ORIGINAL_ARTICLE
Surface Modification of Carbon Nanotubes as a Key Factor on Rheological Characteristics of Water-Based Drilling Muds
This study investigates the effect of functionalized Multi-Walled Carbon NanoTube (f-MWCNT) on rheological properties of water-based drilling muds. Functionalization of multi-walled carbon nanotube was performed by introducing a hydrophilic functional group onto the surface of nanotubes via acid treatment. In order to guarantee the results, X-ray fluorescence, transmission electron microscopy, and thermogravimetric analysis were performed on samples. Temperature and mud density variations were also considered along with the effect of f-MWCNT addition. Furthermore, a novel study was performed on the influence of the degree of functionalization on plastic viscosity and yield stress of drilling mud samples. The results obtained from this study revealed that the addition of f-MWCNT greatly affects the rheological characteristics of water-based drilling muds like plastic viscosity, apparent viscosity, yield stress, and thixotropic properties. Moreover, test results indicated that the shear stress versus shear rate diagram fitted well the Herschel-Bulkley rather than the Bingham plastic model.
https://ijcce.ac.ir/article_28219_06453170c9bf97fb11379f0c0e96c79c.pdf
2018-08-01
1
14
10.30492/ijcce.2018.28219
Carbon Nanotube
degree of functionalization
water-based drilling fluid
plastic viscosity
yield stress
Amin
Kazemi-Beydokhti
a.kazemi@hsu.ac.ir
1
Petroleum and Petrochemical Engineering School, Hakim Sabzevari University, Sabzevar, I.R. IRAN
LEAD_AUTHOR
Seyed Hasan
Hajiabadi
s.h.hajiabadi@hsu.ac.ir
2
Petroleum and Petrochemical Engineering School, Hakim Sabzevari University, Sabzevar, I.R. IRAN
AUTHOR
Ali
Sanati
a.sanati@hsu.ac.ir
3
Petroleum and Petrochemical Engineering School, Hakim Sabzevari University, Sabzevar, I.R. IRAN
AUTHOR
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[31] Kazemi-Beydokhti A., Heris S.Z., Jaafari M., Experimental Investigation of Thermal Conductivity of Medical Nanofluids Based on Functionalised Single-Wall Carbon Nanotube and Conjugated Cisplatin, IET Micro & Nano Letters, 10(5): 241-247 (2015).
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35
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36
ORIGINAL_ARTICLE
Fischer–Tropsch Synthesis with Cu-Co Nanocatalysts Prepared Using Novel Inorganic Precursor Complex
The structural properties and activities of Cu-Co catalysts used in Fischer-Tropsch synthesis are explored according to their method of preparation. Impregnation, co-precipitation, and a novel method of thermal decomposition were applied to an inorganic precursor complex to generate the Cu-promoted alumina- and silica-supported cobalt catalysts. The precursors and the catalysts obtained by their calcination underwent powder x-ray diffraction, thermal gravimetric analysis, specific surface area measurement using the Brunauer-Emmett-Teller method, scanning electron microscopy, and Fourier Transform InfraRed (FT-IR) spectroscopy. The catalytic performance of all calcined catalysts used in Fischer-Tropsch synthesis was investigated at 280 to 360 °C. The Cu-Co/SiO2 catalyst was prepared by thermal decomposition of [Cu(H2O)6][Co(dipic)2].2H2O/SiO2, which served as an optimal precursor for synthesis gas conversion into light olefins. The results highlight the advantages of this novel procedure over impregnation and co-precipitation approaches for effective and durable preparation of cobalt catalysts for Fischer-Tropsch synthesis.
https://ijcce.ac.ir/article_31588_d412d67447b947529e5e143e537f2e43.pdf
2018-08-01
15
26
10.30492/ijcce.2018.31588
Fischer-Tropsch synthesis
Preparation method
Novel precursor
complex
Bimetallic nanocatalyst
Javad
Farzanfar
javadfr@pgs.usb.ac.ir
1
Department of Chemistry, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, I.R. IRAN
AUTHOR
Ali Reza
Rezvani
ali@hamoon.usb.ac.ir
2
Department of Chemistry, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, I.R. IRAN
LEAD_AUTHOR
[1] Trépanier M., Tavasoli A., Anahid S., K. Dalai A., Deactivation Behavior of Carbon Nanotubes Supported Cobalt Catalysts in Fischer-Tropsch Synthesis, Iran. J. Chem. Chem. Eng. (IJCCE), 30(1): 37-47 (2011).
1
[2] Mirzaei A.A., Shahriari S., Arsalanfar M., Effect of Preparation Conditions on the Catalytic Performance of Co/Ni Catalysts for CO Hydrogenation, J. Nat. Gas. Sci. Eng., 3(4): 537–546 (2011).
2
[3] Feyzi M., Mirzaei A.A., Preparation and Characterization of CoMn/TiO2 Catalysts for Production of Light Olefins, Iran. J. Chem. Chem. Eng. (IJCCE), 30(1): 17-28 (2011).
3
[4] Zare A., Zare A., Shiva M., Mirzaei A.A., Effect of Calcination and Reaction Conditions on the Catalytic Performance of Co–Ni/Al2O3 Catalyst for CO Hydrogenation, J. Ind. Eng. Chem., 19(6): 1858–1868 (2013).
4
[5] Tavasoli A., Karimi A., Khodadadi A.A., Mortazavi Y., Mousavian M.A., Accelerated Deactivation and Activity Recovery Studies of Ruthenium and Rhenium Promoted Cobalt Catalysts in Fischer-Tropsch Synthesis, Iran. J. Chem. Chem. Eng. (IJCCE), 24(4): 25-36 (2005).
5
[6] Tavasoli A., Anahid S., Nakhaeipour A., Effects of Confinement in Carbon Nanotubes on the Performance and Lifetime of Fischer-Tropsch Iron Nano Catalysts, Iran. J. Chem. Chem. Eng. (IJCCE), 29(3): 1-12 (2010).
6
[7] Tavasoli A., Sadaghiani K., Nakhaeipour A., Ahangari M., Cobalt Loading Effects on the Structure and Activity for Fischer-Tropsch and Water-Gas Shift Reactions of Co/Al2O3 Catalysts, Iran. J. Chem. Chem. Eng. (IJCCE), 26(1): 9-16 (2007).
7
[8] De La Osa A.R., De Lucas A., Romero A., Valverde J.L., Sánchez P., Influence of the Catalytic Support on the Industrial Fischer-Tropsch Synthetic Diesel Production, Catal. Today, 176: 298-302 (2011).
8
[9] Ali S., Zabidi N.A.M., Al-Marri M.J., Khader M.M., Effect of the Support on Physicochemical Properties and Catalytic Performance of Cobalt Based Nano-Catalysts in Fischer-Tropsch Reaction, Mater. Today Commun., 10: 67–71 (2017).
9
[10] Vosoughi V., Badoga S., Dalai A.K., Abatzoglou N., Modification of Mesoporous Alumina as a Support for Cobalt-Based Catalyst in Fischer-Tropsch Synthesis, Fuel Process. Technol., 162: 55–65 (2017).
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[11] Jalama K., Coville N.J., Xiong H., Hildebrandt D., Glasser D., Taylor S., Carley A., Anderson J.A., Hutchings G.J., A Comparison of Au/Co/Al2O3 and Au/Co/SiO2 Catalysts in the Fischer–Tropsch Reaction, Appl. Catal. A., 395(1-2): 1–9 (2011).
11
[12] Sun Y., Yang G., Zhang L., Sun Z., Fischer-Tropsch Synthesis in a Microchannel Reactor Using Mesoporous Silica Supported Bimetallic Co-Ni Catalyst: Process Optimization and Kinetic Modeling, Chem. Eng. Process. Process Intensif., 119: 44–61 (2017).
12
[13] Mirzaei A.A., Sarani R., Azizi H.R., Vahid S., Oliaei-Torshizi H., Kinetics Modeling of Fischer–Tropsch Synthesis on the Unsupported 4 Fe–Co–Ni (Ternary) Catalyst Prepared Using co-Precipitation Procedure, Fuel, 140: 701–710 (2015).
13
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[15] Feyzi M., Mirzaei A.A., Catalytic behaviors of Co-Mn/TiO2 Catalysts for Fischer–Tropsch Synthesis, J. Fuel Chem. Technol., 40(12): 1435–1443 (2012).
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[16] Lögdberg S., Lualdi M., Järås S., Walmsley J.C., Blekkan E.A., Rytter E., Holmen A., On the Selectivity of Cobalt-Based Fischer–Tropsch Catalysts: Evidence for a Common Precursor for Methane and Long-Chain Hydrocarbons, J. Catal., 274(1): 84–98 (2010).
16
[17] Hadadzadeh H., Rezvani A.R., Salehi Rad A.R., Khozeymeh E., A Novel Method for Preparation of Alumina-Supported Rhenium-Cesium Catalyst, Re-Cs/γ-Al2O3, Iran. J. Chem. Chem. Eng. (IJCCE), 27(3): 37-43 (2008).
17
[18] Farzanfar J., Rezvani A.R., Study of a Mn–Cr/TiO2 Mixed Oxide Nanocatalyst Prepared via an Inorganic Precursor Complex for High-Temperature Water–Gas Shift Reaction, C. R. Chimie, 18(2): 178–186 (2015).
18
[19] Farzanfar J., Rezvani A.R., Inorganic Complex Precursor Route for Preparation of High-Temperature Fischer–Tropsch Synthesis Ni–Co Nanocatalysts, Res. Chem. Intermed., 41(11): 8975–9001 (2015).
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23
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[25] Shakirova O.G., Lavrenova L.G., Korotaev E.V., Kuratieva N.V., Kolokolov F.A., Burdukov A.B., Structure and Spin Crossover in an Iron (II) Compound with Tris(pyrazol-1-yl)methane and the Complex Eu(dipic)2(Hdipic)]2– Anion, J. Struct. Chem., 57: 471-477 (2016).
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[26] Siddiqi Z.A., Khalid M., Shahid M., Kumar S., Sharma P.K., Siddique A., Anjuli, H-bonded Supramolecular Assembly via Proton Transfer: Isolation, X-Ray Crystallographic Characterization and SOD Mimic Activity of [Cu(dipic)2]2[PA-H]4. 5H2O, J. Mol. Struct., 1033: 98-103 (2013).
26
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[29] Renuka N.K., Shijina A.V., Praveen A.K., Mesoporous γ-Alumina Nanoparticles: Synthesis, Characterization and Dye Removal Efficiency, Mater. Lett., 82: 42–44 (2012).
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[30] Damayanti N.P., Preparation of Superhydrophobic PET Fabric from Al2O3–SiO2 Hybrid: Geometrical Approach to Create High Contact Angle Surface from Low Contact Angle Materials, J. Sol-Gel Sci. Technol., 56(1): 47–52 (2010).
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[33] Tian L., Huo C.F., Cao D.B., Yang Y., Xu J., Wu B.S., Xiang H.W., Xu Y.Y., Li Y.W., Effects of Reaction Conditions on Iron-Catalyzed Fischer–Tropsch Synthesis: A Kinetic Monte Carlo Study, J. Mol. Struct. THEOCHEM, 941(1-3): 30–35 (2010).
33
ORIGINAL_ARTICLE
Improving the Proton Conductivity and Antibacterial Properties of Sulfonated Polybenzimidazole/ZnO/Cellulose with Surface Functionalized Cellulose/ZnO Bionanocomposites
New bionanocomposite proton exchange membranes were prepared from sulfonated polybenzimidazole (s-PBI) and various amounts of sulfonated ZnO/cellulose nanohybrids (ZnO/cellulose-SO3H). The use of ZnO/cellulose-SO3H compensates for the decrease in ion exchange capacity of membranes observed when non-sulfonated nano-fillers are utilized. The strong –SO3H/–SO3H interaction between s-PBI chains and ZnO/cellulose-SO3H hybrids leads to ionic cross-linking in the membrane structure, which increases both the thermal stability and methanol resistance of the membranes. The ZnO/cellulose -SO3H in the membranes served as spacers for polymer chains to provide extra space for water permeation, so as to bring high permeation rates to the complex membranes. Moreover, the membranes exhibited excellent antibacterial activities against S. aureus and E. coli. A.
https://ijcce.ac.ir/article_28570_d9e21dc44142358dbdab620f58dac25d.pdf
2018-08-01
27
42
10.30492/ijcce.2018.28570
sulfonated polybenzimidazole
proton exchange
ZnO/cellulose
Antibacterial
Hashem
Ahmadizadegan
h.ahmadizadegan.2005@gmail.com
1
Department of Chemistry, Darab Branch, Islamic Azad University, Darab, I.R. IRAN
LEAD_AUTHOR
Sheida
Esmaielzadeh
esmaielzadehsheida@yahoo.com
2
Department of Chemistry, Darab Branch, Islamic Azad University, Darab, I.R. IRAN
AUTHOR
Mahdi
Ranjbar
3
Department of Chemistry, Darab Branch, Islamic Azad University, Darab, I.R. IRAN
AUTHOR
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[2] Glipa X., Bonnet B., Mula B., Jones D.J., Rozière J., Investigation of the Conduction Properties of Phosphoric and Sulfuric Acid Doped Polybenzimidazole, J. Mater. Chem., 9: 3045-3049 (1999).
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[3] Ma Y.L., Wainright J.S., Litt M.H., Savinell R.F., Conductivity of PBImembranes for High-Temperature Polymer Electrolyte Fuel Cells, J. Electrochem. Soc., 151: A8-A16 (2004).
3
[4] Li Q., He R., Jensen J.O., Bjerrum N.J., PBI-Based Polymer Membranes for High Temperature Fuel Cells-Preparation, Characterization, and Fuel Cell Demonstration, Fuel Cells, 4: 147-159 (2004).
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[5] Li Q., He R., Berg R.W., Hjulers H.A., Bjerrum N.J., Water Uptake and Doping of Polybenzimidazoles as Electrolyte Membranes for Fuel Cells, Solid State Ionics, 168: 177-185 (2004).
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[6] Asensio J.A., Borrós S., Gómez-Romero P., Polymer Electrolyte Fuel Cells Based on Phosphoric-Acid Impregnated Poly(2,5-benzimidazole) Membranes, J. Electrochem. Soc., 151: A304-A310 (2004).
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[13] Qing S., Huang W., Yan D., Synthesis and Characterization of Thermally Stable Sulfonated Polybenzimidazoles Obtained from 3,3-disulfonyl-4,4- dicarboxyldiphenylsulfone, J. Polym. Sci. Part A: Polym. Chem., 43: 4363-4372 (2005)
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[14] Qing S., Huang W., Yan D., Synthesis and Properties of Soluble Sulfonated Polybenzimidazoles, React. Funct. Polym., 66: 219-227 (2006).
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[18] Taherkhani M., Chemical Investigation and Protective Effects of Bioactive Phytochemicals from Artemisia Ciniformis, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 15-26 (2016).
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[21] Inoue K., Ferrante P., Hirano Y., Yasukawa T., Shiku H., Matsue T., A Competitive Immunochromatographic Assay for Testosterone Based on Electrochemical Detection, Talanta, 73: 886-892 (2007).
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[28] Ahmadizadegan H., Effect of Adding Nanoclay (Cloisite-30B) on the Proton Conductivity of Sulfonated Polybenzimidazole, Nanochem Res., 2: 96-108 (2017).
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[35] Perelshtein I., Ruderman E., Perkas N., Tzanov T., Beddow J., Joyce E., Mason T.J., Blanes M., Molla K., Patlolla A., Chitosan and Chitosan-ZnO-Based Complex Nanoparticles: Formation, Characterization, and Antibacterial Activity,
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[36] Anitha S., Brabu B., Thiruvadigal D.J., Gopalakrishnan C., Natarajan T.S., Optical, Bactericidal and Water Repellent Properties of Electrospun Nano-composite Membranes of Cellulose Acetate and ZnO, Carbohydr. Polym., 97: 855-855 (2013).
37
ORIGINAL_ARTICLE
Soybean Oil Transesterification Reactions in the Presence of Mussel Shell: Pseudo-First Order Kinetics
Calcium oxide is one of the appropriate catalysts for biodiesel production. In this study, cheap and compatible with environment catalyst has been used. Mussel shell of Persian Gulf coast is one of the sources of calcium carbonate that is converted to calcium oxide at calcination temperature up to 950°C. Transesterification reaction was carried out at optimum condition of our previous study (calcination temperature of 1050°C, methanol to oil ratio of 24:1 and catalyst to oil ratio of to 12 wt.%) in a 250mL two-necked flask. In this study, the effects of stirrer speed (250 and 350rpm), the reaction temperature (328.15, 333.15, and 338.15K) and reaction time (1, 3, 5, 7 and 8h) on the methyl ester conversion were investigated. The methyl ester conversion, in stirrer speed of 250rpm, reaction temperatures of 328.15 and 333.15K and reaction times of less than 5h is too low. But at the reaction temperature of 338.15K (near to methanol boiling point), the mixing is increased slightly and the reaction occurs at a higher rate and the methyl ester conversion is increased. These results indicate that diffusion has a significant role in the methyl ester conversion rate in the heterogeneously catalyzed reaction. In stirrer speed of 350rpm, the diffusion problem has been solved somewhat and the reaction in the catalyst surface is the controller of the overall reaction rate. In this stirrer speed (350rpm) the methyl ester conversion versus time in all temperature shows pseudo-first-order kinetics. Firstly, the rate was determined at the various temperatures and then the activation energy for the transesterification reaction of soybean oil with methanol was obtained in the presence of mussel shell as the catalyst. Results demonstrate the high precision of the pseudo-first-order kinetics model regard to methyl esters concentration.
https://ijcce.ac.ir/article_28217_d76d46117553c47ade17297895b4438a.pdf
2018-08-01
43
51
10.30492/ijcce.2018.28217
Biodiesel
Kinetics
Heterogeneous catalyst
mussel shell
Transesterification
Majid
Mohadesi
m.mohadesi@gmail.com
1
Chemical Engineering Department, Faculty of Energy, Kermanshah University of Technology, Kermanshah, I.R. IRAN
LEAD_AUTHOR
Gholamreza
Moradi
moradi_m@yahoo.com
2
Catalyst Research Center, Faculty of Chemical and Petroleum Engineering, Razi University, Kermanshah, I.R. IRAN
AUTHOR
Yegane
Davoodbeygi
y.davoodbeygi@yahoo.com
3
Catalyst Research Center, Faculty of Chemical and Petroleum Engineering, Razi University, Kermanshah, I.R. IRAN
AUTHOR
Shokoufe
Hosseini
shokoufe.hosseini@yahoo.com
4
Catalyst Research Center, Faculty of Chemical and Petroleum Engineering, Razi University, Kermanshah, I.R. IRAN
AUTHOR
[1] Semwal S., Arora A.K., Badoni R.P., Tuli D.K., Biodiesel Production Using Heterogeneous Catalysts, Bioresour. Technol., 102(3): 2151–2161 (2011).
1
[2] Marchetti J.M., Errazu A.F., Comparison of Different Heterogeneous Catalysts and Different Alcohols for the Esterification Reaction of Oleic Acid, Fuel, 87(15-16): 3477–2480 (2008).
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[3] Kaur M., Ali A., Lithium ion Impregnated Calcium Oxide as Nano Catalyst for the Biodiesel Production from Karanja and Jatropha Oils, Renew. Energy, 36(11): 2866-2871 (2011).
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[4] Rao G.P.C., Azeez S.A., Krishna R.V., Kumar C.N., Performance & Evaluation of Diesel Engine (4-stroke 1-cylinder) Using Jatropha Oil Blends with Super Charging Method, Int, J, Mod, Trends Sci, Technol., 3(7): 50-59 (2017).
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[5] Tang Y., Meng M., Zhang J., Lu Y., Efficient Preparation of Biodiesel from Rapeseed Oil over Modified CaO, Appl. Energy, 88(8): 2735–2739 (2011).
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[6] Meher L.C., Sagar D.V., Naik S.N., Technical Aspects of Biodiesel Production by Transesterification—a Review, Renew. Sust. Energy Rev., 10(3): 248–268 (2006).
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[7] Taufiq-Yap Y.H., Lee H.V., Hussein M.Z., Yunus R., Calcium-Based Mixed Oxide Catalysts for Methanolysis of Jatropha Curcas Oil to Biodiesel, Biomass Bioenergy, 35(2): 827-834 (2011).
7
[8] Chen C.-L., Huang C.-C., Tran D.-T., Chang J.-S., Biodiesel Synthesis via Heterogeneous Catalysis Using Modified Strontium Oxides as the Catalysts, Bioresour. Technol., 113(1): 8-13 (2012).
8
[9] Tang S., Wang L., Zhang Y., Li S., Tian S., Wang B., Study on Preparation of Ca/Al/Fe3O4 Magnetic Composite Solid Catalyst and its Application in Biodiesel Transesterification, Fuel Process. Technol., 95(1): 84–89 (2012).
9
[10] Kouzu M., Kasuno T., Tajika M., Yamanaka S., Hidaka J., Active Phase of Calcium Oxide Used as Solid Base Catalyst for Transesterification of Soybean oil with Refluxing Methanol, Appl. Catal., A, 334(1-2): 357–365 (2008).
10
[11] Dossin T.F., Reyniers M.-F., Berger R.J., Marin G.B., Simulation of Heterogeneously MgO-Catalyzed Transesterification for Fine-Chemical and Biodiesel Industrial Production, Appl. Catal., B, 67(1-2): 136–148 (2006).
11
[12] Alba-Rubio A.C., Alonso Castillo M.L., Albuquerqu M.C.G., Mariscal R., Cavalcante Jr. C.L., López Granados M., A New and Efficient Procedure for Removing Calcium Soaps in Biodiesel Obtained Using CaO as a Heterogeneous Catalyst, Fuel., 95(1): 464–470 (2012).
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[13] Kouzu M., Kasuno T., Tajika M., Sugimoto Y., Yamanaka S., Hidaka J., Calcium Oxide as a Solid Base Catalyst for Transesterification of Soybean Oil and Its Application to Biodiesel Production, Fuel., 87(12): 2798-2806 (2008).
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[14] Reddy B.M., Patil M.K., Organic Synthesis and Transformations Catalyzed by Sulfated Zirconia, Chem. Rev., 109(6): 2185-2208 (2009).
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[15] Sasidharam M., Kumar R., Transesterification over Various Zeolites under Liquid-Phase Conditions, J. Mol. Catal. A: Chem., 210(1-2): 93-98 (2004).
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[16] Ngamcharussrivichai C., Benjapornkulaphong S., Bunyakiat K., Al2O3-Supported Alkali and Alkali Earth Metal Oxides for Transesterification of Palm Kernel Oil and Coconut Oil, Chem. Eng. J., 145(3): 468-474 (2008).
16
[17] Kumar D., Ali A., Nanocrystalline Lithium Ion Impregnated Calcium Oxide as Heterogeneous Catalyst for Transesterification of High Moisture Containing Cotton Seed Oil, Energy Fuels., 24(3): 2091-2097 (2010).
17
[18] Salamatinia B., Hashemizadeh I., Zuhairi A.A., Alkaline Earth Metal Oxide Catalysts for Biodiesel Production from Palm Oil: Elucidation of Process Behaviors and Modeling Using Response Surface Methodology, Iran. J. Chem. Chem. Eng. (IJCCE), 32(1): 113-126 (2013).
18
[19] Boey P.-L., Maniam G.P., Hamid S.A., Performance of Calcium Oxide as a Heterogeneous Catalyst in Biodiesel Production: A Review, Chem. Eng. J., 168(1): 15–22 (2011).
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[20] Sivasamy A., Cheah K.Y., Fornasiero P., Kemausuor F., Zinoviev S., Miertus S., Catalytic Applications in the Production of Biodiesel from Vegetable Oils, Chem. Sust. Chem., 2(4):278-300 (2009).
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[21] Nakatani N., Takamori H., Takeda K., Sakugawa H., Transesterification of Soybean Oil Using Combusted Oyster Shell Waste as a Catalyst, Bioresour. Technol., 100(3): 1510–1513 (2009).
21
[22] Boey P.-L., Maniam G.P., Hamid S.A., Biodiesel Production via transesterification of Palm Olein Using Waste Mud Crab (Scylla Serrata) Shell as a Heterogeneous Catalyst, Bioresour. Technol., 100(24): 6362–6368 (2009).
22
[23] Boey P.-L., Maniam G.P., Hamid S.A., Utilization of Waste Crab Shell (Scyllaserrata) as a Catalyst in Palm Olein Transesterification, J. Oleo. Sci., 58(10): 499-502 (2009).
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[24] Viriya-empikul N., Krasae P., Puttasawat B., Yoosuk B., Chollacoop N., Faungnawakij K., Waste Shells of Mollusk and Egg as Biodiesel Production Catalysts, Bioresour. Technol., 101(10): 3765–3767 (2010).
24
[25] Rezaei R., Mohadesi M., Moradi GR., Optimization of Biodiesel Production Using Waste Mussel Shell Catalyst, Fuel, 109(1): 534–541 (2013).
25
[26] Dossin T.F., Reyniers M.-F., Marin G.B., Kinetics of Heterogeneously MgO-Catalyzed Transesterification, Appl. Catal., B, 62(1-2): 35-45 (2006).
26
[27] Veljkovic´ V.B., Stamenkovic´ O.S., Todorovic´ Z.B., Lazic´ M.L., Skala D.U., Kinetics of Sunflower Oil Methanolysis Catalyzed by Calcium Oxide, Fuel, 88(9): 1554-1562 (2009).
27
[28] Birla A., Singh B., Upadhyay S.N., Sharma Y.C., Kinetics Studies of Synthesis of Biodiesel From Waste Frying Oil Using a Heterogeneous Catalyst Derived From Snail Shell, Bioresour. Technol., 106(1): 95–100 (2012).
28
[29] Likozar B., Levec J., Effect of Process Conditions on Equilibrium, Reaction Kinetics and Mass Transfer for Triglyceride Transesterification to Biodiesel: Experimental and Modeling Based on Fatty Acid Composition, Fuel Process. Technol., 122(1):30-41 (2014).
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[30] Likozar B., Levec J., Transesterification of Canola, Palm, Peanut, Soybean and Sunflower Oil with Methanol, Ethanol, Isopropanol, Butanol and Tert-Butanol to Biodiesel: Modelling of Chemical Equilibrium, Reaction Kinetics and Mass Transfer Based on Fatty Acid Composition, Appl. Energy, 123(1): 108-120 (2014).
30
[31] Likozar B., Pohar A., Levec J., Transesterification of Oil to Biodiesel in a Continuous Tubular Reactor with Static Mixers: Modelling Reaction Kinetics, Mass Transfer, Scale-up and Optimization Considering Fatty Acid Composition, Fuel Process. Technol., 142(1):326-336 (2016).
31
[32] Zhang L., Sheng B., Xin Z., Liu Q., Sun S., Kinetics of Transesterification of Palm Oil and Dimethyl Carbonate for Biodiesel Production at the Catalysis of Heterogeneous Base Catalyst, Bioresour. Technol., 101(21): 8144–8150 (2010).
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[33] Vujicic D.J., Comic D., Zarubica A., Micic R., Boskovi G., Kinetics of Biodiesel Synthesis from Sunflower Oil over CaO Heterogeneous Catalyst, Fuel, 89(8): 2054–2061 (2010).
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[35] Singh A.K., Fernando S.D., Reaction Kinetics of Soybean Oil Transesterification Using Heterogeneous Metal Oxide Catalysts, Chem. Eng. Technol., 30(12): 1716–1720 (2007).
35
ORIGINAL_ARTICLE
Enzymatic Hydrolysis of Olive Industry Solid Waste into Glucose, the Precursor of Bioethanol
Olive industry solid waste (OISW) is a by-product generated in the process of olive oil extraction. It is a lignocellulosic material consisting of cellulose, hemicelluloses, lignin and other extractives. In this work, a process for hydrolyzing the OISW into its monomers glucose, the precursor of bioethanol was developed. The hydrolysis process involves two stages: in the first stage, the OISW was activated by treating it with a material that opened the cellulose structure and made it more accessible for chemical reagents. Several activating materials were evaluated among them are water, NaOH, Ca(OH)₂ and acetic acid. In the second stage, the OISW was subjected to an enzymatic treatment which hydrolyzed it into sugar. A combination of the two enzymes cellulase (endo-1,4-β-glucanase) and β-glucosidase was used in the hydrolysis. Best hydrolysis results were obtained at enzymes dose of 15.0 mg of cellulase and 20.0 mg/g of β-glucosidase per one gram of OISW at 45 oC and a pH of 4.8. A yield of 85.02% sugar was obtained from the hydrolysis of 10% NaOH pre-treated OISW under a positive pressure of air. Whereas, hydrolysis of cellulose extracted from OISW by the Kraft pulping process and bleached using DEHP beaching sequence produced about 95.30% sugar.
https://ijcce.ac.ir/article_34840_556594c7a823f1e89626a52cdc81ccb9.pdf
2018-08-01
53
61
10.30492/ijcce.2018.34840
Cellulose
Bioethanol
Enzyme
"jeft" olive
Waste
Kraft
Pulping
Bleaching
Othman
Hamed
ohamed@najah.edu
1
Department of Chemistry, An-Najah National University, Nablus, PALESTINE
LEAD_AUTHOR
Shehdeh
Jodeh
sjodeh@hotmail.com
2
Department of Chemistry, An-Najah National University, Nablus, PALESTINE
AUTHOR
Israa
Dagher
israa_dagher@yahoo.com
3
Department of Chemistry, An-Najah National University, Nablus, PALESTINE
AUTHOR
Rachid
Salghi
r.salghi@uiz.ac.ma
4
Equipe de Génie de l’Environnement et de Biotechnologie, ENSA, Université Ibn Zohr, BP 1136, Agadir, MOROCCO
AUTHOR
Khalil
Azzaoui
k.azzaoui@yahoo.com
5
Laboratory of Mineral Solid and Analytical Chemistry LMSAC, Department of Chemistry, Faculty of Sciences, Mohamed 1st University, P.O. Box 717,Oujda 60000, MOROCCO
AUTHOR
Nisreen
Al-Hajj
n.al-hajj@yahoo.com
6
Department of Chemistry, An-Najah National University, Nablus, PALESTINE
AUTHOR
Wade
Jodeh
wjodeh@yahoo.com
7
Department of Human Medicine, Al-Najah National University, P. O. Box 7, Nablus, PALESTINE
AUTHOR
Ismail
Warad
warad@najah.edu
8
Department of Chemistry, An-Najah National University, Nablus, PALESTINE
AUTHOR
[1] Missaglia M., Valensisi G., Trade Policy in Palestine: A Reassessment, J. Policy Modeling., 36: 899-923 (2014).
1
[2] Azbar N., Bayram A., Filibeli A., Muezzinoglu A, Sengul F., Ozer A., A Review of Waste Management Options in Olive Oil Production., Crit. Rev. Environ. Sci. Technol. 34: 209(2004).
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[3] Ouazzane H., Laajine F., El Yamani M., El Hilaly J., Rharrabti Y., Amarouch MY., Mazouzi D., A Review: Olive Mill Solid Waste Characterization and Recycling Opportunities., Journal of Materials and Environmental Sciences 8(8): 2632-2650 (2017).
3
[4] Aden A., Ruth A., Ibsen K, Jechura J., Neeves K., Sheehan J., Wallace B, National Renewable Energy Laboratory; Montague, L., Slayton A., Lukas A, J. Harris Group Seattle, Washington. "Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Pre-hydrolysis and Enzymatic Hydrolysis for Corn Stover". Report by National Renewable Energy Laboratory, June (2002).
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[5] Yu M., Li J., Chang S., Zhang L., Mao Y., Cui T., Yan Z., Luo C., Li S., Bioethanol Production Using the Sodium Hydroxide Pretreated Sweet Sorghum Bagasse Without Washing., Fuel, 175: 20-25(2016).
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[6] Sassner P., Galbe M., Zacchi G., Steam Pretreatment of Salix with and without SO2 Impregnation for Production of Bioethanol., Applied Biochem and Biotech. 121-124: 1101-1117(2005).
6
[7] Romani A., Garrote G., Ballesteros L., Ballesteros M., Second Generation Bioethanol from Steam Exploded Eucalyptus Globulus Wood., Fuel, 111: 66-74 (2013).
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[8] Corma A., Iborra S., Velty., Chemical Routes for the Transformation of Biomass into Chemicals., Chem. Rev., 07:2411-2502(2007).
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[9] Zhang X, Zhang Y, Cellulases: Characteristics, Sources, Production, and Applications. Bioprocessing Technologies in Biorefinery for Sustainable Production of Fuels, Chemicals, and Polymers". First Edition. Wiley, J. and Inc, S. (2013).
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[10] Huber G., Iborra S., Corma A., Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering., Chem. Rev., 106: 4044- 4098(2006).
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[11] Hamed O., Fouad Y., Hamed E., Al-Hajj N., Cellulose Powder from Olive Industry Solid Waste., BioResources., 7(3): 4190-4201(2012).
11
[12] Sannino A., Demitri C., Madaghiele M., Biodegradable Cellulose-Based Hydrogels:Design and Applications., Materials, 2: 353 - 373(2009).
12
[13] Kumar P., Barrett M., Delwiche M., Stroeve P., Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production, Ind. Eng. Chem. Res., 48(8): 3713-3729 (2009).
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[14] Behera, S., Arora, R., Nandhagopal, N., Kumar, S., Importance of Chemical Pretreatment for Bioconversion of Lignocellulosic Biomass, Renewable and Sustainable Energy Reviews, 36: 91-106 (2014).
14
[15] Georgieva, T.I., Birgitte K.A., Potential of Agroindustrial Waste from Olive Oil Industry for Fuel Ethanol Production, Biotechnology Journal, 2(12): 1547-1555(2007).
15
[16] L. Negahdar L., I. Delidovich I., R. Palkovits R., Aqueous-Phase Hydrolysis of Cellulose and Hemicelluloses over Molecular Acidic Catalysts: Insights into the Kinetics and Reaction Mechanism, Appl. Catalysis. B:Env., 184: 285 -298 (2016).
16
[17] Pe´rez, J. Munoz-Dorado, T. de la Rubia, J. Martı´nez, Biodegradation and Biological Treatments of Cellulose, Hemicellulose and Lignin: An Overview,Int Microbiol., 5: 53-63(2002).
17
[18] Klemm D., Heublein B., Fink H., Bohn A., Cellulose: Fascinating Biopolymer and Sustainable Raw Material., Angew. Chem. Int. Ed., 44: 3358-3393 (2005).
18
[19] Foyer G., Chanfi B., Virieux D., David G., Caillol S., Aromatic Dialdehyde Precursors from Lignin Derivatives for the Synthesis of Formaldehyde-Free and High Char Yield Phenolic Resins., Eur. Polym. J., 77: 65-74 (2016).
19
[20] Maresca P., GiovannaFerrari G., Modelling of the Kinetics of Bovine Serum Albumin Enzymatic Hydrolysis Assisted by High Hydrostatic Pressure., Food and Bioproducts Processing105: 1-11 (2017).
20
ORIGINAL_ARTICLE
Synthesis, Characterization, DNA Binding and Nuclease Activity of Cobalt(II) Complexes of Isonicotinoyl Hydrazones
Cobalt(II) complexes of isonicotinoyl hydrazones of two series of ligands have been synthesized and characterized on the basis of elemental analyses, molar conductance, magnetic moment, mass, IR, UV spectral data. Electrochemical behavior of ligands and complexes has been investigated by using cyclic voltammetry. Cyclic voltammetric studies reveal that the oxidation/reduction potentials of all complexes are shifted towards positive or negative values than its corresponding ligands. The interactions of these complexes with calf thymus DNA have been studied by using absorption studies. Bathochromic shift and hypochromism suggest that the intercalative mode of binding of complexes with DNA. Their DNA cleavage activity of complexes was studied on double-stranded pBR322 plasmid DNA using gel electrophoresis experiments in the absence and presence of oxidant (H2O2) and reductant (DTT).
https://ijcce.ac.ir/article_33156_ad175e28b544a7b08bf092860daf3636.pdf
2018-08-01
63
74
10.30492/ijcce.2018.33156
Co(II) complexes
isonicotinoyl hydrazones
Cyclic voltammetry
DNA binding, DNA cleavage
Akkili
Suselamma
suseela.3712@gmail.com
1
Department of Chemistry, Hindu P.G.College for Women, Sananth Nagar, Hyderabad-500038, INDIA
AUTHOR
karredduala
Raja
raja.chem786@gmail.com
2
Department of Chemistry, Rajeev Gandhi Memorial College of Engineering and Technology (Autonomous), Nandyal, Kurnool District, Andhara Pradesh State. INDIA
AUTHOR
Katreddi Hussain
Reddy
khussainreddy@yahoo.co.in
3
Department of Chemistry, Sri Krishnadevaraya University, Anantapuramu-515003, INDIA
LEAD_AUTHOR
[1] Sa´nchez-Delgado R.A., Navarro M., Pe´rez H., Urbina J.A., Toward a Novel Metal-Based Chemotherapy against Tropical Diseases. 2. Synthesis and Antimalarial Activity in Vitro and in Vivo of New Ruthenium− and hodium−Chloroquine Complexes , J. Med. Chem., 39: 1095-1099 (1996).
1
[2] Navarro M., Pe´rez H., Sa´nchez-Delgado R.A., Toward a Novel Metal-Based Chemotherapy Against Tropical Diseases. 3. Synthesis and Antimalarial Activity in Vitro and in Vivo of the New Gold−Chloroquine Complex [Au(PPh3) (CQ)]PF6, J. Med. Chem., 40: 1937-1939 (1997).
2
[3] Chohan Z.H., Rauf A., Studies on Biologic Ally Active Complexes of Cobalt(II) and Nickel(II) with Dithiooxamide-Derived Ligands, J. Inorg. Biochem., 46: 41-48 (1992).
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[4] Malhotra R., Singh J.P., Dudeja M., Dhindsa K.S., Ligational Behavior of N-Substituted Acid Hydrazides Towards Transition Metals and Potentiation of Their Microbiocidal Activity, J. Inorg. Biochem., 46: 119-127 (1992).
4
[5] Lebon F., Ledecq M., Benatallah Z., Sicsic S., Lapouyade R., Kahan O., Garcon A., Reboud-Ravaux M., Durant F.J., Metal-Organic Compounds: A New Approach for Drug Discovery. N1-(4-methyl-2-pyridyl)-2,3,6-trimethoxybenzamide Copper(II) Complex as an Inhibitor of human Immunodeficiency Virus 1 Protease, J. Chem. Soc. Perkin Trans., 2: 795-800 (1999).
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[6] Bharti N., Maurya M.R., Naqvi F., Bhattacharya A., Bhattacharya S., Azam A., Palladium(II) Complexes of NS Donor Ligandsderived from S-methyl-dithiocarbazate, S- benzyldithiocarbazate and Thiosemicarbazide as Antiamoebic Agents, Eur. J. Med. Chem., 35: 481-486 (2000).
6
[7] Sridhar S.K., Pandeya S.N., Stables J.P., Ramesh A., Anticonvulsant Activity of Hydrazones, Schiff and Mannich Bases of Isatin Derivatives, Eur. J. Pharm. Sci., 16: 129-132 (2002).
7
[8] Vicini P., Zani F., Cozzini P., Doytchinova I., Hydrazones of 1,2-benzisothiazole Hydrazides: Synthesis, Antimicrobial Activity and QSAR Investigations, Eur. J. Med. Chem., 37: 553-564 (2002).
8
[9] Kaymakcioglu B.K., Rollas S., Synthesis, Characterization and Evaluation of Antituberculosis Activity of Some Hydrazones, Farmaco., 57: 595-599 (2002).
9
[10] Ragavendran J.V., Sriram D., Patel S.K., Reddy I.V., Bharathwajan N., Stables J., Yogeeswari P., Design and Synthesis of Anticonvulsants from a Combined Phthalimide–GABA–Anilide and Hydrazone Pharmacophore, Eur. J. Med. Chem., 42: 146-151 (2007).
10
[11] Rollas S., Gulerman N., Erdeniz H., Synthesis and Antimicrobial Activity of Some New hydrazones of 4-Fluorobenzoic Acid Hydrazide and 3-acetyl-2,5-disubstituted-1,3,4-oxadiazolines, Farmaco, 57: 171-174 (2002).
11
[12] Sah P.P.T., Peoples S.A., Isonicotinoyl Hydrazones as Antitubercular Agents and Derivatives for Identification of Aldehydes and Ketones. J. Pharm. Sci., 43: 513-524 (1954).
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38
ORIGINAL_ARTICLE
Evaluation of Biodiesel Blending of Cocos Nucifera Oil Methyl Ester Produced from Alkaline-Catalyzed Transesterification Reaction
The prospect of using cocos nucifera Oil for production of biodiesel via transesterification reaction was investigated. The use of ethanol for the transesterification reaction instead of methanol was also evaluated. Test quantities of biodiesel were produced using 100 g, 20.0% and 0.8% of cocos nucifera Oil, ethanol and potassium hydroxide catalyst respectively at 50 °C reaction temperature and 2 h reaction time. The catalyzed transesterification reaction produced biodiesel yield of 10.4%. In order to produce alternative fuel, the biodiesel produced from the cocos nucifera Oil was subsequently blended with petroleum diesel and the blended properties characterized by ASTM standard fuel tests. The property of the blended alternative fuel was determined by comparing cloud point and pour point of the biodiesel blend.
https://ijcce.ac.ir/article_34850_b16443c7aafb29564bb0a376c002e85a.pdf
2018-08-01
75
80
10.30492/ijcce.2018.34850
Biodiesel
blending
Cocos nucifera Oil
transesterification reaction
Yield
Ikechukwu Abuchi
Nnanwube
niaconsult@yahoo.com
1
Department of Chemical Engineering Madonna University, Akpugo Campus, Enugu State, NIGERIA
AUTHOR
Bamidele Victor
Ayodele
bamidele.ayodele@uniben.edu
2
Department of Chemical Engineering, University of Benin, Benin City, NIGERIA
LEAD_AUTHOR
Uchechukwu Herbert
Offor
hconfidence@yahoo.com
3
Department of Chemical and Petroleum Engineering, University of Uyo, Uyo, Akwa Ibom State, NIGERIA
AUTHOR
Ejiroghene Thelma
Akhihiero
4
Department of Chemical Engineering, University of Benin, Benin City, NIGERIA
AUTHOR
Osariemen
Edokpayi
5
Department of Chemical Engineering, University of Benin, Benin City, NIGERIA
AUTHOR
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35
ORIGINAL_ARTICLE
Kinetic Study of Ethyl Hexanoate Synthesis Using Surface Coated Lipase from Candida Rugosa
Kinetics of lipase-catalyzed esterification of hexanoic acid and ethyl alcohol using the solvent-free system, surface coated lipase from Candida rugosa, had been studied. The effect of various parameters such as reaction time, reaction temperature, reaction kinetics, water removal and feasibility of solvent-free system had been focused. Candida Rugosa lipase was more effective than other lipases when ethyl hexanoate was synthesized in n-hexane. The highest esterification yield after 72 h (93 %) was achieved at a pH of 5.2 and the esterification yield was reduced to 73% at pH 4.0. The values of the apparent kinetic parameters were computed as Vmax= 0.146 μmol/min/mg enzyme; KM, Acid = 0.296 M; KM, Alcohol = 0.1388 M; Ki, Acid = 0.40 M; and Ki, Alcohol = 0.309 M. The reaction rate could be described in terms of the Michaelis–Menten equation with a Ping-Pong Bi-Bi mechanism and competitive inhibition by both the substrates.
https://ijcce.ac.ir/article_30874_8033016ba0c97a3257bafd50dfca1f50.pdf
2018-08-01
81
92
10.30492/ijcce.2018.30874
Candida rugosa
ethyl hexanoate
surface coated lipase
Transesterification
kinetic studies
Nambula
Annapurna Devi
nadevi15@gmail.com
1
Department of Chemical Engineering, MVGR College of Engineering, Vizianagaram, (Affiliated to JNTUK), INDIA
LEAD_AUTHOR
Gidla
Bhanu Radhika
gbrchem@gmail.com
2
Department of Chemical Engineering, B V Raju Institute of Technology (Affiliated to JNTUH), Narsapur, Medak District, Telangana, INDIA
AUTHOR
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46
ORIGINAL_ARTICLE
Effect of Pt on Zn-Free Cu-Al Catalysts for Methanol Steam Reforming to Produce Hydrogen
Steam reforming of methanol can be considered as an attractive reaction aiming at hydrogen production for PEM fuel cells. Although Cu/Al-contained catalysts are considerably evaluated in this reaction, further evaluation is essential to evaluate the impact of some promoters like Pt in order to find a comprehensively optimized catalyst. Pt promoter is employed with different methods in this study. Firstly, the amount of Cu loading in Cu/Al ratio is optimized via coprecipitation method. The sample containing 30% wt. of Cu exhibits better performance with methanol conversion of 70% and CO selectivity of 0.44%. Besides, impregnating a different amount of Pt onto Al2O3 reveals an inadequate potential for this reaction. In contrary, doping Pt into Cu/Al catalyst increases the methanol conversion as high as 81% and CO selectivity reaches to approximately zero at 270 °C. In addition, using a dual-bed reactor including Cu/Al and Pt/Al2O3 catalyst displays a relatively satisfactory performance by which the conversion and selectivity are found 83.7% and 1.5%, respectively. In this study, analyses of X-Ray Diffraction, Scanning Electron Microscopy, and BET surface area are used to characterize the synthesized catalysts.
https://ijcce.ac.ir/article_31463_365a899c8da2703754c555d482121ee1.pdf
2018-08-01
93
100
10.30492/ijcce.2018.31463
Methanol Steam Reforming
PEM fuel cells
Hydrogen
Dual-bed reactor
Pt
Cu/Al catalyst
Mehran
Jafari
mehran_jafari1390@yahoo.com
1
Hydrogen and Fuel Cell Research Laboratory, Department of Chemical Engineering, Faculty of Engineering, University of Kashan, Kashan, I.R. IRAN
AUTHOR
Abdullah
Irankhah
irankhah@kashanu.ac.ir
2
Hydrogen and Fuel Cell Research Laboratory, Department of Chemical Engineering, Faculty of Engineering, University of Kashan, Kashan, I.R. IRAN
LEAD_AUTHOR
Masoud
Mahmoudizadeh
masoud_mahmoudi@yahoo.com
3
Hydrogen and Fuel Cell Research Laboratory, Department of Chemical Engineering, Faculty of Engineering, University of Kashan, Kashan, I.R. IRAN
AUTHOR
Najmeh
Hoshyar
nhoshyar@yahoo.com
4
Hydrogen and Fuel Cell Research Laboratory, Department of Chemical Engineering, Faculty of Engineering, University of Kashan, Kashan, I.R. IRAN
AUTHOR
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35
ORIGINAL_ARTICLE
Pseudo-Five-Component Condensation for the Diversity-Oriented Synthesis of Novel Indoles and Quinolines Containing Pseudo-Peptides (Tricarboxamides)
A novel series of indole and quinoline tricarboxamides were synthesized using simple and efficient one-pot pseudo-five-component reactions of 2-formylindole or 2-chloro-3-formyl quinolines, isocyanides, amines, and Meldrum’s acid as a CH-acid in CH2Cl2 at room temperature. This conversion has been achieved via the construction of new bonds including two C-C bonds, two C-N bonds, and one C=O bond. Remarkably, three peptide bonds were formed through a domino sequence including Knoevenagel reaction, [1+4] cycloaddition, deacetonation and also, aminolysis reaction. Particularly, a number of structurally remarkable and pharmacologically significant products were provided in excellent yields.
https://ijcce.ac.ir/article_28213_fe78afbfbacb0eb77ccffc182226c60b.pdf
2018-08-01
101
115
10.30492/ijcce.2018.28213
2-formylindole
2-chloro-3-formyl quinolone
isocyanides
Meldrum’s acid
multicomponent reaction
tricarboxamide
Morteza
Shiri
mshiri@alzahra.ac.ir
1
Department of Chemistry, Faculty of Science, Alzahra University, Tehran, I.R. IRAN
LEAD_AUTHOR
Majid
Mohamed Heravi
mmh1331@yahoo.com
2
Department of Chemistry, Faculty of Science, Alzahra University, Tehran, I.R. IRAN
LEAD_AUTHOR
Vahideh
Zadsirjan
z.zadsirjan@yahoo.com
3
Department of Chemistry, Faculty of Science, Alzahra University, Tehran, I.R. IRAN
AUTHOR
Atefeh
Nejatinezhad-Arani
atefenejati@yahoo.com
4
Department of Chemistry, Faculty of Science, Alzahra University, Tehran, I.R. IRAN
AUTHOR
Suhas Ashok
Shintre
suhas.chem@gmail.com
5
School of Chemistry and Physics, University of KwaZulu-Natal, Private Bag X54001, Durban, 4000, SOUTH AFRICA
AUTHOR
Neil Anthony
Koorbanally
koorbanally@ukzn.ac.za
6
School of Chemistry and Physics, University of KwaZulu-Natal, Private Bag X54001, Durban, 4000, SOUTH AFRICA
AUTHOR
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ORIGINAL_ARTICLE
Influence of Air-Gap Length on CO2 Stripping from Diethanolamine Solution and Water Performance of Surface Modified PVDF Hollow Fiber Membrane Contactor
Surface Modifying Macromolecule (SMM) blended PVDF hollow fibers (HFs) were spun at different air-gaps (o to 20 cm) and used for CO2 stripping from aqueous DEA solution and water. The manufactured fibers were first subjected to various characterization tests such as contact angle and critical water entry pressure measurement to evaluate the HF hydrophobicity and wetting resistance, respectively. The pure helium permeation experiments were also conducted to obtain membrane pore size and effective porosity. Morphology of the HFs was investigated by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The SEM images showed that both outer and inner diameters of HFs decreased significantly by increasing air-gap length which mainly because of elongation of HF caused by gravity while traveling through the air–gap. Also, the gradual decrease in roughness on the external surface of the produced HFs was observed from the AFM images. It was found that the increase of liquid velocity enhances the CO2 stripping flux. It was found that 10 cm air-gap gave maximum stripping flux of 3.34×10-2 and 1.34×10-3 (mol/m2 s) for DEA solution and water, respectively. The increase in gas velocity, on the other hand, did not affect the stripping flux significantly. It was observed that the increase of temperature from 25 to 80 oC led to marked enhancement of stripping flux from 6.30×10-3 to 3.34×10-2 (mol/m2 s) and 6.5×10-5 to 1.34×10-3 (mol/m2 s), for DEA solution and water, respectively. Furthermore, the increase in DEA concentration from 0.25 to 1 mol/L, led to enhancement of the stripping flux from 6.84×10-3 to 3.34×10-2 (mol/m2 s) at a liquid velocity of 0.7 m/s. It was concluded that the HF spun at 10 cm air-gap exhibited the best stripping performance among all fabricated HFs.
https://ijcce.ac.ir/article_28220_a3238812ff94e520f2fbfd4eca93b43b.pdf
2018-08-01
117
129
10.30492/ijcce.2018.28220
PVDF hollow fiber
CO2 stripping
Membrane contactor
air-gap length
Masoud
Rahbari-Sisakht
rahbarisisakht@gmail.com
1
Department of Chemical Engineering, Gachsaran Branch, Islamic Azad University, Gachsaran, I.R. IRAN
LEAD_AUTHOR
Daryoush
Emadzadeh
d.emadzadeh@gmail.com
2
Department of Chemical Engineering, Gachsaran Branch, Islamic Azad University, Gachsaran, I.R. IRAN
AUTHOR
Ahmad
Fauzi Ismail
afauzi@utm.my
3
Advanced Membrane Technology Research Center (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, MALAYSIA
AUTHOR
Fatemeh
Korminouri
fatemehnouri64@yahoo.com
4
Advanced Membrane Technology Research Center (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, MALAYSIA
AUTHOR
Takeshi
Matsuura
matsuura@uottawa.ca
5
Advanced Membrane Technology Research Center (AMTEC), Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor, MALAYSIA
AUTHOR
Ali Reza
Mayahi
alireza.mayahi@yahoo.com
6
Australian Institute for Bioengineering and Nanotechnology (AIBN), University of Queensland, Brisbane 4072, QLD, AUSTRALIA
AUTHOR
[1] Naim R., Ismail A.F., Cheer N.B., Abdullah M.S., Polyvinylidene Fluoride and Polyetherimide Hollow Fiber Membranes for CO2 Stripping in Membrane Contactor, Chemical Engineering Research and Design. 92(7): 1391-1398 (2014).
1
[2] Koonaphapdeelert S., Wu Z., Li K., Carbon Dioxide Stripping in Ceramic Hollow Fibre Membrane Contactors, Chemical Engineering Science, 64(1): 1-8 (2009).
2
[3] Khaisri S., deMontigny D., Tontiwachwuthikul P., Jiraratananon R., CO2 Stripping from Monoethanolamine Using a Membrane Contactor, Journal of Membrane Science, 376(1–2): 110-118 (2011).
3
[4] Rahbari-Sisakht M., Ismail A.F., Rana D., Matsuura T., Effect of Novel Surface Modifying Macromolecules on Morphology and Performance of Polysulfone Hollow fiber Membrane Contactor for CO2 Absorption, Separation and Purification Technology, 99: 61-68 (2012).
4
[5] Rahbari-Sisakht M., Ismail A.F., Rana D., Matsuura T., Emadzadeh D., Effect of SMM Concentration on Morphology and Performance of Surface Modified PVDF Hollow Fiber Membrane Contactor for CO2 Absorption, Separation and Purification Technology, 116: 67-72 (2013).
5
[6] Rahbari-Sisakht M., Ismail A.F., Rana D., Matsuura T., Emadzadeh D., Carbon Dioxide Stripping from Water Through Porous Polysulfone Hollow Fiber Membrane Contactor, Separation and Purification Technology, 108: 119-123 (2013).
6
[7] Ghasem N., Al-Marzouqi M., Duaidar A., Effect of Quenching Temperature on the Performance of Poly(vinylidene fluoride) Microporous Hollow Fiber Membranes Fabricated via Thermally Induced Phase Separation Technique on the Removal of CO2 from CO2-Gas Mixture, International Journal of Greenhouse Gas Control, 5(6): 1550-1558 (2011).
7
[8] Ghasem N., Al-Marzouqi M., Duidar A., Effect of PVDF Concentration on the Morphology and Performance of Hollow Fiber Membrane Employed as Gas–Liquid Membrane Contactor for CO2 Absorption, Separation and Purification Technology, 98: 174-185 (2012).
8
[9] Ghasem N., Al-Marzouqi M., Abdul Rahim N., Modeling of CO2 Absorption in a Membrane Contactor Considering Solvent Evaporation, Separation and Purification Technology, 110: 1-10 (2013).
9
[10] Korminouri F., Rahbari-Sisakht M., Rana D., Matsuura T., Ismail A.F., Study on the Effect of Air–Gap Length on Properties and Performance of Surface Modified PVDF Hollow Fiber Membrane Contactor for Carbon Dioxide Absorption, Separation and Purification Technology, 132: 601-609 (2014).
10
[11] Korminouri F., Rahbari-Sisakht M., Matsuura T., Ismail A.F., Surface Modification of Polysulfone Hollow Fiber Membrane Spun under Different air-Gap Lengths for Carbon Dioxide Absorption in Membrane Contactor System, Chemical Engineering Journal, 264: 453-461 (2015).
11
[12] Simioni M., Kentish S.E., Stevens G.W., Membrane Stripping: Desorption of Carbon Dioxide from Alkali Solvents, Journal of Membrane Science, 378(1–2): 18-27 (2011).
12
[13] Rahbari-Sisakht M., Korminouri F., Emadzadeh D., Matsuura T., Ismail A.F., Effect of Air-Gap Length on Carbon Dioxide Stripping Performance of a Surface Modified Polysulfone Hollow Fiber Membrane Contactor, RSC Advances, 4(103). 59519-59527 (2014).
13
[15] Suk D.E., Matsuura T., Park H.B., Lee Y.M., Synthesis of a New Type of Surface Modifying Macromolecules (nSMM) and Characterization and Testing of nSMM Blended Membranes for Membrane Distillation, Journal of Membrane Science, 277(1–2): 177-185 (2006).
14
[16] Tsai H.A., Huang D.H., Fan S.C., Wang Y.C., Li C.L., Lee K.R., Lai J.Y., Investigation of Surfactant Addition Effect on the Vapor Permeation of Aqueous Ethanol Mixtures Through Polysulfone Hollow Fiber Membranes, Journal of Membrane Science, 198(2): 245-258 (2002).
15
[17] Zhang X., Wen Y., Yang Y., Liu L., Effect of Air-Gap Distance on the Formation and Characterization of Hollow Polyacrylonitrile (PAN) Nascent Fibers. Journal of Macromolecular Science, Part B., 47(6): 1039-1049 (2008).
16
[18] Liu R.X., Qiao X.Y., Chung T.-S., Dual-Layer P84/Polyethersulfone Hollow Fibers for Pervaporation Dehydration of Isopropanol, Journal of Membrane Science, 294(1–2): 103-114 (2007).
17
[19] Khulbe K.C., Feng C.Y., Hamad F., Matsuura T., Khayet M., Structural and Performance Study of Micro Porous Polyetherimide Hollow Fiber Membranes Prepared at Different Air-Gap, Journal of Membrane Science, 245(1–2): 191-198 (2004).
18
[20] Wang D., Li K., Teo W.K., Highly Permeable Polyethersulfone Hollow Fiber Gas Separation Membranes Prepared Using Water as Non-Solvent Additive, Journal of Membrane Science, 176(2): 147-158 (2000).
19
[21] Khayet M., The Effects of Air Gap Length on the Internal and External Morphology of Hollow Fiber Membranes, Chemical Engineering Science, 58(14): 3091-3104 (2003).
20
[22] Khayet M., García-Payo M.C., Qusay F.A., Zubaidy M.A., Structural and Performance Studies of Poly(vinyl chloride) Hollow Fiber Membranes Prepared at Different Air Gap Lengths, Journal of Membrane Science, 330(1–2): 30-39 (2009).
21
[23] Naim R., Ismail A.F., Mansourizadeh A., Effect of Non-Solvent Additives on the Structure and Performance of PVDF Hollow Fiber Membrane Contactor for CO2 Stripping, Journal of Membrane Science, 423–424: 503-513 (2012).
22
[24] Naim R., Khulbe K.C., Ismail A.F., Matsuura T., Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis, Separation and Purification Technology, 109: 98-106 (2013).
23
[25] Mansourizadeh A. Ismail A.F., Influence of Membrane Morphology on Characteristics of Porous Hydrophobic PVDF Hollow Fiber Contactors for CO2 Stripping from Water, Desalination, 287: 220-227 (2012).
24
[26] Rahbari-Sisakht M., Ismail A.F., Rana D., Matsuura T., Carbon Dioxide Stripping from Diethanolamine Solution Through Porous Surface Modified PVDF Hollow Fiber Membrane Contactor, Journal of Membrane Science, 427: 270-275
25
[27] Ismail A.F., Dunkin I.R., Gallivan S.L., Shilton S.J., Production of Super Selective Polysulfone Hollow Fiber Membranes for Gas Separation, Polymer, 40(23): 6499-6506 (1999).
26
[28] Rahbari-Sisakht M., Ismail A.F., Matsuura T., Development of Asymmetric Polysulfone Hollow Fiber Membrane Contactor for CO2 Absorption, Separation and Purification Technology, 86: 215-220 (2012).
27
[29] Rahbari-sisakht M., Ismail A.F., Matsuura T., Effect of Bore Fluid Composition on Structure and Performance of Asymmetric Polysulfone Hollow Fiber Membrane Contactor for CO2 Absorption, Separation and Purification Technology, 88: 99-106 (2012).
28
[30] Rahbari-Sisakht M., Ismail A.F., Rana D., Matsuura T., A Novel Surface Modified Polyvinylidene Fluoride Hollow Fiber Membrane contactor for CO2 Absorption, Journal of Membrane Science, 415–416: 221-228 (2012).
29
[31] Khayet M., Feng C.Y., Khulbe K.C., Matsuura T., Study on the Effect of a Non-Solvent Additive on the Morphology and Performance of Ultrafiltration Hollow-Fiber Membranes, Desalination, 148(1–3): 321-327 (2002).
30
[32] Li M.-H. Chang B.-C., Solubilities of Carbon Dioxide in Water + Monoethanolamine + 2-Amino-2-methyl-1-propanol. Journal of Chemical & Engineering Data. 39(3): 448-452 (1994).
31
[33] Rahbari-Sisakht M., Rana D., Matsuura T., Emadzadeh D., Padaki M., Ismail A.F., Study on CO2 Stripping from Water Through Novel Surface Modified PVDF Hollow Fiber Membrane Contactor, Chemical Engineering Journal, 246: 306-310 (2014).
32
[34] Khulbe K.C., Feng C.Y., Matsuura T., Mosqueada-Jimenaez D.C., Rafat M., Kingston D., Narbaitz R.M., Khayet M., Characterization of Surface-Modified Hollow Fiber Polyethersulfone Membranes Prepared at Different Air Gaps, Journal of Applied Polymer Science,104(2): 710-721 (2007).
33
[35] Mansourizadeh A. Ismail A.F., CO2 Stripping from Water Through Porous PVDF Hollow Fiber Membrane Cntactor, Desalination, 273(2–3): 386-390 (2011).
34
[36] Weiland R.H., Rawal M., and Rice R.G., Stripping of Carbon Dioxide from Monoethanolamine Solutions in a Packed Column, AIChE Journal, 28(6): 963-973 (1982).
35
[37] Mokhatab S., Poe W.A., Speight J.G., "Handbook of Natural Gas Transmission and Processing", Gulf Professional Publishing, Burlington (2006).
36
ORIGINAL_ARTICLE
Adsorption Mechanism of Lead on Wood/Nano-Manganese Oxide Composite
Discharge of untreated industrial wastewater containing heavy metals such as Pb2+ is hazardous to the environment due to their high toxicity. This study reports on the adsorption, desorption, and kinetic study on Pb2+ removal from aqueous solutions using wood/Nano-manganese oxide composite (WB-NMO). The optimum pH, contact time and temperature for adsorption were found to be 5.0, 4 h and 333 K, respectively. Pseudo-second-order kinetics best described the adsorption process with an initial sorption rate of 4.0 mg g min-1, and a half-adsorption time t1/2 of 31.6 min. Best fit for adsorption isotherm was obtained with the Brunauer-Emmett-Teller (BET) model with a maximum adsorption capacity of 213 mg/g for an initial metal concentration of 60 mg/L. Both intra-particle diffusion and film diffusion contribute to the rate-determining step. Desorption experiments with 0.5 mol/L HCl, inferred the reusability of the composite. Adsorption experiment of Pb2+ from industrial wastewater confirmed that the prepared WB-NMO is a promising candidate for wastewater treatment. The WB-NMO demonstrated high Pb2+ removal efficiency and is considered as a promising alternative and reusable composite for lead removal from contaminated effluents.
https://ijcce.ac.ir/article_35073_14b481a26fc88ad211779fe9bd388fd1.pdf
2018-08-01
131
144
10.30492/ijcce.2018.35073
wood
Manganese oxide
Adsorption
Kinetics
Lead
Jamal
Al-Abdullah
prscientific@aec.org.sy
1
Department of Protection and Safety, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
LEAD_AUTHOR
Abdul Ghaffar
Al Lafi
aallafi@aecs.sy
2
Department of Chemistry, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
AUTHOR
Tasneem
Alnama
talnama@aecs.sy
3
Department of Protection and Safety, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
AUTHOR
Wafa’a
Al Masri
wmasri@aecs.sy
4
Department of Protection and Safety, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
AUTHOR
Yusr
Amin
yamin@aecs.sy
5
Department of Protection and Safety, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
AUTHOR
Mohammed Nidal
Alkfri
malkafri@aecs.sy
6
Department of Physics, Atomic Energy Commission, Damascus, P.O. Box 6091, SYRIAN ARAB REPUBLIC
AUTHOR
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[31] Greil P., Biomorphous Ceramics from Lignocellulosics, J. Eur Ceram. Soc., 21(2): 105-118 (2001).
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[51] Nunes L.M., Airoldi C., Some Features of Crystalline Titanium Hydrogenphos-Phate,Modified Sodium and n-Butylammonium Forms and Thermodynamics of Ionic Exchange with K+ and Ca2+, Thermochim. Acta., 328: 297-305 (1999).
50
ORIGINAL_ARTICLE
Effective Removal of Acid Black 1 Dye in Textile Effluent Using Alginate from Brown Algae as a Coagulant
In this study, the Acid Black 1 dye containing effluent collected from a dyeing unit was examined with the alginate extracted from the marine brown algae, Sargassum sp. for its removal. Batch experiments were carried out using standard Jar test apparatus. Fourier Transform InfraRed (FT-IR) Spectroscopy and Scanning Electron Microscopy (SEM) techniques were used to characterize the raw alginate and dye-loaded alginate after the coagulation process. The optimum condition for maximum colour removal of 96.8 % was found to be at 40mg/L of alginate dose, 6g/L of calcium dose and 30 minutes of settling time for the pH of 4.2. The experimental data were analyzed with the first and second order kinetic model and kinetic study on the coagulation process reveals that it follows the second-order kinetic model. The results revealed that alginate extracted from marine brown algae Sargassum sp has the coagulation potential for effective removal of Acid Black 1 dye.
https://ijcce.ac.ir/article_35074_994666df6f80804071f220305183fe18.pdf
2018-08-01
145
151
10.30492/ijcce.2018.35074
Acid Black 1 Dye
marine brown algae
Coagulation
Kinetics
Vijayaraghavan
G
vijaycit2002@yahoo.co.in
1
Department of Environmental and Water Resources Engineering, School of Civil Engineering, Vellore Institute of Technology (VIT), Vellore-632014, INDIA
AUTHOR
Shanthakumar
S
sskumariit@gmail.com
2
Department of Environmental and Water Resources Engineering, School of Civil Engineering, Vellore Institute of Technology (VIT), Vellore-632014, INDIA
LEAD_AUTHOR
[1] Xiaoming P., Xijun H., Dafang F., Frank Lam L.Y., Adsorption Removal of Acid Black 1 from Aqueous Solution Using Ordered Mesoporous Carbon, App. Surface Science, 294: 71-80 (2014).
1
[2] Subash B., Krishnakumar B., Swaminathan M., Shanthi M., Ag2S-ZnO - An Efficient Photo Catalyst for the Mineralization of Acid Black 1 with UV Light, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 105: 314-319 (2013).
2
[3] Aniroodha P. V., Anirudh B. P., Biopolymer Stabilized Iron Sulphide Nanoparticles for Removal of Acid Black 1 Dye, Mat. Sci. Forum, 757: 285-293 (2013).
3
[4]Zazouli M A., Zabihollah Y., Jamshid Y C., Yousef M., Application of Azolla Filiculoides Biomass for Acid Black 1 Dye Adsorption from Aqueous Solution, Iran. J. of Health Sci, 2(3): 24-32 (2014).
4
[5] Masoud Kasiri B., Nasser M., Hasan M., Decolorization of Organic Dye Solution by Ozonation; Optimization with Response Surface Methodology, Int. J. of Ind Chem, 4(3): (2013).
5
[6] Jiang J.Q., The Role of Coagulation in Water Treatment, Current Opinion in Chem. Engg, 8: 36-44 (2015).
6
[7] Ozacar M., Sengil I.A., Effectiveness of Tannins Obtained from Valonia as a Coagulant Aid for Dewatering of Sludge, Water Res, 34: 1407-1412 (2000).
7
[8] Huang C., Chen S., Pan J.R., Optimal Condition for Modification of Chitosan: a Biopolymer for Coagulation of Colloidal Particles, Water Res, 34: 1057-1062 (2000).
8
[9] Salehizadeh H., Shojaosadati S.A., Extracellular Biopolymeric Flocculants: Recent Trends and Biotechnological Importance, Biotech. Advances, 19: 371-385 (2001).
9
[10] Masuelli M.A., Illanes C.O., Review of the Characterization of Sodium Alginate by Intrinsic Viscosity Measurements. Comparative Analysis between Conventional and Single Point Methods, Int. J. of Bio. Mat. Sci. and Engg., 1(1): 1-11 (2014).
10
[11] Devrimci A.H., Yuksel M.A., Sanin F.D, Algal Alginate: A Potential Coagulant for Drinking Water Treatment, Desalination, 299: 16-21 (2012).
11
[12] Ikeda A., Ono T.H., Preparation of Low-Molecular Weight Alginic Acid by Acid hydrolysis, Carbo. Polymers, 42: 412-425 (2000).
12
[13] Kousha M., Daneshvar E., Dopeikar H., Taghavi D., Amit B., Box–Behnken Design Optimization of Acid Black 1 Dye Biosorption by Different Brown Macroalgae, Chem. Engg. Journal, 179: 158-168 (2012).
13
[14] Muthukumar M., Sargunamani D., Selvakumar N., Nedumaran D., Effect of Salt Additives on Decolouration of Acid Black 1 Dye Effluent by Ozonation, Indian J. Chem. Tech, 11: 612-616 (2004).
14
[15] Fenoradosoa T.A., Ali G., Delattre C., Larochevz C., Petit E., Wadouachi A., Michaud P., Extraction and Characterization of an Alginate from the Brown Seaweed Sargassum Turbinarioides Grunow, Journal of Applied Phycology, 22: 131-137 (2010).
15
[16] Zhang J., Shengjun X., Shengtang Z., Zhaoli D., Preparation and Characterization of Tamarind Gum/Sodium Alginate Composite Gel Beads, Iran. Polymer J, 17 (12): 899-906 (2008).
16
[17] Syed J.M., Azhar S., Ionic Studies of Sodium Alginate Isolated from Sargassum Terrarium (Brown Algae) Karachi Coast with 2,1-electrolyte, J. Saudi Chem. Soc, 14 : 117-123 (2010).
17
[18] John Coates, Interpretation of Infrared Spectra, A Practical Approach, “Encyclopedia of Analytical Chemistry”, R.A. Meyers (Ed.) John Wiley & Sons Inc., Chichester, 10815–10837 (2000).
18
[19] Nnaji N.J.N., Ani J.U., Aneke L.E., Onukwuli O.D., Okoro U.C., Ume J.I., Modelling the Coag-Flocculation Kinetics of Cashew Nut Testa Tannins in an Industrial Effluent, J. Ind. and Engg Chem, 20: 1930-1935 (2014).
19
[20] Yin C.Y., Emerging Usage of Plant-Based Coagulants for Water and Wastewater Treatment, Pro. Biochemistry, 45: 1437–1444 (2010).
20
[21] Ram Singh P., Bishwa Nayak R., Dipti Biswal R., Tridib Tripathy., Kaushik Banik., Bio Based Polymeric Flocculants for Industrial Effluent Treatment, Material Res. Innovations, 7: 331–340 (2003).
21
[22] Saranya P., Ramesh S.T., Gandhimathi R., Effectiveness of Natural Coagulants from Non-Plant-Based Sources for Water and Wastewater Treatment—A Review, Desalination and Water Treatment, 52: 6030–6039(2014).
22
[23] Grant G.T., Morris E.R., Rees D.A., Smith P.J.C., Thom D., Biological “Interactions between Polysaccharides and Divalent Cations: The Egg-Box Model”, FEBS Letters, 32 (1973).
23
ORIGINAL_ARTICLE
Citric Acid Removal from Aqueous Solution with Layered Aluminum Hydroxide Crystals
Aluminum hydroxide is a compound with diverse crystalline structures, some of which demonstrate the ability to remove chemicals from aqueous solutions. In this research, aluminum hydroxide with the Bayerite structure was synthesized and used to remove Citric Acid (CA). This structure was not modified under the reaction conditions where CA ranged from 2 to 6 mg of CA in 20 mL of water, the temperature ranged from 30 to 90 °C, and time ranged from 8 to 24 h. The constants in the Freundlich model indicated that adsorption is the phenomenon governing the CA capture by aluminum hydroxide. According to infrared spectroscopy data, adsorption of CA was produced by the hydrogen bond of hydroxyl groups in aluminum hydroxide with either carboxylate or carboxylic groups in CA. The highest removal of CA was 92.12% and the temperature was the only factor with an effect on the percentage of CA removal.
https://ijcce.ac.ir/article_31044_dbe59099947a2eb5fd8764ed1f2d59f0.pdf
2018-08-01
153
161
10.30492/ijcce.2018.31044
Citric acid
Adsorption
Separation
Aluminum hydroxide
Luis Eduardo
Guerra Rodríguez
eduardo.guerra@reduc.edu.cu
1
Facultad de Ciencias Aplicadas a la Industria. Universidad de Camagüey “Ignacio Agramonte Loynaz”. Circunvalación Norte, km 5.5. C.P. 74650. Camagüey, CUBA
AUTHOR
Minerva
Ventura Muñoz
mine.ventura09@gmail.com
2
Departamento de Química, Universidad de Guadalajara, Marcelino García Barragán 1421. C.P. 44430, Guadalajara, Jalisco, MÉXICO
AUTHOR
Erenio
González Suárez
erenio@uclv.edu.cu
3
Departamento de Ingeniería Química. Universidad Central “Martha Abreu de Las Villas”, Carretera Camajuaní km 7.5, Santa Clara, CUBA
AUTHOR
Carmen
Rosselló Matas
carmen.rossello@uib.es
4
Departamento de Química, Facultad de Ciencias. Universidad de las Islas Baleares. Carretera Valldemossa km 7.5 Palma de Mallorca. ESPAÑA
AUTHOR
Gregorio
Carbajal Arizaga
gregoriocarbajal@yahoo.com.mx
5
Departamento de Química, Universidad de Guadalajara, Marcelino García Barragán 1421. C.P. 44430, Guadalajara, Jalisco, MÉXICO
LEAD_AUTHOR
[1] Kamali M., Ghorashi S.A.A., Asadollahi M.A., Controllable Synthesis of Silver Nanoparticles Using Citrate as Complexing Agent: Characterization of Nanopartciles and Effect of pH on Size and Crystallinity, Iran. J. Chem. Chem. Eng. (IJCCE), 31(4): 21–28 (2012).
1
[2] Alaei M., Rashidi A., Mahjoub A., Two Suitable Methods for the Preparation of Inorganic Fullerene-Like (IF) WS2 Nanoparticles, Iran. J. Chem. Chem., Eng. (IJCCE), 28(2): 91–98 (2009).
2
[3] Kudzai C.T., Ajay K., Ambika P., Citric Acid Production by Aspergillus Niger Using Different Substrates. Malays, J. Microbiol., 12(3): 199–204 (2016).
3
[4] Boriová K., Urík M., Bujdoš M., Pifková I., Matúš P., Chemical Mimicking of Bio-Assisted Aluminium Extraction by Aspergillus Niger’s Exometabolites, Environ. Pollut., 218: 281–288 (2016).
4
[5] Liao M., Effects of Organic Acids on Adsorption of Cadmium onto Kaolinite, Goethite, and Bayerite. Pedosphere, 16(2): 185–191 (2006).
5
[6] Zhang Y.-X.; Jia Y., Fluoride Adsorption onto Amorphous Aluminum Hydroxide: Roles of the Surface Acetate Anions, J. Colloid Interface Sci., 483(1): 295–306 (2016).
6
[7] Ganvir V., Das K., Removal of Fluoride from Drinking Water Using Aluminum Hydroxide Coated Rice Husk Ash, J. Hazard. Mater., 185(2–3): 1287–1294 (2011).
7
[8] Chen G., Peng C., Fang J., Dong Y., Zhu X., Cai H., Biosorption of Fluoride from Drinking Water Using Spent Mushroom Compost Biochar Coated with Aluminum Hydroxide, Desalin. Water Treat., 57(26): 12385–12395 (2016).
8
[9] Barathi M., Kumar A.S.K., Rajesh N., Aluminium Hydroxide Impregnated Macroreticular Aromatic Polymeric Resin as a Sustainable Option for Defluoridation, J. Environ. Chem. Eng., 3: 630–641 (2015).
9
[10] Liu R., Ju J., He Z., Hu C., Liu H., Qu J., Utilization of Annealed Aluminum Hydroxide Waste with Incorporated Fluoride for Adsorptive Removal of Heavy Metals, Colloids Surfaces A Physicochem. Eng. Asp., 504: 95–104 (2016).
10
[11] Kamaraj R., Vasudevan S., Facile One-Pot Electrosynthesis of Al(OH)3 - Kinetics and Equilibrium Modeling for Adsorption of 2,4,5-Trichlorophenoxyacetic Acid from Aqueous Solution, New J. Chem., 40: 2249–2258 (2016).
11
[12] Kamaraj R., Davidson D.J., Sozhan G., Vasudevan S., Adsorption of Herbicide 2-(2,4-Dichlorophenoxy) Propanoic Acid by Electrochemically Generated Aluminum Hydroxides: An Alternative to Chemical Dosing, RSC Adv., 5: 39799–39809 (2015).
12
[13] Wypych F., Arízaga G.G.C., Intercalation and Functionalization of Brucite with Carboxylic Acids | Intercalação E Funcionalização Da Brucita Com Ácidos Carboxîlicos, Quim. Nova, 28(1): 24-29 (2005).
13
[14] Demichelis R., Civalleri B., Noel Y., Meyer A., Dovesi R., Structure and Stability of Aluminium Trihydroxides Bayerite and Gibbsite: A Quantum Mechanical Ab Initio Study with the Crystal06 Code. Chem. Phys. Lett., 465(4–6): 220–225 (2008).
14
[15] Vitaly P. Isupov, Lyudmila E. Chupakhina, Raisa P. Mitrofanova, K. A. T., Synthesis, Structure, Properties, and Application of Aluminium Hydroxide Intercalation Compounds, Chem. Sustain. Dev., 8: 121–127 (2000).
15
[16] Liu X., Qiu G., Zhao Y., Zhang N., Yi R., Gallium Oxide Nanorods by the Conversion of Gallium Oxide Hydroxide Nanorods, J. Alloys Compd., 439(1–2): 275–278 (2007).
16
[17] Lee I., Kwak J., Haam S., Lee S.Y., Dipeptide-Assisted Growth of Uniform Gallium Oxohydroxide Spindles, J. Cryst. Growth, 312(14): 2107–2112 (2010).
17
[18] Wypych F., Arízaga G.G.C.,da Costa Gardolinski J.E.F., Intercalation and Functionalization of Zinc Hydroxide Nitrate with Mono- and Dicarboxylic Acids, J. Colloid Interface Sci., 283(1): 130–138 (2005).
18
[19] Arizaga G.G.C., Mangrich A.S., da Costa Gardolinski J.E.F., Wypych F., Chemical Modification of Zinc Hydroxide Nitrate and Zn-Al-Layered Double Hydroxide with Dicarboxylic Acids, J. Colloid Interface Sci., 320(1): 168–176 (2008).
19
[20] Reddy L.S., Ko Y.H., Yu J.S., Hydrothermal Synthesis and Photocatalytic Property of β-Ga2O3 Nanorods, Nanoscale Res. Lett., 10(1): 364 (2015).
20
[21] Azeredo H.M.C., Kontou-Vrettou C., Moates G.K., Wellner N., Cross K., Pereira P.H.F., Waldron K.W., Wheat Straw Hemicellulose Films as Affected by Citric Acid, Food Hydrocoll., 50:1–6 (2015).
21
[22] Zhao J.P., Liu X.R., Qiang L.S., Characteristics of the Precursors and Their Thermal Decomposition during the Preparation of LiNbO3 Thin Films by the Pechini Method, Thin Solid Films, 515(4): 1455–1460 (2006).
22
ORIGINAL_ARTICLE
The Total Phenol, Flavonol Amounts and Antiradical Activity of some Oreganum Species
Total phenol contents of O.vulgare were found between 54.23 mg GAE/g (U4) and 124.55 mg GAE/g (U2), respectively. While total phenol contents of O.minutiflorum change between 49.50 mg GAE/g (U5) and 126.92 mg GAE/g (S3), total flavonol contents were found between 623.87 mg RE/g (U5) and 854.53 mg RE/g (U2). Antioxidant capacity ranged from 42.31 mg AAE/g (U5) to 103.04 mg AAE/g (S3). Total phenol contents of O. majorana changed between 51.86 mg GAE/g (S3) and 125,23 mg GAE/g (S2). Antiradical activity and antioxidant capacity values were found between 695.85 IC50= mg/mL (U5) and 1217.51 IC50= mg/mL S3 and 55.43 mg AAE/g (S3) to 110.90 mg AAE/g (U5), respectively.
https://ijcce.ac.ir/article_35091_70c2a0314d50f1939ef161000259ca37.pdf
2018-08-01
163
168
10.30492/ijcce.2018.35091
Total phenol
flavonol
antioxidant capacity
antiradical activity
Gülcan
Özcan
1
Department of Food Engineering, Faculty of Engineering, University of Süleyman Demirel, 32000 Isparta, TURKEY
AUTHOR
Mehmet Musa
Özcan
mozcan@selcuk.edu.tr
2
Department of Food Engineering, Faculty of Agriculture, University of Selcuk, 42079 Konya, TURKEY
LEAD_AUTHOR
[1] Tepe B., Eminagaoglu O., Aşkın Akbulut H., Aydın E., Antioxidant Potential and Rosmarinic Acid Levels of Theme than Olicextracts of Salviaverticillata (L.) Subsp. Verticillata and Salviaverticillata (L.) subsp. amasiaca (Freyn&Bornm.) Bornm, Food Chem., 100: 985-989 (2007).
1
[2] Ivanauskas L., Jakštas V., Radušienė J., Lukošius A., Aranauskas A., Evaluation of Phenolic Acids and Phenyl Propanoids in Thecrudedrugs, Med(Kaunas) 44(1): 48-55 (2008).
2
[3] Chrpova D., Kourimska L., Gordon M.H., Hermanova V., Roubickova I, Panek J, Antioxidantactivity of Selected Phenols and Herbs Uused in Diets for Medical Conditions, Czec. J. Food.Sci., 28: 317-325 (2010).
3
[4] Proestos C., Sereli D., Komaitis M., Determination of Phenolic Compounds in Aromatic Plants by RP-HPLC and GC-MS, Food Chem., 95:44-52 (2006).
4
[5] Singleton V.L., Rossi J.R., Colorimetry of Total Phenolics with Phosphomolibdic-Phosphothungstic Acid, Am. J. Enol. Vit., 16: 144-158 (1965).
5
[6] Dai G.H., Andary C., Mondolot L., Boubals D., Involment of Phenolic Compounds in the Resistance of Grape Wine Call us to Downy Mildew (Plasmoparaviticola), Eur. J. Plant. Pathol., 101: 541-547 (1995).
6
[7] Dorman H.J.D., Peltoketo Hiltunen R., Tikkanen M.J Characterization of Antioxidant Properties of de-Odourised Aqueous Extracts from Selected Lamiaceae Herbs, Food. Chem., 83: 255-262 (2003).
7
[8] Prieto P., Pineda M., Aguilar M., Spectrophotometric Quantitation of Antioxidant Capacity Through the Formation of a Phosphomolybdenum Complex: Specific application to the Determination of Vitamin E, Anal Biochem., 269: 337-341 (1999).
8
[9] Özdamar K., “SPPS ile Bioistatistik” ETAM A.Ş. Matbaa Tesisleri. Yayın, No: 3. 454 s., Eskişehir (1999).
9
[10] Exarchou V., Nenadis N., Tsimidou M., Gerothanassis I.P., Troganis A., Boskou D., Antioxidant Activities and Phenolic Composition of Extracts from Greek Oregano. Greek Sage. And Summer Savory, J. Agric. Food. Chem., 50: 5294-5299 (2003).
10
[11] Şahin F., Güllüce M., Daferera D., Sökmen A., Sökmen M., PolissiouAgar G., Özer H. ,Biological Activities of the Essential Oil and Methanole Xtract of Origanumvulgar essp. vulgare in the Estern Anatolia Region of Turkey, Food Control, 15: 549-557 (2004).
11
[12] Capecka E., Mareczek A., Leja M., Antioxidant Activity of Fresh and Dry Herbs of Some Lamiaceaespecies, Food Chem., 93: 223-226 (2005).
12
[13].Chun S.S., Vattem D.A., Lin Y.T., Shetty K., Phenolic Antioxidants from Clonal Oregano (Origanumvulgare) with Antimicrobial Activity Against Helicobacterpylori, Process Biochem., 40: 809-816 (2005).
13
[14] Koşar M., Dorman H.J.D., Bachmayer O., Başer K.H.C., Hiltunen R., An Improved On-Line HPLC-DPPH Method for the Screening of Free Radicals Cavenging Compounds in Water Extracts of Lamiaceae Plants, Chem. Nat Comp., 39(2): 161-166 (2003).
14
[15] Mensor L.L., Menezes F.S., Leitao G.G., Reis A.S., Dos Santos T.C., Coube C.S., Leitao S.G., Screening of Brazilian Plant Extracts for Antioxidant Activity by the Use of DPPH Free Radical Method, Phytotherapy Res, 15 (2): 127-130(2001).
15
[16] Refaei M., Pineda M., Aguılar M., Antioxidant Capacity of Extracts from Wild and Crop Plants of the Mediterranean Region, J. Food Sci., 72(1): 59-63 (2007).
16
[17] Skerget M., Kotnik P., Hadolin M., RiznerHras A., Simonic M., Knez Z., Phenols, Proantho cyanidins, Flavones and Antioxidant Activities, Food Chem, 89: 191-198 (2005).
17
ORIGINAL_ARTICLE
Selective Speciation of Ferric Iron by a New Heterocyclic Ligand
The synthesis and analytical applications of the new heterocyclic ligand are described. The complexation reaction of the ligand with some cations was studied in aqueous methanol at room temperature using the spectrophotometric method. Results revealed that only the absorption spectra of the Fe (III)–ligand complex show a high redshift of the absorption maximum in the aqueous methanol solution and the compound reacts with Fe (III) to produce a deep green complex (1:2 mol ratio of Fe(III)/ligand). Furthermore, a highly sensitive, selective and rapid spectrophotometric method is described for the determination of trace amounts of Fe (III) by using the ligand.
https://ijcce.ac.ir/article_28569_ed1e3a4cd1daeeafc735021782c2a73f.pdf
2018-08-01
169
174
10.30492/ijcce.2018.28569
3H-imidazo[4',5':3,4]benzo[1,2-c]isoxazole
Complexation reaction
Iron (III) complex
Absorption spectra
Selective detection
Samaneh
Takhti
takhti299@gmail.com
1
Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
AUTHOR
Mehdi
Pordel
mehdipordel58@mshdiau.ac.ir
2
Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
LEAD_AUTHOR
Mahmoud
Ebrahimi
ebrachem2007@yahoo.com
3
Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
AUTHOR
[1] Szarfman, A., Tonning, J.M., Levine, J.G., Doraiswamy, P.M., Atypical Antipsychotics and Pituitary Tumors: a Pharmacovigilance Study, Pharmacotherapy, 26: 748-758 (2006).
1
[2] Barmade, M.A, Murumkar, P.R, Sharma, M.K., Yadav, M. R., Medicinal Chemistry Perspective of Fused Isoxazole Derivatives, Curr. Top. Med. Chem., 16: 2863-2883 (2016)
2
[3] Ramezani, S., Pordel, M., Beyramabadi, S., Synthesis, Spectroscopic Characterization and DFT/TD-DFT Calculations of new Fluorescent Derivatives of Imidazo [4′, 5′: 3, 4] Benzo [c] Isoxazole, J.Fluoresc., 26: 513-519 (2016).
3
[4] Munsey, M.S., Natale, N.R., The coordination Chemistry of isoxazoles, Coord. Chem. Rev., 109: 251-281 (1991).
4
[5] Sheikhhosseini, E., Mokhtari, T.S., Faryabi, M., Rafiepour, A., Soltaninejad, S., Iron Ore Pellet, A Natural and Reusable Catalyst for Synthesis of Pyrano [2, 3-d] pyrimidine and Dihydropyrano [c] Chromene Derivatives in Aqueous Media, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 43-50 (2016).
5
[6] Frogneux, X., Jacquet, O., Cantat, T., Iron-Catalyzed Hydrosilylation of CO2: CO2 Conversion to Formamides and Methylamines, Catal. Sci. Tech., 4: 1529-1533 (2014).
6
[7]Tabrizi, A. B., Panahi, M., Solid Phase Extraction Using Modified Magnetic Iron Oxide Nanoparticles for Extraction and Spectrofluorimetric Determination of Carvedilol in Human Plasma Samples, Iran. J. Chem. Chem. Eng. (IJCCE), 36(3): 115-125 (2017).
7
[8] Stang, P.J., (Editor.) “Metal-Catalyzed Cross-Coupling Reactions”, John Wiley & Sons Inc.; Jul 11 (2008).
8
[9] Amolegbe S.A., Adewuyi S., Akinremi C.A., Adediji J.F., Lawal A., Atayese A.O., Obaleye J.A., Iron (III) and Copper (II) Complexes Bearing 8-Quinolinol with Amino-Acids Mixed Ligands: Synthesis, Characterization and Antibacterial Investigation, Arab. J. Chem., 8: 742-747 (2015).
9
[10] Takano, K., Ishida, N., Kawabe, K., Moriyama, M., Hibino, S., Choshi, T., Hori, O., Nakamura, Y., A Dibenzoylmethane Derivative Inhibits Lipopolysaccharide-Induced NO Production in Mouse microglial cell line BV-2. Neurochem. Int., 119: 126-131 (2017).
10
[11] Mansour, R.A., Adel, M., Eldesoky, A.M., Separation and Subsequent Determination of Iron in Aqueous and Non-Aqueous Solutions Using Modified Polymer, Int. J.; 2: 914-925 (2014).
11
[12] Preston, P.N., “The Chemistry of Heterocyclic Compounds, Benzimidazoles and Cogeneric Tricyclic Compounds”, John Wiley & Sons, Inc., Part 1, Volume 40, pp 87–105 (2009).
12
[13] Rahimizadeh, M., Pordel, M., Bakavoli, M., Bakhtiarpoor, Z., Orafaie, A., Synthesis of Imidazo [4, 5-a] Acridones and Imidazo [4, 5-a] Acridines as Potential Antibacterial Agents, Monatsh Chem., 140: 633- (2009).
13
[14] Agheli, Z., Pordel, M., Beyramabadi, S.A., New Fe (III) Complex with 8-(4-chlorophenyl)-3-butyl-3H-imidazo [4′, 5′: 3, 4] benzo [1, 2-c] isoxazol-5-amine (5-AIBI) Ligand: Synthesis, Spectroscopic Characterization and DFT Calculations, J. Mol. Struct., 1130: 55-61 (2017).
14
[15] Vosburgh, W.C., Cooper, G.R., Complex Ions. I. The Identification of Complex Ions in Solution by Spectrophotometric Measurements, J. Am. Chem. Soc., 63: 437-442 (1941).
15
[16] Franson, M.A.H., “Standard Methods for Examination of Water and Waste Water”, American Publication Health Associations, p. 368 (1995).
16
ORIGINAL_ARTICLE
Platinum Extraction Modeling from Used Catalyst by Iodine Solutions
Platinum extraction from spent reforming catalysts in iodine solutions under atmospheric pressure at different temperatures, acid concentration, and iodine spices concentration, catalyst particle size, and impeller agitation speed have been studied in our group. In this system, platinum is oxidized from spent catalyst with I3¯ that is formed from the reaction of I2 and I¯ to produce PtI6-2 as its main product. It is obvious that some of the platinum ions in aqueous solution are precipitated as PtI4, especially at high temperatures. Power-law rate equation was used in extraction and precipitation reactions for kinetic modeling. The effect of temperature was studied using the Arrhenius equation. The activation energy for the platinum surface dissolution reaction was calculated as 53 kJ/mol in extraction reaction which indicated that the rate determining step is surface chemical reaction step. The reaction order was 3.01 for platinum concentration in solid and 0.45 for the hydrogen ion concentration, 0.1 for the iodine spices concentration in extraction reaction and 0.54 for platinum ions concentration in precipitation reaction. This model shows good agreement with experimental data.
https://ijcce.ac.ir/article_30586_44cc038007640a37042c4f14230fc2fa.pdf
2018-08-01
175
182
10.30492/ijcce.2018.30586
Kinetics
Pt Extraction
Iodine Solution
Platinum-iodine Ions Precipitation
Power-Law equation
Hamed
Rashidi Moghaddam
hamed.rashidi.m@gmail.com
1
Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, I.R. IRAN
AUTHOR
Morteza
Baghalha
baghalha@sharif.edu
2
Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Jha M.K., Lee J.CH., Kim M.S., Jeong J., Kim B.Su, Kumar V., Hydrometallurgical Recovery/Recycling of Platinum by the Leaching of Spent Catalysts:
1
A Review, Hydrometallurgy, 133: 23–32 (2013).
2
[2] Chen J., Huang K., A New Technique for Extraction of Platinum Group Metals by Pressure Cyanidation, Hydrometallurgy, 82: 164–171 (2006).
3
[3] Shams K., Beiggy M.R.A., Shirazi G., Platinum Recovery from a Spent Industrial Dehydrogenation Catalyst Using Cyanide Leaching Followed by Ion Exchange, Applied Catalysis A: General, 258: 227 (2004)–234.
4
[4] Barakat, M.A., Mahmoud, M.H.H., Recovery of Platinum from Spent Catalyst, Hydrometallurgy, 72: 179–184 (2004).
5
[5] Sajadi S.A.A., Separation and Recovery of Platinum and Palladium from Spent Catalysts using Activated Carbon, Articles in Press, Accepted Manuscript , Available Online from 22 November (2017).
6
[6] Baghalha, M., Khosravian, H., Mortaheb, H., Kinetics of Platinum Extraction from Spent Reforming Catalysts in Aqua-Regia Solution, Hydrometallurgy, 95: 247–253 (2009).
7
[7] Zanjani A., Baghalha M., Factors Affecting Platinum Extraction from Used Reforming Catalysts in Iodine Solutions at Temperatures up to 95 °C, Hydrometallurgy, 97: 119–125 (2009).
8
[8] Qi P.H., Hiskey J.B., Dissolution Kinetics of Gold in Iodide Solutions, Hydrometallurgy, 27: 47-62 (1991).
9
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22
ORIGINAL_ARTICLE
Theoretical Study of the Molecular Complexes between Pyridyne and Acid Sites of Zeolites
The main interaction between pyridine and zeolites leads to form a hydrogen bond between the N atom of pyridine and OH groups of zeolites. The present work reports a theoretical study about the structural, vibrational and topological properties of the charge distribution of the molecular complexes between pyridine and a series of acids sites of zeolites. The calculated structural parameters are the highest occupied molecular orbital energy (EHOMO), lowest unoccupied molecular orbital energy (ELUMO), energy gap (ΔE), hardness (η), softness (S), the absolute electronegativity (χ), the electrophilicity index (ω) and the fractions of electrons transferred (ΔN) from zeolites molecules to pyridine. We show N atom of pyridine attacks to the H atom of the OH bridged group of zeolite clusters.
https://ijcce.ac.ir/article_31174_ff1cd38bb2d5d600cf05da8b4761ebae.pdf
2018-08-01
183
192
10.30492/ijcce.2018.31174
Pyridine
Zeolites, MP2
Fukui function
Maryam
Dehestani
dehestani2002@yahoo.com
1
Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, I.R. IRAN
LEAD_AUTHOR
Sedigheh
Pourestarabadi
s.estarabadi@gmail.com
2
Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, I.R. IRAN
AUTHOR
Leila
Zeidabadinejad
lzeidabadi@yahoo.com
3
Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, I.R. IRAN
AUTHOR
[1] Bakke J. M., Nitropyridines: Synthesis and Reactions, Pure Appl. Chem., 75 (10): 1403-1415 (2003).
1
[2] Badgujar D.M., Talawar M.B., Asthana S.N., Mahulikar P.P., Studies of Antimicrobial Activity of Picryl Amino Pyridine N-Oxid, Pharmaceutical and Agrochemical Compounds, Indian J. Chem, 49B:1675-1677 (2010).
2
[3] Joshaghani M., Sotodehnejad M., Potentiometric Study of Complex Formation between Some Transition Metal Ions and 2 - Aminopyridine, Part 1. A Model for Therapeutic Agent for Wilson’s Disease, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 22(2): 17-21 (2003).
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[5] Corma A., Solid Acid Catalysts, Curr. Opin. Solid State Mater. Sci., 2 (1): 63-75 (1997).
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[7] Holm M.S., Taarning E., Egeblad K., Christensen C.H., Catalysis with Hierarchical Zeolites, Catal. Today, 168 (1): 3-16 (2011).
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[8] Chen C., Cheng T., Shi Y., Tian Y., Adsorption of Cu(II) from Aqueous Solution on Fly Ash Based Linde F (K) Zeolite, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 33 (3): 29-35 (2014).
8
[9] Sistani S., Ehsani MR., Kazemian H., Microwave Assisted Synthesis of Nano Zeolite Seed for Synthesis Membrane and Investigation of its Permeation Properties for H2 Separation, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 29 (4): 99-104 ( 2010).
9
[10] Yousefpour M., Modelling of Adsorption of Zinc and Silver Ions on Analcime and Modified Analcime Zeolites Using Central Composite Design, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 36 (4): 81-90 ( 2017).
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[11] Hinchliffe A., Soscún H., Ab Initio Studies of the Dipole Polarizabilities of Conjugated Molecules: Part 5. The Five-Membered Heterocyclics C4H4E (E = BH, AlH, CH2, SiH2, NH, PH, O and S), J. Mol. Struct: Theochem., 331 (1): 109-125 (1995).
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[12] Soscún H., Hernández J., Castellano O., Diaz G., Hinchliffe A., Ab Initio SCF- MO Study of the Topology of the Charge Distribution of Acid Sites of Zeolites, Int. J. Quantum Chem., 70: 951–960 (1998).
12
[13] Zeidabadinejad L., Dehestani M., Pourestarabadi S., On the Chemical Bonding Features in Palladium Containing Compounds: A Combined QTAIM/DFT Topological Analysis, J. Struct. Chem., 58: 471–478 (2017).
13
[14] Mousavi Fard B., Zeidabadinejad L., Pourastarabadi S., Dehestani M., Investigation of Interaction of Vanillin with Alpha, Beta and Gamma-Cyclodextrin as Drug Delivery Carriers: Brief Report, Tehran Univ Med J, 73(2): 132-137 (2015).
14
[15] Dehestani M., Pourestarabadi S., A density Functional Theory and Quantum Theory of Atoms in Molecules Study on Hydrogen Bonding Interaction between Paracetamol and Water Molecules, Russ. J. Phys. Chem. B, 10 (6): 890–896 (2016).
15
[16] Zeidabadinejad L., Dehestani M., A Theoretical Study of the Structural, Vibrational, and Topological Properties of Charge Distribution of the Molecular Complexes between Furan and Zeolites, Sci. Iran, 22(6): 2262-2270 (2015).
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[17] Dehestani M., Zeidabadinejad L., Pourestarabadi S., QTAIM Investigations of Decorated Graphyne and Boron Nitride for Li Detection, J. Serb. Chem. Soc., 82(3): 289-301 (2017).
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34
ORIGINAL_ARTICLE
Nanofluid Condensation and MHD Flow Modeling over Rotating Plates Using Least Square Method (LSM)
In this study, nanofluid condensation and MHD flow analysis over an inclined and rotating plate are investigated respectively using Least Square Method (LSM) and numerical method. After presenting the governing equations and solving them by LSM, the accuracy of results is examined by the fourth order Runge-Kutta numerical method. For condensation, modeling results show that the condensate film thickness is reduced and in turn, the rate of heat transfer is enhanced by the addition of nanoparticles to the regular fluid. Effect of normalized thickness on velocity and temperature profiles reveals that increasing normalized thickness leads to an increase in f, f’ and a decrease in g, q. Effect of normalized thickness on k and s are similar to those of f’ and g, respectively.
https://ijcce.ac.ir/article_30588_677f107fd2bc0f0bd7d504817bb641bd.pdf
2018-08-01
193
203
10.30492/ijcce.2018.30588
nanofluid
LSM
condensation
Nusselt number
Heat Transfer
Mohammad
Hatami
m.hatami2010@gmail.com
1
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, CHINA
LEAD_AUTHOR
Sobhan
Mosayebidorcheh
sobhan_phd@yahoo.com
2
Young Researchers and Elite Club, Najafabad Branch, Islamic Azad University, Najafabad, I.R. IRAN
AUTHOR
Dengwei
Jing
3
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, CHINA
AUTHOR
[1] Stefan M.J., Versuch Über Die Scheinbare Adhesion, Akad Wissensch Wien Math Natur, 69: 713–721 (1874).
1
[2] Mahmood M, Asghar S, Hossain MA, Squeezed Flow and Heat Transfer over a Porous Surface for Viscous Fluid, Heat Mass Transf, 44: 165–173 (2007).
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[3] Abd-El Aziz M., Unsteady Fluid and Heat Flow Induced by a Stretching Sheet with Mass Transfer and Chemical Reaction, Chem Eng Commun, 197: 1261–1272 (2010).
3
[4] Domairry G., Aziz A., Approximate Analysis of MHD Squeeze Flow between Two Parallel Disks with Suction or Injection by Homotopy Perturbation Method, Math Probl Eng., 2009:603916 (2009).
4
[5] Mustafa M., Hayat T., Obaidat S., On Heat and Mass Transfer in the Unsteady Squeezing Flow between Parallel Plates, Meccanica, 47: 1581-1589 (2012).
5
DOI 10.1007/s11012-012-9536-3.
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[6] Turkyilmazoglu M., Analytical Solutions of Single and Multi-Phase Models for the Condensation of Nanofluid Film Flow and Heat Transfer, European Journal of Mechanics B/Fluids, 53: 272–277 (2015).
7
[7] Hatami M., Domairry G., Transient Vertically Motion of a Soluble Particle in a Newtonian Fluid Media, Powder Technology, 253: 481-485 (2014).
8
[8] Hatami M., Ganji D.D., Motion of a Spherical
9
Particle on a Rotating Parabola Using Lagrangian and High Accuracy Multi-step Differential Transformation Method, Powder Technology, 258: 94-98 (2014).
10
[9] Hatami M., Ganji D.D., Motion of a Spherical Particle in a Fluid Forced Vortex by DQM and DTM, Particuology, 16: 206-212 (2014).
11
[10] Dogonchi A.S., Hatami M., Domairry G., Motion Analysis of a Spherical Solid Particle in Plane Couette Newtonian Fluid Flow, Powder Technology, 274: 186-192 (2015).
12
[11] Haghshenas Fard M., Nasr Esfahany M., Talaie M.R., Numerical Study of Convective Heat Transfer of Nanofluids in a Circular Tube Two-Phase Model Versus Single-Phase Model, International Communications in Heat and Mass Transfer, 37: 91–97 (2010).
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[12] GöktepeS., Atalık K., Ertürk H., Comparison of Single and Two-Phase Models for Nanofluid Convection at the Entrance of a Uniformly Heated Tube, International Journal of Thermal Sciences, 80: 83-92 (2014).
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[13] Syed Tauseef Mohyud-Din, Zulfiqar Ali Zaidi,
15
Umar Khan, Naveed Ahmed, On Heat and Mass Transfer Analysis for the Flow of a Nanofluid between Rotating Parallel Plates, Aerosp. Sci. Technol. (2015),
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[14] HayatT., Imtiaz M., Alsaedi A., KutbiM.A., MHD Three-Dimensional Flow of Nanofluid with Velocity Slip and Nonlinear Thermal Radiation, Journal of Magnetism and Magnetic Materials, 396: 31–37 (2015).
17
[15] Khan J.A., Mustafa M., Hayat T., Alsaedi A., Three-Dimensional Flow of Nanofluid over a Non-Linearly Stretching Sheet: An Application to Solar Energy, Int. J. Heat. Mass. Trans., 86: 158-164(2015).
18
[16] Hatami M., Ganji D.D., Natural Convection of Sodium Alginate (SA) Non-Newtonian Nanofluid Flow between Two Vertical Flat Plates by Analytical and Numerical Methods, Case Studies
19
in Thermal Engineering, 2: 14-22 (2014).
20
[17] Fakour M., Vahabzadeh A., Ganji D.D., Hatami M., Analytical Study of Micropolar Fluid Flow and Heat Transfer in a Channel with Permeable Walls, Journal of Molecular Liquids, 204: 198-204 (2015).
21
[18] Ghasemi S.E., Hatami M., Kalani Sarokolaie A., Ganji D.D., Study on Blood Flow Containing Nanoparticles through Porous Arteries in Presence of Magnetic Field Using Analytical Methods, Physica E: Low-dimensional Systems and Nanostructures, 70: 146-156 (2015)
22
[19] Ghasemi S.E., Hatami M., Mehdizadeh Ahangar Gh.R., Ganji D.D., Electrohydrodynamic Flow Analysis
23
in a Circular Cylindrical Conduit Using Least Square Method, Journal of Electrostatics, 72(1): 47-52 (2014).
24
[20] Rahimi-Gorji M., Pourmehran O., Hatami M.,
25
Ganji D.D., Statistical Optimization of Microchannel Heat Sink (MCHS) Geometry Cooled by Different Nanofluids Using RSM Analysis, The European Physical Journal Plus, 130: 22- (2015).
26
[21] Domairry G., Hatami M., Squeezing Cu–Water Nanofluid Flow Analysis between Parallel Plates
27
by DTM-Padé Method, Journal of Molecular Liquids, 193: 37-44 (2014).
28
[22] Ahmadi A.R., Zahmatkesh A., Hatami M., Ganji D.D., A Comprehensive Analysis of the Flow and Heat Transfer for a Nanofluid over an Unsteady Stretching Flat Plate, Powder Technology, 258: 125-133 (2014).
29
[23] Ozisik M.N., “Heat Conduction”, 2nd ed., John Wiley & Sons Inc. USA, (1993).
30
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[25] Vaferi B., Salimi V., Dehghan Baniani D., Jahanmiri A., Khedri S., Prediction of Transient Pressure
32
Response in the Petroleum Reservoirs Using Orthogonal Collocation, J. of Petrol. Sci. and Eng. (2012).
33
[26] Hatami M., Ganji D.D., Thermal Behavior of Longitudinal Convective–Radiative Porous Fins with Different Section Shapes and Ceramic Materials (SiC and Si3N4), Ceramics International, 40(5): 6765-6775 (2014).
34
[27] Hatami M., Ganji D.D., Investigation of Refrigeration Efficiency for Fully Wet Circular Porous Fins with Variable Sections by Combined Heat and Mass Transfer Analysis, International Journal of Refrigeration, 40: 140-151 (2014).
35
[28] Hatami M., Mehdizadeh Ahangar GH.R., Ganji D.D., Boubaker K., Refrigeration Efficiency Analysis for Fully Wet Semi-Spherical Porous Fins, Energy Conversion and Management, 84: 533-540 (2014).
36
[29] Ghasemi S.E., Valipour P., Hatami M., Ganji D.D., Heat Transfer Study on Solid and Porous Convective Fins with Temperature-Dependent Heat Generation Using Efficient Analytical Method, Journal of Central South University, 21(12): 4592-4598 (2014).
37
[30] Shaoqin G., Huoyuan D., Negative Norm Least-Squares Methods for the Incompressible Magneto-Hydrodynamic Equations, Act. Math. Sci., 28B(3): 675–684 (2008).
38
[31] Ghasemi S.E., Hatami M., Ganji D.D., Thermal Analysis of Convective Fin with Temperature-Dependent Thermal Conductivity and Heat Generation, Case Studies in Thermal Engineering, 4: 1-8 (2014).
39
[32] Aziz A., “Heat Conduction with Maple”, Philadelphia (PA), R.T. Edwards, (2006).
40
[33] Hatami M., Cuijpers M.C.M., Boot M.D., Experimental Optimization of the Vanes Geometry for a Variable Geometry Turbocharger (VGT) Using a Design of Experiment (DoE) Approach, Energy Conversion and Management, 106: 1057-1070 (2015).
41
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42
ORIGINAL_ARTICLE
Conventional and Advanced Exergetic and Exergoeconomic Analysis Applied to an Air Preheater System for Fired Heater (Case Study: Tehran Oil Refinery Company)
TThe present paper evaluates the plan of combustion air pre-heater installation on the fired heater from thermodynamics and thermos-economics point of view. As a real case study, one of the fired heaters (H_101) of Distillation unit in Tehran Oil Refinery, Iran, is intended. With applying an air pre-heater in this study, flue gases temperature falls down from 430 ºC to 200ºCand combustion air temperature grows up from 25ºCto 350 ºC. By examining the energy and exergy analyses before and after the installation of air pre-heater, the increase in thermal efficiency by 20% and exergy efficiency by 37% and accordingly decreasing fuel consumption by 20% is observed. It is also indicated that the most exergy destruction is accrued in the fired heater (57.24%). In this study for the first time, based on advanced exergy analyses and concepts of endogenous/exogenous and avoidable/unavoidable parts, exergy destruction, exergy destruction cost rates and capital investment of combustion air preheater system are found which results show the endogenous and unavoidable parts in overall system are dominant. Also, the effect of flue gases temperature (T5) on the system performance is investigated through sensitivity analyses. It is seen that with rising T5, thermal efficiency and exergy efficiency in real, theory and unavoidable conditions decrease. The results demonstrate the majority parts of exergy destruction in fired heater and air preheater is endogenous, unavoidable and unavoidable endogenous. Considering the cost of air preheater and related equipment and operating and maintenance costs annually, the payback period is estimated to be less than 2 years. In this research, the EES and Excel were applied to calculate the amount.
https://ijcce.ac.ir/article_28879_b00f4533f8ddafc4cc847ce1117f9281.pdf
2018-08-01
205
219
10.30492/ijcce.2018.28879
Air pre-heater
thermal efficiency
Exergy Efficiency
Exergy analyses
Advanced exergy analyses
Ali Reza
Noorpoor
noorpoor@ut.ac.ir
1
Graduate Faculty of Environment, College of Engineering, University of Tehran, PO. Box 1416853534 Tehran, I.R. IRAN
LEAD_AUTHOR
Fatemeh
Mazare
fatemeh.mazare@ut.ac.ir
2
Graduate Faculty of Environment, College of Engineering, University of Tehran, PO. Box 1416853534 Tehran, I.R. IRAN
AUTHOR
[1] Ghodsipour N., Sadrameli M., Experimental and Sensitivity Analysis of a Rotary Air preheater for the Flue Gas Heat Recovery, Applied Thermal Engineering,,. 23(5): 571-580 (2003).
1
[2] Hasanuzzaman M., Nasrudin A.R., Saidur R., Energy Savings in the Combustion Based Process Heating in Industrial Sector, Renewable and Sustainable Energy Reviews, 16(7): 4527-4536 (2012).
2
[3] Shekarchian M., Zarifi F., Moghavvemi M., Motasemi F., Mahlia T.M., Energy, Exergy, Environmental and Economic Analysis of Industrial Fired Heaters Based on Heat Recovery and Preheating Techniques, Energy Conversion and Management, 71: 51-61 (2013).
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[5] Weber R., Orsino S., Lallemant N., Verlaan A., Combustion of Natural Gas with High-Temperature Air and Large Quantities of Flue Gas, Proceedings of the Combustion Institute, 28(1): 1315-1321 (2000).
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[6] Choi G.-M., Katsuki M., Advanced Low NOx Combustion Using Highly Preheated Air, Energy Conversion and Management, 42(5): 639-652 (2001).
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[7] Kawai K., Yoshikawa K., Kobayashi H., Syan T.J., Matsuo M., Katsushima H., Kawai K., High Temperature Air Combustion Boiler for Low BTU Gas, Energy Conversion and Management, 43(9): 1563-1570 (2002).
7
[8] Asgari S., Noorpoor A., Boyaghchi F.A., Parametric Assessment and Multi-Objective Optimization of an Internal Auto-Cascade Refrigeration Cycle Based on Advanced Exergy and Exergoeconomic Concepts, Energy, 125: 576-590 (2017).
8
[9] Boyaghchi F.A., Molaie H., Sensitivity Analysis of Exergy Destruction in a Real Combined Cycle Power Plant Based on Advanced Exergy Method, Energy Conversion and Management, 99: 374-386 (2015).
9
[10] Wang H.Y., Zhao L.L., Zhou Q.T., Xu Z.G., Wang H.Y., Exergy Analysis on the Irreversibility of Rotary Air Preheater in Thermal Power Plant, Energy, 33(4): 647-656 (2008).
10
[11] Tsatsaronis G., Morosuk T., Advanced Exergetic Aanalysis of a Novel System for Generating Electricity and Vaporizing Liquefied Natural Gas, Energy, 35(2): 820-829 (2010).
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[14] Varghese J., Bandyopadhyay S., Improved Area—Energy Targeting for Fired Heater Integrated Heat Exchanger Networks, Chemical Engineering Research and Design, 90(2): 213-219 (2012).
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[15] Aisyah L., Rulianto D., Wibowo C.S., Analysis of the Effect of Preheating System to Improve Efficiency in LPG-fuelled Small Industrial Burner, Energy Procedia, 65: 180-185 (2015).
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[16] Huang M., Zhang Z., Shao W., Xiong Y., Effect of Air Preheat Temperature on the MILD Combustion of Syngas, Energy Conversion and Management, 86: 356-364 (2014).
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[37] Tsatsaronis G., Park M.-H., On Avoidable and Unavoidable Exergy Destructions and Investment Costs in Thermal Systems, Energy Conversion and Management, 43(9): 1259-1270 (2002).
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42
ORIGINAL_ARTICLE
Drying of Matricaria recutita Flowers in Vibrofluidized Bed Dryer: Optimization of Drying Conditions Using Response Surface Methodology
Drying of Matricaria recutita flower was investigated experimentally in a VibroFluidized Bed Dryer (VFBD). The aim of the present work was to optimize the best operating conditions for the drying of Matricaria recutita flower in the VFBD based on experimental design techniques. Response Surface Methodology (RSM) and Central Composite Design (CCD) based on 4-variable with 5-level have been employed to achieve the desirable possible combinations of frequency of vibration (7-15 Hz), inlet air temperature (36-68 °C), air flow rate (16-24 m3/h), and drying time (30-70 min) for the highest responses in terms of moisture removal (MR) and thermal efficiency (). A full quadratic model was used to describe the effects of individual and interactive parameters on the responses. The analysis of the obtained results showed that the inlet air temperature has the largest effect on responses. The optimal process parameters were as follows: frequency of vibration of 10.88 Hz, inlet air temperature of 64.08 °C, air flow rate of 20.63 m3/h and drying time of 69.11 min in which the predicted value for the MR (%) and (%) was 86.76 and 53.05, respectively. The proposed optimal conditions were examined in the laboratory and MR (%) and (%) achieved as 87.12±0.25% and 52.78±0.34%, respectively. The experimental values agreed with those predicted by RSM models, thus indicating the suitability of the model employed and the success of RSM in optimizing the drying conditions.
https://ijcce.ac.ir/article_28216_749887283e4d4b5ddfde3e925e6a07d4.pdf
2018-08-01
221
233
10.30492/ijcce.2018.28216
Matricaria recutita flower
Response surface methodology
Vibrofluidized bed dryer
Moisture removal
thermal efficiency
Sahar
Zamani
zamani_r91@yahoo.com
1
Processes Intensification Research Lab, Department of Chemical Engineering, Faculty of Engineering, Yasouj University, P.O. Box 75918-74831 Yasouj, I.R. IRAN
AUTHOR
Mahmood Reza
Rahimi
mrrahimi@yu.ac.ir
2
Processes Intensification Research Lab, Department of Chemical Engineering, Faculty of Engineering, Yasouj University, P.O. Box 75918-74831 Yasouj, I.R. IRAN
LEAD_AUTHOR
Hossein
Sadeghi
h_sadeghi_m@yahoo.com
3
Medicinal Plants Research Center, Yasuj University of Medical Sciences, P.O. Box 75917-41417 Yasuj, I.R. IRAN
AUTHOR
[1] Chandrashekhar V.M., Halagali K.S.R., Nidavani B., Shalavadi M.H., Biradar B.S., Biswas D., Muchchandi I.S., Anti-Allergic Activity of German Chamomile (Matricaria recutita L.) in Mast Cell Mediated Allergy Model, J. Ethnopharmacol,137(1): 336–340 (2011).
1
[2] Díaz-Maroto M.C., Pérez-Coello M.S., González Vinas M.A., Cabezudo M.D., Influence of Drying on the Flavor Quality of Spearmint (Mentha spicata L.), J. Agric. Food. Chem, 51(5): 1265–1269 (2003).
2
[3] Hamrouni-Sellami I., Bettaieb Rebey I., Sriti J., Zohra Rahali F., Limam F., Marzouk B., Drying Sage (Salvia officinalis L.) Plants and Its Effects on Content, Chemical Composition, and Radical Scavenging Activity of the Essential Oil, Food. Bioprocess. Technol, 5(8):2978-2989 (2011b).
3
[4] Hamrouni-Sellami I., Wannes W.A., Bettaieb I., Berrima S., Chahed T., Marzouk B., Limam F., Qualitative and Quantitative Changes in the Essential Oil of Laurus Nobilis L. Leaves as Affected by Different Drying Methods, Food. Chem, 126(2): 691–769 (2011a).
4
[5] Rahimmalek M., Hossein Golib S.A., Evaluation of Six Drying Treatments with Respect to Essential oil Yield, Composition and Color Characteristics of Thymys daenensis subsp. daenensis. Celak Leaves, Ind. Crop. Prod, 42: 613-619 (2013).
5
[6] Erbay Z., Icier F., Optimization of Hot Air Drying of Olive Leaves Using Response Surface Methodology, J Food Eng, 91(4): 533–541(2009).
6
[7] Torki Harchegan M., Sadeghi M., Ghanbarian D., MohebA.,Dehydration Characteristics of Whole Lemons in a Convective Hot Air Dryer, Iran. J. Chem. Chem. Eng. (IJCCE), 35:65-73(2016).
7
[8] Ghasemi Pirbalouti A., Oraiec M., Pouriamehrc M., Solaymani Babadia E., Effects of Drying Methods on Qualitative and Quantitative of the Essential Oil of Bakhtiari Savory (Satureja bachtiarica Bunge.), Ind. Crop. Prod, 46: 324–327(2013).
8
[9] Rahimi M.R., Zamani R., Sadeghi H., An Investigation on Drying Kinetics of Chamomile Flower in Vibrofluidized Bed Dryer, International Journal of Chemical Engineering and Applications, 5(2): 190-194, (2014).
9
[10] Mića V., Jelena J., Goran V., Branislav S., Experimental Investigation of the Drying Kinetics of Corn in a Packed and Fluidized Bed, Iran. J. Chem. Chem. Eng. (IJCCE), 34(3):43-49(2015).
10
[11]Soysal Y., Microwave Characteristics of Parsley, Biosyst Eng, 89(2):167–173(2004).
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[12] Soysal Y., Oztekin S., Technical and Economic Performance of a Tray Dryerfor Medicinal and Aromatic Plants, J. Agric. Eng. Res, 79(1): 73–79 (2001).
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[14] Mujumdar A.S., Erdesz K., Applications of Vibration Techniques for Drying and Agglomeration in Food Processing, Drying. Technol., 6: 255-274 (1988).
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[15] Abbasyadeh A., Motevali A., Ghobadian B., Khoshtaghaza M., Minaei S., Effect of Air Velocity and Temperature on Energy and Effective Moisture Diffusivity for Russian Olive in Thin-Layer Drying, Iran. J. Chem. Chem. Eng. (IJCCE), 31(1): 75-79 (2012).
15
[16] Rahimi M.R., Zamani R., Sadeghi H., Rahmani Tayebi A., An Experimental Study of Different Drying Methods on the Quality and Quantity Essential Oil of Myrtus communis L.leaves, J. Essent. Oil. Bear. Pl, 18: 1395-1405 (2014).
16
[17] Lopesda Cunha R., dela Cruz A.G., Menegalli F.C., Effects of Operating Conditions on the Quality of Mango Pulp Dried in a Spout Fluidized Bed, Drying Technol, 24(4): 423-432 (2006).
17
[18] Corzo O., Barcho N., Vasquez A., Optimization of a Thin Layer Drying Process for Coroba Slices, J. Food. Eng, 85: 372-380 (2008).
18
[19] Han Q.H., Yin L.J., Li S.J., Yang B.N., Ma J.W., Optimization of Process Parameters for Microwave Vacuum Drying of Apple Slices Using Response Surface Method, Drying Technol., 28(4): 523-532 (2010).
19
[20] Chakraborty R., Bera M., Mukhopadhyay P., Bhattachary P., Prediction of Optimal Conditions of Infrared Assisted Freeze-Drying of Aloe Vera (Aloe Barbadensis) Using Response Surface Methodology, Sep. Purif. Technol., 80(2): 375–384 (2011).
20
[21] Muzaffar K., Kumar P., Parameter Optimization for Spray Drying of Tamarind Pulp Using Response Surface Methodology, Powder. TechnoL., 279: 179–184 (2015)
21
[22] Wang G., Deng Y., Xu X., He X., Zhao Y., Zou Y., Liu Z., Yue J., Optimization of Air Jet Impingement Drying of Okara Using Response Surface Methodology, Food. Control., 59: 743-749 (2016).
22
[23] Goula A.M., Adamopoulos K.G., Spray Drying Performance of a Laboratory Spray Dryer for Tomato Powder Preparation, Drying Technol., 21(7): 1273–1289 (2003).
23
[24] Morgan E., "Chemometrics: Experimental Design", John Wiley & Sons Inc., London (1991).
24
[25]Kundu A., Karmakar M., Ray R., Simultaneous Production of Animal Feed Enzymes (Endoxylanase and Endoglucanase) by Penicillium Janthinellum from Waste Jute Caddies, International Journal of Recycling of Organic Waste in Agriculture, 13: 1-13 (2012).
25
[26] Liu Y., Wei S., Liao M., Optimization of Ultrasonic Extraction of Phenolic Compounds from Euryale Ferox Seed Shells Using Response Surface Methodology, Ind. Crop. Prod., 49: 837–843 (2013).
26
[27] Hamsaveni D.R., Prapulla S.G., Divakar S., Response Surface Methodological Approach for the Synthesis of Isobutyl Butyrate, Process. Biochem., 36: 1103-1110 (2011).
27
[28] Yanga Q., Chenc H., Zhouc X., Zhangd J., Optimum Extraction of Polysaccharides from Opuntia Dillenii and Evaluation of Its Antioxidant Activities, Carbohydr. Polym., 97(2): 736–742 (2013).
28
[29] Ferreira S.L.C., Bruns R.E., Ferreira H.S., Matos G.D., David J.M., Brandao G.C., Silva E.G.P., Portugal L.A., Reis P.S., Souza A.S., Santos W.N.L., Box–Behnken Design: an Alternative for the Optimization of Analytical Methods, Anal. Chim. Acta, 597(2): 179–186(2007).
29
[30] Guo X., Zou X., Sun, M., Optimization of Extraction Process by Response Surface Methodology and Preliminary Characterization of Polysaccharides from Phellinus Ignoramus, Carbohydr. Polym., 80(2): 344–349 (2010).
30
[31] Wei Z.J., Liao A.M., Zhang H.X., Liu J., Jiang S.T., Optimization of Supercritical Carbon Dioxide Extraction of Silkworm Pupal Oil Applying the Response Surface Methodology, Bioresour. Technol., 100(18): 4214–4219 (2009).
31
[32] Lu C.H., Engelmann N.J., Lila M.A., Erdman J.W., Optimization Oflycopene Extraction from Tomato Cell Suspension Culture by Response Surface Methodology, J. Agric. Food. Chem., 56(17): 7710–7714 (2008).
32
[33] Anuradha Jabasingh S., Valli Nachiyar C., Utilization of Pretreated Bagasse for the Sustainable Bioproduction of Cellulase by Aspergillus Nidulans MTCC344 Using Response Surface Methodology, Ind. Crop. Prod., 34(3): 1564–1571 (2011)
33
[34] Muralidhar R.V., Chirumamila R.R., Marchant R., Nigam P., A Response Surfaceapproach for the Comparison of Lipase Production by Candida Cylindracea Using Two Different Carbon Sources, Biochem. Eng. J., 9(1):17–23 (2001).
34
ORIGINAL_ARTICLE
Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model
A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation) and Eyring absolute rate theory were used to fit the viscosity values of ternary aqueous solutions of polymer + electrolyte with considering temperature dependency. The local composition models which are available for correlating the thermodynamic properties of ternary polymer + electrolyte solutions (ternary-Wilson, ternary-modified NRTL, and ternary-modified Wilson) with Eyring absolute rate theory were also used for fitting the viscosity values of ternary solutions for the first time. THe fitting quality of Eyring-TNRF-mNRTL model was compared with these models. The equations of apparent molar volume were also derived from TNRF-mNRTL, ternary-Wilson, ternary-modified NRTL, and ternary-modified Wilson models. These equations were used for correlating the apparent molar volume and density values of ternary polymer + electrolyte solutions.
https://ijcce.ac.ir/article_28218_7854e134555468ae9540b61ac7c418e5.pdf
2018-08-01
235
252
10.30492/ijcce.2018.28218
Modeling
Viscosity
Density
solutions
TNRF-mNRTL model
Ali
Mohammadian-Abriz
ali880015332@gmail.com
1
Department of Chemical Engineering, East Azarbaijan Science and Research Branch, Islamic Azad University, Tabriz, I.R. IRAN
AUTHOR
Roghayeh
Majdan-Cegincara
majdan944@gmail.com
2
Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
LEAD_AUTHOR
[1] Albertsson P.A., Partition of Proteins in Liquid Polymer-Polymer Two-Phase Systems, Nature 182: 709–711 (1958).
1
[2] Rogers R.D., Zhang J., New Technology for ion Separations Polyethylene Glycol Based-Qqueous Biphasic System and Qqueous Biphasic Extraction Chromatography. In: Marinsky, J.A., Marcus, Y. (Eds.), “Ion Exchange and Solvent Extraction”,
2
Vol. 13. Marcel Dekker, New York, pp.141–193 (Chapter 4) (1997).
3
[3] Willauer H.D., Huddleston J.G., Rogers R.D., Solute Partitioning in Aqueous Biphasic Systems Composed of Polyethylene Glycol and Salt: The Partitioning of Small Neutral Organic Species, Ind. Eng. Chem. Res. 41: 1892–1904 (2002).
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[4] Albertsson P.-A., Johansson G., Tjerneld F. “Separation Processes in Biotechnology”, Marcel Dekker, New York, (1990).
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[5] Jimenez Y. P., Taboada M. E., Graber T. A., Galleguillos H. R., Measurement and Modeling of Density and Viscosity of the NaClO4+ H2O+ Poly (Ethylene Glycol) System at Various Temperatures, Fluid Phase Equilibria 334: 22– 29 (2012).
6
[6] Sadeghi R., Jamehbozorg B., Volumetric and Viscosity Studies of Interactions between Sodium Phosphate Salts and Poly(propylene glycol) 400 in Aqueous Solutions at Different Temperatures, Fluid Phase Equilibria 284: 86–981 (2009).
7
[7] Zafarani-Moattar M. T., Salabat A., Measurement and Correlation of Viscosities, Densities, and Water Activities for the System Poly(propylene glycol) + MgSO4 + H2O at 25°C, J. Solution Chem., 27: 663-673 (1998).
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[8] Ahmad Kalayeh S., Ghotbi C., Taghikhani V., Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule, Iran. J. Chem. Chem. Eng. (IJCCE), 32(2): 9-17 (2013).
9
[9] Sadeghi R., Golabiazar R., Ziaii M., Vapor-Liquid Equilibria, Density, Speed of Sound, and Refractive Index of Sodium Tungstate in Water and in Aqueous Solutions of Poly(ethyleneglycol) 6000, J. Chem. Eng. Data 55, 125–133 (2010).
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[10] Chen C.C., Britt H.I., Boston J.F., Evans L.B., Local Composition Model for Excess Gibbs Energy of Electrolyte Systems. Part I: Single Solvent, Single Completely Dissociated Electrolyte Systems, AIChE J. 28: 588-596 (1982).
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[11] Flory P.J., Thermodynamics of High Polymer Solutions, J. Chem. Phys. 9: 660–661 (1941).
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[12] Pitzer K.S., Activity Coefficients in Electrolyte Solutions, J. Am. Chem. Soc., 102: 2902-2906 (1980).
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[13] Glasstone S., Laidler K. J., Eyring H. “The Theory of Rate Process”, McGraw-Hill: New York: (1941).
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[14] Sadeghi R., modified Wilson Model for the Calculation of Vapour + Liquid Equilibrium of Aqueous Polymer + Salt Solutions, J. Chem. Thermodyn., 37: 323–329 (2005).
15
[15] Sadeghi R., A Modified Segment-Based Nonrandom Two-Liquid Model for the Calculation of Vapor–Liquid Equilibrium of Aqueous Polymer–Salt Solutions, Chem. Eng. Sci., 61: 7786–7794 (2006).
16
[16] Sadeghi R. Representation of Vapor–Liquid Equilibria of Aqueous Polymer–Salt Solutions by a New Modified Segment-Based Wilson Model, CALPHAD 31: 164–172 (2007).
17
[17] Chen C.C., A Segment-Based Local Composition Model for the Gibbs Energy of Polymer Solutions,Fluid Phase Equilib. 83: 301-312 (1993).
18
[18] Haghtalab A., Vera J. H., A Nonrandom Factor Model for the Excess Gibbs Energy of Electrolyte Solutions, AIChE J., 34: 803-813 (1988).
19
[19] Zafarani-Moattar M. T., Majdan-Cegincara R. New Local Composition Model for Modeling of Thermodynamic and Transport Properties of Binary Aqueous Electrolyte Solutions, CALPHAD, 35: 109–132 (2011).
20
[20] Zafarani-Moattar M. T., Majdan-Cegincara R., New Excess Gibbs Energy Equation for Modeling the Thermodynamic and Transport Properties of Polymer Solutions and Nanofluids at Different Temperatures, Ind. Eng. Chem. Res., 50: 8245-8262 (2011).
21
[21] Mohammadian-Abriz A., Majdan-Cegincara R., Modeling the Thermodynamic Properties of Solutions Containing Polymer and Electrolyte with New Local Composition Model, Phy. Chem. Res., 5: 505-518 (2017)
22
[22] Esteves M.J.C., Cardoso M.J.E. de M., Barcia O.E.,A Debye-Hückel Model for Calculating the Viscosity of Binary Strong Electrolyte Solutions, Ind. Eng. Chem. Res., 40: 5021-5028 (2001).
23
[23] Novak L.T., Chen C.C., Song Y., Segment-Based Eyring-NRTL Viscosity Model for Mixtures Containing Polymers, Ind. Eng. Chem. Res., 43B 6231-6237 (2004).
24
[24] Martins R.J., M. J. E. de M. Cardoso, Barcia O.E., Excess Gibbs Free Energy Model for Calculating the Viscosity of Binary Liquid Mixtures, Ind. Eng. Chem. Res., 39: 849-854 (2000).
25
[25] Simonson J. M., Pitzer K. S. Thermodynamics of Multicomponent, Miscible Ionic Systems: the System Lithium Nitrate-Potassium Nitrate-Water, J. Phys. Chem., 90: 3009-3013 (1986).
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[26] Sardroodi J. J., Zafarani-Moattar M. T., Apparent Molal Volumes of the Solutions of CaCl2 and Ca(NO3)2 in Ethanol at 298.15: Experimental Data and Correlation by Local Composition Models, Fluid Phase Equilibria, 231: 61–66 (2005).
27
[27] Anathaswamy J., Atkinson G. Thermodynamics of Concentrated Electrolyte Mixtures. 4. Pitzer-Debye-Hueckel Limiting Slopes for Water from 0 to 100. Degree. C and from 1 atm to 1 kbar, J. Chem. Eng. Data, 29: 81-87 (1984).
28
[28] Kell G.S., Density, Thermal Expansivity, and Compressibility of Liquid Water from 0.deg. to 150.deg.. Correlations and Tables for Atmospheric Pressure and Saturation Reviewed and Expressed on 1968 Temperature Scale, J. Chem. Eng. Data, 20: 97-105 (1975).
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[29] Laliberté M., Model for Calculating the Viscosity of Aqueous Solutions, J. Chem. Eng. Data, 52: 321-335 (2007).
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[30] Vidulich G.A., Evans D.F., Kay R.L., The Dielectric Constant of Water and Heavy Water between 0 and 40. Degree, J. Phys. Chem., 71: 656-662 (1967).
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[31] Akerlof G.C., Oshry H.I., The Dielectric Constant of Water at High Temperatures and in Equilibrium with its Vapor, J. Am. Chem. Soc., 72: 2844-2847 (1950).
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[32] Regupathi I., Govindarajan R., Pandian Amaresh S., Murugesan T., Densities and Viscosities of Polyethylene Glycol 6000 + Triammonium Citrate +Water Systems, J. Chem. Eng. Data, 54: 3291-3295 (2009).
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[33] Mei L.-H., Lin D.-Q., Zhu Z.-Q., Han Z.-X., Densities and Viscosities of Polyethylene Glycol + Salt + Water Systems at 20 °C, J. Chem. Eng. Data, 40: 1168-1171 (1995).
34
[34] Salabat A., Dashti H., Phase Compositions, Viscosities and Densities of systems PPG425+ Na2SO4+H2O and PPG425 + (NH4)2SO4 + H2O at 298.15 K, Fluid Phase Equilib., 216: 153-157 (2004).
35
ORIGINAL_ARTICLE
Consequences Modeling of the Akçagaz Accident through Land Use Planning (LUP) Approach
In the study, consequences analysis of Akçagaz LPG Facilities accident was conducted. The consequences analysis, modeling studies were performed by the use of EFFECTS 10.0 Software over two liquefied gas LOC (Loss of Containment) scenarios. One of the scenarios was G1: Instantaneous release corresponding to BLEVE (Boiling Liquid Expanding Vapor Explosion) and the other was G2: Release in 10 min corresponding to UVCE (Unconfined Vapor Cloud Explosion). The highest threat zone distance (1kW/m2 heat radiation distance) was determined as 1699 m, the lethal burn distance as 377 m and distance from the center cloud to threshold overpressure as 342.46 m with the G1 scenario. French, Italian and Austrian methodologies relating to LUP (Land Use Planning) context of the Seveso Directive, which was not implemented in Turkish legislation, were evaluated for BLEVE of The Akçagaz Accident. Three different modeling approaches for BLEVE including static, dynamic and rupture of the vessel were used and the results were compared to the LUP methodology. The value (height of the fire ball: 273m) closed to the actual accident situation (height of the fire ball:200-300m) was obtained with the use of the static modeling approach. The distance access to fragments of the tank was calculated as 409 m with the use of rupture of vessel modeling approach which was compatible with the actual accident value (~500m). High lethality, the beginning of lethality, irreversible effects, indirect/reversible effects radius of The Akçagaz Accident were calculated for each country LUP methodology. The determined distances with the use of static BLEVE model correlation were obtained at the highest value again. High lethality radius was determined for French and Italian as 173.37 m and 86.13 m, respectively. The LUP methodology used in France is said to be more restrictive based on the large impact distances. On the other hand, when the TOTAL specifications (GS EP SAF 253& 262) are considered, which are dependent on demand but very important, the threshold values for health effects are seen to be much more stringent.
https://ijcce.ac.ir/article_35109_8d77593f844d0b3a9f66d0a2a6342f05.pdf
2018-08-01
253
264
10.30492/ijcce.2018.35109
LPG
BLEVE
VCE
Consequences Analysis
The Akçagaz Accident
LUP (Land Use Planning)
Saliha
Çetinyokuş
s.saliha@gmail.com
1
Chemical and Chemical Processing Technologies Technical Sciences Vocational School, Gazi University, Ankara, TURKEY
LEAD_AUTHOR
[1] http://www.emdat.be/(2016).
1
[2] “Regulation on Prevention of Major Industrial Accidents and Mitigation of Impacts”, 30 December 2013 Date and 28867 No. The Official Gazette.
2
[3] Papazoglou I.A., Nivolianitou Z.S., Bonanos G.S., Land Use Planning Policies Stemming from the Implementation of the SEVESO-II Directive in the EU, Journal of Hazardous Materials, 61: 345–353 (1998).
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[4] Christou M.D., Amendola A., Smeder M., The Control of Major Accident Hazards: The Land-Use Planning Issue, Journal of Hazardous Materials, 65: 151-178 (1999).
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[5] Christou M., Gyenes Z., Struck M., Christou M., Gyenes Z., Struck M., Risk Assessment in Support to Land-Use Planning in Europe: Towards More Consistent Decisions?, Journal of Loss Prevention in the Process Industries, 24: 219-226 (2011).
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[6] Antonioni G., Spadoni G., Cozzani V., Application of Domino Effect Quantitative Risk Assessment to an Extended Industrial Area, Journal of Loss Prevention in the Process Industries, 22: 614–624 (2009).
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