produced without agglomeration at the nanoscale, its absorption in the body is more and faster. In this research, the induction time parameter is assessed for nucleation of zinc sulfate nanoparticles at room temperature and various supersaturations using acetone (as anti-solvent) in the presence of sodium dodecyl sulfate surfactant (SDS). The nucleation mechanism of zinc sulfate nanoparticles altered from primary to secondary by adding SDS surfactant in solution. The morphology of the zinc sulfate nanoparticles was analyzed by a Scanning Electron Microscope (SEM) and Transmission Electron Microscopy (TEM) tests. The TEM results revealed that the size of the nanoparticles is between 30 and 35 nm in the presence of SDS surfactant. The experimental data proved that the induction time reduces and improves with increasing supersaturation and SDS concentration, respectively. Meanwhile, the nucleation rate increases with the decrease in the interfacial tension of the zinc sulfate particles. The experimental results were also compared with the predictions of classical nucleation theory and the results proved good agreement between them.
https://ijcce.ac.ir/article_32596_9ca20e1e075a794e964236b171895629.pdf
2019-12-01
45
52
10.30492/ijcce.2019.32596
Nucleation
Induction time
Supersaturation
SDS
Zinc-Sulfate nanoparticles
Ali Reza
Jahangiri
jahangiritmu@yahoo.com
1
Faculty of Engineering, Shahrekord University, Shahrekord, I.R. IRAN
LEAD_AUTHOR
Mehdi
Sedighi
sedighi.ac@gmail.com
2
Department of Chemical Engineering, University of Qom, Qom, I.R. IRAN
AUTHOR
Farhad
Salimi
f.salimi@iauksh.ac.ir
3
Department of Chemical Engineering, Kermanshah Branch, Islamic Azad University, Kermanshah, I.R. IRAN
AUTHOR
[1] Dehno Khalaji A., Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35 (3): 17-20 (2016).
1
[2] Ghadami Jadval Ghadam A., Idrees M., Characterization of CaCO3 Nanoparticles Synthesized by Reverse Microemulsion Technique in Different Concentrations of Surfactants, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 32(3): 27-35
2
[3] Ghaemi M., Gholamipour S., Controllable Synthesis and Characterization of Silver Nanoparticles Using Sargassum Angostifolium, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(1): 1-10 (2017)
3
[4] Gutsch A., Krämer M., Michael G., Mühlenweg H., Pridöhl M., Zimmermann G., Gas-Phase Production of Nanoparticles, KONA Powder and Particle J., 20(0): 24-37 (2002).
4
[5] Wegner, K., Pratsinis, S.E., Gas-Phase Synthesis of Nanoparticles: Scale-up and Design of Flame Reactors, Powder Tech., 150(2): 117-122 (2005).
5
[6] Shimomura M., Sawadaishi T., Bottom-up Strategy of Materials Fabrication: a New Trend in Nanotechnology of Soft Materials, Curr. Opin. Colloid Interface Sci, 6(1): 11-16 (2001).
6
[7] Kashchiev, D., van Rosmalen, G.M., Review: Nucleation in Solutions Revisited, Cryst. Res. Technol., 38(7-8): 555-574 (2003).
7
[8] Carl C., “Nanostructured Materials” (Second Edition), William Andrew Publishing, Norwich, NY, (2007).
8
[9] Hatami N., Ghader S., Induction Time of Silver Nanoparticles Precipitation: Experiment and Modeling, Cryst. Res. Technol., 44(9): 953-960 (2009).
9
[10] Ghader S., Manteghian M., Kokabi M., Mamoory R.S., Induction Time of Reaction Crystallization of Silver Nanoparticles, Chem. Eng. Tech., 30(8): 1129-1133 (2007).
10
[11] Mahabadi M.A., Manteghian M., Induction Time in Formation of Copper Nanoparticles, Journal Nanosains & Nanoteknologi, 6: 32-37(2009).
11
[12] Kobari M., Kubota N., Hirasawa I., Computer Simulation of Metastable Zone width for Unseeded Potassium Sulfate Aqueous Solution, J. Cryst. Growth., 317(1): 64-69 (2011).
12
[13] Sadeghi, M.M., Manteghian, M., Determining the Stability of Potassium Sulfate Nanoparticles Influence of Mineral and Organic Additives, J. Phys. Sci. 21: 91-101 (2016).
13
[14] Naser I., Manteghian M., Bastani D., Mohammadzadeh M., A Comprehensive Empirical Correlation for prediction of Supersolubility and Width of the Metastable Zone in Crystallization, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 22 (2), 23-34 (2003)
14
[15] Mullin J.W., “Crystallization” (Fourth Edition), Butterworth-Heinemann, Oxford, (2001).
15
[16] Jones, A.G., “Crystallization Process Systems (3 - Crystallization Principles and Techniques)”, Butterworth-Heinemann, Oxford, (2002).
16
[17] Myerson A.S., Ginde R., “Handbook of Industrial Crystallization (2 - Crystals, Crystal Growth, and Nucleation)”, (Second Edition), Butterworth-Heinemann, Woburn, (2002).
17
[18] Tai C.Y., Chien W.C., Interpreting the Effects of Operating Variables on the Induction Period of CaCl2–Na2CO3 System by a Cluster Coagulation Model, Chem. Eng. Sci., 58(14): 3233-3241 (2003).
18
[19] Xu C.-h., Liu D.-j., Chen W., Effects of Operating Variables and Additive on the Induction Period of MgSO4–NaOH System, J. Cryst. Grow., 310(18): 4138-4142 (2008).
19
[20] Simiari M., Manteghian M., Ghashamshmi-Iraj M., Effect of Different Variables on the Size Distribution of Barium Chromate Nanoparticles, Mod. Appl. Sci., 11(3): 32- (2016).
20
[21] Manteghian M., Faravar A., Induction Time of Induced Crystallization of Potassium Chloride Nanoparticles, J. Chem. Eng. Res. Studies, 1(3): (2014).
21
[22] Isopescu R., Mateescu C., Mihai M., Dabija G., The Effects of Organic Additives on Induction Time and Characteristics of Precipitated Calcium Carbonate, Chem. Eng. Res. Des., 88(11): 1450-1454 (2010).
22
[23] Kanagadurai R., Durairajan R., Sankar R., Sivanesan G., Elangovan S., Jayavel R., Nucleation Kinetics, Growth and Characterization Studies of a Diamagnetic Crystal-Zinc Sulphate Heptahydrate (ZSHH), J. Chemistry, 6(3): 871-879 (2009).
23
[24] Flaten E.M., Seiersten M., Andreassen J.-P., Induction Time Studies of Calcium Carbonate in Ethylene Glycol and Water, Chem. Eng. Res. Design, 88(12): 1659-1668 (2010).
24
ORIGINAL_ARTICLE
Electrochemical Sensing of H2S Gas in Air by Carboxylated Multi-walled Carbon Nanotubes
The electrochemical sensor for detecting hydrogen sulfide was fabricated. H2S gas molecules pass through polytetrafluoroethylene membrane with 0.22 mm pore size. Carboxylated multi-walled carbon nanotubes (MWCNTs-COOH) were used to fabricate working and counter electrodes. It can be seen from Field Emission Scanning Electron Microscopy (FESEM) images of the working electrode that MWCNTs-COOH is distributed fairly uniform on the hydrophobic membrane. Quantitative results of Energy Dispersive X-ray (EDX) analysis show the presence of carbon (85.95 wt %) and oxygen (12.95 wt %) on the working electrode. The cyclic voltammetry results show the MWCNTs-COOH responds to H2S. The sensor response up to 56 ppm of H2S gas was measured by chronoamperometry. The sensor showed linear behavior up to 16 ppm. The detection limit of the sensor is 310 ppb and its sensitivity 48 hours after assembling is 0.1436 µA/ ppm. The averages of response and recovery times for 10 ppm of H2S were obtained 6.06 and 4.13 minutes respectively. The sensor with functionalized carbon nanotubes has many advantages than the sensor with raw carbon nanotubes; include more uniformity of fabricated electrodes, greater response, and less noise. Using functionalized carbon nanotubes concerning raw nanotubes increases the response of the sensor by 14.8 times at 10 ppm of H2S. Also, the response of the sensor to 250 ppm concentration of carbon monoxide gas was 4.35 nA which is very low concerning sensor response for hydrogen sulfide (1.64 µA for 10 ppm of H2S).
https://ijcce.ac.ir/article_32649_ee66689ea48b758ecc6a031462a9301d.pdf
2019-12-01
53
62
10.30492/ijcce.2019.32649
Hydrogen Sulfide
Electrochemical sensor
MWCNTs- COOH
Hydrophobic Polytetrafluoroethylene Membrane
Sulfuric Acid
Nahid
Parsafar
nhdparsafar@gmail.com
1
Department of Physics, Research Institute of Applied Sciences, Academic Center of Education, Culture and Research (ACECR), Tehran, I.R. IRAN
LEAD_AUTHOR
Vahid
Ghafouri
vahid.ghafouri5@gmail.com
2
Department of Physics, Research Institute of Applied Sciences, Academic Center of Education, Culture and Research (ACECR), Tehran, I.R. IRAN
AUTHOR
Aghdas
Banaei
banaei@acecr.ac.ir
3
Department of Physics, Research Institute of Applied Sciences, Academic Center of Education, Culture and Research (ACECR), Tehran, I.R. IRAN
AUTHOR
[1] www.osha.gov, OSHA Fact Sheet, Hydrogen Sulfide
1
[2] www.osha.gov. Hydrogen Sulfide, Health Hazards, United States Department of Labor: Occupational Safety and Health Administration.
2
[3]Dorman D.C., Moulin F.J. M., McManus B.E., Mahle K.C., James R.A., Struve M.F., Cytochrome Oxidase Inhibition Induced by Acute Hydrogen Sulfide Inhalation: Correlation with Tissue Sulfide Concentrations in the Rat Brain, Liver, Lung, and Nasal Epithelium, Toxicological Sciences, 65(1): 18–251 (2002).
3
[4] Goleij M., Fakhraee H., Response Surface Methodology Optimization of Cobalt (II) and Lead (II) Removal from Aqueous Solution Using MWCNT-Fe3O4 Nanocomposite, Iran. J. Chem. Chem. Eng. (IJCCE), 36(5): 129-141 (2017).
4
[5] Wang Y., Yeow J.T., A Review of Carbon Nanotubes-Based Gas Sensors, Journal of Sensors, 2009 (2009).
5
[6] Barkade S., Gajare G., Mishra S., Sonawane S.H., Recent Trends in Carbon Nanotubes/Graphene Functionalization for Gas/Vapor Sensing: A Review, in Chemical Functionalization of Carbon Nanomaterials: Chemistry and Applications, CRC Press., 868-897 (2015).
6
[7] Ouyang M., Wen J. L., “Performance of F-CNTs Sensors Towards Ethanol Vapor Using Different Functional Groups, In: Nano/Micro Engineered and Molecular Systems (NEMS)”, 5th IEEE International Conference., (2010).
7
[8] Stetter J.R., Penrose W.R., Yao S., Sensors, Chemical Sensors, Electrochemical Sensors, and ECS, Journal of the Electrochemical Society, 150 (2): S11-S16 (2003).
8
[9] Fang G.J., Liu Z.L., Liu C.Q., Yao K.L. ,Room Temperature H2S Sensing Properties and Mechanism of CeO2-SnO2 Sol-Gel Thin Films, Sensors and Actuators B: Chemical, 66: 46–48 (2000).
9
[10] Fam D.W.H., Tok A.I.Y., Palaniappan A., Nopphawan P., Lohani A., Mhaisalkar S.G., Selective Sensing of Hydrogen Sulphide Using Silver Nanoparticle Decorated Carbon Nanotubes, Sensors and Actuators B: Chemical, 138: 189–192 (2009).
10
[11] Mubeen S., Zhang T., Chartuprayoon N., Rheem Y., Mulchandani A., Myung N,. Deshusses M.A., Sensitive Detection of H2S Using Gold Nanoparticle Decorated Single-Walled Carbon Nanotubes, Analytical Chemistry, 82(1): 250-257 (2010).
11
[12] Zanolli Z., Leghrib R., Felten A., Pireaux J.J., Llobet E., Charlier J.C., Gas Sensing with Au-Decorated Carbon Nanotubes, ACS Nano., 5: 4592–4599 (2011).
12
[13] Moon S., Vuong N.M., Lee D., Kim D., Lee H., Kim D., Hong S.K., Yoon S.G., Co3O4–SWCNT Composites for H2S Gas Sensor Application, Sensors and Actuators B: Chemical., 222: 166–172 (2016).
13
[14] Gomes M.T.S., Nogueira P.S.T., Oliveira J.A., Quantification of CO2, SO2, NH3, and H2S with a Single Coated Piezoelectric Quartz Crystal, Sensors and Actuators B: Chemical, 68(1): 218-222 (2000).
14
[15] Asad M., Sheikhi M.H., Surface Acoustic Wave Based H2S Gas Sensors Incorporating Sensitive Layers of Single Wall Carbon Nanotubes Decorated with Cu Nanoparticles, Sensors and Actuators B: Chemical, 198: 134-141 (2014).
15
[16] Llobet E., Brunet J., Pauly A., Ndiaye A., Varenne C., Nanomaterials for the Selective Detection of Hydrogen Sulfide in Air, Sensors., 17(2): 391 (2017).
16
[17] McDonagh C., Burke C.S., MacCraith B.D., Optical Chemical Sensors, Chemical Reviews, 108(2): 400-422 (2008).
17
[18] Willer U., Scheel D., Kostjucenko I., Bohling C., Schade W., Faber E., Fiber-Optic Evanescent-Field Laser Sensor for in-Situ Gas Diagnostics, Spectrochim. Acta, Part A., 58: 2427-2432 (2002).
18
[19] Virji S., Fowler J.D., Baker C.O., Huang J., Kaner R.B., Weiller B.H., Polyaniline Nanofiber Composites with Metal Salts: Chemical Sensors for Hydrogen Sulfide, Nano Micro Small, 1(6): 624-627 (2005).
19
[20] Pandey S.K., Kim K.H., Tang K.T., A Review of Sensor-Based Methods for Monitoring Hydrogen Sulfide, TrAC Trends in Analytical Chemistry, 32: 87-99 (2012).
20
[21] Lawrence N.S., Deo R.P., Wang J., Electrochemical Determination of Hydrogen Sulfide at Carbon Nanotube Modified Electrodes, Analytica Chimica Acta., 517: 131-137 (2004).
21
ORIGINAL_ARTICLE
Adsorption of Ni2+ Ions onto NaX and NaY Zeolites: Equilibrium, Kinetics, Intra Crystalline Diffusion, and Thermodynamic Studies
This paper focuses on intra crystalline diffusion of Ni2+ ions onto NaX and NaY zeolites. The zeolites are obtained by the hydrothermal synthesis method. The samples were characterized by several techniques: X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) coupled with Energy Dispersive Spectroscopy (EDS) and InfraRed Spectroscopy (FT-IR). Physical parameters such as pH solution (2 - 7), adsorbent dose (0.25 - 2 g/L), initial concentration of Ni (II) ions (50 - 200 mg/L) and temperature (298 - 323 K) are optimized. The maximum uptake is 99% and 97% for NaX and NaY zeolite respectively under the optimum conditions: pH ∼ 7 and adsorbent dose of 1 g/L for initial concentration of 50 mg/L at 298 K. The best interpretation of the experimental data is obtained by the Langmuir isotherm with a maximum adsorption capacity of 111.85 and 77.57 mg/g for NaX and NaY respectively. The results show that the kinetic data for both zeolites follow the pseudo-second-order model, indicating the presence of physical adsorption. The free energy (DGo), enthalpy (DHo), and entropy (DS°) are evaluated. The process has proved it's spontaneous and endothermic. Diffusion mechanisms of Ni (II)ions adsorption onto NaX and NaY has shown that intraparticle diffusion is the limiting step of the process. The NaX and NaY have been applied to wastewater from the Algerian industrial zone to eliminate the Ni2+ effluents using the optimal parameters. It has been found that the Ni2+ ions removal yield was 77.81% for NaX and 83.86% for NaY.
https://ijcce.ac.ir/article_33252_f68d5aafb36159294063ebc4ccceee31.pdf
2019-12-01
63
81
10.30492/ijcce.2019.33252
Adsorption
Nickel ions
Zeolite
kinetic
diffusion
thermodynamic
Ferhat
Djawad
ferhat_djawed@hotmail.fr
1
Laboratory of Materials Technology, University of Science and Technology Houari Boumediene, B.P. 32, El-Alia, Bab-Ezzouar, Algiers, ALGERIA
AUTHOR
Nibou
Djamel
dnibou@yahoo.fr
2
Laboratory of Materials Technology, University of Science and Technology Houari Boumediene, B.P. 32, El-Alia, Bab-Ezzouar, Algiers, ALGERIA
LEAD_AUTHOR
Mekatel
Elhadj
hmekatel@yahoo.fr
3
Laboratory of Materials Technology, University of Science and Technology Houari Boumediene, B.P. 32, El-Alia, Bab-Ezzouar, Algiers, ALGERIA
AUTHOR
Amokrane
Samira
samiraamokrane@gmail.com
4
Laboratory of Materials Technology, University of Science and Technology Houari Boumediene, B.P. 32, El-Alia, Bab-Ezzouar, Algiers, ALGERIA
AUTHOR
[1] Mekatel H., Amokrane S., Benturki A., Nibou D.,Treatment of Polluted Aqueous Solutions by Ni2+, Pb2+, Zn2+, Cr+6, Cd2+ and Co2+ Ions by Ion Exchange Process Using Faujasite Zeolite, Proc. Eng., 33: 52–57 (2012).
1
[2] Nibou D., Amokrane S., Catalytic Performances of Exchanged Y Faujasites by Ce3+, La3+, UO22+, Co2+, Sr2+, Pb2+, Tl+ and NH4+ Cations in Toluene Dismutation Reaction, Compt. Rend. Chim., 13(5): 527-537 (2010).
2
[3] Tan P., Hu Y., Bi Q., Competitive Adsorption of Cu2+ Cd2+ and Ni2+ from an Aqueous Competitive Adsorption of Cu2+, Cd2+ and Ni2+ from an Aqueous Solution on Graphene Oxide Membranes, Colloid Surface A.,509: 56-64 (2016).
3
[4] Nezamzadeh-Ejhieh A., Shahanshahi M., Modification of Clinoptilolite Nano-Particles with Hexadecylpyridinium Bromide Surfactant as an Active Component of Cr (VI) Selective Electrode,
4
J. Ind. Eng. Chem., 19(6): 2026-2033 (2013).
5
[5] Derikvandi, H., Nezamzadeh-Ejhieh A., Increased Photocatalytic Activity of NiO and ZnO in Photodegradation of a Model Drug Aqueous Solution: Effect of Coupling, Supporting, Particles Size and Calcination Temperature, J. Hazard. Mater., 321: 629-638 (2017).
6
[6] Nibou D., Mekatel H., Amokrane S., Barkat M., Trari M., Adsorption of Zn2+ Ions onto NaA and NaX Zeolites: Kinetic, Equilibrium and Thermodynamic Studies, J. Hazard. Mater., 173: 637-646 (2010).
7
[7] Aid A., Amokrane S., Nibou D., Mekatel E., Trari M., Hulea V., Modeling Biosorption of Cr (VI) onto Ulva Compressa L. from Aqueous Solutions, Wat. Sci. Tech., 77 (1), 60-69 (2018).
8
[8] Esmaeili N., Kazemian H., Bastani D., Synthesis of Nano Particles of LTA Zeolite by Means of Microemulsion Technique, Iran. J. Chem. Chem. Eng. (IJCCE), 30.2: 1-8 (2011).
9
[9] Esmaeili N., Kazemian H., Bastani D., Controlled Crystallization of LTA Zeolitic Nanoparticles from a Clear Solution Using Organic Template, Iran. J. Chem. Chem. Eng. (IJCCE), 30.2: 9-14 (2011).
10
[10] Tosheva L., Valentin P.V., Nanozeolites: Synthesis, Crystallization Mechanism, and Applications, Chem. Mater., 17(10): 2494-2513 (2005).
11
[11] Nezamzadeh-Ejhieh A., Shahriari E., Photocatalytic Decolorization of Methyl Green Using Fe (II)-o-Phenanthroline as Supported onto Zeolite Y, J. Ind. Eng. Chem., 20.5: 2719-27 (2014).
12
[12] Krobba A., Nibou D., Amokrane S., Mekatel H., Adsorption of Copper (II) onto Molecular Sieves NaY, Desal. Wat. Treat., 37: 1–7 (2012).
13
[13] Amokrane S., Rebiai R., Nibou D., Behaviour of Zeolite A, Faujasites X and Y Molecular Sieves in Nitrogen Gas Adsorption, J. Appl. Sci., 7: 1985-1988 (2007).
14
[14] Breck D.W., "Zeolite Molecular Sieves-Structure Chemistry and Use", Wiley Interscience, New York (1974).
15
[15] Nezamzadeh-Ejhieh A., Khorsandi M., Hotodecolorization of Eriochrome Black T Using NiS–P Zeolite as a Heterogeneous Catalyst, J. Hazard. Mater., 176(1-3): 629-637 (2010)
16
[16] Nezamzadeh-Ejhieh A., Khorsandi S., Photocatalytic Degradation of 4-nitrophenol with ZnO Supported Nano-Clinoptilolite Zeolite, J. Ind. Eng. Chem. 20(3): 937-946 (2014).
17
[17] Mahdavi M., Nezamzadeh-Ejhieh A., An aluminum Selective Electrode via Modification of PVC Membrane by Modified Clinoptilolite Nanoparticles with Hexadecyltrimethyl Ammonium Bromide (HDTMA-Br) Surfactant Containing Arsenazo III, J. Colloid Interf. Sci., 494: 317-324 (2017).
18
[18] Sistani S., Ehsani M.R., Kazemian H., Microwave Assisted Synthesis of Nano Zeolite Seed for Synthesis Membrane and Investigation of its Permeation Properties for H2 Separation, Iran. J. Chem. Chem. Eng. (IJCCE), 29(4): 99-104 (2010).
19
[19] Frising T., Leflaive P., Extraframework Cation Distributions in X and Y Faujasite Zeolites: A Review, Mic. Mes. Mat., 114: 27-63 (2008).
20
[20] Barkat M., Nibou D., Amokrane S., Chegrouche S., Mellah A., Uranium (VI) Adsorption on Synthesized 4A and P1 Zeolites: Equilibrium, Kinetic, and Thermodynamic Studies, Com. Rend. Chim., 18(3): 261-269 (2015).
21
[21] Barrer R., Zeolites and Clay Minerals as Sorbents and Molecular Sieves, (1978).
22
[22] Houhoune F., Djamel N., Samira A., Mahfoud B., Modelling and Adsorption Studies of Removal Uranium (VI) Ions on Synthesised Zeolite NaY, Des. Wat. Treat., 51 (28-30): 5583-5591(2013)
23
[23] Blanchard G., Maunaye M., Martin G., Removal of Heavy Metals from Waters by Means of Natural Zeolites, Water. Res, 18: 1501-1507 (1984).
24
[24] Barkat M., Nibou D., Chegrouche S., Mellah A., Kinetics and Thermodynamics Studies of Chromium (VI) Ions Adsorption onto Activated Carbon from Aqueous Solutions, Chem. Eng. Proc. Pro. Intens., 48 (1): 38-47 (2009).
25
[25] Beyond G., Adamson A., Myers L., The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites, J. Am. Chem. Soc., 69: 2836-2848 (1947).
26
[26] Turse R., Rieman III W., Kinetics of Ion Exchange in a Chelating Resin, J. Phs. Chem., 65: 1821-1824 (1961).
27
[27] Biškup B., Subotić B., Kinetic Analysis of the Exchange Processes between Sodium Ions from Zeolite A and Cadmium, Copper and Nickel Ions from Solutions, Sep. Puri. Technol., 37: 17-31 (2004).
28
[28] Sinha P., Panicker P., Amalraj R., Krishnasamy V., Treatment of Radioactive Liquid Waste Containing Caesium by Indigenously Available Synthetic Zeolites: A Comparative Study, Waste. Manage., 15: 149-157 (1995).
29
[29] Aid A., Amokrane S., Nibou D., Mekatel H., Removal of Cr⁶⁺, Co²⁺ and Ni²⁺ Ions from Aqueous Solutions by Algerian Enteromorpha Compressa (L.) Biomass, World Academy of Science, Engineering and Technology, Inter. J. Ecol. Eng., 11(7): - (2017).
30
[30] Mekatel H., Amokrane S., Bellal B., Trari M., Nibou D., Photocatalytic Reduction of Cr (VI) on Nanosized Fe2O3 Supported on Natural Algerian Clay: Characteristics, Kinetic and Thermodynamic Study, Chem. Eng. J., 200:611-618 (2012).
31
[31] Baerlicher C., Meier W.M., Olson D.H., "Atlas of Zeolite Fromewerk Types”, 5th Revised Ed., Elsevier, Amesterdam (2001).
32
[32] Khodadadi, B., Bordbar M., Sonochemical Synthesis of Undoped and Co-Doped ZnO Nanostructures and Investigation of Optical and Photocatalytic Properties, Iran. J. Catal., 6(1): 37-42 (2016).
33
[33] Nezamzadeh-Ejhieh, A., Afshari E., Modification of a PVC-Membrane Electrode by Surfactant Modified Clinoptilolite Zeolite Towards Potentiometric Determination of Sulfide, Micro. Meso. Mater., 153: 267-274 (2012).
34
[34] Nezamzadeh-Ejhieh A., Badri A., Application of Surfactant Modified Zeolite Membrane Electrode Towards Potentiometric Determination of Perchlorate, J. Electroanal. Chem. 660(1): 71-79 (2011).
35
[35] Nezamzadeh-Ejhieh A., Badri A., Surfactant Modified ZSM-5 Zeolite as an Active Component of Membrane Electrode Towards Thiocyanate, Desalination, 281: 248-256 (2011).
36
[36] Mekatel EH., Amokrane S., Aid A., Nibou D., Trari M., Adsorption of Methyl Orange on Nanoparticles of a Synthetic Zeolite NaA/CuO, Com. Rend. Chim., 18(3), 336-344 (2015).
37
[37] Senobari S., Nezamzadeh-Ejhieh A., A Comprehensive Study on the Enhanced Photocatalytic Activity of CuO-NiO Nanoparticles: Designing the Experiments, J. Mol. Liq., 261: 208-217 (2018).
38
[38] Anari-Anaraki, M., Nezamzadeh-Ejhieh A., Modification of an Iranian Clinoptilolite Nano-Particles by Hexadecyltrimethyl Ammonium Cationic Surfactant and Dithizone for Removal of Pb (II) from Aqueous Solution, J. Colloid. Interf. Sci., 440: 272-281 (2015).
39
[39] Nibou D., Amokrane S., Lebaili N., Use of NaX Porous Materials in the Recovery of Iron Ions, Desalination 250 (1): 459-462 (2010).
40
[40] Borandegi M., Nezamzadeh-Ejhieh A., Enhanced Removal Efficiency of Clinoptilolite Nano-Particles Toward Co (II) from Aqueous Solution by Modification with Glutamic Acid, Colloids Surf. A: Physicochem. Eng. Aspects 479: 35-45 (2015).
41
[41] Garba Z.N., Ugbaga N.I., Abdullahi A.K., Evaluation of Optimum Adsorption Conditions for Ni (II) and Cd (II) Removal from Aqueous Solution by Modified Plantain Peels (MPP), Beni-Suef Univ. J. Basic Appl. Sci., 5: 170-179 (2016).
42
[42] Marcos C., Rodríguez I., Thermoexfoliated Commercial Vermiculites for Ni2+ Removal, Appl. Clay. Sci., 132: 685-693 (2016).
43
[43] Fakari S., Nezamzadeh-Ejhieh A., Synergistic Effects of ion Exchange and Complexation Processes in Cysteine-Modified Clinoptilolite Nanoparticles for Removal of Cu (II) from Aqueous Solutions in Batch and Continuous Flow Systems, New J. Chem. 41(10): 3811-3820 (2017).
44
[44] Eshraghi F., Nezamzadeh-Ejhieh A., EDTA-Functionalized Clinoptilolite Nanoparticles as an Effective Adsorbent for Pb (II) Removal, Environ. Sci. Pol. Res., 25(14): 14043-14056 (2018).
45
[45] Lamgmuir I., The Constitution and Fundamental Properties of Solids and Liquids, Part 1. Solids, J. Am. Chem. Soc., 38: 2221-2295 (1916).
46
[46] Freundlich H., Uber die Adsorption in Losungen [Adsorption in Solution], Z. Phys. Chem., 57: - (1906).
47
[47] Temkin M.I., Adsorption Equilibrium and the Kinetics of Processes on Nonhomogeneous Surfaces and in the Interaction between Adsorbed Molecules, Zh. Fiz. Chim,15: 296-332 (1941).
48
[48] Nezamzadeh-Ejhieh A., Kabiri-Samani M., Effective Removal of Ni (II) from Aqueous Solutions by Modification of Nano Particles of Clinoptilolite with Dimethylglyoxime, J. Hazard. Mater., 260: 339-349 (2013).
49
[49] Heidari-Chaleshtori M., Nezamzadeh-Ejhieh A., Clinoptilolite Nano-Particles Modified with Aspartic Acid for Removal of Cu (II) from Aqueous Solutions: Isotherms and Kinetic Aspects, New J. Chem. 39.12: 9396-9406 (2015).
50
[50] Ghasemi M., Javadian H., Ghasemi N., Agarwal S.,. Gupta V.K., Microporous Nanocrystalline NaA Zeolite Prepared by Microwave Assisted Hydrothermal Method and Determination of Kinetic, Isotherm and Thermodynamic Parameters of the Batch Sorption of Ni (II), J. Mol. Liq., 215: 161-169 (2016).
51
[51] Fritzsche S., Haberlandt R., Jost S.,. Schüring A., Modelling Diffusion in Zeolites by Molecular Dynamics Simulations, Mol. Simulat., 25: 27-40 (2000).
52
[52] Dissanayake D., Wijesinghe W., Iqbal S., Priyantha N., Iqbal M., Isotherm and Kinetic Study on Ni (II) and Pb (II) Biosorption by the Fern Asplenium Nidus L, Ecol. Eng., 88: 237-241 (2016).
53
[53] Naghash A., Nezamzadeh-Ejhieh A., Comparison of the Efficiency of Modified Cinoptilolite with HDTMA and HDP Surfactants for the Removal of Phosphate in Aqueous Solutions, J. Ind. Eng. Chem. 31: 185-191 (2015).
54
[54] Shirzadi H., Nezamzadeh-Ejhieh A., An Efficient Modified Zeolite for Simultaneous Removal of Pb (II) and Hg (II) from Aqueous Solution, J. Mol. Liq., 230: 221-229 (2017).
55
[55] Tajiki, A., Abdouss, M., Synthesis and Characterization of Graphene Oxide Nano-Sheets for Effective Removal of Copper Phthalocyanine from Aqueous Media, Iran. J. Chem. Chem. Eng. (IJCCE),36(4): 1-9 (2017).
56
[56] Yousefpour M., Modelling of Adsorption of Zinc and Silver Ions on Analcime and Modified Analcime Zeolites Using Central Composite Design, Iran. J. Chem. Chem. Eng. (IJCCE), 36 (4): 81-90 (2017).
57
[57] Wu F.C., Tseng R.L., Juang R.S., Initial Behavior of Intraparticle Diffusion Model Used in the Description of Adsorption Kinetics, Chem. Eng. J, 153: 1-8 (2009).
58
[58] Martins L.F., Parreira M.C.B., Ramalho J.P.P., Morgado P., Filipe E.J., Prediction of Diffusion Coefficients of Chlorophenols in Water by Computer Simulation, Fluid Phase Equilibr, 396: 9-19 (2015).
59
[59] Nuhoglu Y., Malkoc E., Thermodynamic and Kinetic Studies for Environmentaly Friendly Ni (II) Biosorption Using Waste Pomace of Olive Oil Factory, Bioresource Technol 100: 2375-2380 (2009).
60
[60] Wu Y., Wang L., Kinetic and Thermodynamic Studies of the Biosorption of Ni (II) by Modified Rape Straw, Procedia Environ Sci., 31: 75-80 (2016).
61
[61] Pitcher S., Slade R., Ward N., Heavy Metal Removal from Motorway Stormwater Using Zeolites, Sci. Total Environ., 334: 161-166 (2004).
62
[62] Çoruh S., Ergun O.N., Ni2+ Removal from Aqueous Solutions Using Conditioned Clinoptilolites: Kinetic and Isotherm Studies, Environmental Progress & Sustainable Energy 28: 162-172 (2009).
63
[63] Turkman A., Aslan S., Ege I., Treatment of Metal Containing Wastewaters by Natural Zeolites, Fresen. Environ. Bull, 13: 574-580 (2004).
64
[64] Quintelas C., Rocha Z., Silva B., Fonseca B., Figueiredo H., Tavares T., Biosorptive Performance of an Escherichia Coli Biofilm Supported on Zeolite NaY for the Removal of Cr (VI), Cd (II), Fe (III) and Ni (II), Chem. Eng. J., 152: 110-115 (2009).
65
[65] Lam Y.F., Lee L.Y., Chua S.J., Lim S.S., Gan S., Insights into the Equilibrium, Kinetic and Thermodynamics of Nickel Removal by Environmental Friendly Lansium Domesticum Peel Biosorbent, Ecotoxicol. Environ. Saf., 127: 61-70 (2016).
66
[66] Sudha R., Srinivasan K., Premkumar P., Removal of Nickel (II) from Aqueous Solution Using Citrus Limettioides Peel and Seed Carbon, Ecotoxicol. Environ. Saf., 117: 115-123 (2015).
67
ORIGINAL_ARTICLE
Application of Copper Vanadate Nanoparticles for Removal of Methylene Blue from Aqueous Solution: Kinetics, Equilibrium, and Thermodynamic Studies
Copper vanadate nanoparticles were synthesized by a simple coprecipitation method in an aqueous medium and the products were used as adsorbents for eliminating methylene blue (MB) from water. The structure and morphology of the produced nanoparticles were evaluated through X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis. The results indicated that the particles were 22-40 nm in diameter. Further, batch adsorption experiments were performed to evaluate the potential capability of the product for the removal of MB and optimizing the adsorption conditions. The effects of pH, the quantity of the adsorbent, contact time, dye concentration, and temperature on adsorption were determined. Fitting of the experimental data into the Langmuir and Freundlich adsorption models revealed good compliance with the Langmuir model with a maximum adsorption capacity of 151.5 mg/g at pH= 4.0. Evaluation of the kinetic and thermodynamic parameters showed that the adsorption process follows a pseudo-second-order kinetic model and reaches equilibrium after 10 min. The desorption of the dye and recycling potential of the adsorbent was also studied.
https://ijcce.ac.ir/article_32990_6fb4389f0de83e55e315d769957aab55.pdf
2019-12-01
83
92
10.30492/ijcce.2019.32990
Copper vanadate
nanoparticles
Removal
adsorbent
Methylene blue
Shiva
Dehghan Abkenar
dehghan54@yahoo.com
1
Department of Chemistry, Savadkooh Branch, Islamic Azad University, Savadkooh, I.R. IRAN
LEAD_AUTHOR
Mohammad Reza
Ganjali
ganjali@gmail.com
2
Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, I.R. IRAN
AUTHOR
Morteza
Hossieni
hosseini.morteza54@gmail.com
3
Department of Life Science Engineering, Faculty of New Sciences and Technologies, University of Tehran, Tehran, I.R. IRAN
AUTHOR
Meisam
Sadeghpour Karimi
mesa1363@yahoo.com
4
Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, I.R. IRAN
AUTHOR
[1] Ahmed MJ., Dhedan S., Equilibrium Isotherm and Kinetic Modeling of Methylene Blue Adsorption on Agricultural Wastes-Based Activated Carbons, Fluid Phase Equilibria, 317: 9-14 (2012).
1
[2] Ai L., Zhou Y., Jiang J., Removal of Methylene Blue from Aqueous Solution by Montmorillonite/ CoFe2O4 Composite with Magnetic Separation Performance, Desalination, 266 (1-3): 72–77 (2011).
2
[3] Namasivayam C., Sumithra S., Removal of Direct red 12B and Methylene Blue from Water by Adsorption onto Fe (III)/Cr (III) Hydroxide, an Industrial Solid Waste, J. Environ. Manag., 74(3): 207–215 (2005).
3
[4] Qu S., Huang F., Yu S., Chen G., Kong J., Magnetic Removal of Dyes from Aqueous Solution Using Multi-Walled Carbon Nanotubes Filled with Fe2O3 Particles, J. Hazard. Mater., 160(2-3): 643-647 (2008).
4
[5] Chen S., Zhang J., Zhang C., Yue Q., Li Y., Li C., Equilibrium and Kinetic Studies of Methyl Orange and Methyl violet Adsorption on Activated Carbon Derived from Phragmites Australis, Desalination 252(1-3): 149-156 (2010).
5
[6] Pugazhenthiran N., Ramkumar S., Kumar P.S., Anandan S., In-situ Preparation of Heteropolytungstic Acid on TiMCM-41 Nanoporous Framework for Photocatalytic Degradation of Textile Dye Methyl Orange, Microp. Mesop. Mater., 131(1-3): 170-176 (2010).
6
[7] Oei B.C., Ibrahim S., Wang S., Ang, H.M., Surfactant Modified Barley Straw for Removal of Acid and Reactive Dyes from Aqueous Solution, Bioresource Technol., 100(18): 4292-4295 (2009).
7
[8] Jalil A.A., Triwahyono S., Adama S.H., Rahima N.D., Aziz M.A.A., Hairomc N.H.H., Razali N.A.M., Abidin M.A.Z., Khairul M., Mohamadiah A., Adsorption of Methyl Orange from Aqueous Solution Onto Calcined Lapindo Volcanic Mud, J. Hazard. Mater., 181: 755-762 (2010).
8
[9] Cheung W.H., Szeto Y.S., McKay G., Enhancing the Adsorption Capacities of Acid Dyes by Chitosan Nano Particles, Bioresource Technol., 100(3): 1143-1148 (2009).
9
[10] Hajiaghababaei L., Abozari S., Badiei A., Zarabadi Poor P., Dehghan Abkenar S., Ganjali M.R., Mohammadi Ziarani G., Amino Ethyl-Functionalized SBA-15: A Promising Adsorbent for Anionic and Cationic Dyes Removal, Iran. J. Chem. Chem. Eng. (IJCCE), 36(1): 97-108 (2017).
10
[11] Lui C., Omer A.M., Ouyang X.K., The Adsorptive Removal of Cationic Methylen Blue Dye Using Carboxymethyl Cellulose/k-Carrageenan/Activated Montmorillonite Composite Beads: Isotherm and Kinetic Studies, Int. J. Biolog. Macromol., 106: 823-833 (2017).
11
[12] Dehghan Abkenar S., Khobi M., Tarasi R., Hosseini M., Shafiee A., Gangali M.R., Fast Removal of Methylene Blue from Aqueous Solution using Magnetic-modified Fe3O4 Nanoparticles, J. Environ. Chem. Eng., 141(1): 04014049 (2015).
12
[13] Ferrero F., Adsorption of Methylene Blue on Magnesium Silicate: Kinetics, Equilibria and Comparison with Other Adsorbents, J. Environ. Sci., 22(3): 467-473 (2010).
13
[14] Li L., Liu S., Zhu T., Application of Activated Carbon Derived from Scrap Tires for Adsorption of Rhodamine B, J. Environ. Sci., 22(8): 1273-1280 (2010).
14
[15] Silva L.A.D., C.Rangel M.D., Borges S.M.S., Oliva S.T.D., Paulino P.N., Fraga M.A., Marchetti S.G., Methylene Blue Oxidation over Iron Oxide Supported on Activated Carbon Derived from Peanut Hulls, Catalysis Today 289: 237-248 (2017).
15
[16] Kruid J., Fogel R., Leigh Limson J., Quantitative Methylene Blue Decolourisation Assays as Rapid Screening Tools for Assessing the Efficiency of Catalytic Reactions, Chemosphere, 175: 247-252 (2017).
16
[17] Zhao K., Zhao G., Li P., Gao J., Lv B., Li D., A Novel Method for Photodegradation of High –Chroma Dye Wastewater via Electrochemical Pre- Oxidation, Chemosphere, 80(4): 410-415 (2010).
17
[18] Rajeev J., Megha M., Shalini S., Alok M., Removal of the Hazardous Dye Rhodamine B Through Photocatalytic and Adsorption Treatments, J. Environ. Management, 85(4): 956-964 (2007).
18
[19] Malik R., Ramteke D.R., Wate S.R., Adsorption of Malachite Green on Ground Nut Shell Waste Based Powdered Activated Carbon, Waste Management, 27(9): 1129-1138 (2007).
19
[20] Wu J.S., Liu C.H., Chu K.H., Suen S.Y., Removal of Cationic Dye Methyl Violet 2B from Water by Cation Exchange Membranes, J. Membrane Sci., 309(1-2): 239-245 (2008).
20
[21] Beakou B.H., El Hassani K., M.A. Houssaini, Belbahloul M., Oukani E., Anouar A., Novel Activated Carbon from Manihot Escuenta Crantz for Removal of Methylene Blue, Sustainable Environ. Res., 27(5): 215-222 (2017).
21
[22] Karaca S., Gurses A., Acıkyıldız M., Ejder M., Adsorption of Cationic Dye from Aqueous Solutions by Activated Carbon, Microp. Mesop. Mater., 115(3): 376-382 (2008).
22
[23] Weng, C. H., and Y. F. Pan., Adsorption of a cationic Dye (methylene blue) onto Spent Activated Clay, Journal of Hazardous Materials 144 (1-2): 355-362 (2007).
23
[24] Alpat K.S., Ozbayrak O., Alpat S., Akcay H., The Adsorption Kinetics and Removal of Cationic Dye, Toluidine Blue O, from Aqueous Solution with Turkish Zeolite, J. Hazard. Mater. 151(1): 213-220 (2008).
24
[25] Noroozi B., Sorial G.A., Bahrami H., Arami M., Equilibrium and Kinetic Adsorption Study of a Cationic Dye by a Natural Adsorbent—Silkworm Pupa, J. Hazard. Mater., 139(1): 167–174 (2007).
25
[26] Mittal A., Mittal J., Malviya A., Kaur D., Gupta V.K., Adsorption of Hazardous dye Crystal Violet from Wastewater by Waste Materials, J. Coll. Interf. Sci., 343(2): 463-473 (2010).
26
[27] Kamranifar M., Naghizadeh A., Montmorillonite Nanoparticles in Removal of Textile Dyes from Aqueous Solutions: Study of Kinetics and Thermodynamics, Iran. J. Chem. Chem. Eng. (IJCCE), 36(6): 127-137 (2017).
27
[28] Borghei Y.S., Hosseini M., Ganjali M.R., Fluorometric Determination of Micro RNA via FRET between Silver Nanoclusters and CdTe Quantum Dots, Microchim. Acta, 184(12): 4713–4721 (2017).
28
[29] Borghei Y.S., Hosseini M., Ganjali M.R., Detection of Large Deletion in Human BRCA1 Gene in Human Breast Carcinoma MCF-7 Cells by Using DNA− Silver Nanoclusters, Methods Applications in Fluorescence, 6(1): 015001 (2017).
29
[30] Sabet F.S., Hosseini M., Khabbaz H., Dadmehr M., Ganjali M.R., FRET-Based Aptamer Biosensor for Selective and Sensitive Detection of Aflatoxin B1 in Peanut and Rice, Food Chem., 220: 527-532 (2017).
30
[31] Ahmadi S. H., Davar P., Manbohi H., Adsorptive Removal Reactive Orange 122from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent, Iran. J. Chem. Chem. Eng.(IJCC), 35: 63-73 (2016).
31
[32] Zhang S., Li H., Yang Z., Controllable Synthesis of WO3 with Different Crystalline Phases and its Applications on Methylene Blue Removal from Aqueous Solution, J. Alloy. Comp., 722: 555-563 (2017).
32
[33] Mukherjee J., Dutta D.P., Ramakumar J., Tyagi A.K., A Comprehensive Study on the Uptake of Dyes, Cu(II) and Radioactive 137 Cs(I) by Sonochemically Synthesized Strontium/Yttrium Tungstate and Molybdate Nanoparticles, J. Environ. Chem. Eng., 4(3): 3050 (2016).
33
[34] Han G.H., Yang S.Z., Huang Y.F., Yang J., Chai W.C., Zhang R., Chen D.L., Hydrothermal Synthesis and Electrochemical Sensing Properties of Copper Vanadate Nanocrystals with Controlled Morphologies, Transactions of Nonferrous Metal. Soc. China, 27: 1105−1116 (2017).
34
[35] Borghei Y.S., Hosseini M., Ganjali M.R., Synthesis of Fluorescent Cysteine-gold Nano-clusters (Cys-Au-NCs) and their Application as Nano-Biosensors for the Determination of Cysteine, Current Nanosci., 13(6): 610-615 (2017).
35
[36] Rahimi-Nasrabadi M., Pourmortazavi S.M., Ganjali M.R., Novrouzi P., Faridbod F., Sadeghpour Karimi M., Preparation of Dysprosium Carbonate and Dysprosium Oxide Efficient Photocatalyst Nanoparticles through Direct Carbonation and Precursor Thermal Decomposition, J. Mater. Sci., 28(4): 3325-3336 (2017).
36
[37] Rahimi-Nasrabadi M., Pourmortazavi S.M., Sadeghpour Karimi M., Aghazadeh M., Ganjali M.R., Norouzi P., “Erbium(Iii) Tungstate Nanoparticles; Optimized Synthesis and Photocatalytic Evaluation, J. Mater. Sci., 28(9): 6399-6406 (2017).
37
[38] Rahimi-Nasrabadi M., Pourmortazavi S.M., Aghazadeh M., Ganjali M.R., Sadeghpour Karimi M., Novrouzi P., Samarium Carbonate and Samarium Oxide; Synthesis, Characterization and Evaluation of the Photo-Catalytic Behavior, J. Mater. Sci., 28(7): 5574-5583 (2017).
38
[39] Rahimi-Nasrabadi M., Mizani F., Hosseini M., Homayoun Keihan A., Ganjali M.R., Detection of Hydrogen Peroxide and Glucose by Using Tb2(MoO4)3 Nanoplates as Peroxidase Mimics, Spectrochim. Acta Part A, 186: 82-88 (2017).
39
[40] Lagergren S., About the Theory of so-Called Adsorption of Soluble Substances, Kungliga Svenska Vetens Kapsakademiens Handlingar 24: 1-39 (1898).
40
[41] Ho Y.S., McKay G., Sorption of Dye from Aqueous Solution by Peat, Chem. Eng. J. 70(2): 115-124 (1998).
41
[42] Langmuir I., The Constitution and Fundamental Properties of Solids and Liquids, J. Am. Chem. Soc. 38(1): 2221-2295 (1916).
42
[43] Freundlich H.M.F., Over the Adsorption in Solution, J. Phys. Chem. 57: 385-471 (1906).
43
[44] Haghseresht F., Lu G., Adsorption Characteristics of Phenolic Compounds onto Coal-Reject-Derived Adsorbents, Energy & Fuels 12(6): 1100-1107 (1998).
44
[45] Giles C.H., Macewan T.H., Nakhwa S.N., Smith D., Studies in Adsorption. Part XI. A System of Classification of Solution Adsorption Isotherms, and Its use in Diagnosis of Adsorption mechanisms and in Measurement of Specific Surface Areas of Solids, J. Chem. Soc. 10: 3973-3993 (1960).
45
[46] Yang J., Zhang M., Zhang Y., Ding L., Zheng J., Xu J., Facile Synthesis of Magnetic Magnesium Silicate Hollow Nanotubes with High Capacity for Removal of Methylene Blue, J. Alloy. Comp., 721: 722-778 (2017).
46
[47] Zhang Z., Kong J., Novel Magnetic Fe3O4@C Nanoparticles as Adsorbents for Removal of Organic Dyes from Aqueous Solution, J. Hazard. Mater., 193: 325–329 (2011).
47
[48] Asfaram A., Ghaedi M., Ahmadi Azqhandi M.H., Goudarzi A., Hajati S., Ultrasound-Assisted Binary Adsorption of Dyes onto Mn@ CuS/ZnS-NC-AC as a Novel Adsorbent: Application of Chemometrics for Optimization and Modeling, J. Indust. Eng. Chem., 54: 377-388 (2017).
48
[49] Wang P., Cao M., Wang C., Ao Y, Hou J, Qian J., Kinetics and Thermodynamics of Adsorption of Methylene Blue by a Magnetic Graphene-Carbon Nanotube Composite, Appl. Surface Sci., 290: 116–124 (2014).
49
ORIGINAL_ARTICLE
Synthesis of Low-Cost Nanochitosan from Persian Gulf Shrimp Shell for Efficient Removal of Reactive Blue 29 (RB29) Dye from Aqueous Solution
Untreated wastewater disposal containing synthetic dyes produces serious problems in the environment. Industrial wastewater containing dye requires treatment by a suitable process before discharging into the environment. The present study has been performed as a batch experimental study. Nanochitosan was synthesized from the Persian Gulf shrimp shell. The effect of the various parameters including pH, initial concentration of the RB29 dye, the equation contact time, and the adsorbent dosage as well as isotherm, thermodynamic and kinetic of the adsorption process were evaluated. The results of this study demonstrated that the maximum adsorption capacity of the nano chitosan, which occurred in pH=4, adsorbent dosage of 0.2 g/L, the concentration of 50 mg/L of RB29 dye and during 90 minutes, was 113.22 mg/g. Temkin and Dubinin-Radushkeish isotherms and pseudo-second-order kinetic equations have shown better results for describing the adsorption process. The entropic changes (ΔS°) and enthalpy changes (ΔH°) were 36.65J/mole K and 6.43 kJ/mole respectively. Also, the Gibbs free energy (ΔG) was negative. Therefore nano chitosan can be used as a suitable low-cost adsorbent for the removal of RB29 dye from aqueous solutions
https://ijcce.ac.ir/article_33788_e16becd2a38cf63ec1d8299a6fa76cc9.pdf
2019-12-01
93
103
10.30492/ijcce.2019.33788
RB29 dye
nanochitosan
Adsorption
Isotherm
thermodynamic
Kinetics
Ali
Naghizadeh
aliinaghizadeh@gmail.com
1
Medical Toxicology and Drug Abuse Research Center (MTDRC), Birjand University of Medical Sciences, Birjand, I.R. IRAN
LEAD_AUTHOR
Maryam
Ghafouri
maryamghafoory787@gmail.com
2
Department of Environmental Health Engineering, Student Research Committee, Faculty of Health, Birjand University of Medical Sciences, Birjand, I.R. IRAN
AUTHOR
[1] Gozálvez-Zafrilla J., Sanz-Escribano D., Lora-García J., Hidalgo M.L., Nanofiltration of Secondary Effluent for Wastewater Reuse in the Textile Industry, Desalination, 222(1-3): 272-279 (2008).
1
[2] Figueroa S., Vazquez L., Alvarez-Gallegos A., Decolorizing Textile Wastewater with Fenton's Reagent Electrogenerated with a Solar Photovoltaic Cell, Water Research, 43(2): 283-294 (2009).
2
[3] Ip A.W., Barford J.P., McKay G., A Comparative Study on the Kinetics and Mechanisms of Removal of Reactive Black 5 by Adsorption onto Aactivated Carbons and Bone Char, Chemical Engineering Journal, 157(2-3): 434-442 (2010).
3
[4] Zhang L., Cheng Z., Guo X., Jiang X., Liu R., Process Optimization, Kinetics and Equilibrium of Orange G and Acid Orange 7 Adsorptions onto Chitosan/Surfactant, Journal of Molecular Liquids, 197: 353-367 (2014).
4
[5] Elkady M., Ibrahim A.M., El-Latif M.A., Assessment of the Adsorption Kinetics, Equilibrium and Thermodynamic for the Potential Removal of Reactive Red Dye Using Eggshell Biocomposite Beads, Desalination, 278(1-3): 412-423 (2011).
5
[6] Carneiro P.A., Umbuzeiro G.A., Oliveira D.P., Zanoni M.V.B., Assessment of Water Contamination Caused by a Mutagenic Textile Effluent/Dyehouse Effluent Bearing Disperse Dyes, Journal of Hazardous Materials,174(1-3): 694-699 (2010).
6
[7] Shojaei S., Shojaei S., Experimental Design and Modeling of Removal of Acid Green 25 dye by Nanoscale Zero-Valent Iron, Euro-Mediterranean Journal for Environmental Integration, 2(1): 15- (2017).
7
[8] Hajiaghababaei L., Abozari S., Badiei A., Zarabadi Poor P., DehghanAbkenar S., Ganjali M.R., et al. Amino Ethyl-Functionalized SBA-15: A Promising Adsorbent for Anionic and Cationic Dyes Removal, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(1): 97-108 (2017).
8
[9] Maljaei A., Arami M., Mahmoodi N.M., Decolorization and Aromatic Ring Degradation of Colored Textile Wastewater Using Indirect Electrochemical Oxidation Method, Desalination, 249(3): 1074-8 (2009).
9
[10] Tunc Ö., Tanacı H., Aksu Z., Potential Use of Cotton Plant Wastes for the Removal of Remazol Black B Reactive Dye, Journal of Hazardous Materials, 163(1):187-98 (2009).
10
[11] Yu S., Liu M., Ma M., Qi M., Lü Z, Gao C., Impacts of Membrane Properties on Reactive dye Removal from Dye/Salt Mixtures by Asymmetric Cellulose Acetate and Composite Polyamide Nanofiltration Membranes, Journal of Membrane Science, 350(1-2): 83-91 (2010).
11
[12] Andrade L.S., Ruotolo L.A.M., Rocha-Filho R.C., Bocchi N., Biaggio S.R., Iniesta J., et al. On the Performance of Fe and Fe, F Doped Ti–Pt/PbO2 Electrodes in the Electrooxidation of the Blue Reactive 19 Dye in Simulated Textile Wastewater, Chemosphere, 66(11): 2035-43 (2007).
12
[13] Sharma P., Kaur H., Sharma M., Sahore V., A Review on Applicability of Naturally Available Adsorbents for the Removal of Hazardous Dyes from Aqueous Waste, Environmental Monitoring and Assessment, 183(1-4):151-95 (2011).
13
[14] Kyzas G.Z., Fu J., Matis K.A., The Change from Past to Future for Adsorbent Materials in Treatment of Dyeing Wastewaters, Materials, 6(11):5131-58 (2013).
14
[15] Lee C.G., Chitin, Chitinases and Chitinase-Like Proteins in Allergic Inflammation and Tissue Remodeling, Yonsei Medical Journal, 50(1):22-30 (2009).
15
[16] Qu X., Alvarez P.J., Li Q., Applications of Nanotechnology in Water and Wastewater Treatment, Water Research, 47(12): 3931-3946 (2013).
16
[17] Sivakami M., Gomathi T., Venkatesan J., Jeong H-S., Kim S-K., Sudha P., Preparation and Characterization of Nano Chitosan for Treatment Wastewaters, International Journal of Biological Macromolecules, 57: 204-212 (2013).
17
[18] Hu Z., Zhang J., Chan W., Szeto Y., The Sorption of Acid Dye onto Chitosan Nanoparticles, Polymer, 47(16):5838- 5842 (2006).
18
[19] Kana M., Radi M., Elsabee M.Z., Wastewater Treatment with Chitosan Nano-Particles, International Journal of Nanotechnology and Application, 3(2): 39-50 (2013).
19
[20] Perera U., Rajapakse N., Chitosan Nanoparticles: Preparation, Characterization, and Applications. Seafood Processing by-Products, Springer, 371-87 (2014).
20
[21] Guo J., Chen S., Liu L., Li B., Yang P., Zhang L., et al. Adsorption of Dye from Wastewater Using Chitosan–CTAB Modified Bentonites, Journal of Colloid and Interface Science, 382(1): 61-66 (2012).
21
[22] Travlou N.A., Kyzas G.Z., Lazaridis N.K., Deliyanni E.A., Graphite Oxide/Chitosan Composite for Reactive Dye Removal, Chemical Engineering Journal, 217: 256-265 (2013).
22
[23] Wan Ngah W.S., Ariff N.F.M., Hashim A., Hanafiah M.A.K.M., Malachite Green Adsorption onto Chitosan Coated Bentonite Beads: Isotherms, Kinetics and Mechanism, CLEAN–Soil, Air, Water, 38(4):394-400 (2010).
23
[24] Mahmoodi N.M., Salehi R., Arami M., Bahrami H., Dye Removal from Colored Textile Wastewater Using Chitosan in Binary Systems, Desalination, 267(1):64-72 (2011).
24
[25] Dehghani M.H., Naghizadeh A., Rashidi A., Derakhshani E., Adsorption of Reactive Blue 29 Dye from Aqueous Solution by Multiwall Carbon Nanotubes, Desalination and Water Treatment, 51(40-42): 7655-7662 (2013).
25
[26] Rhazi M., Desbrieres J., Tolaimate A., Alagui A, Vottero P., Investigation of Different Natural Sources of Chitin: Influence of the Source and Deacetylation Process on the Physicochemical Characteristics of Chitosan, Polymer International, 49(4): 337-344 (2000).
26
[27] Percot A., Viton C., Domard A., Optimization of Chitin Extraction From Shrimp Shells, Biomacromolecules, 4(1):12-18 (2003).
27
[28] Islam M.M., Masum S.M., Rahman M.M., Molla M.A.I., Shaikh A., Roy S., Preparation of Chitosan From Shrimp Shell and Investigation of Its Properties, Int J Basic Appl Sci., 11(1):116 - (2011).
28
[29] Chiou M., Li H., Adsorption Behavior of Reactive Dye in Aqueous Solution on Chemical Cross-Linked Chitosan Beads, Chemosphere, 50(8):1095-1105 (2003).
29
[30] Zhu H-Y., Jiang R., Xiao L., Li W., A Novel Magnetically Separable γ-Fe2O3/Crosslinked Chitosan Adsorbent: Preparation, Characterization and Adsorption Application for Removal of Hazardous Azo Dye, Journal of Hazardous Materials, 179(1-3): 251-257 (2010).
30
[31] Sun X-F. Wang S-G., Cheng W., Fan M., Tian B-H., Gao B-Y., et al. Enhancement of Acidic Dye Biosorption Capacity on Poly (ethylenimine) Grafted Anaerobic Granular Sludge, Journal of Hazardous Materials, 189(1-2): 27-33 (2011).
31
[32] Naghizadeh A., Ghafouri M., Synthesis and Performance Evaluation of Chitosan Prepared from Persian Gulf Shrimp Shell in Removal of Reactive Blue 29 Dye from Aqueous Solution (Isotherm, Thermodynamic and Kinetic Study), Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36(3): 25-36 (2017).
32
[33] Dawood S., Sen T.K., Removal of Anionic Dye Congo Red from Aqueous Solution by Raw Pine and Acid-Treated Pine Cone Powder as Adsorbent: Equilibrium, Thermodynamic, Kinetics, Mechanism and Process Design, Water Research, 46(6): 1933-1946 (2012).
33
[34] Sulak M., Demirbas E., Kobya M., Removal of Astrazon Yellow 7GL from Aqueous Solutions by Adsorption onto Wheat Bran, Bioresource Technology, 98(13): 2590-2598 (2007).
34
[35] Cardoso N.F., Pinto R.B., Lima E.C., Calvete T., Amavisca C.V., Royer B., et al. Removal of Remazol Black B Textile Dye from Aqueous Solution by Adsorption, Desalination, 269(1-3):92-103 (2011).
35
[36] Shirzad-Siboni M., Fallah S., Tajasosi S., Removal of Acid Red 18 and Reactive Black 5 Dyes from Aquatic Solution by Using of Adsorption on Azollafiliculoides: a Kinetic Study, Journal of Guilan University of Medical Sciences, 22(88): 42-50 (2014).
36
[37] Ashtekar V., Bhandari V., Shirsath S, Jolhe Pscp, Ghodke S., Dye Wastewater Treatment: Removal of Reactive Dyes Using Inorganic and Organic Coagulants, I Control Pollution, 30(1): - (1970).
37
[38] Dareini F., Amini M.A., Zarei S.H., Saghi M.H., Removal of Acid Black 1 Dye from Aqueous Solution Using Nano-Iron Particles, (2014).
38
[39] Ehrampoush M., Ghanizadeh G., Ghaneian M., Equilibrium and Kinetics Study of Reactive Red 123 Dye Removal from Aqueous Solution by Adsorption on Eggshell, (2011).
39
[40] Thinakaran N., Baskaralingam P., Pulikesi M., Panneerselvam P., Sivanesan S., Removal of Acid Violet 17 from Aqueous Solutions by Adsorption Onto Activated Carbon Prepared From Sunflower Seed Hull, Journal of Hazardous Materials, 151(2-3): 316-322 (2008).
40
[41] Naghizadeh A., Nasseri S., Rashidi A., Kalantary R.R., Adsorption Kinetics and Thermodynamics of Hydrophobic Natural Organic Matter (NOM) Removal from Aqueous Solution by Multi-Wall Carbon Nanotubes, Water Science & Technology: Water Supply, 13: 273-285 (2013).
41
[42] Naghizadeh A., Kamranifar M., Yari A.R., Mohammadi M.J., Equilibrium and Kinetics Study of Reactive Dyes Removal from Aqueous Solutions by Bentonite Nanoparticles, Desalination and Water Treatment, 97: 329-337 (2017).
42
[43] Najafi Saleh A., Dehghani M.H., Nabizadeh R., Mahvi A.H., Yaghmaeian K., Faraji H., Ghaderpoori M., Yousefi M., Mohammadi A.A., Data on the Acid Black 1 Dye Adsorbtion from Aqueous Solutions by Low-Cost Adsorbent- Cerastoderma Lamarcki Shell Collected From the Northern Coast of Caspian Sea, Data in Brief, 17: 774-780 (2018)
43
ORIGINAL_ARTICLE
Optimization of Photocatalytic Reduction of Cr(VI) in Water with Nano ZnO/Todorokite as a Catalyst: Using Taguchi Experimental Design
In the present work, the solid-state dispersion method has been used to stabilize ZnOon Todorokite (TD). ZnO/TD catalysts have been characterized by SEM and XRD. Optimum process conditions were determined for the removal of Cr(VI) from water using the Taguchi fractional design method. Four controllable factors containing pH, photocatalyst amount, irradiation intensity, and initial concentration of Cr(VI) at three levels were identified for each factor. The optimum conditions were found to be as follows pH= 2, photocatalyst amount= 100 mg/L, irradiation intensity= 7.63 and Cr(VI) concentrations= 15 ppm. In optimum conditions, a first-order reaction to k= 0.1492 min−1 was observed in the photocatalytic reduction of Cr(VI) in water by UV/ZnO/TD.
https://ijcce.ac.ir/article_32872_003e1da8e9facb65c12f1727a6e59be5.pdf
2019-12-01
105
113
10.30492/ijcce.2019.32872
ZnO/TD
photocatalytic-reduction
Taguchi
Cr(VI)
Maryam
Sabonian
m-sabonian92@iau-arak.ac.ir
1
Department of Chemistry, Arak Branch, Islamic Azad University, Arak, I.R. IRAN
AUTHOR
Kazem
Mahanpoor
k-mahanpoor@iau-arak.ac.ir
2
Department of Chemistry, Arak Branch, Islamic Azad University, Arak, I.R. IRAN
LEAD_AUTHOR
[1] Khalil L.B., Mourad W.E., Rophael M.W., Photocatalytic Reduction of Environmental Pollutant Cr(VI) over Some Semiconductors under UV/Visible Light Illumination. Appl. Catal., B, 17: 267-273 (1998).
1
[2] Riahi Samani M., Borghei S.M., Olad A., Chaichi M.J., Influence of Polyaniline Synthesis Conditions on its Capability for Removal and Recovery of Chromium from Aqueous Solution. Iran. J. Chem. Chem. Eng.(IJCCE),30: 97-100 (2011).
2
[3] Fu H., Lu G., Li S., Adsorption and Photo-Induced Reduction of Cr(VI) Ion in Cr(VI)-4CP (4-Chlorophenol) Aqueous System in the Presence of TiO2 as Photocatalyst. J. Photochem. Photobiol., A, 114: 81-88 (1998).
3
[4] Alaa M., Osman T.A., Toprak M.S., Muhammed M., Yilmaz Eda., Uheida A., Visible Light Photocatalytic Reduction of Cr(VI) by Surface Modified CNT/Titanium Dioxide Composites Nanofibers, J. Mol. Catal. A: Chem., 424: 45-53 (2016).
4
[5] Litter M.I., Heterogeneous Photocatalysis: Transition Metal Ions in Photocatalytic Systems, Appl. Catal., B, 23: 89-114 (1999).
5
[6] Gupta V., Rastogi A., Nayak A., Adsorption Studies on the Removal of Hexavalent Chromium from Aqueous Solution Using a Low Cost Fertilizer Industry Waste Material, J. Colloid Interface Sci., 342: 135-141 (2010).
6
[7] Gupta S., Babu B.V., Modeling, Simulation, and Experimental Validation for Continuous Cr (VI) Removal from Aqueous Solutions Using Sawdust as an Adsorbent. Bioresour. Technol., 100: 5633-5640 (2009).
7
[8] Yoon J., Shim E., Bae S., Joo H., Application of Immobilized Nanotubular TiO2 Electrode for Photocatalytic Hydrogen Evolution: Reduction of Hexavalent Chromium (Cr(VI)) in Water, J. Hazard. Mater., 161: 1069-1074 (2009).
8
[9] Golder A.K., Chanda A.K., Samanta A.N., Ray S., Removal of Hexavalent Chromium by Electrochemical Reduction-Precipitation: Investigation of Process Performance and Reaction Stoichiometry, Sep. Purif. Technol., 76: 345-350 (2011).
9
[10] Kebir M., Chabani M., Nasrallah N., Bensmaili A., Trari M., Coupling Adsorption with Photocatalysis Process for the Cr(VI) Removal, Desalination, 270: 166-173 (2011).
10
[11] Colón G., Hidalgo M.C., Navı́o J.A., Photocatalytic Deactivation of Commercial TiO2 Samples During Simultaneous Photoreduction of Cr(VI) and Photooxidation of Salicylic Acid, J. Photochem. Photobiol., A, 138: 79-85 (2001).
11
[12] Giménez J., Aguado M.A., Cervera-March S., Photocatalytic Reduction of Chromium (VI) with Titania Powders in a Flow System. Kinetics and Catalyst Activity, J. Mol. Catal. A: Chem., 105: 67-78 (1996).
12
[13] Navı́o J.A., Colón G., Trillas M., Peral J., Domenech X., Testa J.J., Padron J., Rodrı́guez D., Litter M.I., Heterogeneous Photocatalytic Reactions of Nitrite Oxidation and Cr(VI) Reduction on Iron-Doped Titania Prepared by the Wet Impregnation Method. Appl. Catal., B, 16:187-196 (1998).
13
[14]Ming Ma C., Shuen Shen Y., Hsiang Lin P., Photoreduction of Cr(VI) Ions in Aqueous Solutions by UV/TiO2 Photocatalytic Processes, Int. J. Photoenergy, 2012: 1-7 (2012).
14
[15] Nabizadeh R., Jahangiri Rad M., Nitrate Adsorption by Pan-Oxime-Nano Fe2O3 Using a Two-Level Full Factorial Design, Research Journal of Nanoscience and Nanotechnology, 6: 1-7 (2016).
15
[16] Özgür Ü., Alivov Ya.I., Liu C., Teke A., Reshchikov M.A., Doğan S., Avrutin V., Cho S.-J., Morkoç H., A Comprehensive Review of ZnO Materials and Devices. J. Appl. Phys., 98(4): 041301 (2005).
16
[17] Manavizadeh N., Khodayari A.R., Asl Soleimani A., Bagherzadeh S., A Study of ZnO Buffer Layer Effect on Physical Properties of ITO Thin Films Deposited on Different Substrates, Iran. J. Chem. Chem. Eng. (IJCCE),31: 37-42 (2012).
17
[18] Al-Dahash G., Mubdir Khilkala W., Abdul Vahid S.N., Preparation and Characterization of ZnO Nanoparticles by Laser Ablation in NaOH Aqueous Solution, Iran. J. Chem. Chem. Eng.(IJCCE), 37:11-16 (2018).
18
[19] Al-Sagheer F.A., Zaki M.I., Synthesis and Surface Characterization of Todorokite-type Microporous Manganese Oxides: Implications for Shape-Selective Oxidation Catalysts, Microporous Mesoporous Mater., 67: 43–52 (2004).
19
[20] Alanis C., Natividad R., Barrera-Diaz C., Martinez-Miranda V., Prince J., Valente J.S., Photocatalytically Enhanced Cr(VI) Removal by Mixed Oxides Derived from Me Al (Me: Mg and/or Zn) Layered Double Hydroxides, Appl. Catal., B, 140: 546-551 (2013).
20
[21] Cai X., Cai Y., Liu Y., Deng S., Wang Y., Wang Y., Djerdj I., Photocatalytic Degradation Properties of Ni(OH)2 Nanosheets/ZnO Nanorods Composites for Azo Dyes under Visible-Light Irradiation, Ceram. Int., 40:57-65 (2014).
21
[22] Sudeepan J., Kumar K., Barman T.K., Sahoo, P., Study of Friction and Wear of ABS/ZnO Polymer Composite Using Taguchi Technique, Procedia Materials Science, 6: 391-400 (2014).
22
[23] Ross P.J., “Taghuchi Techniques for Quality Engineering”, McGraw-Hill, New York, (1998).
23
[24] Donmez B., Celik C., Colak S., Yartas¸ A., Dissolution Optimization of Copper from Anode Slime in H2SO4 Solutions, Ind. Eng. Chem. Res., 37: 3382-3387 (1998).
24
[25] Copur M., Pekdemir T., Celik C., Colak, S., Determination of the Optimum Conditions for the Dissolution of Stibnite in HCl Solutions. Ind. Eng. Chem. Res., 36: 682-687 (1997).
25
[26] Khoei A.R., Masters I. Gethin D.T., Design Optimisation of Aluminium Recycling Processes Using Taguchi Technique, J. Mater. Process. Technol., 127: 96-106 (2002).
26
[27] Tortum A., Celik C., Aydin A.C., Determination of the Optimum Conditions for Tire Rubber in Asphalt Concrete, Build. Environ., 40: 1492-1504 (2005).
27
[28] Balakhonov S.V., Churagulov B.R., Gudilin E.A., Selective Cleaning of Ions of Heavy Metals from Water solutions using the H-form of Todorokite Synthesized by the Hydrothermal Method, J. Surf. Invest., 2:152-155 (2008).
28
[29] Jin Z., Zhang Y.X., Meng F.L., Jia Y., Luo T., Yu X.Y., Wang J., Liu J.H., Huang X.J., Facile Synthesis of Porous Single Crystalline ZnO Nanoplates and their Application in Photocatalytic Reduction of Cr(VI) in the Presence of Phenol. J. Hazard. Mater., 276: 400-407 (2014).
29
[30] Chakrabarti S., Chaudhuri B., Bhattacharjee S., Ray A.K., Dutta B.K., Photo-Reduction of Hexavalent Chromium in Aqueous Solution in the Presence of Zinc Oxide as Semiconductor Catalyst, Chem. Eng. J., 153: 86-93 (2009).
30
[31] Kabra K., Chaudhary R., Sawhney, R.L., Treatment of Hazardous Organic and Inorganic Compounds through Aqueous-Phase Photocatalysis: A Review. Ind. Eng. Chem. Res., 43: 7683-7696 (2004).
31
[32] Wang S., Wang Z., Zhuang Q., Photocatalytic Reduction of the Environmental Pollutant CrVI Over a Cadmium Sulphide Powder under Visible Light Illumination, Appl. Catal., B, 1: 257–270 (1992).
32
[33] Mehrotra k., Yablonsky G.S., Ray A.K., Macro Kinetic Studies for Photocatalytic Degradation of Benzoic Acid in Immobilized Systems, Chemosphere, 60: 1427-1436 (2005).
33
ORIGINAL_ARTICLE
Ion Imprinted Affinity Cryogels for the Selective Adsorption Uranium in Real Samples
In this research, selective adsorption of U(VI) in aqueous solutionsin the presence of various lanthanide ions by using U(VI)-imprinted cryogel polymer was conducted. For this purpose, the prepared pHEMA-(MAH)3-U(VI) cryogel polymer by free radical polymerization method. U(VI) was desorbed with 5.0 mol/L HNO3 and thus U(VI)-imprinted were created onto p-HEMA-(MAH)3 cryogel polymer. To determine the optimum conditions, in the process of selective adsorption of U(VI) ion to U(VI)-imprinted p-HEMA-(MAH)3 cryogel polymer, some parameters such as pH, flow rate, initial U(VI) concentration were investigated. Under the optimum conditions, the maximum adsorption capacity was obtained as 74.80 mg/g. Selectivity studies were also carried out in the presence of Nd(III), La(III) and Y(III) ions using U(VI)-imprinted p-HEMA-(MAH)3 cryogel polymer. The obtained adsorption order under competitive conditions was U(VI) ˃ La(III) ˃Y(III) ˃Nd(III).
https://ijcce.ac.ir/article_39703_34413197935c93ed9d123213ed0020b6.pdf
2019-12-01
115
125
10.30492/ijcce.2019.39703
U(VI)-imprinted cryogel polymer
p-HEMA-(MAH)3
Selective adsorption
Purification
İbrahim
Dolak
idolak@dicle.edu.tr
1
Vocational School of Technical Sciences, Dicle University, Diyarbakır, TURKEY
LEAD_AUTHOR
[1] Wang J., Chen Z., Shao D., Li Y., Xu Z., Cheng C, Asiri A.M., Marwani H.M., Hu S., Adsorption of U(VI) on Bentonite in Simulation Environmental conditions, Journal of Molecular Liquids, 242: 678–684 (2017).
1
[2] Iliaa R., Liatsou I., Savva I., Vasile E., Vekas L., Marinica, O., Mpekris F., Pashalidis I., Christoforou T.K., Magnetoresponsive Polymer Networks as Adsorbents for the Removal of U(VI) Ions from Aqueous Media, European Polymer Journal, 97:138-146 (2017).
2
[3] Li F., Yang Z., Weng H., Chen G., Lin M., Zhao C., High Efficient Separation of U(VI) and Th(IV) from Rare Earth Elements in Strong Acidic Solution
3
by Selective Sorption on Phenanthroline Diamide Functionalized Graphene Oxide, Chemical Engineering Journal, 332: 340-350 (2018).
4
[4] Wang Y.L., Huang C., Li F.J., Dong Y.M., Sun X.Q., Process for the Separation of Thorium and Rare Earth Elements from Radioactive Waste Residues Using Cyanex® 572 as a New Extractant, Hydrometallurgy, 169: 158–164 (2017).
5
[5] Lu Y., Wei H., Zhang Z., Li Y., Wu G., Liao W., Selective Extraction and Separation of Thorium from Rare Earths by a Phosphorodiamidate Extractant, Hydrometallurgy, 163: 192–197 (2016).
6
[6] Wang Y., Wu L., Yang Y., Feng W., Yuan L., Efficient Separation of Thorium from Rare Earths with a Hydrogen-Bonded Oligoaramide Extractant in Highly Acidic Media, Journal of Radioanalytical Nuclear Chemistry, 305: 543–549 (2015).
7
[7] Zhu Z., Pranolo Y., Cheng C.Y., Separation of Uranium and Thorium from Rare Earths for Rare Earth Production - A Review, Mineral Engineering, 77: 185–196 (2015).
8
[8] Gu Z., Probing the Problems of Thorium Utilization as a Nuclear Energy Resource, Chinese Journal of Nuclear Science and Engineering, 27: 97–105 (2007).
9
[9] Abdollahy M., Shojaosadati S.A., Tavakoli H.Z., Valivand A., Bioleaching of Low Grade Uranium Ore of Saghand Mine, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 10: 71-79 (2011).
10
[10] Chmielewski A.G., Nuclear Fissile Fuels Worldwide Reserves, Nukleonika, 53: 11–14 (2008).
11
[11] Horwitz E.P., Dietz M.L., Chiarizia R., Diamond H., Essling A.M., Graczyk M., Separation and Preconcentration of Uranium from Acidic Media by Extraction Chromatography, Analytica Chimica Acta, 266: 25-37 (1992).
12
[12] Dolak I., Karakaplan M., Ziyadanogulları B., Ziyadanogulları R., Solvent Extraction, Preconcentration and Determination of Thorium with Monoaza 18-Crown-6 Derivative, Bulletin of the Korean Chemical Society, 32: 1564-1568 (2011).
13
[13] Yener I., Oral E.V., Dolak I., Ozdemir O., Ziyadanogulları R., A New Method for Preconcentration of Th (IV) and Ce (III) by Thermophilic Anoxybacillus Flavithermus Immobilized on Amberlite XAD-16 Resin as a Novel Biosorbent, Ecological Engineering, 103: 43-49 (2017).
14
[14] Kaminski M.D., Nunez L., Separation of Uranium from Nitric- and Hydrochloric-acid Solutions with Extractant-Coated Magnetic Microparticles, Separation Science and Technology, 35: 2003-2018 (2000).
15
[15] Haerizade B.N., Ghavami M., Koohi M., Darzi S.J., Rezaee N., Kasaei M.Z., Green Removal of Toxic Pb(II) from Water by a Novel and Recyclable Ag/γ-Fe2O3@r-GO Nanocomposite, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37: 29-37 (2018).
16
[16] Dolak I., Tegin I., Guzel R., Ziyadanogulları R., Removal and Preconcentration of Pb(II), Cr(III), Cr(VI) from the Aqueous Solution and Speciation of Cr(III)-Cr(VI)- by Using Functionalized Amberlite XAD-16 Resin with Dithioethylenediamine, Asian Journal of Chemistry, 22: 6117-6124 (2010).
17
[17] İnam R., Çaykara T., Özyürek C., Polarographic Determination of Uranyl Ion Adsorption on Poly-(2-Hydroxyethyl Methacrylate/itaconic acid) Hydrogels, Separation Science and Technology, 36: 1451-1461 (2001).
18
[18] Sana S., Roostaazad R., Yaghmaei S., Biosorption of Uranium (VI) from Aqueous Solution by Pretreated Aspergillus niger Using Sodium Hydroxide, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 8: 65-74 (2015).
19
[19] Dolak I., Keçili R., Hür D., Ersöz A., Say R., Ion-Imprinted Polymers for Selective Recognition of Neodymium (III) in Environmental Samples, Industrial & Engineering Chemistry Research, 54: 5328-5335 (2015).
20
[20] Keçili R., Dolak I., Ziyadanoğulları B., Ersöz A., Say R., Ion Imprinted Cryogel-Based Supermacroporous Trapsfor Selective Separation of Cerium (III)in Real Samples, Journal of Rare Earths, 36: 857-862 (2018).
21
[21] Dolak I., Selective Separation and Preconcentration of Thorium (IV) in Bastnaesite Ore Using Thorium (IV)-Imprinted Cryogel Polymer, Hacettepe Journal of Biology and Chemistry, 46: 187-197 (2018).
22
[22] Harkins D.A., Schweitzer G.K., Preparation of Site-Selective Ion-Exchange Resins, Separation Science and Technology, 26: 345-354 (1991).
23
[23] Panahi H.A., Zadeh M.S., Tavangari S., Moniri E., Ghassemi J., Nickel Adsorption from Environmental Samples by Ion Imprinted Aniline -Formaldehyde Polymer, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 31: 35-44 (2012).
24
[24] Wulff G., Molecular Imprinting in Cross-Linked Materials with the Aid of Molecular Templates—a Way Towards Artificial Antibodies, Angewandte Chemie International Edition, 34: 1812-1832 (1995).
25
[25] Pakdehi S.G., Adsorptive Removal of Al, Zn, Fe, Cr and Pb from Hydrogen Peroxide Solution by IR-120 Cation Exchange Resin, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 11: 75-84 (2016).
26
[26] Dhal P.K., Arnold F.H., Metal-Coordination Interactions in the Template-Mediated Synthesis of Substrate-Selective Polymers: Recognition of Bis(imidazole) Substrates by Copper(II) Iminodiacetate Containing Polymers, Macromolecules, 25: 7051-7059 (1992).
27
[27] Chen F., Yang Z., Tang Y., Wang X., Selective Extraction and Determination of Di(2-ethylhexyl) Phthalate in Aqueous Solution by HPLC Coupled with Molecularly Imprinted Solid-phase Extraction, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36: 127-136 (2017).
28
[28] Didaskalou C., Buyuktiryaki S., Kecili R., Fonte C.P., Szekely G., Valorisation of Agricultural Waste with an Adsorption/Nanofiltration Hybrid Process: from Materials to Sustainable Process Design, Green Chemistry, 19: 3116-3125 (2017).
29
[29] Székely G., Fritz E., Bandarra J., Heggie W., Sellergren B., Removal of Potentially Genotoxic Acetamide and Arylsulfonate Impurities from Crude Drugs by Molecular Imprinting, Journal of Chromatography A, 1240: 52-58 (2012).
30
[30] Dolak I., Keçili R., Onat R., Ziyadanoğulları B., Ersöz A., Say R., Molecularly Imprinted Affinity Cryogels for the Selective Recognition of Myoglobin in Blood Serum, Journal of Molecular Structure, 1174: 171-176 (2018).
31
[31] Székely G., Bandarra J., Heggie W., Sellergren B., Ferreira F.C., A Hybrid Approach to Reach Stringent Low Genotoxic Impurity Contents in Active Pharmaceutical Ingredients: Combining Molecularly Imprinted Polymers and Organic Solvent Nanofiltration for Removal of 1,3-Diisopropylurea, Separation and Purification Technology, 86: 79-87 (2012).
32
[32] Saylan Y., Yilmaz F., Özgür E., Derazshamshir A., Yavuz H., Denizli A., Molecular Imprinting of Macromolecules for Sensor Applications, Sensors, 17: 1-30 (2017).
33
[33] Sellergren B., Imprinted Chiral Stationary Phases in High-Performance Liquid Chromatography, Journal of Chromatofraphy A, 906: 227-252 (2001).
34
[34] Wei S., Mizaikoff B., Recent Advances on Noncovalent Molecular Imprints for Affinity Separations, Journal of Separation Science, 30: 1794-1805 (2007).
35
[35] Vedadghavami A., Minoei F., Hosseini S.S., Practical Techniques for Improving Teh Performance of Polymeric Membranes and Processes for Protein Separation and Purification, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37: 1-23 (2018).
36
[36] Lasáková M., Jandera P., Molecularly Imprinted Polymers and Their Application in Solid Phase extraction, Journal of Separation Science, 32: 788-812 (2009).
37
[37] Alvarez-Lorenzo C., Concheiro A., Molecularly Imprinted Polymers for Drug Delivery, Journal of Chromatography B, 804: 231-245 (2004).
38
[38] Vidyasankar S., Arnold F.H., Molecular Imprinting: Selective Materials for Separations, Sensors and Catalysis, Current Opinial Biotechnology, 6: 218-224 (1995).
39
[39] Monier M., Abdel-Latif D.A., Fabrication of Au(III) Ion-Imprinted Polymer Based on Thiol-Modified Chitosan, International Journal of Biological Macromolecules, 105: 777-787 (2017).
40
[40] Moussa M., Pichon V., Mariet C., Vercouter T., Delaunay N., Potential of Ion Imprinted Polymers Synthesized by Trapping Approach for Selective Solid Phase Extraction of Lanthanides, Talanta, 161: 459-468 (2016).
41
[41] Moorthy M.S., Tapaswi P.K., Park S.S., Mathew A., Cho H.-J., Ha C.-S., On-imprinted Mesoporous Silica Hybrids for Selective Recognition of Target Metal Ions, Microporous and Mesoporous Materials, 180: 162-171 (2013).
42
[42] Monier M., Abdel-Latif D.A., Abou El-Reash Y.G., Ion-Imprinted Modified Chitosan Resin for Selective Removal of Pd(II) Ions, Journal of Colloidal and Interface Science, 469: 344-354 (2016).
43
[43] Mitreva M., Dakova I., Karadjova I., Iron(II) Ion Imprinted Polymer for Fe(II)/Fe(III) Speciation in Wine, Microchemica Journal, 132: 238-244 (2017).
44
[44] Msaadi R., Ammar S., Chehimi M.M., Yagci Y., Diazonium-Based Ion-Imprinted Polymer/Clay Nanocomposite for the Selective Extraction of Lead(II) Ions in Aqueous Media, European Polymer Journal, 89: 367-380 (2017).
45
[45] Roushani M., Abbasi S., Khani H., Sahraei R., Synthesis and Application of Ion-Imprinted Polymer Nanoparticles for the Extraction and Preconcentration of Zinc Ions, Food Chemistry, 173: 266-273 (2015).
46
[46] Fayazi M., Ghanei M.M., Taher M.A., Ghanei-Motlagh R., Salavati M.R., Synthesis and Application of a Novel Nanostructured Ion-Imprinted Polymer for the Preconcentration and Determination of Thallium(I) Ions in Water Samples, Journal of Hazardous Materials, 309: 27-36 (2016).
47
[47] Candan N., Tüzmen N., Andaç M., Andaç C.A., Say R., Denizli A., Cadmium Removal out of Human Plasma Using Ion-Imprinted Beads in a Magnetic Column, Materials Science and Engineering C, 29: 144-152 (2009).
48
[48] Gao B., Meng J., Xu Y., Zhang Y., Preparation of Fe(III) Ion Surface-Imprinted Material for Removing Fe(III) Impurity from Lanthanide Ion Solutions, Journal of Industrial Engineering and Chemistry, 24: 351-358 (2015).
49
[49] Bereli N., Saylan Y., Uzun L., Say R., Denizli A., L-Histidine Imprinted Supermacroporous Cryogels for Protein Recognition, Separation and Purification Technology, 82: 28-35 (2011).
50
[50] Baysal Z., Aksoy E., Dolak I., Ersöz A., Say R., Adsorption Behaviours of Lysozyme onto Poly-Hydroxyethyl Methacrylate Cryogels Containing Methacryloyl Antipyrine-Ce(III), International Journal of Polymeric Materials and Polymeric Biomaterials, 67: 199-204 (2018).
51
[51] Kupai J., Razali M., Buyuktiryaki S., Kecili R., Szekely G., Long-Term Stability and Reusability of Molecularly Imprinted Polymers, Polymer Chemistry, 8: 666-673 (2017).
52
[52] Fodi T., Didaskalou C., Kupai J., Balogh G.T., Huszthy P., Szekely G., Nanofiltration‐Enabled In Situ Solvent and Reagent Recycle for Sustainable Continuous‐Flow Synthesis, Chem Sus Chem, 10: 3435-3444 (2017).
53
ORIGINAL_ARTICLE
Adsorption of Zinc and Lead onto Sediments of the Dam Chorfa
At the laboratory level, we studied the effects of various factors, the initial concentration of metal ions, the pH of the solution, the amount of mud used and contact time, on the adsorption of zinc, and leads ions onto dam material (Mascara, Algeria). The constituents of silt sediment are quartz, calcite, and a mixture of clays. The equilibrium time was of the order of 60 min. The adsorption diagram is smooth and continuous leading to saturation, suggesting the possible monolayer coverage of zinc and lead ions on the surface of the adsorbent. The extent of adsorption increases with an increase in pH. Furthermore, the adsorption of metals increases with an increasing amount of adsorbent. The adsorption modeling was carried out using the Langmuir and Freundlich adsorption models to determine the mechanistic parameters associated with the adsorption process. The Langmuir–Freundlich isotherm model was the best to describe the experimental data. The maximum sorption capacity was found to be 42.73 and 131.57 mg/g for Zn2+ and Pb2+, respectively.
https://ijcce.ac.ir/article_34229_6cbfd0dc5cc5769f0a734b90a10ec295.pdf
2019-12-01
127
133
10.30492/ijcce.2019.34229
Sediment
mud
Langmuir model
Freundlich model
Kinetics
Adsorption
Mohamed El-Amine
Bekhti
bekhti23@yahoo.com
1
Université Djilali Liabès, Faubourg Larbi Benm’hidi B.P. 89, Sidi Bel-Abbès 22000; ALGERIA
AUTHOR
Ahmed
Yahiaoui
yahiaoui.ahmed@yahoo.fr
2
Laboratoire de Chimie Organique, Macromoléculaire et des Matériaux, Université Mustapha Stambouli de Mascara, Bp 763 Mascara 29000; ALGERIA
AUTHOR
Aicha
Hachmaoui
aicha.fatima@yahoo.fr
3
Laboratoire de Chimie Organique, Macromoléculaire et des Matériaux, Université Mustapha Stambouli de Mascara, Bp 763 Mascara 29000; ALGERIA
AUTHOR
Abdelghani
Benyoucef
a.benyoucel@univ-mascara.dz
4
Laboratoire de Génie des Procèdés et Chimie des Solutions, Université Mustapha Stambouli de Mascara, Bp 763 Mascara 29000; ALGERIA
LEAD_AUTHOR
[1] Bhattacharyya K.G., Gupta S.S., Pb(II) Uptake by Kaolinite and Montmorillonite in Aqueous Medium: Influence of Acid Activation of the Clays, Colloids and Surfaces A., 277(1-3): 191-200 (2006).
1
[2] Cheng T., Chen C., Tang R., Han C., Tian Y., Competitive Adsorption of Cu, Ni, Pb, and Cd from Aqueous Solution Onto Fly Ash-Based Linde F(K) Zeolite., Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 37(1): 61-72 (2018)
2
[3] Moghaddam M.S., Rahdar S., Taghavi M., Cadmium Removal from Aqueous Solutions Using Saxaul Tree Ash, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35(3): 45-52
3
[4] Arfaoui S., Srasra E., Frini-Srasra N., Application of Clays to Treatment of Tannery Sewages, Desalination, 185(1-3): 419-426 (2005)
4
[5] Hamdi N., Srasra E., Removal of Fluoride from Acidic Wastewater by Clay Mineral: Effect of Solid–Liquid Ratios, Desalination, 206(1-3): 238-244 (2007)
5
[6] Srasra E., Bergaya F., Van Damme H., Ariguib N.K., Surface Properties of an Activated Bentonite-Decolorisation of Rape-Seed Oils, Applied Clay Science. 4(5-6): 411-421 (1989)
6
[7] Şölener M., Tunali S., Özcan A.S., Özcan A., Gedikbey T., Adsorption Characteristics of Lead(II) Ions onto the Clay/poly(methoxyethyl)acrylamide (PMEA) Composite from Aqueous Solutions, Desalination, 223(1-3): 308-322 (2008)
7
[8] Wang L.K., Vaccari D.A., Li Y., Shammas N.K., “Chemical Precipitation, Physicochemical Treatment Processes”. Humana Press, New Jersey (2004)
8
[9] Krishna G.B., Susmita S.G., Influence of Acid Activation on Adsorption of Ni(II) and Cu(II) on kaolinite and Montmorillonite: Kinetic and Thermodynamic Study, Chemical Engineering Journal, 136(1): 1-13 (2008)
9
[10] Tran H.H., Roddick F.A., O'Donell, J.A., Comparison of Chromatography and Desiccant Silica Gels for the Adsorption of Metal Ions-I. Adsorption and Kinetics, Water Res., 33(13): 2992-3000 (1999).
10
[11] Dimitrova S.V., Use of Granular Slag Columns for Lead Removal, Water Res, 36(16): 4001-4008 (2002).
11
[12] Shukla A., Zhang Y.H., Dubey P., Margrave J.L., Shukla S.S., The Role of Sawdust in the Removal of Unwanted Materials from Water, J. Hazard. Mater., 95(1-2): 137-152 (2002).
12
[13] Al-Asheh S., Duvnjak Z., Sorption of Heavy Metals by Canola Meal. Water, Air, and Soil Pollution. 114(3): 251-276 (1999).
13
[14] Mateos F.J.G., Moulefera I., Rosas J.M., Benyoucef A., Mirasol J.R., Cordero T., Alcohol Dehydrogenation on Kraft Lignin-Derived Chars with Surface Basicity, Catalysts, 7(10): 308 (2017).
14
[15] Bhattacharyya K.G., Sen Gupta S., Influence of Acid Activation on Adsorption of Ni(II) and Cu(II)
15
on Kaolinite and Montmorillonite: Kinetic and Thermodynamic Study, Chemical Engineering Journal, 136(1): 1-13 (2008).
16
[16] Bhattacharyya K.G., Sen Gupta S., Influence of Acid Activation on Adsorption of Ni(II) and Cu(II) on Kaolinite and Montmorillonite: Kinetic and Thermodynamic Study, Chem. Eng. J., 136(1): 1-13 (2008)
17
[17] Boyanov B., Konarev V., Kolev N., Removal of Cobalt and Nickel from Zinc Sulphate Solutions Using Activated Cementation, Journal of Mining and Metallurgy, 40(1): 41-55 (2004)
18
[18] Zehhaf A., Benyoucef A., Quijada C., Taleb S., Morallón E., Algerian Natural Montmorillonites
19
for Arsenic(III) Removal in Aqueous Solution, International Journal of Environmental Science and Technology, 12(2): 595-602 (2015).
20
[19] Mekhloufi M., Zehhaf A., Benyoucef A., Quijada C., Morallon E., Removal of 8-Quinolinecarboxylic Acid Pesticide from Aqueous Solution by Adsorption on Activated Montmorillonites, Environmental Monitoring and Assessment, 185(12): 10365-10375 (2013).
21
[20] Zehhaf A., Benyoucef A., Berenguer R., Quijada C., Taleb S., Morallon E., Lead Ion Adsorption
22
from Aqueous Solutions in Modified Algerian Montmorillonites, Journal of Thermal Analysis and Calorimetry, 110(3): 1069-1077 (2012).
23
[21] Ouadjenia F., Marouf R., Schott J., Yahiaoui A., Removal of Cu(II), Cd(II) and Cr(III) Ions from Aqueous Solution by Dam Silt, Arabian Journal of Chemistry, 6(4): 401-406 (2013).
24
[22] Freundlich H.M.F., Uber die Adsorption in Losungen. Zeitschrift für Physikalische Chemie, 57: 385-470 (1906).
25
[23] He Q., Hu Z., Jiang Y., Chang X., Tu Z., Zhang L., Preconcentration of Cu(II), Fe(III) and Pb(II)
26
with 2-((2-aminoethylamino)methyl)phenol-functionalized Activated Carbon Followed by ICP-OES Determination, Journal of Hazardous Materials, 175(1-3): 710-714 (2010)
27
[24] Şengil İ.A., Özacar M., Competitive Biosorption of Pb2+, Cu2+ and Zn2+ Ions from Aqueous Solutions onto Valonia Tannin Resin, Journal of Hazardous Materials, 166(2-3): 1488-1494 (2009)
28
[25] Gulnaz O., Kaya A., Matyar F., Arikan B., Sorption of Basic Dyes from Aqueous Solution by Activated Sludge, Journal of Hazardous Materials, 108(3): 183-188 (2004)
29
[26] Metcalf E., “Wastewater Engineering: Treatment, Disposal and Reuse”, Irwin/McGraw, Hill Boston (1991)
30
ORIGINAL_ARTICLE
The Study on the Reduction of the Viscosity of Transported Heavy Crude Oil by Fe(II) and Fe(III) Complexes with Phthalic Acid
The coordination compounds of Fe (II) and Fe(III) with phthalic acid were synthesized. The compounds were studied by X-Ray Diffraction (XRD), Differential Thermal Analysis (DTA), and IR spectroscopy. It has been established that, regardless of the oxidative number of iron, the synthesis products have the same chemical composition and chemical formula - [Fe2(o-C6H4(COO)2)3]. It also found that the carboxyl groups of phthalate dianion have a monodentate and bridging function and the complex itself is a polymer-layered structure. Based on the obtained results, a schematic structure of the complex was proposed. Also were studied the thermal stability of the complex in the temperature range 20-660 °С and the supramolecular interaction of this substance with the rheological properties of heavy commercial oils. This significantly reduces the viscosity of heavy oil during transportation. Coordination polymer-based composites have been developed and tested. The use of composite solves several technological problems associated with the transport of high-viscosity oil.
https://ijcce.ac.ir/article_34156_0b1c29fd1671b7792b723c7121bacec5.pdf
2019-12-01
135
140
10.30492/ijcce.2019.34156
complex
structure
Muradhanly
reagent
rheology
coordination polymer
nanomer
Vali Hanaga
Nurullayev
veliehet1973@mail.ru
1
Scientific-Research Institute "Geotechnological Problems of Oil, Gas and Chemistry", AZ1010, st. D.Aliyeva, 227, Baku, AZERBAIJAN
LEAD_AUTHOR
Beybala Taci
Usubaliyev
2
Azerbaijan State University of Oil & Industry, Scientific-Research Institute "Geotechnological Problems of Oil, Gas and Chemistry", AZ1010, st. D.Aliyeva, 227, Baku, AZERBAIJAN
LEAD_AUTHOR
Dilgam Babir
Taghiyev
3
Institute of Catalysis and Inorganic Chemistry after the Name of M.F.Naghiyev, National Academy of Sciences of Azerbaijan, Baku, AZERBAIJAN
AUTHOR
[1] Kopylovich M.N., Karabach Y.Y., Mahmudov K.T., Haukka M.M., Kirillov A.M., Heterometallic Cop Per (II)–Potassium 3D Coordination Polymers Driven by Multifunctionalized Azo Derivatives of β-Diketones, Crystal Growth & DesignJournal, 11(10): 4247-4252 (2011)
1
[2] Mahmudov K.T., Kopylovich M.N., da Silva M.F.C.G., Pombeiro A.J.L., Non-covalent Interactions in the Synthesis of Coordination Compounds: Recent Advances, Coordination Chemistry Reviews Journal, 3(45): 54-72 (2017)
2
[3] Kopylovich M.N., MFCG da Silva, Martins L.M, Kouznetsov M.L, Synthesis, Structure and Electrochemical Behaviour of Na, Mg II, Mn II, Zn II, Cd II and Ni II Complexes of 3-(2-carboxyphenylhydrazone) Pentane-2, 4-dione Polyhedron 50 (1): 374-382 (2013).
3
[4] Gurbanov A.V, Mahmudov, K.T., Sutradhar M., FCG da Silva, TA Mahmudov T.A, Copper (II) Complexes with Carboxylic-or Sulfonic-Functionalized Arylhydrazones of Acetoacetanilide and Their Application in Cyanosilylation of Aldehydes. Journal of Organometallic Chemistry, 8 (34): 22-27 (2017).
4
[5] Shixaliyev N.Q., Maharramov A.M., Gurbanov A.V., Gurbanova N.V., Structure and Supramolecular Arrangement of Bis (2, 4-bis (trichloromethyl)-1, 3, 5-triazapenta-dienato)-M (II)[M= Ni (II), Cu (II) and Pd (II)] Complexes, Journal of Molecular Structure, 10(41): 213-218 (2013).
5
[6] Usubaliyev B.T., Taghiyev D.B., Nurullayev V.H., and others, Structural and Chemical Research of Coordination Compounds of Hexaaqua Bisbenzol-1, 2, 4, 5- Tetracarbonate Diiron (II) With A Layered-Porous Structure, For Heavy Crude Oil, International Journal of Nano Studies & Technology, 2(55):123-127 (2016).
6
[7] Ganbarov D.M., Tomuyeva A.Sh., Usubaliyev B.T, Synthesis and Structure-Chemical Studies of Clathrate Compounds of Terephthalates of Copper (ii) and Cadmium (ii), Chemistry and Chemical Technology, 3(52): 3-11 (2012).
7
[8] Usubaliyev B.T., Taghiyev D.B., Nurullayev V.H., et al Structural and Chemical Research of Coordination Compounds of Hexaaqua Bisbenzol 1,2,4,5-Tetracarbonate Diiron (II) with a Layered-Porous Structure, Journal of Nanomaterials & Molecular Nanotechnology, 1(4):1-5 (2017).
8
[9] Usubaliyev B.T., Taghiyev D.B., Nurullayev V.H., and others, Use of Nanostructured Hexaaqua Bisbenzol-1, 2, 4, 5-Tetracarbonate Diiron (II) Coordination Compounds (BAF-1 and GAF-2)
9
to Reduce the Viscosity of Transported Heavy Crude Oil, Middle-East Journal of Scientific Research, 3(25):127-136 ( 2017).
10
[10] Usubaliyev B.T., Nurullayev V.H., and others, Synthesis and Structural - Chemical Research of Coordination Compounds of Tetraaqua Bisbenzol -1,2,4,5 - Tetracarboksilat Dizinc (II), Bulletin of Environment, Pharmacology and Life Sciences, 5(4): 10-16 (2016).
11
[11] Liu Hsin-Kuan., Tai-Hsing Tsao., Chia-Her Lin., Vítezslav Zima, Direct-Mixing Assembly of a Magnesium Coordination Complex as Recyclable Water Adsorbent, Vítezslav Zima, 12(4):1044-1047 (2010).
12
[12] Usubaliyev B.T., MunshiyevaM.K., Aliyeva F.B. et al, Synthesis, Physical – and Structure-Chemical Research of Coordinating Compounds of Diaquo-1,2,4,5-benzoltetracarbonat Dicopper (II), Bull. Env. Pharmacol. Life Sci., 5(3): 12-17 ( 2016).
13
[13] Usubaliyev B.T., Taghiyev D.B., Nurullayev V.H., et al, Synthesis and Structural-Chemical Studies of Hexoaquatribenzene- 1, 2, 4, 5- Tetracarbon-Tetrairon (III) Coordinator Compound, Frontiers in Nanoscience and Nanotechnology, 3(2): 1-4 (2017).
14
[14] Usubaliev B. T., Ramazanova E. E., Nurullaev V. H., and others, The Use of Nanostructured Coordination Compounds to Reduce Viscosities of Heavy Commercial Oils During Transportation, Problems of Collecting, Preparing and Transporting Oil and oil Products, 4(3):117-126 (2015).
15
[15] Nurullayev V.H., Transporting Mixtures of Fuel Oil and Low-Viscosity Crude by Pipeline, Oil and Gaz Journal, 5(9):78-81 (2017).
16
ORIGINAL_ARTICLE
Development of a Polyfunctional Dipodal Schiff Base: An Efficient Chelator and a Potential Zinc Sensor
A novel polyfunctional dipodal ligand, L = N,N'-bis[2-[(2-hydroxy-1-naphthyl)methyleneamino]ethyl]propanediamide (DOTA2HNAP) was developed and characterized through elemental and spectral analyses. The complexation behavior of the ligand was investigated with Co2+, Cu2+, and Zn2+ metal ions by potentiometric and spectrophotometric methods in the H2O-DMSO mixture (99:1) at µ = 0.1M KCl and 25 ± 1 °C. Four protonation constants for –OH of naphtholate groups and –N of imine were determined for the ligand. The ligand forms monomeric complexes of ML type with the metal ions, where coordination occurs through N-imine and O-naphtholate donors (N2O2). In the case of a complex of copper, an additional species, MLH-2, was formed due to ionization of the amide groups in a higher pH. The minimum energy structures of the metal complexes in solution have been obtained through molecular modeling studies by using the semi-empirical/ PM3 method. The photophysical properties of DOTA2HNAP were investigated in the presence of a wide range of biologically relevant metal ions. The fluorescence emission of the ligand at 450 nm (λex = 361 nm) exhibited a remarkable enhancement with Zn2+ ions (1 equivalent) at physiological pH amongst all metal ions. Such behavior enables the ligand to be considered as a suitable model for the detection of Zn2+ towards environmental applications.
https://ijcce.ac.ir/article_32441_adbae40b3ada9f5369dc36b11fa66d68.pdf
2019-12-01
141
156
10.30492/ijcce.2019.32441
Fluorescence spectroscopy
Dipodal chelator
Zn2+ Sensor
Potentiometric
Spectrophotometry
Transition metals
Amit
Gupta
siderophores@gmail.com
1
Department of Chemistry, National Institute of Engineering and Technology Kurukshetra, Haryana-136119, INDIA
AUTHOR
Vijay
Dangi
91dangi@gmail.com
2
Department of Chemistry, National Institute of Engineering and Technology Kurukshetra, Haryana-136119, INDIA
AUTHOR
Minati
Baral
minatibnitkkr@gmail.com
3
Department of Chemistry, National Institute of Engineering and Technology Kurukshetra, Haryana-136119, INDIA
LEAD_AUTHOR
B
Kanungo
b.kanungo@gmail.com
4
Department of Chemistry, Sant Longowal Institute of Engineering and Technology, Longowal, Punjab-148106, INDIA
AUTHOR
[1] Mathews C.K., van Holde K.E., Ahern K.G., Enzymes: Biological Catalysts, In book Biochemistry, 3rd ed.; Roberts B., Weber L., Marsh J., Publication: Benjamin/ Cummings, San Fransisco, 391 (1999).
1
[2] Ngo Anh H., Bose Sohini, Do Loi H., Intracellular Chemistry: Integrating Molecular Inorganic Catalysts with Living Systems, Chemistry - A European Journal, 24(42): 10584-10594 (2018).
2
[3] Ziyang H., Rongfeng Z., Peng R.C., Genetically Encoded Fluorescent Sensors for Measuring Transition and Heavy Metals in Biological Systems, Current Opinion in Chemical Biology, 4387-96 (2018).
3
[4] Badiye A., Kapoor N., Khajuria H., Copper Toxicity: A Comprehensive Study, Res. J. Recent Sci., 2: 58-67 (2013).
4
[5] Plum L.M., Rink L., Haase H., The Essential Toxin: Impact of Zinc on Human Health, Int. J. Environ. Res. Public Health 7: 1342-1365 (2010).
5
[6] Mao X., Wong A.A., Crawford R.W., Cobalt Toxicity — an Emerging Clinical Problem in Patients with Metal-on-Metal Hip Prostheses? MJA, 194: 649-651 (2011).
6
[7] Abu-Dief F.A., Ibrahim M.A., Mohamed A., Review on Versatile Applications of Transition Metal Complexes Incorporating Schiff Bases, Beni-Suef University J. Basic App. Sci., 4: 119 -133 (2015).
7
[8] Kumar G., Kumar D., Singh C.P., Kumar A., Rana V.B., Synthesis, Physical Characterization and Antimicrobial Activity of Trivalent Metal Schiff Base Complexes, J. Serb. Chem. Soc., 75(5): 629–637 (2010).
8
[9] Chang, E.L., Simmers C., Knight D.A., Cobalt Complexes as Antiviral and Antibacterial Agents. Pharmaceuticals, 3: 1711-1728 (2010).
9
[10] Creaven B.S., Duff B., Egan D.A., Kavanagh K., Rosair G., Thangella V.R., Walsh M., Anticancer and Antifungal Activity of Copper(II) Complexes of Quinolin-2(1H)-one-Derived Schiff Bases, Inorg. Chim. Acta, 363: 4048–4058 (2010).
10
[11] Antonov L., Fabian W.M.F., Nedeltcheva D., Kamounah F.S., Tautomerism of 2-Hydroxynaphthaldehyde Schiff Bases, J. Chem. Soc. Perkin. Trans., 2: 1173-1179 (2000).
11
[12] Abdullah M. Asiri A.M., Badahdah K.O., Khan S.A., g. Al-sehem A., s. Al-Amoudi M., Bukhari A.A., Spectroscopic Study and Semi-Empirical Calculations of Tautomeric Forms of Schiff Bases Derived from 2-Hydroxy-1-Naphthaldehyde and Substituted 2-Aminothiophene, Org. Chem. Insights., 3: 1–8 (2010).
12
[13] Furniss B.S., Hannaford A.J., Smith P.W.G., Tatchell A.R., “Vogel’s Textbook of Practical Organic Chemistry”, 5th ed., Longman Scientific & Technical, London, 131-234 (1989).
13
[14] Instruction Manual for Orion Star A111 pH meter Accompanied with Ross Ultra Combination pH Electrode 8102BNUWP of Thermo Scientific.
14
[15] Gan P., Sabatini A., Vacca A., Investigation of Equilibria in solution: Determination of Equilibrium Constants with the HYPERQUAD Suit Programs, Talanta, 53: 1739 (1996).
15
[16] Alderighia L., Gans P., Ineco A., Peters D., Sabatini A., Vacca A., Hyperquad Simulation and Speciation (HySS): a Utility Program for the Investigation of Equilibria Involving Soluble and Partially Soluble Species, Coord. Chem. Rev., 184: 311 (1999).
16
[17] Gan P., Sabatini A., Vacca A., Determination of Equilibrium Constants from Spectrophotometric Data Obtained from Solutions of Known pH: The Program pHab, Ann. Chim. (Rome), 89: 45-49 (1999).
17
[18] Lee S., Rao B.A., Son Y.A., A Highly Selective Fluorescent Chemosensor for Hg2+ Based on a Squaraine–bis(rhodamine-B) Derivative. Part II, Sensors and Actuators B, 210: 519–532 (2015).
18
[19] Bellamy L.J., “The Infra-red Spectra of Complex Molecules”, 3rd ed., Chapman and Hall Ltd., London, (1975).
19
[20] Sahoo S.K., Muthu S.E., Baral M., Kanungo B.K., Potentiometric and Spectrophotometric Study of a New Dipodal Ligand N,N’-bis{2-[(2-hydroxybenzylidine) amino]ethyl}malonamide with Co(II), Ni(II), Cu(II) and Zn(II), Spectrochim. Acta. A, 63: 574-586 (2006).
20
[21] Sosa J.M., Vinkovi´ M., c-Topi´ D.V., NMR Spectroscopyof 2-hydroxy-1-naphthylidene Schiff Bases with Chloroandhydroxy Substitutedaniline Moiety, Croatica Chim. Acta, 79: 489–495 (2006).
21
[22] Dogan A., Sakyan I., Kilic E., Potentiometric Studies on Some α-Amino Acid- Schiff Bases and Their Manganese (III) Complexes in Dimethylsulfoxide-Water Mixtures at 25°C, J. Sol. Chem. 33: 1539-1546 (2004).
22
[23] EI-Taher M.A., EI-Hatey M.T., Hussain T.M., Effect of Partially Aqueous Solutions of Different pH’s on the Hydrolysis Rate of Some Schiff Bases. Polish J. Chem., 75: 79-91 (2001).
23
[24] Fabbirizzi L., Perotti A., Poggi A., The Deprotonated Amido vs. the Amino Group in the Stabilization of Coordinated Trivalent Copper and Nickel Cations. An Electrochemical Evaluation, Inorg. Chem., 22: 1411 (1983).
24
[25] Basoglu A., Parlayan S., Ocak M, Alp H., Halit K., Ozdemir M., Ocak U., Complexation of Metal Ions with the Novel 2-hydroxy-1-naphthaldehyde-derived Diamine Schiff Base Carrying a Macrobicyclic Moiety with N2O2S2 Mxed Donor in Acetonitrile-Dichloromethane, Polyhedron, 28: 1115-1120 (2009).
25
[26] Temel H., Cakir U., Otludil B,, Ugras H.I. Synthesis, Spectral and Biological Studies of Mn(II), Ni(II), Cu(II), and Zn(II) Complexes with a Tetradentate Schiff Base Ligand. Complexation Studies and the Determination of Stability Constants, Synth. React. Inorg. Met.-Org. Chem., 31: 1323-1337 (2001).
26
[27] Amar R.A.A., Abdel-Nasser M., Alaghaz A., Synthesis, Spectroscopic Characterization and Potentiometric Studies of a Tetradentate [N2O2] Schiff Base, N, N’-bis(2-hydroxybenzylidene)-1,1-Diaminoethane and Its Co (II), Ni(II), Cu(II) and Zn(II) Complexes, 8:8686-8699 (2013).
27
[28] Jung H.S., Verwilst P., Kim W.Y., Kim J.S., Fluorescent and Colorimetric Sensors for the Detection of Humidity or Water Content, Chem. Soc. Rev.,(2016).DOI: 10.1039/c5cs00494b.
28
[29] Zhao J., Ji S., Chen Y., Guo H., Yang P., Excited State Intramolecular Proton Transfer (ESIPT): from Principle Photophysics to the Development of new Chromophores and Applications in Fluorescent Molecular Probes and Luminescent Materials, Phys. Chem. Chem. Phys., 14: 8803–8817 (2012).
29
[30] Rodriguez-Cordoba W., Zugazagoitia J.S., Collado-Fregoso E., Peon J., Fluorescent Chemosensor Based on Schiff Base for Selective Detection of Zinc(II) in Aqueous Solution, J. Phys. Chem. A, 111: 6241-6247 (2007).
30
[31] Li L., Dang Y.Q., Li H.W., Wang B., Wu Y., Fluorescent Chemosensor Based on Schiff Base for Selective Detection of zinc(II) in Aqueous Solution Tetrahedron Lett., 51: 618–621 (2010).
31
[32] Zhang M., Lu W., Zhou J., Du G., Jiang L., Ling J., Shen Z., A Simple and Effective Fluorescent Chemosensor for the Cascade Recognition of Zn 2þ and H2PO4 Ions in Protic Media, Tetrahedron, 70: 1011-1015 (2014).
32
[33] Misra A., Shahid M., Dwivedi P., Srivastava P., Ali R., Razi S.S., A Simple Naphthalimide-Based Receptor for Selective Recognition of Fluoride Anion, ARKIVOC, 133-145 (2013).
33
[34] Sahana A., Banerjee A., Das S., Lohar S., Karak D., Sarkar B., Mukhopadhyay S.K., Mukherjee A.K., Das D., A Naphthalene-Based Al3+ Selective Fluorescent Sensor for Living Cell Imaging, Org. Biomol. Chem., 9: 5523 (2011).
34
[35] Singh N., Kaur N., Callan J.F., Incorporation of Siderophore Binding Sites in a Dipodal Fluorescent Sensor for Fe(III). J. Fluoresc., 19: 649–654 (2009).
35
[36] Li J., Yin C., Huo F., Development of Fluorescent Zinc Chemosensors Based on Various Fluorophores and Their Applications in Zinc Recognition, Dyes and Pigments, 131: 100-133 (2016).
36
[37] Zhu H., Fan J., Wang B., Peng X., Fluorescent, MRI, and Colorimetric Chemical Sensors for the First-Row d-Block Metal Ions, Chemical Society Reviews, 44(13): 4337-4366 (2015).
37
[38] Carter, Kyle P.; Young, Alexandra M.; Palmer, Amy E.; Fluorescent Sensors for Measuring Metal Ions in Living Systems; Chemical Reviews, 2014, 114(8), 4564-4601.
38
[39] Thiagarajany V., Ramamurthy P., Dual Fluorescence in a Schiff Base Derived from an Acridinedione Dye: Excited State Intramolecular Proton Transfer. Bull. Chem. Soc. Jpn., 80: 1307–1315 (2007).
39
[40] Roy P., Dhara K., Manassero M., Banerjee P., Synthesis, Characterization and Selective Fluorescent Zinc(II) Sensing Property of Three Schiff-Base Compounds, Inorg. Chim. Acta, 362: 2927–2932 (2009).
40
[41] Costamagna J., Vargas J., Latorre R., Alvarado A., Mena G., Coordination Compounds of Copper, Nickel, Iron, with Schiff Bases Derived from Hydroxynaphthaldehyde and Salicylaldehyde, Coord. Chem. Rev., 119: 67-88 (1992).
41
[42] Hariharan M., Urbach F.L., The Stereochemistry of Tetradentate Schiff Base Complexes of Cobalt (II), Inorg. Chem., 8: 556-559 (1963).
42
[43] Irving H., Williams R.J.P., "The Stability of Transition-Metal Complexes", Inorganic Chemistry Laboratory, Oxford, 3192-3210 (1952).
43
ORIGINAL_ARTICLE
Optimization Extraction of Terbium by Supported Liquid Membrane Using D2EHPA and TOPO
The extraction of Terbium (III)from aqueous nitrate solutions with a supported liquid membrane was investigated using a mixture of di-(2-ethylhexyl phosphoric acid (D2EHPA) and tri-octyl phosphine oxide (TOPO) with a molar ratio 1/0.4. The Hydrophobic Polyvinylidene Fluoride (PVDF) membrane was used as solid support. The sorption process followed pseudo-second-order kinetics. The quantity of 8.29 mg/g was extracted using a Supported Liquid Membrane (SLM). The influence of the ionic strength, stirring rate, extraction time, and the interactions between them on the extraction yield of Terbium (III) ions was investigated using the factorial designs. The analysis of variance was used to show the relative importance of the extraction process parameters.
https://ijcce.ac.ir/article_34228_b1e28f753a7be1890ecfdec3dd826024.pdf
2019-12-01
157
165
10.30492/ijcce.2019.34228
Extraction
Analysis
Supported liquid membrane
Rare earth
D2EHPA
TOPO
Sid Ahmed
Elhabiri
elhabirisa.chem@gmail.com
1
Tlemcen University, Faculty of Sciences, Department of Chemistry, Laboratory of Separation and Purification Technologies, Box 119, 13000, Tlemcen, ALGERIA
AUTHOR
Mohammed Amine
Didi
madidi13@yahoo.fr
2
Tlemcen University, Faculty of Sciences, Department of Chemistry, Laboratory of Separation and Purification Technologies, Box 119, 13000, Tlemcen, ALGERIA
LEAD_AUTHOR
[1] León G., Martínez G., Guzmán M.A., Moreno J.I., Miguel B., Fernández-López J.A., Increasing Stability and Transport Efficiency of Supported Liquid Membranes Through a Novel Ultrasound-Assisted Preparation method. Its Application to Cobalt(II) Removal, Ultrason. Sonochem., 20(2): 650-654 (2013).
1
[2] Jakubowska N., Polkowska Z., Namiesnik J., Analytical Applications of Membrane Extraction for Biomedical and Environmental Liquid Sample Preparation, Anal. Chem., 35(3): 217-235 (2005).
2
[3] Zaheri P., Abolghasemi H., Maraghe M.G., Mohammadi T., Intensification of Europium Extraction Through a Supported Liquid Membrane Using Mixture of D2EHPA and Cyanex272 as Carrier, Chem. Eng. Process., 92: 18-24 (2015).
3
[4] Singh S.K., Misra S.K., Tripathi S.C., Singh D.K., Studies on Permeation of Uranium (VI) from Phosphoric Acid Medium Through Supported Liquid Membrane Comprising a Binary Mixture of PC88A and Cyanex 923 in n-Dodecane as Carrier, Desalination, 250(1): 19-25 (2010).
4
[5] Amara-Rekkab A., Didi M.A., Design Optimization of Extraction Procedure for Mercury (II) Using Chelex-100 Resin, Desalin Water Treat., 57 (15): 6950-6958 (2016).
5
[6] Naït-Tahar S., Didi M.A., Cloud Point Extraction of Uranyl Ions Using TX-100 with N-butyl N’-Triethoxy Methyl Imidazolium/D2EHPA-H Ionic Liquid in Acetate Media, Current Physical Chemistry, 7(1): 57-62 (2017).
6
[7] Boutheyna A., Didi M. A., Removal of Copper (II) and Iron (III) Mixture by Pilot Nanofiltration,Eur. Chem. Bulletin, 5(12): 545-552 (2016).
7
[8] Ashraf W., Mian A., Selective Separation and Preconcentration Studies of Chromium(VI) with Alamine 336 Supported Liquid Membrane, Toxicol. Environ. Chem., 88(2): 187-196 (2006).
8
[9] Belkhouche N.E., Didi M.A. Romero R., Jonsson J.A., Villemin D., Study of New Organophosphorus Derivates Carriers on the Selective Recovery of M (II) and M (III) Metals, Using Supported Liquid Membrane Extraction, J. Membrane. Sci., 284: 398-405 (2006).
9
[10] Liang P., Binghua Y., Xinglong F., Study on Transport of Dy(III) by Dispersion Supported Liquid Membrane, J. Rare Earth, 27(3): 447-456 (2009).
10
[11] Liang P., Liming W., Guoqiang, Y., Separation of Eu(III) with Supported Dispersion Liquid Membrane System Containing D2EHPA as Carrier and HNO3 Solution as Stripping Solution, J. Rare Earth, 29(1): 7-14 (2011).
11
[12] Medjahed B., Didi M.A., Removal of Copper Ions Using Aliquat 336/TBP Based Supported Liquid Membrane, Scientific Study and Research, 14(3): 163 – 172 (2013).
12
[13] Vasylechko V.O., Gryshchouk G.V., Zakordonskiy V.P., Patsay I.O., Len’c N.V., Vyviurska O.A., Sorption of Terbium on Transcarpathian Clinoptilolite, Micropor. Mesopor. Mat., 167: 155-161 (2013).
13
[14] Chen Z., Ding F., Hao F., Bian Z., Ding B., Zhu Y., Chen F., Huang C., A Highly Efficient OLED Based on Terbium Complexes, Org. Electron., 10(5): 939–947 (2009).
14
[15] Kumar B.N., Radhika S., Kantama M.L., Reddy B.R., Solid–liquid Extraction of Terbium from Phosphoric Acid Solutions Using Solvent-Impregnated Resin Containing TOPS 99, J. Chem. Technol. Biot., 86 (4): 562-569 (2011).
15
[16] Vani T.J.S., Rao K.S.V.K., Liquid-Liquid Extraction of Terbium (III) from Thiocyanate Solution by TPBD with some Synergistic Ligands (DOSO, TOPO, TPhPO), Indian Journal of Advances in Chemical Science, 1: 10-16 (2012).
16
[17] Huang J., Hu Y., Li G., Disposable Terbium (III) Salicylate Complex Imprinted Membrane Using Solid Phase Surface Fluorescence Method for Fast Separation and Detection of Salicylic Acid in Pharmaceuticals and Human Urine, Talanta, 107: 49-54 (2013).
17
[18] Amara-Rekkab A., Didi M.A,Villemin D.,Samarium(III) removal by Liquid–Liquid and Solid Phase Extraction. Kinetics and Thermodynamics Aspects, Eur. Chem. Bulletin.,4(4):190-195 (2015).
18
[19] Meena A.K., Kadirvelu K., Mishra G. K., Rajagopal C., Nagar P. N., Adsorptive Removal of Heavy Metals from Aqueous Solution by Treated Sawdust (Acacia arabica), J. Hazard. Mate.r, 150(3): 604–611 (2008).
19
[20] Belkhouche N.E., Didi M.A., Villemin D., Separation of Nickel and Copper by Solvent Extraction Using Di-2 Ethylhexylphosphoric Acid-Based Synergistic Mixture, Solvent Extr. Ion. Exc., 23: 677-693 (2005).
20
[21] Belyouci O.,Didi M.A., Sorption and Separation Study of Praseodymium and Cadmium by Magnetic bentonite. Factorial Design Optimization,Desalin. Water Treat., 68:199–210 (2017).
21
ORIGINAL_ARTICLE
Comparative of Physico-Chemical Properties of Wheat Germ Oil Extracted with Cold Press and Supercritical CO2 Extraction
In this study, moisture content, free fatty acids, peroxide, iodine value, unsaponifiable matter, saponification value, fatty acid composition and tocopherol contents of wheat germ oil obtained by SC-CO2 extraction and cold press technology were investigated. Moisture, free fatty acid (FFA), peroxide value, iodine value, unsaponifiable matter and saponification value of cold press and supercritical CO2 extraction method oils were established as 0.097% and 13.32, 0.84% and 5.9%, 8.9 meq O2/kg and 15.8, 132 and 128, 6.5 g/kg and 8.04 and 197 and 182mg KOH/g, respectively. Major fatty acids of samples were determined as palmitic, oleic, and linoleic acids. Campesterol and β-stosterols of wheat germ oils obtained by the cold press and supercritical CO2 extraction are the major sterols. The germ oil extracted by both methods contained 24.19% and 23.44 % campesterol and 60.98% and 61.56% β-stosterol, respectively. While germ oil obtained supercritical CO2 extraction contains 50.60% α-tocopherol and 49.39% β-tocopherol, the oil obtained by cold press contained 73.12% α-tocopherol and 26.83% β-tocopherol. Supercritical CO2 extraction is conducted for the process that must be decided whether the pilot or industrial scale. Supercritical CO2 extraction that high oil yield is very high investment costs.
https://ijcce.ac.ir/article_34240_fe49e2a6ad7541fac33d7c4c2edb4df3.pdf
2019-12-01
167
174
10.30492/ijcce.2019.34240
Wheat germ oil
cold press
Süper critical carbon dioxide extraction
tocopherol
fatty acids
Mehmet Musa
Özcan
mozcan@selcuk.edu.tr
1
Department of Food Engineering, Faculty of Agriculture, Selcuk University, 42031 Konya, TURKEY
LEAD_AUTHOR
Derya
Ören
akkuyu34@hotmail.com
2
Food Engineering, Zade Oil Company, Konya, TURKEY
AUTHOR
[1] de Vasconcelos M.C., Bennett R., Castro C., Cardoso P., Saavedra M.J., Rosa E.A., Study of Composition, Stabilization and Processing of Wheat Germ and Maize Industrial By-Products. Ind. Crops. Prod., 42: 292-298 (2013)
1
[2] Gomez A.M., de La Ossa E.M., Quality of Wheat Germ oil Extracted by Liquid and Supercritical carbon dioxide. J. Am. Oil Chem. Soc.,77(9): 969-974 (2000).
2
[3] Woerfel J.B., “Extraction” In: “Erickson D.R., editör, Practical Handbook of Soybean Processing and Utilization”, Champaign, IL: AOCS Press. p 65-92, (1995).
3
[4] Yu L., Zhou K., Parry J., Antioxidant Properties of Coldpressed Black Caraway, Carrot, Cranberry, and Hemp seed Oils, Food Chem., 91: 723–729 (2005).
4
[5] Crews C, Hough P, Godward J, Brereton P, Lees M, Guiet S., Quantitation of the Main Constituents of Some Authentic Grape-Seed Oils of Different Origin, J Agric Food Chem., 54: 6261–6265 (2006).
5
[6] Khosravi-Darani K., Vasheghani-Farahani E., Application of Supercritical Fluid Extraction in Biotechnology, Crit. Rev. Biotechnol.,25(4): 231-42 (2005).
6
[7] Khosravi-Darani K., Research Activities on Supercritical Fluid Science in Food Biotechnology, Crit. Rev. Food Sci. Nutr.,50(6): 479-488 (2010)
7
[8] Khosravi-Darani K., Vasheghani-Farahani E., Yamini, Y., Solubility of Polyhydroxy Butyrate in Supercritical Carbon Dioxide, J. Chem. Eng. Data, 48: 860-863 (2003).
8
[9] Khosravi-Darani K., Vasheghani-Farahani E., Shojaosadati S.A., Yamini Y., The Effect of Process Variables on Supercritical Fluid Disruption of Ralstonia Eutropha Cells for Poly (hydroxybutyrate) Recovery, Biotechnol. Prog., 6: 1757-1765 (2004)
9
[10] Hartono R., Mansoori G.A., Suwono A., Prediction of Solubility of Biomolecules in Supercritical Solvents, Chem. Eng. Sci., 56: 6949-6958 (2001).
10
[11] Nguyen, U., Evans, D.A., Frakman G., “Natural Antioxidants Produced by Supercritical Extraction. In: Supercritical Fluids Processing of Food and Biomaterials”, S.H. Rizvi, (Ed.), pp. (103-113), Chapman and Hall, ISBN 0751401846, Glasgow (1994).
11
[12] Crabas N., Marongiu B., Piras A., Pivetta T., Porcedda S., Extraction, Separation and Isolation of Volatiles and dyes from Calendula Officinalis L. and Aloysia Trphilla (L’Her) Britton by Süpercritical CO2, J. Essent. Res., 15: 272-277 (2003).
12
[13] Marongiu B., Piras A., Porcedda S., Comparative Analysis of the Oil and Süpercritical CO2 Extract of Elettaria cardamomum (L) Maton, J. Agric. Food Chem., 52: 6278-6282 (2004).
13
[14] Piras A., Rosa A., Falconieri D., Porcedda S., Dessì M.A., Marongiu B., Extraction of Oil from Wheat Germ by Supercritical CO2, Molecules, 14: 2573-2581 (2009).
14
[15] AOAC. “Official Methods of Analysis”, 15th edn. Association of Official Analytical Chemists, Washington, DC, (1990).
15
[16] Hişil Y., “Instrumental Analysis Techniques: (Eng. Fac. Publ. 55). Ege University, Bornova –İzmir, 1998. (in Turkish).
16
[17] Matthäus B., Özcan M.M., Quantitation of Fatty Acids, Sterols, and Tocopherols in Turpentine (Pistacia terebinthus Chia) Growing wild in Turkey, J Agric Food Chem., 54(20): 7667-7671 (2006).
17
[18] Balz M., Schulte E., Their H.P., Trennung Von Tocopherolen und Tocotrienolen Durch HPLC, Fat. Sci. Technol., 94: 209-213 (1992).
18
[19] Firestone D., “Physical and Chemical Characteristics of Oils, Fats and Waxes”, AOCS Pres: Champaign, IL, p. 152, (1999).
19
[20] Eisenmenger M., “Superciritical Fluid Extractioni Fractionation, and Characterizataion of Wheat Germ Oil”, M.S Thesis, Oklahoma State University, Stillwater, OK, (2005).
20
[21] Dunford N.T., Goto M., Temelli F., Modeling of oil Extraction with Supercritical Carbon Dioxide from Atlantic Mackerel (Scomber scombrus) at Different Moisture Contents, J. Supercritical Fluids, 13: 303–309 (1998).
21
[22] Irmak S., Dunford N.T., Policosanol Contents and Compositions of Wheat Varieties, J. Agric. Food Chem., 53: 5583-5586 (2005).
22
[23] Barnes P.J., Lipid Composition of Wheat Germ and Wheat Germ Oil, Fette Seifen Anstrichm, 84: 256-269 (1982).
23
[24] Dunford N.T., Zhang M.Q., Pressurized Solvent Extraction of Wheat Germ Oil, Food Res. Int., 36: 905-909 (2003).
24
[25] Wang T., Johnson L., Refining High-Free Fatty Acid Wheat Germ Oil, J. Am. Oil Chem. Soc., 78: 71-76 (2001).
25
[26] Gustone F.D., Harwood J.L., Padley F.B., “The Lipid Handbook”, 2nd ed. Chapman & Hall. Londonp, p. 130, (1994).
26
[27] Mistry B., Min D., Effects of Fatty Acids on Oxidative Stability of Soybean Oil, J. Food Sci., 52: 831- (1987).
27
[28] Jiang S.T., Niu L., Optimization and Evaluation of Wheat Germ Oil Extracted by Süpercritical CO2, Grasas Y Aceites, 62(2): 181-189 (2011).
28
[29] Brandolini A., Hidalgo A., Wheat Germ: Not Only a By-Product, Int. J. Food Sci. Nutr., 63 (S1): 71-74 (2012).
29
[30] Shao P., Sun P., Ying Y., Response Surface Optimization of Wheat Germ Oil Yield by Süpercritical Carbon Dioxide Extraction, Food Bioprod. Process, 86: 227-231 (2008).
30
[31] Özcan M.M., Rosa A., Dessı M.A., Marongiu B., Piras A., AL-Juhaimi F.Y., Quality of Wheat Germ Oil Obtained by Cold Pressing and Supercritical Carbon Dioxide Extraction, Czech J. Food Sci., 31: 236–240 (2013).
31
[3]2 Dunford N.T., Martinez J., “Nutritional Components of Supercritical Carbon Dioxide Extracted Wheat Germ Oil, Proceedings of 6th International Symposium on Supercritical Fluids”, April 28-30, Versailles, France. Vol. 1, Page: 273-278, (2004).
32
[33] Itoh T., Tamura T., Matsumoto T., Sterol Composition of 19 Vegetable Oils, J. Am. Oil Chem. Soc., 50(4): 122-125 (1973).
33
[34] Anderson R.J., Shriner R.L., Burr G.O., The Phytosterols of Wheat Germ Oil, J. Am. Oil Chem. Soc., 48: 2987-2996 (1926).
34
[35] Kiosseoglou B., Boskou D., On the Level of Esterified Sterols in Cotton Seed, Tomato Seed, Wheat Germ and Safflower, Oleagineux, 42: 169-170 (1987).
35
[36] Traber M.G., Packer L., Vitamin E, Beyond Antioxidant Function, Am. J. Clin. Nutr., 62: 15015-15095 (1995).
36
ORIGINAL_ARTICLE
Protonation of Propene on Silica-Grafted Hydroxylated Molybdenum and Tungsten Oxide Metathesis Catalysts: A DFT Study
Theoretical assessment of the protonation reaction in the activation of propene on hydroxylated Mo(VI) and W(VI) metathesis catalysts is presented in this paper using the density functional theory calculations and five support clusters varying from simple SiO4H3 clusters to a large Si4O13H9 cluster. The bond distances and thermochemical data were similar for most of the clusters. The formation of isopropoxide was more favorable than a propoxide counterpart bonded via the primary carbon atom, with the Gibbs free energies of –3.73 and –7.78 kcal/mol, respectively, for the W catalyst. Overall, the 1T cluster models with optimized H atoms or an all-relaxed alternative would be considered appropriate replacements for a larger 4T cluster model saturated with OH groups and optimized terminal hydrogen atoms. The largest deviations in the energetic data were observed between the protonated structures formed on the two larger clusters saturated with either OH or H groups.
https://ijcce.ac.ir/article_33219_f9118706b461fa158ca6e3c12719f538.pdf
2019-12-01
175
187
10.30492/ijcce.2019.33219
metathesis
propene
density functional theory
tungsten
molybdenum
protonation
activation
silica
Mohammad
Ghashghaee
ghashghaee.m@gmail.com
1
Department of Process Design and Construction, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, I.R. IRAN
AUTHOR
Mehdi
Ghambarian
m.ghambarian@ippi.ac.ir
2
Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112 Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Ghashghaee M., Shirvani S., Two-step Thermal Cracking of an Extra-Heavy Fuel Oil: Experimental Evaluation, Characterization, and Kinetics, Ind. Eng. Chem. Res., 57(22): 7421–7430 (2018).
1
[2] Ghashghaee M., Karimzadeh R., Multivariable Optimization of Thermal Cracking Severity, Chem. Eng. Res. Des., 89(7): 1067–1077 (2011).
2
[3] Ghashghaee M., Karimzadeh R., Applicability of Protolytic Mechanism to Steady-State Heterogeneous Dehydrogenation of Ethane Revisited, Micropor. Mesopor. Mat., 170: 318–330 (2013).
3
[4] Hajheidary M., Ghashghaee M., Karimzadeh R., Olefins Production from LPG via Dehydrogenative Cracking over Three ZSM-5 Catalysts, J. Sci. Ind. Res., 72(12): 760–766 (2013).
4
[5] Karimzadeh R., Ghashghaee M., Design of a Flexible Pilot Plant Reactor for the Steam Cracking Process, Chem. Eng. Technol., 31(2): 278–286 (2008).
5
[6] Shirvani S., Ghashghaee M., Combined Effect of Nanoporous Diluent and Steam on Catalytic Upgrading of Fuel Oil to Olefins and Fuels over USY Catalyst, Petrol. Sci. Technol., 36(11): 750–755 (2018).
6
[7] Ghashghaee M., Karimzadeh R., Dynamic Modeling and Simulation of Steam Cracking Furnaces, Chem. Eng. Technol., 30(7): 835–843 (2007).
7
[8] Sedighi M., Keyvanloo K., Towfighi Darian J., Olefin Production from Heavy Liquid Hydrocarbon Thermal Cracking: Kinetics and Product Distribution, Iran. J. Chem. Chem. Eng. (IJCCE), 29(4): 135–147 (2010).
8
[9] Ghashghaee M., Heterogeneous Catalysts for Gas-phase Conversion of Ethylene to Higher Olefins, Rev. Chem. Eng.: DOI: 10.1515/revce-2017-0003 (2017).
9
[10] Ghashghaee M., Farzaneh V., Nanostructured Hydrotalcite-Supported RuBaK Catalyst for Direct Conversion of Ethylene to Propylene, Russ. J. Appl. Chem., 91(6): 970−974 (2018).
10
[11] Lwin S., Wachs I.E., Olefin Metathesis by Supported Metal Oxide Catalysts, ACS Catal., 4(8): 2505–2520 (2014).
11
[12] Fierro J.L.G., “Metal Oxides: Chemistry and Applications”, CRC Press, Taylor & Francis Group, Boca Raton (2006).
12
[13] Amakawa K., Wrabetz S., Kröhnert J., Tzolova-Müller G., Schlögl R., Trunschke A., In Situ Generation of Active Sites in Olefin Metathesis, J. Am. Chem. Soc., 134(28): 11462–11473 (2012).
13
[14] Handzlik J., Kurleto K., Theoretical Investigations of Heterogeneous Olefin Metathesis Catalysts, Curr. Org. Chem., 17(22): 2796–2813 (2013).
14
[15] Handzlik J., Sautet P., Structure of Dimeric Molybdenum(VI) Oxide Species on γ-Alumina: A Periodic Density Functional Theory Study, J. Phys. Chem. C, 114(45): 19406–19414 (2010).
15
[16] Handzlik J., Computational Study of the Properties and Metathesis Activity of Mo Methylidene Species in HZSM-5 Zeolite, J. Mol. Catal. A-Chem., 316(1–2): 106–111 (2010).
16
[17] Handzlik J., Ogonowski J., Structure of Isolated Molybdenum(VI) and Molybdenum(IV) Oxide Species on Silica: Periodic and Cluster DFT Studies, J. Phys. Chem. C, 116(9): 5571–5584 (2012).
17
[18] Maihom T., Probst M., Liktrakul J., A DFT Study of Tungsten–Methylidene Formation on a W/ZSM-5 Zeolite: The Metathesis Active Site, Chem. Phys. Chem., 16(15): 3334–3339 (2015).
18
[19] Amakawa K., “Active Site for Propene Metathesis in Silica-Supported Molybdenum Oxide Catalysts”, Department of Inorganic Chemistry: Technischen Universität Berlin (2013).
19
[20] Amakawa K., Kröhnert J., Wrabetz S., Frank B., Hemmann F., Jäger C., Schlögl R., Trunschke A., Active Sites in Olefin Metathesis over Supported Molybdena Catalysts, Chem. Cat. Chem., 7(24): 4059–4065 (2015).
20
[21] Amakawa K., Sun L., Guo C., Hävecker M., Kube P., Wachs I.E., Lwin S., Frenkel A.I., Patlolla A., Hermann K., Schlögl R., Trunschke A., How Strain Affects the Reactivity of Surface Metal Oxide Catalysts, Angew. Chem. Int. Edit., 52(51): 13553–13557 (2013).
21
[22] Lavrenov A.V., Saifulina L.F., Buluchevskii E.A., Bogdanets E.N., Propylene Production Technology: Today and Tomorrow, Catal. Ind., 7(3): 175–187 (2015).
22
[23] Butler J.R., Metathesis Catalyst for Olefin Production, US Patent, (US 12/568,958), US20110077444 A1 (2011).
23
[24] Sindorf D.W., Maciel G.E., Silicon-29 NMR Study of Dehydrated/Rehydrated Silica Gel Using Cross Polarization and Magic-Angle Spinning, J. Am. Chem. Soc., 105(6): 1487–1493 (1983).
24
[25] Zhang B., Lu Y., He H., Wang J., Zhang C., Yu Y., Xue L., Experimental and Density Functional Theory Study of the Adsorption of N2O on Ion-Exchanged ZSM-5: Part II. The Adsorption of N2O on Main-Group Ion-Exchanged ZSM-5, J. Environ. Sci., 23(4): 681–686 (2011).
25
[26] Balar M., Azizi Z., Ghashghaee M., Theoretical Identification of Structural Heterogeneities of Divalent Nickel Active Sites in NiMCM-41 Nanoporous Catalysts, J. Nanostruct. Chem., 6(4): 365–372 (2016).
26
[27] Ghashghaee M., Ghambarian M., Azizi Z., Characterization of Extraframework Zn2+ Cationic Sites in Silicalite-2: a Computational Study, Struct. Chem., 27(2): 467–475 (2016).
27
[28] Ghambarian M., Azizi Z., Ghashghaee M., Diversity of Monomeric Dioxo Chromium Species in Cr/Silicalite-2 Catalysts: A Hybrid Density Functional Study, Comp. Mater. Sci., 118: 147–154 (2016).
28
[29] Ghambarian M., Azizi Z., Ghashghaee M., Cluster Modeling and Coordination Structures of Cu+ Ions in Al-Incorporated Cu-MEL Catalysts – A Density Functional Theory Study, J. Mex. Chem. Soc., 61(1): 1–13 (2017).
29
[30] Ghambarian M., Ghashghaee M., Azizi Z., Coordination and Siting of Cu+ Ion Adsorbed into Silicalite-2 Porous Structure: A Density Functional Theory Study, Phys. Chem. Res., 5(1): 135–152 (2017).
30
[31] Valiev M., Bylaska E.J., Govind N., Kowalski K., Straatsma T.P., Van Dam H.J.J., Wang D., Nieplocha J., Apra E., Windus T.L., de Jong W.A., NWChem: A Comprehensive and Scalable Open-Source Solution for Large Scale Molecular Simulations, Comput. Phys. Commun., 181(9): 1477–1489 (2010).
31
[32] Lu T., Chen F., Multiwfn: A Multifunctional Wavefunction Analyzer, J. Comput. Chem., 33(5): 580–592 (2012).
32
[33] Bruno I.J., Cole J.C., Edgington P.R., Kessler M., Macrae C.F., McCabe P., Pearson J., Taylor R.,
33
New Software for Searching the Cambridge Structural Database and Visualizing Crystal Structures, Acta Crystallogr. B, 58(3 Part 1): 389–397 (2002).
34
[34] Zhao Y., Truhlar D.G., The M06 Suite of Density Functionals for Main Group Thermochemistry, Thermochemical Kinetics, Noncovalent Interactions, Excited States, and Transition Elements: Two New Functionals and Systematic Testing of Four M06-Class Functionals and 12 Other Functionals, Theor. Chem. Acc., 120(1-3): 215–241 (2008).
35
[35] Feller D., The Role of Databases in Support of Computational Chemistry Calculations, J. Comput. Chem., 17(13): 1571–1586 (1996).
36
[36] Yumura T., Yamashita H., Torigoe H., Kobayashi H., Kuroda Y., Site-Specific Xe Additions Into Cu-ZSM-5 Zeolite, Phys. Chem. Chem. Phys., 12(10): 2392–2400 (2010).
37
[37] Göltl F., Hafner J., Structure and Properties of Metal-Exchanged Zeolites Studied Using Gradient-Corrected and Hybrid Functionals. I. Structure and Energetics, J. Chem. Phys., 136(6): 064501-064501–064501-064517 (2012).
38
[38] Ghashghaee M., Ghambarian M., Methane Adsorption and Hydrogen atom Abstraction at Diatomic Radical Cation Metal oxo Clusters: First-Principles Calculations, Mol. Simul., 44(10): 850–863 (2018).
39
[39] Fukui K., Yonezawa T., Shingu H., A Molecular Orbital Theory of Reactivity in Aromatic Hydrocarbons, J. Chem. Phys., 20(4): 722–725 (1952).
40
[40] Glendening E., Badenhoop J., Reed A., Carpenter J., Weinhold F., “NBO 3.1”, Theoretical Chemistry Institute, University of Wisconsin, Madison, WI: (1996).
41
[41] Datta D., On Pearson’s HSAB Principle, Inorg. Chem., 31(13): 2797–2800 (1992).
42
ORIGINAL_ARTICLE
Influence of Operational Parameters and Kinetic Modelling of Catalytic Wet Air Oxidation of Phenol by Al/Zr Pillared Clay Catalyst
Single and mixed oxide Al/Zr-pillared clay (Al/Zr-PILC) catalysts were synthesized and tested for catalytic wet air oxidation (CWAO) of aqueous phenol solution under milder conditions, in a semi-batch reactor. The catalysts were synthesized from natural bentonite clay using ultrasonic treatment during the aging and intercalation steps and were characterized using High Resolution Scanning Electron Microscopy-Energy Dispersive angle X-ray spectrometry (HRSEM-EDX), powder X-ray diffraction (p-XRD), nitrogen adsorption/desorption, Fourier Transforms InfraRed Spectroscopy (FTIR) and zeta potential. Successful pillaring of aluminum and zirconium oxides into the clay was confirmed by p-XRD with increased basal spacing (1.92 nm) and higher specific surface area (230 m2/g). The influence of stirrer speed (200-1000 rpm), catalyst dosage (1-3 g/L), initial pH (1-3), initial phenol concentration (500-1500 mg/L), the effect of temperature (80-150 °C) and oxygen pressure (5-15 bar) was evaluated on phenol conversion and their reaction kinetics. At the optimum conditions of initial pH of 3, catalyst dosage of 2 g/L, initial phenol concentration of 1000 mg/L, reaction temperature of 100 °C, and oxygen pressure of 10 bar, the complete removal of phenol was achieved by Al/Zr-PILC within 120 min. The CWAO process was well-described by the first-order power rate law kinetics model. The apparent activation energy of the reaction calculated by Arrhenius equation was 21.306 kJ/mol.
https://ijcce.ac.ir/article_33442_83a9905c03afaf437311785751eca2f7.pdf
2019-12-01
189
203
10.30492/ijcce.2019.33442
kinetic modeling
Al/Zr pillared clay
phenol removal
catalytic wet air oxidation
John
Moma
john.moma@wits.ac.za
1
Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, P/Bag 3, WITS 2050, Johannesburg, SOUTH AFRICA
LEAD_AUTHOR
Maloyi
Jeffey
jeffreyb@mintek.co.za
2
Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, P/Bag 3, WITS 2050, Johannesburg, SOUTH AFRICA
AUTHOR
Thabang
Ntho
thabangnt@mintek.co.za
3
Advanced Materials Division, MINTEK, Private Bag X3015, Randburg 2125, SOUTH AFRICA
AUTHOR
[1] Baloyi J., Ntho T., Moma J., Synthesis and Application of Pillared Clay Heterogeneous Catalysts for Wastewater Treatment: A Review, RSC Advances, 8: 5197-5211 (2018).
1
[2] Abid M.F., Alwan G.M., Abdul-Ridha L.A., Study on Catalytic Wet Air Oxidation Process for Phenol Degradation in Synthetic Wastewater Using Trickle Bed Reactor, Arabian Journal for Science and Engineering, 41: 2659-2670 (2016).
2
[3] Eftaxias A., Font J., Fortuny A., Fabregat A., Stüber F., Kinetics of Phenol Oxidation in a Trickle Bed Reactor over Active Carbon Catalyst, Journal of Chemical Technology and Biotechnology, 80: 677-687 (2005).
3
[4] Guo J., Catalytic Wet Oxidation over Pillared Clay Catalyst in Packed-Bed Reactors: Experiments and Modeling, (2005).
4
[5] Arena F., Italiano C., Spadaro L., Efficiency and Reactivity Pattern of Ceria-Based Noble Metal and Transition Metal-Oxide Catalysts in the Wet Air Oxidation of Phenol, Applied Catalysis B: Environmental, 115: 336-345(2012).
5
[6] Tomul F., Effect of Ultrasound on the Structural and Textural Properties of Copper-Impregnated Cerium-Modified Zirconium-Pillared Bentonite, Applied Surface Science, 258: 1836-1848(2011).
6
[7] Sassi H., Lafaye G., Amor H.B., Gannouni A., Jeday M.R., Barbier J., Wastewater Treatment by Catalytic Wet Air Oxidation Process over Al-Fe Pillared Clays Synthesized Using Microwave Irradiation, Frontiers of Environmental Science & Engineering, 12: 2- (2018).
7
[8] Mnasri-Ghnimi S., Frini-Srasra N., Promoting Effect of Cerium on the Characteristic and Catalytic Activity of Al, Zr, and Al–Zr Pillared Clay, Applied Clay Science, 88: 214-220 (2014).
8
[9] Ma C., Wen Y., Yue Q., Li A., Fu J., Zhang N., Gai H., Zheng J., Chen B.H., Oxygen-Vacancy-Promoted Catalytic Wet Air Oxidation of Phenol from MnOx–CeO2, RSC Advances, 7: 27079-27088 (2017).
9
[10] Fortuny A., Bengoa C., Font J., Fabregat A., Bimetallic Catalysts for Continuous Catalytic Wet Air Oxidation of Phenol, Journal of Hazardous Materials, 64: 181-193 (1999).
10
[11] Eftaxias A., "Catalytic Wet Air Oxidation of Phenol in a Trickle Bed Reactor: Kinteics and Reactor Modelling", Universitat Rovira i Virgili, (2002).
11
[12] Pintar A., Levec J., Catalytic Oxidation of Organics in Aqueous Solutions: I. Kinetics of Phenol Oxidation, Journal of Catalysis, 135: 345-357 (1992).
12
[13] Fortuny A., Bengoa C., Font J., Castells F., Fabregat A., Water pollution Abatement by Catalytic Wet Air Oxidation in a Trickle Bed Reactor, Catalysis Today, 53: 107-114(1999).
13
[14] Safaa M., Catalytic Wet Air Oxidation of Phenolic Compounds in Wastewater in a Trickle Bed Reactor at High Pressure, (2009).
14
[15] Quintanilla A., Casas J.A., Rodriguez J.J., Kreutzer M.T., Kapteijn F., Moulijn J.A., Kinetics of the Wet Oxidation of Phenol over an Fe/Activated Carbon Catalyst, International Journal of Chemical Reactor Engineering, 5 (2007).
15
[16] Quintanilla A., Casas J.A., Rodriguez J.J., Catalytic Wet Air Oxidation of Phenol with Modified Activated Carbons and Fe/Activated Carbon Catalysts, Applied Catalysis B: Environmental, 76: 135-145 (2007).
16
[17] Tomul F., Balci S., Characterization of Al, Cr-Pillared Clays and CO Oxidation, Applied Clay Science, 43: 13-20 (2009).
17
[18] Grim R.E., "Clay Mineralogy". 2nd ed. McGraw-Hill Book Company, New York, (1968) 185-224.
18
[19] Schwieger W., Lagaly G., Auerbach S.M., Carrado K.A., Dutta P.K., Handbook of layered Materials, in, Marcel Dekker, Inc., New York,(2004).
19
[20] Canizares P., Valverde J.L., Kou M.R.S., Molina C.B., Synthesis and Characterization of PILCs with Single and Mixed Oxide Pillars Prepared from Two Different Bentonites, A Comparative Study, Microporous and Mesoporous Materials, 29: 267-281 (1999).
20
[21] Awate S.V., Waghmode S.B., Agashe M.S., Synthesis, Characterization and Catalytic Evaluation of Zirconia-Pillared Montmorillonite for Linear Alkylation of Benzene, Catalysis Communications, 5: 407-411(2004).
21
[22] Jung H., Paek S.-M., Yoon J.-B., Choy J.-H., Zr K-Edge XAS Study on ZrO2-Pillared Aluminosilicate, Journal of Porous Materials, 14: 369-377(2007).
22
[23] Mnasri S., Hamdi N., Frini-Srasra N., Srasra E., Acid–Base Properties of Pillared Interlayered Clays with Single and Mixed Zr–Al Oxide Pillars Prepared from Tunisian-Interstratified Illite–Smectite, Arabian Journal of Chemistry, (2014).
23
[24] Zhang H., Liang X., Yang C., Niu C., Wang J., Su X., Nano γ-Fe2O3/Bentonite Magnetic Composites: Synthesis, Characterization and Application as Adsorbents, Journal of Alloys and Compounds, 688: 1019-1027(2016).
24
[25] Rathnayake S.I., Martens W.N., Xi Y., Frost R.L., Ayoko G.A., Remediation of Cr (VI) by Inorganic-Organic Clay, Journal of Colloid and Interface Science, 490: 163-173(2017).
25
[26] Madejová J., FTIR Techniques in Clay Mineral Studies, Vibrational Spectroscopy, 31: 1-10(2003).
26
[27] Kumararaja P., Manjaiah K.M., Datta S.C., Sarkar B., Remediation of Metal Contaminated Soil by Aluminium Pillared Bentonite: Synthesis, Characterisation, Equilibrium Study and Plant Growth Experiment, Applied Clay Science, 137: 115-122 (2017).
27
[28] Basoglu F.T., Balci S., Catalytic Properties and Activity of Copper and Silver Containing Al-Pillared Bentonite for CO Oxidation, Journal of Molecular Structure, 1106: 382-389(2016).
28
[29] Wu L.M., Tong D.S., Zhao L.Z., Yu W.H.,
29
Zhou C.H., Wang H., Fourier Transform Infrared Spectroscopy Analysis for Hydrothermal Transformation of Microcrystalline Cellulose on Montmorillonite, Applied Clay Science, 95: 74-82(2014).
30
[30] Acemana S., Lahav N., Yariv S., A Thermo-FTIR-Spectroscopy Analysis of Al-Pillared Smectites Differing in Source of Charge, in KBr Disks, Thermochimica Acta, 340: 349-366(1999).
31
[31] Ye W., Zhao B., Gao H., Huang J., Zhang X., Preparation of Highly Efficient and Stable Fe, Zn, Al-Pillared Montmorillonite as Heterogeneous Catalyst for Catalytic Wet Peroxide Oxidation of Orange II, Journal of Porous Materials, 23: 301-310 (2016).
32
[32] Lefrancois M., Malbois G., The Nature of the Acidic Sites on Mordenite, Journal of Catalysis, 20: 350-358 (1971).
33
[33] Kojima M., Rautenbach M.W., O'Connor C.T., Acidity Characterization of Ion-Exchanged Mordenite, Journal of Catalysis, 112: 495-504 (1988).
34
[34] Loveless B.T., Gyanani A., Muggli D.S., Discrepancy between TPD-and FTIR-Based Measurements of Brønsted and Lewis Acidity for Sulfated Zirconia, Applied Catalysis B: Environmental, 84: 591-597 (2008).
35
[35] Fatimah I., Preparation of ZrO2/Al2O3-Montmorillonite Composite as Catalyst for Phenol Hydroxylation, Journal of Advanced Research, 5: 663-670 (2014).
36
[36] Fetter G., Heredia G., Velázquez L.A., Maubert A.M., Bosch P., Synthesis of Sluminum-Pillared Montmorillonites Using Highly Concentrated clay Suspensions, Applied Catalysis A: General, 162:
37
41-45 (1997).
38
[37] Fetter G., Heredia G., Maubert A.M., Bosch P., Synthesis of Al-Intercalated Montmorillonites Using Microwave Irradiation, Journal of Materials Chemistry, 6: 1857-1858 (1996).
39
[38] Katdare S.P., Ramaswamy V., Ramaswamy A.V., Factors Affecting the Preparation of Alumina Pillared Montmorillonite Employing Ultrasonics, Microporous and Mesoporous Materials, 37: 329-336 (2000).
40
[39] Santos A., Yustos P., Quintanilla A., Rodrıguez S., Garcıa-Ochoa F., Route of the Catalytic Oxidation of Phenol in Aqueous Phase, Applied Catalysis B: Environmental, 39: 97-113(2002).
41
[40] Yang G., Chen H., Qin H., Zhang X., Feng Y., Effect of Nitrogen Doping on the Catalytic Activity of Activated Carbon and Distribution of Oxidation Products in Catalytic Wet Oxidation of Phenol,
42
The Canadian Journal of Chemical Engineering, 95: 1518-1525 (2017).
43
[41] Yang S., Li X., Zhu W., Wang J., Descorme C., Catalytic Activity, Stability and Structure of Multi-Walled Carbon Nanotubes in the Wet Air Oxidation of Phenol, Carbon, 46: 445-452 (2008).
44
[42] Guo J., Al-Dahhan M., Catalytic Wet Oxidation of Phenol by Hydrogen Peroxide over Pillared Clay Catalyst, Industrial & Engineering Chemistry Research, 42: 2450-2460 (2003).
45
[43] Yadav A.,. Teja A.K, Verma N., Removal of Phenol from Water by Catalytic wet Air Oxidation Using Carbon Bead–Supported Iron Nanoparticle–Containing Carbon Nanofibers in an Especially Configured Reactor, Journal of Environmental Chemical Engineering, 4: 1504-1513 (2016).
46
[44] Wu Q., Hu X., Yue P.-l., Kinetics Study on Catalytic Wet Air Oxidation of Phenol, Chemical Engineering Science, 58: 923-928(2003).
47
[45] Lin S.S., Chang D.J., Wang C.-H., Chen C.C., Catalytic Wet Air Oxidation of Phenol by CeO2 Catalyst—Effect of Reaction Conditions, Water Research, 37: 793-800(2003).
48
[46] Arena F., Italiano C., Raneri A., Saja C., Mechanistic and Kinetic Insights into the Wet Air Oxidation of Phenol with Oxygen (CWAO) by Homogeneous and Heterogeneous Transition-Metal Catalysts, Applied Catalysis B: Environmental, 99: 321-328 (2010).
49
[47] Chang L., Chen I.P., Lin S.-S., An Assessment of the Suitable Operating Conditions for the CeO2/γ-Al2O3 Catalyzed Wet Air Oxidation of Phenol, Chemosphere, 58: 485-492(2005).
50
[48] Pintar A., Levec J., Catalytic Liquid-Phase Oxidation of Refractory Organics in Waste Water, Chemical Engineering Science, 47: 2395-2400 (1992).
51
[49] Santos A., Yustos P., Quintanilla A., Garcia-Ochoa F., Kinetic model of Wet Oxidation of Phenol at Basic pH Using a Copper Catalyst, Chemical Engineering Science, 60: 4866-4878 (2005).
52
[50] Akyurtlu J.F., Akyurtlu A., Kovenklioglu S., Catalytic Oxidation of Phenol in Aqueous Solutions, Catalysis Today, 40: 343-352(1998).
53
[51] Stüber F., Polaert I., Delmas H., Font J., Fortuny A., Fabregat A., Catalytic Wet Air Oxidation of Phenol Using Active Carbon: Performance of Discontinuous and Continuous Reactors, Journal of Chemical Technology and Biotechnology, 76: 743-751(2001).
54
ORIGINAL_ARTICLE
Microwave-Assisted Synthesis of Novel Functionalized Ketenimines and Azadienes via a Solvent-Free Reaction of Isatoic Anhydride, Alkyl-Isocyanides and Dialkyl Acetylenedicarboxylates
Ketenimines and azadienes are transient intermediates in organic chemistry especially in elimination-addition processes and in the formation of heterocyclic systems. These compounds play a considerable role as intermediates in the synthesis of heterocyclic ring systems. In this present research synthesis of novel ketenimines and azadienes via multicomponent reactions (MCRs) based on alkyl-Isocyanides is reported. Following our ongoing interest in isocyanide-based MCRs, we reported stereoselective reactions between 4H-3,1-benzoxazine-2,4(1H)-dione (isatoic anhydride) with dialkylacetylenedicarboxylates in the presence of alkyl isocyanides under solvent-free microwave conditions which leads to novel functionalized ketenimines and azadienes in a green route. The results show that the microwave-assisted leaching process has advantages over the conventional ones, concerning energy-consumption, processing time, and environmental protection.
https://ijcce.ac.ir/article_32873_c9a9f43793b9e92b547de102f317a9db.pdf
2019-12-01
205
211
10.30492/ijcce.2019.32873
Microwave-Assisted
Alkyl-Isocyanides
Ketenimine
Azadiene
Isatoic anhydride
Samira
Arab-Salmanabadi
s.arab@qodsiau.ac.ir
1
Department of Chemistry, Shahr-e-Qods Branch, Islamic Azad University,Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Tierney J.P., Lidström p., "Microwave Assisted Organic Synthesis", John Wiely & Sons, Inc., U.S.A (2009).
1
[2] Van der Eycken E., Kappe C.O., "Microwave Assisted Synthesis of Heterocycles", Springer, U.S.A (2006).
2
[3] Papadaki E., Delaude L., Magrioti V., Microwave-Assisted Synthesis of Hydroxymethyl Ketones Using Azolium-2-Carboxylate Zwitterions as Catalyst Precursors, Tetrahedron, 73(52): 7295-7300 (2017).
3
[4] Liu Y., Xiao N., Gong N., Wang H., Shi X., Gu W., Ye l., One-Step Microwave-Assisted Polyol Synthesis of Green Lminescent Carbon Dots as Optical Nanoprobes, Carbon, 6: 258-264 (2014).
4
[5] Poursattar Marjani A., Khalafy J., Chitan M., Mahmoodi S., Microwave-Assisted Synthesis of Acridine-1,8(2H,5H)-diones via a One-pot, Three Component Reaction, Iran. J. Chem. Chem. Eng. (IJCCE), 36(2): 1-6 (2017).
5
[6] Kadi H., Moussaoui R., Sadia D., Microwave Assisted Extraction of Olive Oil Pomace by Acidic Hexane, Iran. J. Chem. Chem. Eng. (IJCCE), 35(4): 7295-7300 (2016).
6
[7] Domling A. and Ugi, I., Multicomponent Reactions with Isocyanides Angew Chem. Int. Ed. Eng., 39(18): 3918-3169 (2000).
7
[8] Arab-Salmanabadi S., Dorvar M., Notash B., Synthesis of Novel Functionalized Dihydroimidazo[2,1-a]Isoquinolines and Dihydroimidazo[2,1-a] Quinolines: Single Crystal X-Ray Studies of (Z)-Methyl 2-(1-(benzo[d]thiazol-2-yl)-2-oxo-1,2-dihydroimidazo[2,1-a]isoquinolin-3(10bH)-ylidene)Acetate, Tetrahedron, 71(8): 1292-1296 (2015).
8
[9] Arab-Salmanabadi S., Synthesis and Spectral Characterization of Novel Bis‐thiazole Derivatives via Ring Closure of Benzo[d]thiazol‐2‐amine, Various α‐Haloketones, and S‐Nucleophiles, J. Heterocyclic Chem., 54(6): 3600-3606 (2017).
9
[10] Reichen W.,Oxygen, Nitrogen and Sulfur-Substituted Heteroallenes, Chem. Rev., 78(5): 569-588 (1978).
10
[11] Motoyoshiya J., Teranishi A., Mikoshiba R., Yamamoto I., Gotoh H., c-Phosphonoketenimines, Characterization and Synthetic Application to Heterocycles, J. Org. Chem., 45(26): 5385–5387 (1980).
11
[12] Yavari I., Arab-Salmanabadi S., Aminkhani A., Synthesis of Functionalized Azadienes from Aminobenzothiazole, Acetylenic Esters and Isocyanides, Chinese Chem. Lett., 23(1): 49–52 (2012).
12
[13] Cristau H.J., Jouanin I., Taillefer M., New Synthesis of Diphenyl-N-(substituted)ketenimines from Diaminophosphonium Diazaylides, J. Organomet. Chem., 584(1): 68–72 (1999).
13
[14] Krow, G., Synthesis and Reactions of Ketenimines, Angew Chem. Int. Ed. Eng., 10(7): 435-449 (1971).
14
[15] Yavari, I., Djahaniani, H., Nassiri F., Synthesis of Highly Functionalized 1-Azadienes and Ketenimines, Monatshefte für Chemie / Chemical Monthly, 135(5): 543-548 (2004).
15
[16] Alajarin, M., Vidal A., Ortin M.M., First Radical Addition onto Ketenimines: a Novel Synthesis of Indoles, Tetrahedron Lett., 44(15): 3027-3030 (2003).
16
[17] Arrieta A., Cossio F.P., Lecea B., 2-Chloro-1,3-Dimethylimidazolinium Chloride. 2. Its Application to the Construction of Heterocycles through Dehydration Reactions, J. Org. Chem. 64(19): 6989–6992 (1999).
17
[18] Aumann, R., Jasper, B., Lage, M., Kerbs B., Organic Syntheses via Transition Metal Complexes. 72. (2-(Acyloxy)ethenyl)carbene Complexes by Michael Addition of Carboxylic Acids to Alkynylcarbene Complexes (M = Cr, W). (2-(Acyloxy)ethenyl)ketene Imines by Ligand Disengagement with Isocyanid, Organometallics, 13(9): 3502–3509 (1994).
18
[19] Getzmann R., Moller M.H., Rodewald U., Frohlich R., Grehl M., Wurthwein, E.U, Metallated Ketenimines: Deprotonation of N-Isopropyl-Diphenylketenimine and Subsequent Trapping Reactions with Electrophiles A Theoretical and Experimental Study, Tetrahedron, 51(13): 3767-3786 (1995).
19
[20] Yavari I., Arab-Salmanabadi S., Aminkhani A., Synthesis of Functionalized 5H-spiro[furan-2,2′-indene]-1′,3′,5-triones from Primary Amines, Acetylenic Esters and Ninhydrin, J. Iranian Chem. Soc., 9(3): 503-506 (2012).
20
[21] Nair V.J., Rajesh C., Vinod A.U., Bindu S., Sreekanth A.R., Mathess J.S., Balagopal L., Strategies for Heterocyclic Construction via Novel Multicomponent Reactions Based on Isocyanides and Nucleophilic Carbenes, Acc. Chem. Res., 36(12): 899-907 (2003).
21
ORIGINAL_ARTICLE
Synthesis, X-Rays Analysis, Docking Study and Cholinesterase Inhibition Activity of 2,3-dihydroquinazolin-4(1H)-one Derivatives
In search of potent cholinesterase inhibitors, we have carried out the synthesis and biologically evaluation of various benzaldehyde based 2,3-dihydroquinazolin-4(1H)-one derivatives. In vitro assay results revealed that all the synthesized compounds showed activity against both enzymes (AChE and BChE) and in few cases, the inhibition activity was even higher than or comparable to the standard drug galantamine. Overall, compounds having chloro or methoxy group attached to the para position of benzaldehyde resulted in potent cholinesterase inhibitors. Within the series, Bromo derivatives 4a-i were more active than their un-substituted counterparts. Amongst all, compound 4c (6,8-dibromo-2-(3-bromo-4-chloro-phenyl)-2,3-dihydro-1H-quinazolin-4-one) with selectivity index of 3.7 for AChE, displayed IC50 values of 3.7±1.05 µM (AChE) and 13.7±0.64 µM (BChE) and can be considered as potential lead compound with a feature of dual cholinesterase (AChE/BChE) inhibition. Insight into the mechanism of inhibition of the synthesized compounds was provided by computed binding modes in the active site of AChE and BChE. Docking study on both isomers of the quinazoline also supported in vitro assay results. Preliminary in silico studies by using online admetSAR server showed that all compounds possessed good pharmacokinetic profile except nitro and methoxy substituted derivatives which were predicted to exhibit AMES toxicity. The synthesized compounds can be used as a structural foundation for the preparation of new potent cholinesterase inhibitors.
https://ijcce.ac.ir/article_32440_9b61b620dd3349e32b740dba925073ce.pdf
2019-12-01
213
227
10.30492/ijcce.2019.32440
Cholinesterases
2,3-dihydroquinazolin-4(1H)-one
Dual inhibitors
Alzheimer’s Disease
Muhammad
Sarfraz
sarfrazzed@gmail.com
1
Department of Chemistry, University of Sargodha, Sargodha, PAKISTAN
LEAD_AUTHOR
Umer
Rashid
umer_rashid39@hotmail.com
2
Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad, PAKISTAN
AUTHOR
Nargis
Sultana
nargissultana1@yahoo.co.uk
3
Department of Chemistry, University of Sargodha, Sargodha, PAKISTAN
AUTHOR
Muhammad Ilyas
Tariq
tariqmi@uos.edu.pk
4
Department of Chemistry, University of Sargodha, Sargodha, PAKISTAN
LEAD_AUTHOR
[1] Nagaraj A., Reddy C.S., Synthesis and Biological Study of Novel Bis-Chalcones, Bis-thiazines and Bis-Pyrimidines, J. Iran. Chem. Soc., 5(2): 262-7 (2008).
1
[2] Henary M., Paranjpe S., Owens E.A., Substituted Benzothiazoles: Synthesis and Medicinal Characteristics, Heterocycl. Commun., 19(2): 89-99 (2013).
2
[3] Ju Y., Varma R. S., Aqueous N-heterocyclization of Primary Amines and Hydrazines with Dihalides: Microwave-Assisted Syntheses of N-Azacycloalkanes, Isoindole, Pyrazole, Pyrazolidine, and Phthalazine Derivatives, J. Org. Chem., 71(1): 135-141 (2006).
3
[4] Bur S.K., Padwa A., The Pummerer Reaction: Methodology and Strategy for the Synthesis of Heterocyclic Compounds, Chem. Rev., 104(5): 2401-32 (2004).
4
[5] Evans B.E., Rittle K.E., Bock M.G., DiPardo R.M., Freidinger R.M., Whitter W.L., Lundell G.F.,
5
Veber D.F., Anderson P.S., Chang R.S., Lotti V.J., Methods for Drug Discovery: Development of Potent, Selective, Orally Effective Cholecystokinin Antagonists, J. Med. Chem., 31(12): 2235-46 (1988).
6
[6] DeSimone R.W., Currie K.S., Mitchell S.A., Darrow J.W., Pippin D.A., Privileged Structures: Applications in Drug Discovery, Comb. Chem. High Throughput Screening, 7(5): 473-93 (2004).
7
[7] Delgabo J., Remers W.A., "Wilson and Gisvold's Textbook of Organic Medicinal and Pharmaceutical Chemistry", (Eds.) Lippincott-Raven Publ. New York (2004).
8
[8] Azizian J., Kefayati H., Mehrdad M., Jadidi K., Sarrafi Y., A Facile One-Pot Method for Synthesis of 2,4-Dichloroquinoline Derivatives, Iran. J. Chem. Chem. Eng.(IJCCE), 20(1): 20-21 (2001).
9
[9] Shaabani A., Farhangi E., Shaabani S., A Rapid Combinatorial Library Synthesis of Benzazolo[2,1-b]quinazolinones and Triazolo[2,1-b]quinazolinones, Iran. J. Chem. Chem. Eng. (IJCCE), 32(1), 3-10 (2013).
10
[10] Shaabani A., Bazgir A., Arab Ameri S., Sharifi Kiasaraie M., Samadi S., Comparison of Catalytic Effect of Alkali and Alkaline Earth Metals Hydrogen Sulfate: As the Promoter for an Efficient Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones under Solvent-Free Conditions, Iran. J. Chem. Chem. Eng. (IJCCE), 24(3): 67-71 (2005).
11
[11] Sarfraz M., Ahmad S., Tariq M.I., Qaiser M.N., Synthesis, in Silico Study and Antiurease Potential of Imine Derivatives, Iran. J. Sci. Technol. Trans. Sci., (2018) https://doi.org/10.1007/s4099.
12
[12] Joule J.A., Mills K., "Heterocyclic Chemistry at a Glance", John Wiley & Sons (2012).
13
[13] Flemmig M., Melzig M.F., Serine‐Proteases as Plasminogen Activators in Terms of Fibrinolysis, J. Pharm. Pharmacol., 64(8): 1025-39 (2012).
14
[14] Whitcomb D.C., Lowe M.E., Human Pancreatic Digestive Enzymes, Dig. Dis. Sci., 52(1): 1-7 (2007).
15
[15] Leung K.C., Li V., Ng Y.Z., Chan T.T., Chang R.S., Wong R.Y., Systematic Review of Cholinesterase Inhibitors on Cognition and Behavioral Symptoms in Patients of Chinese Descent with Alzheimer’s Disease, Vascular Dementia, or Mixed Dementia, Geriatrics, 2(3): 2-9 (2017)
16
[16] McGleenon B.M., Dynan K.B., Passmore A.P., Acetylcholinesterase Inhibitors in Alzheimer’s Disease, Br. J. Clin. Pharmacol., 48: 471-480 (1999).
17
[17] Lane R.M., Potkin S.G., Enz A., Targeting Acetylcholinesterase and Butyrylcholinesterase in Dementia, Int. J. Neuropsychopharmacol., 9: 101-124 (2006).
18
[18] Anand P., Singh B., A Review on Cholinesterase Inhibitors for Alzheimer’s Disease, Arch. Phar. Res., 36: 375-399 (2013).
19
[19] Mashkovskii M.D., Glushkov R.G., Drugs for the Treatment of Alzheimer's disease, Pharm. Chem. J., 35: 179-182 (2001).
20
[20] Jamil N., Sultana N., Ashraf R., Sarfraz M., Tariq M.I., Mustaqeem M., Tris-diamine-derived Transition Metal Complexes of Flurbiprofen as Cholinesterase Inhibitors, Trop. J. Pharm. Res., 17 (3): 451-459 (2018).
21
[21] Sangi D.P., Monteiro J.L., Vanzolini K.L., Cass Q.B., Paixão M.W., Corrêa A.G., Microwave-Assisted Synthesis of N-Heterocycles and Their Evaluation Using an Acetylcholinesterase Immobilized Capillary Reactor, J. Braz. Chem. Soc., 25: 887-889 (2014).
22
[22] Ahmad S., Iftikhar F., Ullah F., Sadiq A., Rashid U., Rational Design and Synthesis of Dihydropyrimidine Based Dual Binding site Acetylcholinesterase Inhibitors, Bioorg. Chem., 69: 91-101 (2016).
23
[23] Gawad N.M., Georgey H.H., Youssef R.M., El Sayed N.A., Design, Synthesis, and Anticonvulsant Activity of Novel Quinazolinone Analogues, Med. Chem. Res., 20: 1280-1286 (2011).
24
[24] El-Hashash M.A., Elshahawi M.M., Ragab E.A., Nagdy S., Synthesis and Antifungal Activity of Novel Quinazolin-4 (3 H)-one Derivatives, Synth. Commun., 45(19): 2240-50 (2015).
25
[25] Cohen E., Klarberg B., Vaughan Jr J.R., Quinazolinone Sulfonamides. A New Class of Diuretic Agents1, J. Am. Chem. Soc., 82: 2731-2735(1960).
26
[26] Li Z., Wang B., Hou J.Q., Huang S.L., Ou T.M., Tan J.H., An L.K., Li D., Gu L.Q., Huang Z.S., 2-(2-Indolyl-)-4 (3 H)-quinazolines Derivates as New Inhibitors of AChE: Design, Synthesis, Biological Evaluation and Molecular Modeling, J. Enzym. Inhib. Med. Chem., 28: 583-592 (2013).
27
[27] Uraz M., Karakuş S., Mohsen U.A., Kaplancıklı Z.A., Rollas S., The Synthesis and Evaluation of Anti-Acetylcholinesterase Activity of Some 4 (3H)-[27] Quinazolinone Derivatives Bearing Substituted 1,3,4-thiadiazole, Marmara Pharm. J., 21: 96-101 (2017).
28
[28] Sarfraz M., Sultana N., Rashid U., Akram M.S., Sadiq A., Tariq M.I. Synthesis, Biological Evaluation and Docking Studies of 2, 3-Dihydroquinazolin-4 (1H)-one Derivatives as Inhibitors of Cholinesterases, Bioorg. Chem., 70: 237-244 (2017).
29
[29] Sultana N., Sarfraz M., Tanoli S.T., Akram M.S., Sadiq A., Rashid U., Tariq M.I., Synthesis, Crystal Structure Determination, Biological Screening and Docking studies of N1-Substituted Derivatives of 2, 3-dihydroquinazolin-4 (1H)-one as Inhibitors of Cholinesterases, Bioorg. Chem., 72: 256-267 (2017).
30
[30] Sarfraz M., Sultana N., Jamil M., Tariq M.I. Synthesis, in silico study and Cholinesterases Inhibition activity of 2-substituted 2,3-Dihydroquinazolin-4(1H)-one Derivatives, Rev. Roum. Chim., 63(3): 227-234 (2018).
31
[31] Maiden T.M., Harrity J.P., Recent Developments in Transition Metal Catalysis for Quinazolinone Synthesis, Org. Biomol. Chem., 14: 8014-8025 (2016).
32
[32] Pouramiri B., Fayazi R., Tavakolinejad Kermani E., Facile and Rapid Synthesis of 3,4-Dihydropyrimidin-2(1H)-one Derivatives Using [Et3NH][HSO4] as Environmentally Benign and Green Catalyst, Iran. J. Chem. Chem. Eng. (IJCCE), 37(1): 159-167 (2018).
33
[33] Hu B.Q., Wang L.X., Xiang J.F., Yang L., Tang Y.L., Cu (II)-Catalyzed Domino Reaction of 2-Halobenzamide and Arylmethanamine to Construct 2-aryl Quinazolinone, Chin. Chem. Lett., 26: 369-372 (2015).
34
[34] Kancherla M., Katlakanti M., Seku K., Badathala V., Boric Acid Supported on Montmorillonites as Catalysts for Synthesis of 2,3-dihydroquinazolin-4(1H)-ones, Iran. J. Chem. Chem. Eng. (IJCCE), Article in press (2018).
35
[35] Yarim M., Sarac S., Separation of the Enantiomers of 4-aryl-7, 7-dimethyl-and 1, 7, 7-trimethyl-1, 2, 3, 4, 5, 6, 7, 8-octahydroquinazoline-2, 5-diones by Chiral HPLC, Chromatographia., 56(5-6): 307-12 (2002).
36
[36] Cabrera-Rivera F.A., Escalante J., Synthesis, Resolution and Absolute Configuration of 2, 3-Dihydro-2-Tert-Butyl-3-N-Benzylquinazolin-4-One: A Possible Chiral Auxiliary for Synthesis of β-Amino Cyclohexancarboxylic Acid, Int. J. Org. Chem., 4: 48-54 (2014).
37
[37] Escalante J., González-Tototzin M.A., Synthesis, Resolution and Absolute Configuration of Trans 4, 5-diphenyl-pyrrolidin-2-one: a Possible Chiral Auxiliary, Tetrahedron: Asymmetry, 14: 981-985 (2003).
38
[38] Ellman G.L., Courtney K.D., Andres Jr V., Featherstone R.M., A new and Rapid Colorimetric Determination of Acetylcholinesterase Activity, Biochem. Pharmacol., 7: 88-95 (1961).
39
[39] Dvir H., Silman I., Harel M., Rosenberry T.L., Sussman J.L., Acetylcholinesterase: from 3D Structure to Function, Chem. Biol. Interact., 187(1-3): 10-22 (2010).
40
[40] Cheung J., Rudolph M.J., Burshteyn F., Cassidy M.S., Gary E.N., Love J., Franklin M.C., Height J.J., Structures of Human Acetylcholinesterase in Complex with Pharmacologically Important Ligands, J. Med. Chem., 55(22): 10282-10286 (2012).
41
[41] Verdonk M.L., Cole J.C., Hartshorn M.J., Murray C.W., Taylor R.D., Improved Protein–Ligand Docking Using GOLD, Proteins: Struct. Funct. Bioinf., 52(4): 609-23 (2003).
42
[42] Sheldrick G.M., A Short History of SHELX, Acta Crystallogr Sect. A: Found. Crystallogr., 64: 112-122 (2008).
43
[43] Siemens, "SAINT Area-Detector Control and Integration Software", Siemens Analytical X-ray Instruments Inc., Madison, WI, USA (1995).
44
[44] Biovia D.S., "Materials Studio Modeling Environment", Dassault Systèmes, San Diego (2015).
45
[45] Cheng F., Li W., Zhou Y., Shen J., Wu Z., Liu G., Lee P.W., Tang Y., Admet SAR: a Comprehensive Source and Free Tool for Assessment of Chemical ADMET Properties, Chem. Inf. Model., 52: 3099-3105 (2012)
46
[46] Kola I., Landis J., Can the Pharmaceutical Industry Reduce Attrition Rates?, Nat. Rev. Drug. Discovery, 3: 711-716 (2004).
47
ORIGINAL_ARTICLE
Synthesis, Reactions and Antioxidant Activity of 5-(3', 4'-dihydroxy-tetrahydrofuran-2'-yl)-2-methyl-3-carbohydrazide
In this manuscript, we describe the synthesis of the carbohydrazide 2. Acid-catalyzed condensation with several carbonyl compounds to afford the corresponding carbohydrazide derivatives 3-12. Their acetylation afforded the corresponding acetyl derivatives 13-22. Oxidative cyclization of O-acetyl derivatives 19-22 afforded the corresponding 1,3,4-oxadiazole derivatives 23-26. On the other hand, condensation of the dicarbonyl compound 27 with several aroylhydrazines to give the corresponding bisaroylhydrazones 28-32 cyclization of 28-31 afforded 1,3,4-oxadiazoles 33-36. The structures of the prepared compounds were confirmed by 1HNMR and Mass Spectra. The mechanism of the formation of the products was discussed. Furthermore, the antioxidant activities of some of the prepared compounds were examined.
https://ijcce.ac.ir/article_34239_891490bd5bc928a86e0569172e428fa2.pdf
2019-12-01
229
242
10.30492/ijcce.2019.34239
carbohydrazides
bisaroylhydrazones
1, 3, 4-oxadiazoles
Mohamed
El Sadek
elsadek_mm@yahoo.com
1
Chemistry Department, Faculty of Science, Alexandria University, Alexandria 21231, EGYPT
LEAD_AUTHOR
Samir Ahmed
Magd
samirahmed10387@yahoo.com
2
Chemistry Department, Faculty of Science, Alexandria University, Alexandria 21231, EGYPT
AUTHOR
Seham Yassen
Hassan
sehamyassen@yahoo.com
3
Chemistry Department, Faculty of Science, Alexandria University, Alexandria 21231, EGYPT
AUTHOR
Mohamed A.
Mostafa
dr_abdel_zaher@hotmail.com
4
Chemistry Department, Faculty of Science, Alexandria University, Alexandria 21231, EGYPT
AUTHOR
Galile
Yacouat
galila_69@yahoo.com
5
Biochemistry Department, Faculty of Science, Alexandria University, Alexandria 21231, EGYPT
AUTHOR
[1] Khalilullah H., Ahsan, J.M., Hedaitullah M., Khan S.; Ahmed B., 1, 3, 4-oxadiazole: a Biologically Active Scaffold, Mini Reviews in Medicinal Chemistry.,12: 789-801 (2012).
1
[2] Shakir R.M., Ariffin A., Abdulla M.A., Synthesis of New 2, 5-di-substituted 1, 3, 4-oxadiazoles Bearing 2, 6-di-tert-butylphenol Moieties and Evaluation of their Antioxidant Activity, Molecules., 19: 3436-3449 (2014).
2
[3] Alp A.S., Kilcigıl, G.; Özdamar E.D., ÇOBAN T., Eke B., Synthesis and Evaluation of Antioxidant Activities of Novel 1, 3, 4-oxadiazole and Imine Containing 1H Benzimid-Azoles, Turkish Journal of Chemistry., 39: 42-53 (2015).
3
[4] Suresh D.B., Jamatsing D.R., Pravin S.K., Ratnamala S.B., Synthesis, Characterization and Antioxidant Activity of Carvacrol Containing Novel Thiadiazole and Oxadiazole Moieties. Mod. Chem. Appl., 4: 1-4 (2016).
4
[5] Patrao P., Khader A.M.A., Kalluraya B., Synthesis of New 5-Naphthyl Substituted 1, 3, 4-Oxadiazole Derivatives and their Antioxidant Activity, Der. Pharm Chem., 5: 24-32(2013).
5
[6] Grewal A.S., Redhu S., Synthesis, Antibacterial and Antifungal Activity of 2, 5-Disubstituted-1, 3, 4-oxadiazole Derivatives, Pharm. Tech. Res., 6: 2015-2021 (2014).
6
[7] Selvakumar B., Vaidyanathan S.P., Madhuri S., Elango K.P., Synthesis and Antiviral Activity of Sulfonohydrazide and 1, 3, 4-oxadiazole Derivatives of 6, 6-dimethyl-9-oxo-4, 5, 6, 7, 8, 9-Hexahydropyrazolo [5, 1-b] Quinazoline, Journal of Chemical Research, 41: 221-224 (2017).
7
[8] Parikh P.K., Marvaniya H.M., Sen D.J., Synthesis and Biological Evaluation of 1, 3, 4-oxadiazole Derivatives as Potential Antibacterial and Antifungal Agents, Int. J. Drug Dev. & Res., 3: 248-255 (2011).
8
[9] Özdemir A., Sever B., Altıntop M.D., Temel H.E., Atlı Ö., Baysal M., Demirci F., Synthesis and Evaluation of New Oxadiazole, Thiadiazole, and Triazole Derivatives as Potential Anticancer Agents Targeting MMP-9, Molecules, 22: 1109- (2017).
9
[10] Bondock S., Adel S., Etman H.A., Badria F.A., Synthesis and Antitumor Evaluation of Some New 1, 3, 4-oxadiazole-based Heterocycles, European Journal of Medicinal Chemistry, 48: 192-199 (2012).
10
[11] Singh A.K., Lohani M., Parthsarthy R., Synthesis, Characterization and Anti-Inflammatory Activity of Some 1, 3,4 -Oxadiazole Derivatives, IJPR , 12: 319-323 (2013).
11
[12] Shyma P.C., Kalluraya B., SK P., AM V., Synthesis, Characterization, Antidiabetic and Antioxidant Activity of 1, 3, 4-oxadiazole Derivatives Bearing 6-Methyl Pyridine Moiety, Der. Pharm. Chemica, 7: 137-45(2015).
12
[13] El-Sadek M.M., Hassan S.Y., El-Dayem N.S., Yacout G.A., 5-(5-Aryl-1, 3, 4-oxadiazole-2-carbonyl) Furan-3-carboxylate and New Cyclic C-Glycoside Analogues from Carbohydrate Precursors with MAO-B, Antimicrobial and Antifungal Activities, Molecules, 17: 7010-7027 (2012).
13
[14] A.Gómez Sánchez and A. Rodríguez Roldán, Carbohydr.Res., 22: 53-62 (1972).
14
[15] Guthrie R.D., Honeyman J., Chem. and Industry, I: 557-562 (1958).
15
[16] John W.Rowen, Florence H. Forziati and Richard E.Reeves, J. Chem. Soc., 20: 1697 (1951).
16
[17] Alexandrou, N.E. Reassignment of Structures of the Dihydro-v-Tetrazines. II: Mechanism of Oxidation of Diacylhydrazones, Tetrahedron, 22: 1309–1316 (1966).
17
[18] El Khadem H., Shaban M.A.E., Carbohydrate Derivatives of 1-substituted 1,2,3-triazoles, J. Chem. Soc., 1967: 519–520(1967).
18
[19] El-Khadem, H.; Shaban, M.A.E.; Nassr, M.A.M. Oxidation of mesoxalaldehyde bis- and tris-(benzoylhydrazones). J. Chem. Soc.,1969, p. 1416–1418(1969).
19
[20] El-Khadem H., El-Sadik M.M., Meshreki M.H., Reactions of Phenylglyoxal Bisarylhydrazones, J. Chem. Soc., 1968: 2097–2099(1968).
20
[21] Burns J.L., Van Dalfsen J.M., Shawar R.M., Otto K.L., Garber R.L., Quan J.M., Smith A.L., Journal of Infectious Diseases, 179: 1190-1196(1999).
21
ORIGINAL_ARTICLE
Docking and Biological Screening of Bezo[A]phenothiazinones as Novel Inhibitors of Bacterial Peptidogloycan Transpeptidase
Rising cases of antibiotic-resistant bacteria is a public health concern. Many approved antibiotics target penicillin-binding proteins example peptidoglycan transpeptidase (PTPase). Due to wide pharmacological activity of phenothiazines, new styryl, aryl, alkynyl, and thiophenyl benzo[a]phenothiazines were synthesized and their inhibitory potency against PTPasein silico and Gram-positive/Gram-negative bacteria evaluated. The compounds inhibited the activity of PTPase at 18.93 - 75.48 µM and their best-docked poses identified interaction with PTPase Tyr318, His336, and His352. Experimental results agreed with computational predictions and further confirmed the benzo[a]phenothiazines as potential antibiotics. Also, the identified essential residues could be targeted during the rational optimization of the analogs.
https://ijcce.ac.ir/article_34223_7bf2d9ecdef99a62aa7667b9cd821a53.pdf
2019-12-01
243
250
10.30492/ijcce.2019.34223
phenothiazines
Antimicrobial
peptidoglycan transpeptidase
docking
binding mode
Akachukwu E.
Ibezim
akachukwu.ibezim@unn.edu.ng
1
Department of Pharmaceutical and Medicinal Chemistry, University of Nigeria, Nsukka, NIGERIA
AUTHOR
Efeturi
Onoabedje A.
efeturi.onoabedje@unn.edu.ng
2
Department of Pure and Industrial Chemistry, University of University, Nsukka, NIGERIA
LEAD_AUTHOR
Kovo G.
Akpomie
kovo.akpomie@unn.edu.ng
3
Department of Pure and Industrial Chemistry, University of University, Nsukka, NIGERIA
AUTHOR
[1] Laxminarayan R., Duse A., Wattal C., Zaidi A.K., Wertheim H.F., Sumpradit N., Vlieghe E., Hara G.L., Gould I.M., Goossens H., Greko C., So A.D., Bigdeli M., Tomson G., Woodhouse W., Ombaka E., Peralta A.Q., Qamar F.N., Mir F., Kariuki S., Bhutta Z.A., Coates A., Bergstrom R., Wright G.D., Brown E.D., Cars O., Antibiotic Resistance-the Need for Global Solutions, Lancet. Infect. Dis., 13: 1057–1098 (2013).
1
[2] Hoffman S.J., Outterson K., Røttingen J.A., Cars O., Clift C., Rizvi Z., Rotberg F., Tomson G., Zorzet A., An International Legal Framework to Address Antimicrobial Resistance, Bulletin of the World Health Organization, 93: 66-78 (2015).
2
[3] Franz A.W., Rominger F., Muller T.J.J., Synthesis and Electronic Properties of Stericallydemanding N-Arylphenothiazines and Unexpected Buchwald-Hartwigaminations, J. Org. Chem., 73: 1795-1804 (2008).
3
[4] Kumar N., Sharma A.K., Garg R., Yadav A.K., Antimicrobial Screening and Synthesis of Some Novel Benzo[a]phenothiazine and Rbofuransides, Indian J. Chem., 45B: 747-756(2006).
4
[5] Swarnkar P.K., Kriplani P., Gupta G.N., Ojha K.G., Synthesis and Antibacterial Activity of Some New Phenothiazine Derivatives, Elect. J. Chem., 4: 14–20 (2007).
5
[6] Mosnaim A.D., Ranade V.V., Wolf M.E., Puente J., Antonieta V.M., Phenothiazine Molecule Provides the Basic Chemical Structure for Various Classes of Pharmaco-Therapeutic Agents, Am. J. Ther., 13: 261-273 (2006).
6
[7] Arulmurugan S., Kavitha H.P., Synthesis, Characterization and Study of Antibacterial Activity of Some Novel Tetrazole Derivatives, Orbital. Electr. J. Chem., 2: 271-276 (2010).
7
[8] Pluta K., Morak-Miodawska B., Jelen M., Biological Activities of Synthesized Phenothiazines, Eur. J. Med. Chem. 46: 3179-3189 (2011).
8
[9] Motohashi N., Kurihara T., Yamanaka W., Satoh K., Sakagami H., Molnar J., Relationship between Biological Activity and Dipole Moment in Benzo[a]phenothiazines, Anticancer Research., 17: 3431-3435 (2011).
9
[10] Onoabedje E.A., Okoro U.C., Sarkar A., Knight D.W., Fuctionalization of Linear and Angular Phenothiazine and Phenoxazine Ring Systems via Pd(0)/Xphos Mediated Suzuki-Miyaura Cross-Coupling Reactions, J. Heterocyclic. Chem., 53: 1787 – 1794 (2016).
10
[11] Onoabedje E. A, Okoro U. C, Knight D. W., Rapid Access to New Angular Phenothiazine and Phenoxazine Dyes. J. Heterocyclic. Chem., 54: 206 – 214 (2017).
11
[12] Onoabedje E.A, Okoro U.C, Sarkar A, Knight D.W., Synthesis and Structure of New Alkynyl Derivatives of Phenothiazine and Phenoxazine, J. Sulfur Chem., 34: 269 – 281 (2016).
12
[13] Ntie-Kang F, Nwodo N. J, Ibezim A, Simoben C. V, Karaman B, Ngwa V. F, Sippl W, Adikwu M. U, Mbaze L. M., Molecular Modeling of Potential Anticancer Agents from African Medicinal Plants, J. Chem. Inf. Model., 54: 2433-2450 (2014).
13
[14] Onoabedje E. A, Ibezim A, Okafor S. N, Onoabedje U. S, Okoro U. C., Oxazin-5-Ones as a Novel Class of Penicillin Binding Protein Inhibitors: Design, Synthesis and Structure Activity Relationship, PLoS ONE., 11: 234-240 (2016).
14
[15] Ibezim E. A, Nwodo N. J, Nnaji J. N, Ujam O. T, Olubiyi O. O, Mba C. J., In-silico Investigation of Morpholines as Novel Class of Trypanosomal TriosephosphateIsomerase Inhibitors, Med. Chem. Res. doi:10.1007/s00044-016-1739-z (2016).
15
[16] Ibezim E. A, Olujide O. O, Ata A. K, Mbah C. J, Nwodo N. J., Structure-based Design of Natural Products as Anti-Schistosoma Drug: Virtual Screening, Structure Activity Relationship and Molecular Dynamic Studies, Current Computer-aided Drug Design, 13: 91 – 100 (2017).
16
[17] Metuge J. A, Kang F. N, Fuhngwa V, Babiaka S. B, Samje M, Cho-Ngwa F., Molecular Modeling of Plant Metabolites with Anti-Onchocerca Activity, Med Chem Res., 24: 2127–2141 (2015).
17
[18] Banzhaf A. T. M, Gross C. A Vollmer W., From the Regulation of Peptidoglycan Synthesis to Bacterial Growth and Morphology, Nature Reviews., 10: 123-136 (2012).
18
[19] Kumar P., Kaushik A., Lloyd E.P., Li S.G., Mattoo R., Ammerman N.C., Bell D.T., Perryman A.L., Zandi T.A., Ekins S., Ginell S.L., Townsend C.A., Freundlich J.S., Lamichhane G., Non-Classical Transpeptidases Yield insight Into New Antibacterial, Nat. Chem. Biol. 13: 54-61 (2017)
19
[20] Von-Rechenberg M, Blake B. K, Ho Y. S, Zhen Y, Chepanoske C. L, Richardson B. E, Xu N, Kery V., Ampicillin/Penicillin-Binding Protein Interactions as a Model Drug-Target System to Optimize Affinity Pull-down and Mass Spectrometric Strategies for Target and Pathway Identification, Proteomics., 5: 1764-7173 (2005).
20
[21] Lipinski C.A., Lombardo F., Dominy B.W., Feeney P.J., Experimental and Computational Approaches to Estimate Solubility and Permeability in Drug Discovery and Development Settings, Adv. Drug. Deliv. Rev., 23: 3–25 (1997).
21
[22] Pluta K., Morak-Miodawska B., Jelen M., Recent Progress in Biological Activity of Synthesized Phenothiazines, Eur. J. Med. Chem., 46: 3180-3188 (2011).
22
[23] Berman H.M., Westbrook J., Feng Z., Gilliland G., Bhat T.N., Weissig H., Shindyalov I.N., Bourne P.E., The Protein Data Bank, Nucleic Acids Res., 28: 235−342 (2000).
23
[24] Morris G.M., Goodsell D.S., Halliday R.S., Huey R., Hart W.E., Belew R.K., Automated Docking Using a Lamarckian Genetic Algorithm and an Empirical Binding Free Energy Function, J. Comp. Chem. 19: 1639-1662 (1998).
24
[25] Kitchen D.B., Decornez H., Furr J.R., Bajorath J., Docking and Scoring in Virtual Screening for Drug Discovery: Methods and Applications, Nat. Rev. Drug. Discov. 3: 935–949 (2004).[26] Accelrys., “Discovery Studio Visualizer Software” (2014).
25
[27] DeLano W.L., “The PyMOL Molecular Graphics Sstem”, DeLano Scientific LLC, San Carlos, CA, USA (2013).
26
[28] Tagg J. R, McGiven A. R., Assay system for bacteriocins, Appl. Microbiol., 21: 943-950 (1971).
27
[29] National Committee for Clinical Laboratory Standards, “National Committee for Clinical Laboratory Standards (NCCLS) Publication”, Villanova, Pa, USA (1993).
28
ORIGINAL_ARTICLE
Synthesis, Characterization and Crystal Structure of Caffeine Complex of Mn(II) p-Hydroxybenzoate
A new manganese(II) complex containing p-hydroxybenzoate and caffeine ligands, namely [Mn(OH-C6H4COO)2(H2O)4].2(C8H10N4O2).8H2O has been prepared. The synthesized complex has been characterized by elemental analyses, FT-IR spectroscopy, X-ray crystallography, and molar conductance measurements. The thermal properties of the complex were analyzed by TGA/DTA. The complex crystallizes in the monoclinic space group P21/c having cell dimensions a=11.1311(2), b=14.3579(3), c=13.5383(3) Å, β=101.879(2)º, V=2117.34(8) Å3, Z=2. In the mononuclear complex, Mn atom is coordinated by two p-hydroxybenzoate anions and four water molecules. Moreover, the asymmetric unit of the complex also contains four uncoordinated water molecules and one caffeine ligand. Crystal structure of the complex has 3D supramolecular networks formed via O-HOH···Ocaf, O-Hw···Ow, O-Hw···Ncaf, O-Hw···Ocaf, and O-Hw···Ocar hydrogen bonds.
https://ijcce.ac.ir/article_32841_f554fd21bcd251ab376df843681ea82e.pdf
2019-12-01
251
259
10.30492/ijcce.2019.32841
Mn(II)
Caffeine
p-hydroxybenzoic acid
supramolecular crystal structure
Füreya Elif
Özbek
fozturkkan36@gmail.com
1
Kafkas University, Department of Chemical Engineering, Faculty of Engineering and Architecture, 36300 Kars, TURKEY
LEAD_AUTHOR
Mustafa
Sertçelik
mustafasertcelik@gmail.com
2
Kafkas University, Department of Chemical Engineering, Faculty of Engineering and Architecture, 36300 Kars, TURKEY
AUTHOR
Erdal
Taşdemir
erdaltasdemir36@gmail.com
3
Kafkas University, Department of Chemistry, Faculty of Sciences and Arts, 36300 Kars, TURKEY
AUTHOR
Tuncer
Hökelek
merzifon@hacettepe.edu.tr
4
Department of Physics, Hacettepe University, 06800 Beytepe, Ankara, TURKEY
AUTHOR
Raziye
Çatak Çelik
rcelik@aksaray.edu.tr
5
Scientific and Technological Application and Research Center, Aksaray University, 68100 Aksaray, TURKEY
AUTHOR
Hacali
Necefoğlu
alinecef@hotmail.com
6
Kafkas University, Department of Chemistry, Faculty of Sciences and Arts, 36300 Kars, TURKEY
AUTHOR
[1] Salem N.M.H., Rashad A.R., El Sayed L., Foro S., Haase W., Iskander M.F., Synthesis, Characterization, Molecular Structure and Supramolecular Architectures of Some Copper(II) Complexes Derived from Salicylaldehyde Semicarbazone, Inorganica Chim. Acta, 432: 231–242 (2015).
1
doi:10.1016/j.ica.2015.04.019
2
[2] Chakrabarty R., Mukherjee P.S., Stang P.J., Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles, Chem. Rev., 111: 6810–6918 (2011).
3
doi:10.1021/cr200077m
4
[3] Gale P.A., Supramolecular Chemistry Anniversary, Chem. Soc. Rev., 36: 141 (2007).
5
doi:10.1039/b617780h
6
[4] Xin-Jian, W., Yi-Ping, C., Ze-Min, X., Su-Zhi, G., Feng, C., Ling-Yan, Z., Jian-Zhong, C., Synthesis, crystal structures and intermolecular interactions of two Mn(II) complexes with 4,4′-bipy and methyl Benzoates, J. Mol. Struct., 1035:318–325 (2013).
7
doi:10.1016/j.molstruc.2012.10.034
8
[5] Baran E.J., Yilmaz V.T., Metal Complexes of Saccharin, Coord. Chem. Rev., 250:1980–1999 (2006).
9
doi:10.1016/j.ccr.2005.11.021
10
[6] Lin C.J., Zheng Y.Q., Zhang D.Y., Xu W., Syntheses, Crystal Structures, and Characterization of Copper(II) Carboxylate Complexes Incorporating o-hydroxybenzoic Acid and p-hydroxybenzoic Acid, Russ. J. Coord. Chem., 40: 932–942 (2014).
11
doi:10.1134/S1070328414120094
12
[7] Dorkov P., Pantcheva I.N., Sheldrick W.S., Mayer-Figge H., Petrova R., Mitewa M., Synthesis, Structure and Antimicrobial Activity of Manganese(II) and Cobalt(II) Complexes of the Polyether Ionophore Antibiotic Sodium Monensin A., J. Inorg. Biochem., 102:26–32 (2008).
13
doi:10.1016/j.jinorgbio.2007.06.033
14
[8] Mandal S., Rout A.K., Ghosh A., Pilet G., Bandyopadhyay D., Synthesis, Structure and Antibacterial Activity of Manganese(III) Complexes of a Schiff Base Derived from Furfurylamine, Polyhedron., 28:3858–3862 (2009).
15
doi:10.1016/j.poly.2009.08.034
16
[9] Li M.X., Chen C.L., Zhang D., Niu J.Y., Ji B.S.: Mn(II), Co(II) and Zn(II) Complexes with Heterocyclic Substituted Thiosemicarbazones: Synthesis, Characterization, X-Ray Crystal Structures and Antitumor Comparison, Eur. J. Med. Chem., 45, 3169–3177 (2010).
17
doi:10.1016/j.ejmech.2010.04.009
18
[10] Qiu-Yun C., Dong-Fang Z., Juan H., Wen-Jie G., Jing G., Synthesis, Anticancer Activities, Interaction with DNA and Mitochondria of Manganese Complexes, J. Inorg. Biochem., 104:1141–1147 (2010).
19
doi:10.1016/j.jinorgbio.2010.06.012
20
[11] Singh D.P., Kumar K., Sharma C., New 14-Membered Octaazamacrocyclic Complexes: Synthesis, Spectral, Antibacterial and Antifungal Studies, Eur. J. Med. Chem., 45:1230–1236 (2010).
21
doi:10.1016/j.ejmech.2009.12.009
22
[12] Hua Q., Su Z., Zhao Y., Okamura T., Xu G.-C., Sun W.-Y., Ueyama N., Synthesis, Structure and Property of Manganese(II) Complexes with Mixed Tetradentate Imidazole-Containing Ligand and Benzenedicarboxylate, Inorganica Chim. Acta., 363:3550–3557 (2010).
23
doi:10.1016/j.ica.2010.07.012
24
[13] Lindsay Smith J.R., Gilbert B.C., Mairata i Payeras A., Murray J., Lowdon T.R., Oakes J., Pons i Prats R., Walton P.H., Manganese 1,4,7-trimethyl-1,4,7-Triazacyclononane Complexes: Versatile Catalysts for the Oxidation of Organic Compounds with Hydrogen Peroxide, J. Mol. Catal. Chem., 251:114–122 (2006).
25
doi:10.1016/j.molcata.2006.02.025
26
[14] Rajabi M., Gholivand K., Salami R., Molaei F., Thibonnet J., Zare K., Tirani F.F., Schenk K.J., Synthesis, Structural Determination, Theoretical Studies and Catalytic Activity of Mn(II) Complex of N-isonicotinyl Phosphoric Triamide Ligand, Inorganica Chim. Acta.., 432:149–157 (2015).
27
doi:10.1016/j.ica.2015.04.005
28
[15] Shnulin A.N., Nadzhafov G.N., Mamedov K.S., Crystal Structures of Manganese(II) p-Hydroxybenzoate Octahydrate and Trihydrate, J. Struct. Chem., 25:421–429 (1984).
29
doi:10.1007/BF00749335
30
[16] Su J.-R., Zhang L., Xu D.-J., Aqua(4-hydroxybenzoato-κO)bis(1,10-phenanthroline-κ2N,N ′)manganese(II) 4-hydroxybenzoate monohydrate, Acta Crystallogr. Sect. E Struct. Rep. Online, 61:m939–m941 (2005).
31
doi:10.1107/S1600536805011694
32
[17] Hu Z.-Q., Wu L.-B., Lai G.-Q., Bis(2,2′-bipyridine-κ2N,N′)bis(4-hydroxybenzoato-κO) manganese(II), Acta Crystallogr. Sect. E Struct. Rep. Online, 62:m712–m713 (2006).
33
doi:10.1107/S1600536806007422
34
[18] Liu F.-C., Xue M., Wang H.-C., Ou-Yang J., New Divalent Manganese Complex with Pyridine Carboxylate N-oxide Ligand: Synthesis, Structure and Magnetic Properties, J. Solid State Chem., 183:1949–1954 (2010).
35
doi:10.1016/j.jssc.2010.06.010
36
[19] Che, S.-C., Hu M., Zhang Z.-H., Sun F.-A., Wang L., Zhou W.-Y., He M.-Y., Chen Q., Syntheses, Structures, and Properties of Zinc(II), Cadmium(II), Cobalt(II), and Manganese(II) Coordination Polymers with Tetraiodoterephthalate, Transit. Met. Chem., 37:619–627 (2012).
37
doi:10.1007/s11243-012-9630-3
38
[20] Esteves D., Tedesco J.C.D., Pedro S.S., Cruz C., Reis M.S., Brandão, P., New Manganese (II) Structures Derived from 2,6-dichlorobenzoic Acid: Syntheses, Crystal Structures and Magnetism, Mater. Chem. Phys., 147:611–616 (2014).
39
doi:10.1016/j.matchemphys.2014.05.037
40
[21]Čechová D., Martišková A., Padělková Z., Gal’a L., Dlháň L., Valigura D., Valko M., Boča R., Moncol J., Manganese(II) One-dimensional Coordination Polymers with Nitrobenzoato or Nitrosalicylato bridges: Syntheses, Crystal Structures, and Magnetic Properties, Polyhedron., 79:129–137 (2014).
41
doi:10.1016/j.poly.2014.05.005
42
[22] Zhao Q.-H., Zhao L., Wang K.-M., Zhou H., catena -Poly[[[bis(μ-4-hydroxybenzoato)bis[(4-hydroxybenzoato)manganese(II)]]-di-μ-4,4′-bipyridine] 4,4′-bipyridine disolvate tetrahydrate], Acta Crystallogr. Sect. E Struct. Rep. Online., 66:m358–m358 (2010).
43
doi:10.1107/S1600536810007245
44
[23] Taşdemir E., Özbek F.E., Sertçelik M., Hökelek T., Çelik R.Ç., Necefoğlu H., Supramolecular Complexes of Co(II), Ni(II) and Zn(II) p-Hydroxybenzoates with Caffeine: Synthesis, Spectral Characterization and Crystal Structure, J. Mol. Struct., 1119:472–478 (2016).
45
doi:10.1016/j.molstruc.2016.05.006
46
[24] Sheldrick G.M., A Short History of SHELX, Acta Crystallogr. A., 64:112–122 (2008).
47
doi:10.1107/S0108767307043930
48
[25] Farrugia L.J., WinGX and ORTEP for Windows: An Update, J. Appl. Crystallogr., 45:849–854 (2012)
49
doi:10.1107/S0021889812029111
50
[26] Spek A.L., PLATON SQUEEZE: a Tool for the Calculation of the Disordered Solvent Contribution to the Calculated Structure Factors, Acta Crystallogr. C,. 71:9-18 (2015).
51
doi:10.1107/S2053229614024929
52
[27] Icbudak H., Heren Z., Kose D.A., Necefoglu H., Bis(nicotinamide) and bis(N,N-diethyl nicotinamide) p-hydroxybenzoate Complexes of Ni(II), Cu(II) and Zn(II), J. Therm. Anal. Calorim., 76: 837–851 (2004).
53
doi:10.1023/B:JTAN.0000032269.12381.42
54
[28] Homzová K., Győryová K., Bujdošová Z., Hudecová D., Ganajová M., Vargová Z., Kovářová J., Synthesis, Thermal, Spectral and Biological Properties of Zinc(II) 4-hydroxybenzoate Complexes, J. Therm. Anal. Calorim., 116: 77–91 (2014).
55
doi:10.1007/s10973-014-3702-x
56
[29] Zhang H.-J., Gou R.-H., Yan L., Yang R.-D., Synthesis, Characterization and Luminescence Property of N,N′-di(pyridine N-oxide-2-yl)pyridine-2,6-dicarboxamide and Corresponding lanthanide (III) Complexes, Spectrochim. Acta. A. Mol. Biomol. Spectrosc., 66: 289–294 (2007).
57
doi:10.1016/j.saa.2006.02.054
58
[30] Bellamy L.J., The Infrared Spectra of Complex Molecules, second ed., Halsted Press, a division of John Wiley & Sons, Inc., Methuen, London (1958).
59
[31] Nikolaev V.A., Logvinenko L.T., Myachina, Thermal Analysis. Vol. 2, Academic Press, New York (1969)
60
[32] Geary W.J., The Use of Conductivity Measurements in Organic Solvents for the Characterisation of Coordination Compounds, Coord. Chem. Rev., 7:81–122 (1971).
61
doi:10.1016/S0010-8545(00)80009-0
62
ORIGINAL_ARTICLE
Energy Consumption Modeling in Activated Sludge Process Using Coupling PCA-ANFIS Approach
The main challenge in Wastewater Treatment Plants (WWTP) by activated sludge process is the reduction of the energy consumption that varies according to the pollutant load of influent. However, this energy is fundamentally used for aerators in a biological process. The modeling of energy consumption according to the decision parameters deemed necessary for good control of the active sludge process namely the removal yields of parameters pollutant such as Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Suspended solids (SS) and Ammoniac (NH4+) that must meet the required standards. To achieve this objective, a coupling of two approaches, the principal components analysis (PCA) method and the Adaptatif Neural Fuzzy Inference System (ANFIS) model was envisaged, to improve the performance of fuzzy reasoning. Indeed, PCA as a factorization tool allowing the reducing of the variable that allows the reduction of the complexity of the studied phenomenon. The neuro-fuzzy learning from the data projected on the principal axes allows the improvement of the model, both in learning and validation periods. The comparative study between ANFIS model, the regression PCA model, and the coupling PCA-ANFIS method applied to the raw data was effected. The results indicate a significant improvement in the validation criteria obtained in the coupling PCA-ANFIS model compared to the other models for the learning and validation periods. The result shows that the coupling PCA-ANFIS can be used to extract information from data and to describe the nonlinearity of complex wastewater treatment processes.
https://ijcce.ac.ir/article_39704_ab43036749d3f28e9576d6b6a15b0333.pdf
2019-12-01
261
273
10.30492/ijcce.2019.39704
Wastewater
Activated sludge
ANFIS Modeling
PCA
Radia
Maachou
maachouradia@yahoo.fr
1
Laboratory of Faculty of Chemistry, Electrochemistry-Corrosion, Metallurgy and Mineral Chemistry, BP 32 El-Allia, PC 16111, USTHB, Algiers, ALGERIA
AUTHOR
Abdeluahab
Lefkir
a_lefkir06@yahoo.fr
2
ENSTP, Laboratory of TPiTE, Bp 32 Kouba Algiers, ALGERIA
LEAD_AUTHOR
Abdelmalek
Bermad
bermad_61@yahoo.fr
3
ENP, Ecole Nationale Polytechnique, B.P. 182-16200, El Harrach, Algiers, ALGERIA
AUTHOR
Soraya
Abdelaziz
4
ENP, Ecole Nationale Polytechnique, B.P. 182-16200, El Harrach, Algiers, ALGERIA
AUTHOR
[1] Holenda B., Domokos Y., Reédey A´., Fazakas J., Aeration Optimization of a Wastewater Treatment Plant Using Genetic Algorithm, Optim. Control Appl. Meth., 28: 191–208 (2007).
1
[2] Ozturk M. C., Serrat F.M., Teymour F., Optimization of Aeration Profiles in the Activated Sludge Process, Chemical Engineering Science, 139:1–14 (2016).
2
[3] Rieger L., Alex J., Gujer W., Siegrist H., Modelling of Aeration Systems at Wastewater Treatment Plants, Water Science & Technology, 53: 439–447 (2006).
3
[4] Fernandez F.J., Castro M.C., Rodrigo M.A., Canizares P., Reduction of Aeration Costs by Tuning a Multi-set Point on/off Controller: A Case Study, Control Engineering Practice, 19: 1231–1237 (2011).
4
[5] Duchène Ph., Cotteux E., Capela S., Applying Fine Bubble Aeration to Small Aeration Tanks, Water Science & Technology, 44(2–3): 203–210 (2001).
5
[6] Gujer W., Henze M., Mino T., Van M., Activated Sludge Model No. 3, Water Sci. Technol., 39: 183–193 (1999).
6
[7] Henze M., Gujer W., Mino T., Matsuo T., Wentzel M.C., Gerrit v. R. Marais, Mark C. M. Van Loosdrecht, , Activated Sludge Model No.2d, ASM2D, Water Sci. Technol., 39 (1): 165-182 (1999).
7
[8] Maachou R., Lefkir A., Bermad A., Djaoui T., Khouider A., Statistical Analysis of Pollution Parameters in Activated Sludge Process, Desalination and Water Treatment, 72: 85–91 (2017)
8
[9] Qiao J., Li W., Han H., Soft Computing of Biochemical Oxygen Demand Using an Improved T–S Fuzzy Neural Network Chinese Journal of Chemical Engineering, 22: 1254–1259 (2014).
9
[10] Civelekoglu G., Yigit N.O., Diamadopoulos E., Kitis M., Modelling of COD Removal in a Biological Wastewater Treatment Plant Using Adaptive Neuro-Fuzzy Inference System and Artificial Neural Network, Water Science & Technology—WST, 60.6, (2009)
10
[12] Maachou R., Lefkir A., Merabtene T., Hamriche A., Bermad A., Contribution to Optimize Decision Parameters in Activated-Sludge Process Using ANFIS Model, MATEC Web of Conferences, 120: 05001 (2017)
11
[13] Agheri M., Mirbagheri S.A., Bagheri Z., Kamarkhani A.M., Modeling and Optimization of Activated Sludge Bulking for a Real Wastewater Treatment Plant Using Hybrid Artificial Neural Networks-Genetic Algorithm Approach, Process Safety and Environmental Protection, 95: 12–25 (2015).
12
[14] Huang M., Ma Y,Wan J, Zhang H, Wang Y,. Modeling a Paper-Making Wastewater Treatment Process by Means of an Adaptive Network-Based Fuzzy Inference System and Principal Component Analysis, Ind. Eng. Chem. Res., 51: 6166−6174 (2012).
13
[15] Wan J., Huang M., Maa Y., Guoa W., Wanga Y., Zhangc, H Weijiang., Prediction of Effluent Quality of a Paper Mill Wastewater Treatment Using an Adaptive Network-Based Fuzzy Inference System, Applied Soft Computing, 11: 3238–3246 (2011).
14
[16] Dong-Jin Choi, Heekyung Park, A Hybrid Artificial Neural Network as a Software Sensor for Optimal Control of a Wastewater Treatment Process, Wat. Res., 35: 3959–3967 (2001).
15
[17] Huang M., Yongwen Ma, Jinquan Wan , Yan Wang, Yangmei Chen, Changkyoo Yoo., Improving Nitrogen Removal Using a Fuzzy Neural Network-Based Control System in the Anoxic/Oxic Process, Environ Sci Pollut Res., 21: 12074–12084 (2014).
16
[18] Huang M., Wan J., Yan Wang, Yongwen Ma., Modeling of a Paper-Making Wastewater Treatment Process Using a Fuzzy Neural Network, Korean J. Chem. Eng., 29(5): 636-643 (2012).
17
[19] Maachou R., Lefkir A., Khouider A., Bermad A., Modeling of Activated Sludge Process Using Artificial Neuro-Fuzzy-Inference System (ANFIS), Desalination and Water Treatment, 57:45, 21182-21188, (2016).
18
[20] Ghaedi M., et al, Principal Component Analysis- Adaptive Neuro-Fuzzy Inference System Modeling and Genetic Algorithm Optimization of Adsorption of Methylene Blue by Activated Carbon Derived from Pistacia Khinjuk, Ecotoxicology and Environmental Safety, 96: 110-117 (2013).
19
[21] Huang M., Ma Y., Wan J., Chen X.A,. Sensor-Software Based on a Genetic Algorithm-Based Neural Fuzzy System for Modeling and Simulating a Wastewater Treatment Process, Applied Soft Computing, 27: 1–10 (2015)
20
[22] Huang M., Han W., Wan J., Ma Y., Chena. X.O., Multi-objective Optimisation for Design and Operation of Anaerobic Digestion Using GA-ANN and NSGA-IIJ Chem Technol Biotechnol, (2014)
21
[23] Traoré A., Grieu S., Frédérik T., Monique P., Colprim J., Control of Sludge Height in a Secondary Settler Using Fuzzy Algorithms, Computers and Chemical Engineering, 30: 1235–1242 (2006)
22
[24] Wangyani., Control of Sludge Recycle Flow in Wastewater Treatment Plants Using Fuzzy Logic Controller., AISC, 180: 313-318 (2013)
23
[25] Huang M., Ma Y., Jinquan W., Yan W., Yangmei C., Changkyoo Y, Improving Nitrogen Removal Using a Fuzzy Neural Control System in the Anoxic/Oxic Process, Environ Science Pollution Research, 21: 12074–12084 (2014)
24
[26] Tsai Y., Ouyang C F., Chiang W.L., Wu M.Y., Construction of an on-Line Fuzzy Controller for the Dynamic Activated Sludge Process, Water Research,28: 913-921 (1994)
25
[27] Fu C.S., Poch M., Fuzzy Model and Decision of COD Control for an Activated Sludge Process, Fuzzy Sets and Systems, 93: 281-292 (1998).
26
[28] Alex J., Jumar U., Tschepetzki R., “A Fuzzy Controller for Activated Sludge Waste Water Plants, Artificial Intelligence in Real Time”, Control, Valencia, Spain, (1994).
27
[29] Anderson J.S., Kim H., McAvoy T.J., Hao O.J., Control of an Alternating Aerobic–Anoxic Activated Sludge System Part 1. Control Engineering Practice, 8: 271–278 (2000).
28
[30] Hao O.J., Huang J., Alternating Aerobic–Anoxic Process for Nitrogen Removal: Performance Evaluation, Water Environment Research, 68(1): 83–93 (1996).
29
[31] Huang J., Hao O.J., Alternating Aerobic–Anoxic Process for Nitrogen Removal: Dynamic Modeling, Water Environment Research, 68(1): 93–101 (1996)
30
[32] Heduit A., Ducheme P., Sintes L., Optimization of Nitrogen Removal in Small Activated Sludge Plants, Water Science and Technology, 22(3–4): 123–130 (1990).
31
[33] Lefkir A, MaachouR., Bermad A., KhouiderA., Factorization of Physicochemical Parameters of Activated Sludge Process Using the Principal Component Analysis, Desalination and Water Treatment, 57:43, 20292-20297 (2016)
32
[34] Jiao, Wei, Xiang, Shuguang, Quantitative Safety and Health Assessment Based on Fuzzy Inference and AHP at Preliminary Design Stage, Iran. J. Chem. Chem. Eng. (IJCCE), 35(4): 153-165 (2016)
33
[35] Teppola P., Mujunen S.P.,.Minkkinen P., Adaptive Fuzzy C-Means Clustering in Process Monitoring Chemometrics and Intelligent Laboratory Systems, 45: 23-38 (1999).
34
[36] Saghatoleslami N., Mousavi M., Sargolzaei J., Khoshnood M., A Neuro-Fuzzy Model for a Dynamic Prediction of Milk Ultrafiltration Flux and Resistance, Iran. J. Chem. Chem. Eng. (IJCCE), 26(2): 53-61 (2007).
35
[37] Mohammed N., Ramli M., Azlan H., Badrul M.J., Bawadi A., Online Composition Prediction of a Debutanizer Column Using Artificial Neural Network, Iran. J. Chem. Chem. Eng. (IJCCE), 36(2): 153-175 (2017).
36
[38] Hreiz R., Latifi M.A., Roche N., Optimal Design and Operation of Activated Sludge Processes: State-of-the-Art, Chemical Engineering Journal, 281: 900-920 (2015)
37
ORIGINAL_ARTICLE
Antibacterial Activity of the Lipopeptide Biosurfactant Produced by Bacillus mojavensis PTCC 1696
Bacillus mojavensis PTCC 1696 (a member of Bacillus subtilis group) has been isolated from the Iranian oil field (Masjed-I Soleyman), to examine its ability to produce biosurfactant (lipopeptide type) [28]. The present study was designed to characterize the antibacterial activity of the isolated biosurfactant. The antibacterial activity towards several bacteria including clinical isolates and type strains species was examined. For detecting the extent of antibacterial activity, the agar disc diffusion method was used, where the measured diameter of the zone of inhibition was used as an index for determining the antibacterial activity. Among the test microorganisms, the antibacterial activity was highest in Pseudomonas aeruginosa ATCC 27853. At concentration as low as 16 μg/ml, the inhibitory effect of the lipopeptide biosurfactant was detectable. The stability of the test biosurfactant also was examined over a wide range of temperatures (40–100°C)and pH values (2-11). The stability was further tested using protease and lipase, where the substance showed clear sensitivity towards lipase. The potentiality of this antibacterial agent in clinical applications is of interest and needs to be further recognized.
https://ijcce.ac.ir/article_32436_16f4c802b4fc74d0900c2cb75c8c9ba4.pdf
2019-12-01
275
284
10.30492/ijcce.2019.32436
Antibacterial activity
Lipopeptide, biosurfactant
Surface activity
Bacillus mojavensis PTCC 1696
Hossein
Ghojavand
h_ghojavand@aut.ac.ir
1
Administration of Technology Affairs, Deputy of Engineering, Research and Technology, Ministry of Petroleum of Iran, Tehran, I.R. IRAN
LEAD_AUTHOR
Masoud
Mohammadi Behnazar
mmasoud93@gmail.com
2
Department of Chemical Engineering, Amirkabir University of Technology, Tehran, I.R. IRAN
AUTHOR
Farzaneh
Vahabzadeh
far@aut.ac.ir
3
Department of Chemical Engineering, Amirkabir University of Technology, Tehran, I.R. IRAN
AUTHOR
[1] Marchant R., Banat I.M., Biosurfactants: A Sustainable Replacement for Chemical Surfactants?, Biotechnol. Lett., 34: 1597-1605 (2012).
1
[2] He C., Dong W., Li J., Li Y., Huang C., Ma Y., Characterization of Rhamnolipid Biosurfactants Produced by Recombinant Pseudomonas aeruginosa Strain DAB with Removal of Crude Oil, Biotechnol. Lett., 39 (9): 1381-1388 (2017).
2
[3] Ren H., Su Y., Zhang J., Pan H., Chen B., Wang Y., Recombinant Protein, AlnA, Combined with Transgenic Alfalfa Remediates Polychlorinated Biphenyl-Contaminated Soils: Efficiency and Rhizosphere Microbial Community Response, Biotechnol. Lett., 38(11): 1893-1901 (2016).
3
[4] Singh A., Van Hamme J.D., Ward O.P., Surfactants in Microbiology and Biotechnology: Part 2. Application Aspects, Biotechnol. Adv., 25: 99-121 (2007).
4
[5] Nitschkea M., Costa S.G.V.A.O., Biosurfactants in Food Industry, Trends. Food. Sci. Technol., 18: 252-259 (2007).
5
[6] Winterburn J.B., Martin P.J., Foam Mitigation and Exploitation in Biosurfactant Production, Biotechnol. Lett., 34: (2) 187-195 (2012).
6
[7] Imura T., Ito S., Azumi R., Yanagishita H., Sakai H., Abe M., Kitamoto D., Monolayers Assembled
7
from a Glycolipid Biosurfactant from Pseudozyma (Candida) Antarctica Serve as a High-Affinity Ligand System for Immunoglobulin G and M, Biotechnol. Lett., 29 (6): 865-870 (2007).
8
[8] Cameotra S.S., Makkar R.S., Recent Applications of Biosurfactants as Biological and Immunological Molecules, Curr. Opin. Microbiol., 7: 262–266 (2004).
9
[9] Leathers T.D., Price N.P., Bischoff K.M., Manitchotpisit P., Skory C.D., Production of Novel Types of Antibacterial Liamocins by Diverse Strains of Aureobasidium Pullulans Grown on Different Culture Media, Biotechnol. Lett., 37(10): 2075–2081 (2015).
10
[10] Singh P., Cameotra S.S., Potential Applications of Microbial Surfactants in Biomedical Sciences, Trends. Biotechnol., 22 (3): 142-146 (2004).
11
[11] Rodrigues L., Banat I.M., Teixeira J., Oliveira R., Biosurfactants: Potential Applications in Medicine, J. Antimicrob. Chemother., 57: 609–618 (2006).
12
[12] Elshikh O., Ahmed S., Funston S., Dunlop P., McGaw M., Marchant R., Banat I.M., Resazurin-Based 96-Well Plate Microdilution Method for the Determination of Minimum Inhibitory Concentration of Biosurfactants, Biotechnol. Lett., 38(6): 1015–1019 (2016).
13
[13] Ghribi D., Abdelkefi-Mesrati L., Mnif I., Kammoun R., Ayadi I., Saadaoui I., Maktouf S., Chaabouni-Ellouze S., Investigation of Antimicrobial Activity and Statistical Optimization of Bacillus subtilis SPB1 Biosurfactant Production in Solid-State Fermentation, J. Biomed. Biotechnol., 2012: 1-12 (2012).
14
[14] Luna J.M., Rufino R.D., Sarubbo L.A., Rodrigues L.R.M., Teixeira J.A.C., Campos-Takaki G.M., Evaluation Antimicrobial and Antiadhesive Properties of the Biosurfactant Lunasan Produced by Candida sphaerica UCP 0995, Curr. Microbiol., 62: 1527-1534 (2011).
15
[15] Gudiña E.J., Rocha V., Teixeira J.A., Rodrigues L.R., Antimicrobial and Antiadhesive Properties of a Biosurfactant Isolated from Lactobacillus paracasei ssp. paracasei A20, Lett. Appl. Microbiol., 50 (4): 419-424 (2010).
16
[16] Rufino R.D., Luna J.M., Sarubbo L.A., Rodrigues L.R.M., Teixeira J.A.C., Campos-Takaki G.M., Antimicrobial and Anti-Adhesive Potential of a Biosurfactant Rufisan Produced by Candida lipolytica UCP 0988, Colloids. Surf. B. Biointerfaces., 84: 1-5 (2011)
17
[17] Steenbergen J.N., Alder J., Thorne G.M., Tally F.P., Daptomycin: a Lipopeptide Antibiotic for the Treatment of Serious Gram-Positive Infections, J. Antimicrob. Chemother., 55: 283-288 (2005).
18
[18] Sansinenea E., Ortiz A., Secondary Metabolites of Soil Bacillus spp., Biotechnol. Lett., 33 (8): 1523-1538 (2011).
19
[19] Bach H., Gutnick D.L., Potential Applications of Bioemulsifiers in the Oil Industry. In: Petroleum Biotechnology, Developments and Perspectives. “Studies in Surface Science and Catalysis” Vol. 151 (2004).
20
[20] Bechard J., Eastwell K.C., Mazza G., Skura B., Isolation and Partial Chemical Characterization of an Antimicrobial Peptide Produced by a Strain of Bacillus subtilis, J. Agric. Food. Chem., 46(12): 5355-5361 (1998).
21
[21] Yakimov M.M., Timmis K.N., Wray V., Fredrickson H.L., Characterization of a New Lipopeptide Surfactant Produced by Termotolerant and Halotolerant Subsurface Bacillus licheniformis BAS50, Appl. Environ. Microbiol., 1706-1713 (1995).
22
[22] Sabaté D.C., Audisio M.C., Inhibitory Activity of Surfactin, Produced by Different Bacillus subtilis Subsp. subtilis strains, against Listeria monocytogenes sensitive and Bacteriocin-Resistant Strains, Microbiol. Res., 168: 125-129 (2013).
23
[23] Motta A.S., Cannavan F.S., Tsai S.M., Brandelli A., Characterization of a Broad Range Antibacterial Substance from a New Bacillus Species isolated from Amazon Basin, Arch. Microbiol., 188: 367-375 (2007).
24
[24] Olivera F.C., Caron G.R., Brandelli A., Bacteriocin-Like Substance Production by Bacillus licheniformis Strain P40, Lett. Appl. Microbiol., 38: 251-256 (2004).
25
[25] Thorne G.M., Alder J., Daptomycin: a Novel Lipopeptide Antibiotic, Clin. Microbiol. Newsl., 24: 33-40 (2002).
26
[26] Ahn C.Y., Joung S.H., Jeon J.W., Kim H.S., Yoon B.D., Oh H.M. Selective Control of Cyanobacteria by Surfactin-Containing Culture Broth of Bacillus subtilis C1, Biotechnol. Lett., 25 (14): 1137-1142 (2003).
27
[27] Nielsen T.H., Sørensen D., Tobiasen C., Andersen J.B., Christophersen C., Givskov M., Sørensen J., Antibiotic and Biosurfactant Properties of Cyclic Lipopeptides Produced by Fluorescent Pseudomonas spp. from the Sugar Beet Rhizosphere, Appl. Environ. Microbiol., 68 (7): 3416-3423 (2002).
28
[28] Ghojavand H., Vahabzadeh F., Mehranian M., Radmehr M., Shahraki A.K., Zolfagharian F.,
29
Emadi M.A., Roayaei E., Isolation of Thermotolerant, Halotolerant, Facultative Biosurfactant Producing Bacteria, Appl. Microbiol. Biotechnol., 80: 1073-1085 (2008).
30
[29] Cladera-Olivera F., Caron G.R., Brandelli A., Bacteriocin-Like Substance Production by Bacillus licheniformis Strain P40, Lett. Appl. Microbiol., 38: 251-256 (2004).
31
[30] Yeh M.S., Wei Y.H., Chang J.S., Bioreactor Design for Enhanced Carrier-Assisted Surfactin Production with Bacillus subtilis, Process. Biochem., 41: 1799-1805 (2006).
32
[31] Kim H.S., Yoon B.D., Lee C.H., Suh H.H., Oh H.M., Katsuragy T., Production and Properties of a Lipopeptide Biosurfactant from Bacillus subtilis C9, J. Ferment. Bioeng., 84: 41-46 (1997).
33
[32] Cooper D.G., MacDonald C.R., Duff S F.B., Kosaric N., Enhanced Production of Surfactin From Bacillus subtilis by Continuous Product Removal and Metal Cation Additions, Appl. Environ. Microbiol., 42: 408–412 (1981).
34
[33] Lin S.C., Carswell K.S., Sharma M.M., Georgiou G., Continuous Production of the Lipopeptide Biosurfactant of Bacillus licheniformis JF-2, Appl. Microbiol. Biotechnol., 41: 281-285 (1994).
35
[34] Mukherjee A.K., Das K., Microbial surfactants and Their Potential Applications, In: “Biosurfactants Advances in Experimental Medicine and Bbiology”, Vol. 672, Springer Science+Business Media, LLC. Landes Bioscience, (2010).
36
[35] Ben Ayed H., Jridi M., Maalej H., Nasri M., Hmidet H., Characterization and Stability of Biosurfactant Produced by Bacillus Mojavensis A21 and Its Application in Enhancing Solubility of Hydrocarbon,
37
J. Chem Technol. Biotechnol., 89: 1007-1014 (2014).
38
[36] Gomaa E.Z., Antimicrobial Activity of a Biosurfactant Produced by Bacillus licheniformis Strain M104 Grown on Whey, Afr. J. Microbiol. Res., 20: 4396-4403 (2012).
39
[37] Baindara P., Mandal S.M., Chawla N., Singh P.K., Pinnaka A.K., Korpole S., Characterization of Two Antimicrobial Peptides Produced by a Halotolerant Bacillus subtilis Strain SK.DU.4 Isolated from a Rhizosphere Soil Sample, AMB Express 3: 2 (2013).
40
[38] Mah T.F., O’Toole G.A., Mechanisms of Biofilm Resistance to Antimicrobial Agents, Trends. Microbiol., 9: 34-39, (2001).
41
[39] Cao X.H., Liao Z.Y., Wang C.L., Yang W.Y., Lu M.F., Evaluation of a Lipopeptide Biosurfactant from Bacillus natto TK-1 as a Potential Source of Anti-Adhesive, Antimicrobial and Antitumor Activities, Braz. J. Microbiol., 40: 373-379 (2009).
42
[40] Fang X., Fang Z., Zhao J., Zou Y., Li T., Wang J., Guo Y., Chang D., Su L., Ni P., Liu C., Draft Genome Sequence of Pseudomonas aeruginosa Strain ATCC 27853, J. Bacteriol., 194 (14): 3755 (2012)
43
[41] Matzneller P., Manafi M., Zeitlinger M. Antimicrobial Effect of Statins: Organic Solvents Might Falsify Microbiological Testing Results, Int. J. Clin. Pharmacol. Ther., 49: 666-671 (2011).
44
[42] Tabbene O., Kalai L., Slimene I.B., Karkouch I., Elkahoui S., Gharbi A., Cosette P., Mangoni M.L., Jouenne T., Limam F., Anti-Candida effect of Bacillomycin D-like Lipopeptides from Bacillus subtilis B38, FEMS Microbiol. Lett., 316: 108-114 (2011).
45
[43] Tabbene O., Slimene I.B., Bouabdallah F., Mangoni M.L., Urdaci M.C., Limam F., Production of Anti-Methicillin-Resistant Staphylococcus Activity from Bacillus subtilis sp. Strain B38 Newly Isolated from Soil, Appl. Biochem. Biotechnol., 157: 407-719 (2009).
46
[44] D’Costa V.M., Mukhtar T.A., Patel T., Koteva K., Waglechner N., Hughes D.W., Wright G.D.,
47
Pascale G.D., Inactivation of the Lipopeptide Antibiotic Daptomycin by Hydrolytic Mechanisms, Antimicrob. Agents. Chemother., 56 (2): 757–764 (2012).
48
ORIGINAL_ARTICLE
Optimizing Different Angles of Venturi in Biodiesel Production Using CFD Analysis
The purpose of this paper is to find the optimal geometry of Venturi for the production of biodiesel by hydrodynamic cavitation. Intensive methods such as hydrodynamic cavitation eliminate the limitation of mass transfer in the transesterification reaction. In this paper, a venturi design was developed to create cavitation in biodiesel production. The most important property of venturi in creating cavitation and retrieving the pressure is the convergence and divergence angles. The four convergence angles of 22°, 20°, 17°, and 15° and four divergence angles of 12°, 10°, 7° and 5° in Gambit 2.4 software were designed and evaluated with Fluent 6.3 software and their CFD was analyzed. The maximum pressure recovery (85% of input pressure) and cavitation generation was for venturi 17-10 (Convergence angle 17° and divergence angle 10°), which was used in the experimental setup of biodiesel production. The biodiesel production efficiency with this venturi was 95.6%. The FTIR spectrum of the biodiesel was taken to confirm its purity.
https://ijcce.ac.ir/article_32597_00f2ae919965c6cb3e9063e25ed7a89c.pdf
2019-12-01
285
295
10.30492/ijcce.2019.32597
Biodiesel
Venturi
Fluent
CFD
Hydrodynamic cavitation
Hamid Reza
Chitsaz
st_h_chitsaz@azad.ac.ir
1
Department of chemical engineering, South Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
Mohammad Reza
Omidkhah
omidkhah@modares.ac.ir
2
Department of chemical engineering, South Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
LEAD_AUTHOR
Barat
Ghobadian
ghobadib@modares.ac.ir
3
Department of Mechanics of Agricultural Machinery Engineering, University of Tarbiat Modares, Tehran, I.R. IRAN
AUTHOR
Mehdi
Arjomand
m_arjmand@azad.ac.ir
4
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
[1] Polczmann G., O.Toth A., Beck, Hancsok J., Investigation of Storage Stability of Diesel Fuels Containing Biodiesel Produced from Waste Cooking Oil, J. Clean. Prod., 111 (2016).
1
[2] MarchettiJ.M., Miguel V.U., Errazu A.F., Possible Methods for Biodiesel Production, Renewable and Sustainable Energy Reviews, 11: 1300-1311 (2007).
2
[3] GerpenJ.V., Biodiesel Processing and Production, Fuel Processing Technology, 86: 1097–1107(2005).
3
[4] Meher L.C., Sagar D.V., Naik S.N., Technical Aspects of Biodiesel Production by Transesterification, Renewable and Sustainable Energy Reviews, 10: 248–268 (2006).
4
[5] AbderrahimB., Yolanda D., Mercedes M., Jose A., Pilot Plant Studies of Biodiesel Production Using Brassica Carinata as Raw Material, Catalysis Today., 106: 193–196 (2005).
5
[6] Pal A., Kachhwaha S., Waste Cooking Oil: A Promising Feedstock for Biodiesel Production Through Power Ultrasound and Hydrodynamic Cavitation, Journal of Scientific and Industrial Research, 72 (2013).
6
[7] Mazubert A., Taylor C., Aubin J., ad Poux M., Key Role of Temperature Monitoring in Interpretation of Microwave Effect on Transesterification and Esterification Reactions for Biodiesel Production, BioresourseTechnolgy, 161 (2014).
7
[8] Chuah L.F., Yusup S., AbdAziz A.R., Bokhari A., Jaromír K., MohdZamri A., Intensification of Biodiesel Synthesis from Waste Cooking Oil (Palm Olein) in a Hydrodynamic Cavitation Reactor: Effect of Operating Parameters on Methyl Ester Conversion, Chemical Engineering and Processing, 95: 235-240 (2015).
8
[9] Mellouk H., Meullemiestre A., Maache-Rezzoug Z., Bejjani B., Dani A., and Rezzoug S.A.,Valorization of Industrial Wastes from French Maritime Pine Bark by Solvent free Microwave Extraction of Volatiles. J. Clean. Prod., 112 (Part 5), 4398-4405 (2016).
9
[10] Motasemi F., Ani F.N., A Review on Microwave-Assisted Production of Biodiesel, Sustain. Energy Rev., 16 (2012).
10
[11] Qiu Z., Zhao L., Weatherley L., Process Intensification Technologies in Continuous Biodiesel Production, Chem. Eng. Process., 49 (2010).
11
[12] YusupS., Bokhari A., Chuah L.F., Ahamd J., Pre-Blended Methyl Esters Production from Crude Palm and Rubber Seed Oil via Hydrodynamic Cavitation Reactor, Chem. Eng. Trans., 43: 517-522 (2015).
12
[13] Pal A., Verma A., Kachhwaha S., Maji S., Biodiesel Production Through Hydrodynamic Cavitation and Performance Testing, Renewable Energy, 35: 619-624 (2010).
13
[14] Nithin T., Jain N., Hiriyannaiah A., Optimization of Venturi Flow Meter Model for the Angle of Divergence with Minimal Pressure Drop by Computational Fluid Dynamics Method, Industrial Engineering and Management Studies (2012).
14
[15] Kumar J., Singh J., Kansal H., “Singh Narula G., Singh P., CFD Analysis of Flow Through Venturi”, IJRMET .4, 2 (2014).
15
[16] Benbella A., Shannak A., Frictional Pressure Drop of Gas Liquid Two-Phase Flow in Pipes Nuclear Engineering and Design, 238 (2008).
16
[17] Bhramara P., Rao V.D., Sharma K.V., Reddy T.K.K., CFD Analysis of Two Phase Flow in a Horizontal Pipe-Prediction of Pressure Drop, Industrial and Aerospace Engineering, 3: 2 (2009).
17
[18] Hari P., Vijay, Subrahmanya V., CFD Simulation on Different Geometries of Venturimeter IJRET, 03,07(2014).
18
[19] Ghayal D., Pandit A.B., Rathod V.K., Optimization of Biodiesel Production in a Hydrodynamic Cavitation Reactor Using Used Frying Oil, Ultrason. Sonochemistry, 20: 322-328 (2013).
19
[20] Chuah L.F., JaromírKlemesJ., Yusup S., Bokhari A., Majeed Akbar M., Cleaner Production of Rubber Seed Oil Methyl Ester Using a Hydrodynamic Cavitation: Optimisation and Parametric Study, Journal of Cleaner Production, 136: 1-13 (2016).
20
[21] FujunW., “Analyze to CFD (Computational Fluid Dynamics)”, Beijing Tsinghua University Press, (2004).
21
[22] Sajjadi B., Abdul Aziz A.R., Ibrahim S., Mechanistic Analysis of Cavitation Assisted Transesterification on Biodiesel Characteristics, Ultrason. Sonochemistry, 22: 463-473(2015).
22
ORIGINAL_ARTICLE
Pyrolysis–Gas Chromatography of Lakhra Coal: Effect of Temperature and Inorganic Matter on the Product Distribution
The objective of this article was to study the effect of pyrolysis temperature and mineral matter on the distribution of the products of C1-C6 hydrocarbons. Pakistani lignite named Lakhra 6B was used to study the effect of inorganic substances on the reactivity of coal. The experiments were performed using pyrolysis gas chromatography to investigate the activity of virgin coal, HCl acid-washed coal, and acid-washed coal with (Ca(C2H3O2)2, Mg(C2H3O2)2, NaC2H3O2, KC2H3O2), added respectively. The products obtained were monitored by a gas chromatograph. The main products identified were methane, ethane, ethylene, propane, 1-butene, n-butane, 1-pentene, n-pentane, and benzene. The results showed that coal conversion to methane increased with an increase in temperature and the amount of this hydrocarbon was high among all the hydrocarbons formed. It was observed that the addition of metal ions affected the yields of the products selectively. The yield of benzene was observed to be high in the case of calcium and magnesium form coals. The other cations form coals produced a smaller quantity of benzene in the temperature range studied. From the results, it can be concluded that metal ions played a selective role in controlling the yield of C1-C6 hydrocarbons products from coal pyrolysis in general and benzene yield in particular.
https://ijcce.ac.ir/article_39705_df7a4cd97c8d3bf00fc1ac30f771271e.pdf
2019-12-01
297
305
10.30492/ijcce.2019.39705
Lignite coal
Pyrolysis-gas chromatography
Mineral matter
Temperature
Product distribution
Jan
Nisar
pashkalawati@gmail.com
1
National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar-25120, PAKISTAN
LEAD_AUTHOR
Iftikhar Ahmad
Awan
iftiawan_99@yahoo.com
2
National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar-25120, PAKISTAN
AUTHOR
Munawar
Iqbal
bosalvee@yahoo.com
3
Department of Chemistry, The University of Lahore, Lahore, PAKISTAN
AUTHOR
Mazhar
Abbas
mazhar381@yahoo.com
4
Jhang-Campus, University of Veterinary & Animal Sciences, Lahore, PAKISTAN
AUTHOR
Sirajuddin
---
5
International Center for Chemical and Biological Sciences, HEJ Research Institute of Chemistry, University of Karachi, Karachi 75270, Pakistan
AUTHOR
[1] Khan Z., “Pakistan Coal Power Generation Potential”, Private Power and Infrastructure Board Pakistan,
1
1–64 (2004).
2
[2] Hu D., Guo Z., Wang Z., Xiao Q., Metabolism Analysis and Eco-Environmental Impact assessment of Two Typical Cement Production Systems in Chinese Enterprises, Ecol. Inform, 26:70-77 (2015).
3
[3] Wang W., Dong C., Dong W., Yang C., Ju T., Huang L., Zongming R., The Design and Implementation of Risk Assessment Model for Hazard Installations Based on AHP–FCE Method: A Case study of Nansi Lake Basin, Ecol. Inform, 36: 162-171 (2015).
4
[4] Xia X.H., Hu Y., Alsaedi A., Hayat T., Wu X.D., Chen GQ., Structure Decomposition Analysis for Energy-related GHG Emission in Beijing: Urban Metabolism and Hierarchical Structure, Ecol. Inform, 26:60-69 (2015).
5
[5] Yang Q., Guo S., Yuan WH., Shen Q., Chen YQ., Wang XH., WU TH., Chen Z-M., Alsaedi A., Hayat T., Energy-Dominated Carbon Metabolism: A Case Study of Hubei Province, China, Ecol. Inform, 26: 85-92 (2015).
6
[6] Zhang B., Chen Z.M., Qiao H., Chen B., Hayat T., Alsaedi A., China's Non-CO2 Greenhouse Gas Emissions: Inventory and Input–Output Analysis, Ecol. Inform., 26:101-110(2015).
7
[7] Ellis N., Masnadi MS., Roberts DG., Kochanek MA., Ilyushechkin AY., Mineral Matter Interactions During co-pyrolysis of Coal and Biomass and Their Impact on Intrinsic Char co-gasification Reactivity, Chem. Eng. J., 279:402-408 (2015).
8
[8] Wei X., Zhang G., Cai Y., Li L., Li H., The Volatilization of Trace Elements During Oxidative Pyrolysis of a Coal from an Endemic Arsenosis Area in Southwest Guizhou, China, J. Anal. Appl. Pyrol., 98:184-193(2012).
9
[9] Fernandez-Turiel J-L., Georgakopoulos A., Gimeno D., Papastergios G., Kolovos N., Ash Deposition in a Pulverized Coal-Fired Power Plant After High-Calcium Lignite Combustion, Energy. Fuel, 18:1512-1518(2004).
10
[10] Zhu W., Song W., Lin W., Catalytic Gasification of Char from co-pyrolysis of Coal and Biomass, Fuel Proces. Technol., 89: 890-896 (2008).
11
[11] Sadhukhan A.K., Gupta P., Goyal T., Saha RK., Modelling of Pyrolysis of Coal–Biomass Blends Using Thermogravimetric Analysis, Bioresource Technol., 99: 8022-8026 (2008).
12
[12] Amin M.N., Li Y., Razzaq R., Lu X., Li C., Zhang S., Pyrolysis of low Rank Coal by Nickel Based Zeolite Catalysts in the Two-Staged Bed Reactor, J. Anal. Appl. Pyrol.,118: 54-62 (2016).
13
[13] Bičáková O., Straka P., Co-pyrolysis of Waste Tire/Coal mixtures for Smokeless Fuel, Maltenes and Hydrogen-Rich Gas Production, Energy. Convers. Manage.,116:203-213(2016).
14
[14] Chen Z., Shi Y., Lai D., Gao S., Shi Z., Tian Y., Xu G., Coal Rapid Pyrolysis in a Transport Bed under Steam-Containing Syngas Atmosphere Relevant to the Integrated Fluidized Bed Gasification, Fuel, 176:200-208(2016).
15
[15] Dai B., Zhang L., Cui J-f., Hoadley A., Zhang L., Integration of Pyrolysis and Entrained-bed Gasification for the Production of Chemicals from Victorian Brown Coal - Process Simulation and Exergy Analysis, Fuel Proces. Technol., 155: 21-31 (2017).
16
[16] Jia X., Wang Q., Cen K., Cheng L., Sulfur Transformation During the Pyrolysis of Coal Mixed with Coal Ash in a Fixed Bed Reactor, Fuel., 177: 260-267(2016).
17
[17] Luo K., Zhang C., Zhu S., Bai Y., Li F., Tar Formation During Coal Pyrolysis under N2 and CO2 Atmospheres at Elevated Pressures, J. Anal. Appl. Pyrol., 118: 130-135 (2016).
18
[18] Montiano M.G., Díaz-Faes E., Barriocanal C., Kinetics of co-Pyrolysis of Sawdust, Coal and Tar, Bioresource Technol.,205:222-229(2016).
19
[19] Mushtaq F., Mat R., Ani F.N., Fuel Production from Microwave Assisted Pyrolysis of Coal with Carbon Surfaces, Energ. Conver. Manage., 110: 142-153 (2016).
20
[20] Niu Z., Liu G., Yin H., Wu D., Zhou C., Investigation of Mechanism and Kinetics of Non-Isothermal Low Temperature Pyrolysis of Perhydrous Bituminous Coal by in-Situ FT-IR, Fuel., 172: 1-10 (2016).
21
[21] Qu Y., Chu M., Shen G-d., Yuan Y., Zhang Y., Inhibitory Effect of Coal Direct Liquefaction Residue on Lignite Pulverization During co-Pyrolysis, Fuel Proces. Technol.,147: 57–63 (2016).
22
[22] Wang X., Guo H., Liu F., Hu R., Wang M., Effects of CO2 on Sulfur Removal and Its Release Behavior During Coal Pyrolysis, Fuel, 165: 484-489 (2016).
23
[23] Wu Z., Wang S., Zhao J., Chen L., Meng H., Thermochemical Behavior and Char Morphology Analysis of Bended Bituminous Coal and Lignocellulosic Biomass Model Compound co-Pyrolysis: Effects of Cellulose and Carboxymethylcellulose Sodium, Fuel, 171: 65-73 (2016).
24
[24] Zellagui S., Schönnenbeck C., Zouaoui-Mahzoul N., Leyssens G., Authier O., Thunin E., Porcheron L. , Brilhac J-F., Pyrolysis of Coal and Woody Biomass under N2 and CO2 Atmospheres Using a Drop Tube Furnace - Experimental Study and Kinetic Modeling, Fuel Proces. Technol., 148: 99-109 (2016).
25
[25] Zhong M., Gao S., Zhou Q., Yue J., Ma F., Xu G., Characterization of Char from High Temperature Fluidized Bed Coal Pyrolysis in Complex Atmospheres, Particuology, 25: 59-67 (2016).
26
[26] Pervaiz M., Butt K.M., Raza M.A., Rasheed A., Ahmad S., Adnan A., Iqbal M., Extraction and Applications of Aluminum Hydroxide from Bauxite for Commercial Consumption, Chem. Int., 1: 99-102 (2015).
27
[27] Liu Q., Hu H, Zhou Q., Zhu S., Chen G., Effect of Inorganic Matter on Reactivity and Kinetics of coal Pyrolysis, Reprints of Symposia-American Chemical Society, Division of Fuel Chemistry, 48: 368-369 (2003).
28
[28] Franklin HD., Peters W.A., Howard J.B., Mineral Matter Effects on the Rapid Pyrolysis and Hydropyrolysis of a Bituminous Coal. 1. Effects on Yields of Char, tar and Light Gaseous Volatiles, Fuel, 61:155-160 (1982).
29
[29] Franklin H.D., Peters W.A., Howard J.B., Mineral Matter Effects on the Rapid Pyrolysis and Hydropyrolysis of a Bituminous Coal: 2. Effects of Yields of C3-C8 Hydrocarbons, Fuel, 61: 1213-1217(1982).
30
[30] Wu H., Hayashi J-i., Chiba T., Takarada T., Li C-Z., Volatilisation and Catalytic Effects of Alkali and Alkaline Earth Metallic Species During the Pyrolysis and Gasification of Victorian Brown Coal. Part V. Combined Effects of Na Concentration and Char Structure on Char Reactivity, Fuel, 83: 23-30 (2004).
31
[31] Awan I.A., Nisar J., Yamin A., Mahmood T., Pyrolysis of Metal Ions Exchanged Coal, J. Chem. Soc. Pak., 25: 88-92 (2003).
32
[32] Nisar J., Awan I.A., Ahmad T., Naz G., Analysis of Aliphatic and Aromatic Hydrocarbons Resulting from Pakistani Coals by Pyrolysis-Gas Chromatography, J. Chem. Soc. Pak.,2 9: 247-250 (2007).
33
[33] Ahmad T., Awan I.A., Nisar J., Ahmad I., Influence of Inherent Minerals and Pyrolysis Temperature on the Yield of Pyrolysates of Some Pakistani Coals, Energ. Convers. Manage., 50: 1163-1171 (2009).
34
[34] Giam C.S., Goodwin T.E., Giam P.Y., Rion K.F., Smith S.G., Characterization of Lignites by Pyrolysis Gas Chromatography, Anal. Chem., 49: 1540–1543(1977).
35
[35] van Heek K.H., Hodek W., Structure and Pyrolysis Behaviour of Different Coals and Relevant Model Substances, Fuel, 73: 886-896 (1994).
36
[36] Xu Y., Zhang Y., Wang Y., Zhang G., Chen L., Gas Evolution Characteristics of Lignite During Low-Temperature Pyrolysis, J. Anal. Appl. Pyrol., 104: 625-631 (2013).
37
[37] Zhang Y., Liang P., Jiao T., Wu J., Zhang H., Effect of Foreign Minerals on Sulfur Transformation in the Step Conversion of Coal Pyrolysis and Combustion, J. Anal. Appl. Pyrol., 127: 240-245 (2017).
38
[38] Kou J-W., Bai Z-Q., Bai J., Guo Z-X., Li W., Effects of Mineral Matter and Temperatures on Conversion of Carboxylic Acids and Their Derivatives During Pyrolysis of Brown Coals, Fuel Proces. Technol., 152: 46 -55 (2016).
39
[39] Li R., Chen Q., Xia H., Study on Pyrolysis Characteristics of Pretreated High‑Sodium (Na) Zhundong Coal by Skimmer-Type Interfaced TG-DTA-EI/PI-MS System, Fuel Proces. Technol., 170: 79 -87 (2018).
40