ORIGINAL_ARTICLE
Synthesis and Characterization of Co-Mn Nanocatalyst Prepared by Thermal Decomposition for Fischer-Tropsch Reaction
Nano-structure of Co–Mn spinel oxide was prepared by thermal decomposition method using [Co(NH3)4CO3]MnO4 as the precursor. The properties of the synthesized material were characterized by X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Transmission Electron Microscopy (TEM), surface area measurements, Energy-Dispersive X-ray (EDX) spectroscopy analysis, UV-Vis spectrophotometer (UV-Vis), Fourier Transform InfraRed (FT-IR), Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) analyses. The results show that Co–Mn spinel oxide is spherical in shape and possess crystallite size is about 12 nm. The catalytic activity and product selectivity were also investigated, in a micro-reactor (Fischer–Tropsch Synthesis (FTS) reaction) and the results compared with conventional Co-Mn oxide catalyst. The catalyst performance increased as the particle size of the catalyst decreased. Moreover, the olefin to paraffin ratios was increased, compared to the conventional catalyst.
https://ijcce.ac.ir/article_27986_eeef084d67709da368693ea7dfb9e4be.pdf
2018-06-01
1
9
10.30492/ijcce.2018.27986
Nano-structure catalyst
Co–Mn spinel oxide
Fischer–Tropsch Synthesis
Ghobad
Mansouri
mansouri.ilam.pnu@gmail.com
1
Department of Chemistry, Payame Noor University, P.O. Box 19395-3697 Tehran, I.R. IRAN
AUTHOR
Mohsen
Mansouri
mansouri2010@yahoo.com
2
Department of Chemical Engineering, Ilam University, P.O. Box 69315-516 Ilam, I.R. IRAN
LEAD_AUTHOR
[1] Tihay F., Pourroy G., Richard-Plouet M., Roger AC., Kiennemann A., Effect of Fischer–Tropsch Synthesis on the Microstructure of Fe–Co-Based Metal/Spinel Composite Materials, Appl. Catal. A Gen., 206: 29-42 (2001)
1
[2] Duvenhage D.J., Coville N., Fe:CoTiO2 Bimetallic Catalysts for the Fischer-Tropsch Reaction I. Characterization and Reactor Studies, J. Appl. Catal. A Gen. 153: 43-67 (1997)
2
[3] Cabet C., Roger A.C., Kiennemann A., Läkamp S., Pourroy G., Synthesis of New Fe–Co Based Metal/Oxide Composite Materials: Application to the Fischer–Tropsch Synthesis, J. Catal., 173: 64-73 (1998)
3
[4] Gholami Z., Zabidi N.A.M., Gholami F., Synthesis and Characterization of Niobium-Promoted Cobalt/Iron Catalysts Supported on Carbon Nanotubes for the Hydrogenation of Carbon Monoxide, J. Fuel Chem. Technol., 44: 815–821 (2016)
4
[5] Tihay F., Roger A.C., Kiennemann A., Pourroy G., Fe–Co Based Metal/Spinel to Produce Light Olefins from Syngas, Catal. Today, 58: 263-269 (2000)
5
[6] Reshetenko T.V., Avdeeva L.B., Khassin A.A., Kustova G.N., Ushakov V.A., Moroz E.M., Shmakov A.N., Coprecipitated Iron-Containing Catalysts (Fe-Al2O3, Fe-Co-Al2O3, Fe-Ni-Al2O3) for Methane Decomposition at Moderate Temperatures: I. Genesis of Calcined and Reduced Catalysts, Appl. Catal. A Gen., 268: 127-138 (2004)
6
[7] de la Pen’a O’Shea V.A., Menéndez N.N., Tornero J.D., Fierro J.L.G., Unusually High Selectivity to C2+ Alcohols on Bimetallic CoFe Catalysts During CO Hydrogenation, Catal. Lett., 88: 123-128 (2003)
7
[8]. Mirzaei A.A., Habibpour R., Kashi E., Preparation and Optimization of Mixed Iron Cobalt Oxide Catalysts for Conversion of Synthesis Gas to Light Olefins, Appl. Catal. A Gen., 296: 222-231 (2005).
8
[9] van der Laan G.P., Beenackers A.A.C.M., Kinetics and Selectivity of the Fischer-Tropsch Synthesis: A Literature Review, Catal. Rev. Sci. Eng., 41: 255-318 (1999)
9
[10] González-Cortés S.L., Rodulfo-Baechler S.M.A., Oliveros A., Orozco J., Fontal B., Mora A.J., Delgado G., Synthesis of Light Alkenes on Manganese Promoted Iron and Iron-Cobalt Fischer-Tropsch Catalysts, React. Kinet. Catal. Lett., 75: 3-12 (2002)
10
[11] Keyser M.J., Everson R.C., Espinoza R.L., Fischer–Tropsch Studies with Cobalt–Manganese Oxide Catalysts: Synthesis Performance in a Fixed bed Reactor, Appl. Catal. A Gen., 171: 99-107 (1998)
11
[12] Barrault J., Selective Hydrogenation of Carbon Monoxide on Supported Iron or Cobalt Catalysts. Effects of Manganese Oxide and (or) Chlorine, Stud. Surf. Sci. Catal., 11: 225-231 (1982)
12
[13] Barrault J., Forquy C., Menezo J.C., Maurel R., Selective Hydrocondensation of CO to Light Olefins with Alumina-Supported Iron Catalysts, React. Kinet. Catal. Lett., 15: 153-158 (1980)
13
[14] Barrault J., Forquy C., Perrichon V., Effects of Manganese Oxide and Sulphate on Olefin Selectivity of Iron Supported Catalysts in the Fischer-Tropsch Reaction, Appl. Catal., 5: 119-125 (1983)
14
[15] Mansouri M., Atashi H., Fischer-Tropsch Synthesis over Potassium-Promoted Co-Fe/SiO2 Catalyst, Indian J. Chem. Tech., 23: 453-461 (2016)
15
[16] Feyzi M., Hassankhani A., TiO2 Supported Cobalt-Manganese Nano Catalysts for Light Olefins Production from Syngas, J. Energy Chem., 22: 645-652 (2013)
16
[17] Park J.Y., Lee Y.J., Karandikar P.R., Jun K.W., Ha K.S., Park H.G., Fischer–Tropsch Catalysts Deposited with Size-Controlled Co3O4 Nanocrystals: Effect of Co Particle Size on Catalytic Activity and Stability, Appl. Catal. A Gen., 411–412: 15-23 (2012).
17
[18] Zeng B., Hou B., Jia L., Li D., Sun Y., Fischer–Tropsch Synthesis over Different Structured Catalysts: The Effect of Silica Coating onto Nanoparticles, J. Mol. Catal. A Chem., 379:263-268 (2013).
18
[19] Nakhaei Pour A., Housaindokht M.R., Torabi F., Water–Gas Shift Kinetics over Lanthanum-Promoted Iron Catalyst in Fischer–Tropsch Synthesis: Thermodynamic Analysis of Nanoparticle Size Effect, J. Iran Chem. Soc., 11: 1639-1648 (2014)
19
[20] Li T., Wang H., Yang Y., Xiang H., Li Y., Study on an Iron–Nickel bimetallic Fischer–Tropsch Synthesis Catalyst, Fuel Process. Tech., 118: 117-124 (2014)
20
[21] Farzad S., Haghtalab A., Rashidi A., Comprehensive Study of Nanostructured Supports with High Surface Area for Fischer-Tropsch Synthesis, J. Energy Chem., 22: 573-581 (2013).
21
[22] Zhang H.T., Chen X.H., Size-Dependent X-Ray Photoelectron Spectroscopy and Complex Magnetic Properties of CoMn2O4 Spinel Nanocrystals, Nanotechnology, 17: 1384–1390 (2006)
22
[23] He T., Chen D., Jiao X., Wang Y., Duan Y., Solubility-Controlled Synthesis of High-Quality Co3O4 Nanocrystals, Chem. Mater., 17: 4023-4030 (2005)
23
[24] Tavakoli H., Mamoory R.S., Zarei A.R., Inverse Co-Precipitation Synthesis of Copper Chromite Nanoparticles, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 51-55 (2016)
24
[25] Ahmadi S.H., Davar P., Manbohi A., Adsorptive Removal of Reactive Orange 122 from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 63-73 (2016)
25
[26] Li D., Zhong G-Q., Zang Q., Solid–Solid Synthesis, Crystal Structure and Thermal Decomposition of Copper(II) Complex of 2-Picolinic Acid, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 21-29 (2016)
26
[27] Rad A.R.S., Khoshgouei M.B., Rezvani A.R., Water Gas Shift Reaction over Zn–Ni/SiO2 Catalyst Prepared from Zn(H2O)6]2[Ni(NCS)6]·H2O/SiO2 Precursor, J. Mol. Catal. A Chem., 344: 11-17 (2011)
27
[28] Barrett E.P., Joyner L.G., Halenda P.P., The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Ntrogen Isotherms, J. Am. Chem. Soc., 73: 373-380 (1951)
28
[29] Mansouri M., Atashi H., Farshchi Tabrizi F., Mirzaei A.A., Mansouri G., Kinetics Studies of Nano-Structured Cobalt–Manganese Oxide Catalysts in Fischer–Tropsch Synthesis, J. Ind. Eng. Chem., 19: 1177–1183(2013)
29
[30] Mansouri, M. Atashi, H. Khalilipour, M.M. Setareshenas, N. Shahraki, F., Rate Expression of Fischer-Tropsch Synthesis Over Co–Mn Nanocatalyst by Response Surface Methodology (RSM), J. Korean Chem. Soc., 57: 769-777 (2013)
30
[31] Kaviyarasu K., Raja A., Devarajan P.A., Structural Elucidation and Spectral Characterizations of Co3O4 Nanoflakes, Spectrochim. Acta. A Mol. Biomol. Spectrosc., 114: 586-591 (2013)
31
[32] Kótai L., Argay G., Holly S., Szentmihályi K., Keszler Á., Pukánszky B., Anorg Z., Study on the Existence of Hydrogen Bonds in Ammonium Permanganate, Z. Anorg. Allg. Chem., 627: 114-118 (2001)
32
[33] Zhang Y.C., Qiao T., Hu X.Y., Hu X.Y., Zhou W.D., Simple Hydrothermal Preparation of γ-MnOOH Nanowires and Their Low-Temperature Thermal Conversion to β-MnO2 Nanowires, J. Cryst. Growth., 280: 652-657 (2005)
33
[34] Rohani Bastami T., Entezari M.H., A Novel Approach for the Synthesis of Superparamagnetic Mn3O4 Nanocrystals by Ultrasonic Bath, Ultrason. Sonochem., 19: 560-569 (2012)
34
[35] Salavati-Niasari M., Khansari A., Davar F., Synthesis and Characterization of Cobalt Oxide Nanoparticles by Thermal Treatment Process, Inorg. Chim. Acta., 362: 4937-4942 (2009)
35
[36] Xu R., Zeng H.C., Synthesis of Co3O4 Nanocubes and Their Close- and Non-Close-Packed Organizations, Langmuir, 20: 9780-9790 (2004)
36
[37] Dry M.E., In “The Fischer–Tropsch Synthesis, Catalysis: Science and Technology”, Anderson J.R., Boudart M., (eds.) (Springer-Verlag: NY) pp.160-255 (1981)
37
ORIGINAL_ARTICLE
Synthesis of Kaolin Loaded Ag and Ni Nanocomposites and Their Applicability for the Removal of Malachite Green Oxalate Dye
The present study focuses on the synthesis of Kaolin loaded Silver (Ag-KNC) and Nickel (Ni-KNC) nanocomposites by co-precipitation method. The surface morphology of them was determined by SEM technique while chemical composition was determined by FT-IR technique. The removal of Malachite Green Oxalate (MGO) was preceded by the adsorption method using (Ag-KNC) and (Ni-KNC). The adsorption models like Freundlich, Langmuir, and D-R (Dubinin-Radushkevich) was utilized to figure out the applicability of the tactic. Moreover, the pH at the point of zero charges (pHpzc) was determined to find surface neutrality. The effect of electrolyte (KCl) on the removal efficacy of MGO was additionally investigated. Furthermore, the ionic strength and thickness of Electrical Double Layer (EDL) were also determined. Thermodynamic parameters like free energy (∆Go), entropy (∆So) and enthalpy (∆Ho), of the system, was also investigated. The adsorption Kinetic was resolute by Intra Particle Diffusion (IPD) and Boyd’s models. Moreover, the adsorption efficacy was effectuality was ascertained to be 88% for (Kaolin), 97% for (Ag-KNC) and 95% for (Ni-KNC) systems.
https://ijcce.ac.ir/article_34141_eddb678c7b363b27d7f61e5a9909e100.pdf
2018-06-01
11
22
10.30492/ijcce.2018.34141
Nanocomposites
Adsorption models
pHpzc
EDL
FT-IR
SEM
Hajira
Tahir
hajirat@uok.edu.pk
1
Department of Chemistry, University of Karachi, Karachi, PAKISTAN
LEAD_AUTHOR
Saud
Atika
2
Department of Chemistry, University of Karachi, Karachi, PAKISTAN
AUTHOR
Saad
Muhammad
3
Department of Chemistry, University of Karachi, Karachi, PAKISTAN
AUTHOR
[1] Xun W., Jing Z., Qing P.andYadong L.,A General Strategy for Nanocrystal Synthesis, Nature, 437: 121-124 (2005).
1
[2] Balci S., Bittner A.M., Hahn K., Scheu C., Knez M., Kadri A., Wege C., JeskeH.and Kern K., Copper Nanowires within the Central Channel of Tobacco Mosaic Virus Particles, Electrochimicaacta, 51(28): 6251- 6257 (2006).
2
[3] Meng H., Peng H., Chunlei Z., Feng C., Can W., Jiebing M., Rong H., Daxiang C.,A General Strategy for the Synthesis of Upconversion Rare Earth Fluoride Nanocrystalsvia a Novel OA/Ionic Liquid Two-Phase System, Chemical Communications (Cambridge, England), 47(33): 9510 - 9512 (2011) .
3
[4] Hajira T., Uroos A., Lignocellulosic: Non-Conventional Low Cost Biosorbent for the Elution of Coomassie Brilliant Blue (R-250),International Journal of Chemistry, 6(2): 56-72(2014).
4
[5] Nandapure B.I., Kondawar S.B., Salunkhe M.Y., Nandapure A.I.,Magnetic And Transport Properties of Conducting polyaniline/nickel Oxide Nanocomposites, Advanced Materials Letters, 4(2): 134-140 (2013).
5
[6] Ramana G.V., Balaji P., Kumar R.N., PrabhakarK.V., Jain P.K,Mechanical properties of Multi-Walled Carbon Nanotubes Reinforced Polymer Nanocomposites, Indian journal of Engineering & Material Sciences, 17: 331-337 (2010).
6
[7] Amy M.M., Namiko Y., Matthew A.P., Kenneth E.G.,Thermal Conduction in Aligned Carbon Nanotube PolymerNanocomposites with High PackingDensity, ACS Nano, 5(6): 4818-4825 (2011).
7
[8] Joy K.M., Young W.C., Nak S.C.,Preparation and Characterization of Rubber-Toughened poly(trimethylene terephthalate)/ organoclaynanocomposite, Polymer Engineering & Science, 47(6): 863-870 (2007).
8
[9] Sarika S., Barick K.C., Bahadur D.I.,Functional Oxide Nanomaterials and Nanocomposites for the Removal of Heavy Metals and Dyes, Nanomaterials and Nanotechnology, 3(20): 1-19 (2013).
9
[10] Shameli K., Ahmad M.B., Yunus W.Z., Ibrahim N.A., Darroudi M.,Synthesis and Characterization of Silver/Talc Nanocomposites Using the Wet Chemical Reduction Method, Journal of Nanomedicine, 5: 743-751 (2010).
10
[11] Saeedeh H., Mohammad R.S.,Novel Ag/Kaolin Nanocomposite as Adsorbent for Removal of Acid Cyanine 5R from Aqueous Solution, Journal of Chemistry, 2013: 1-7 (2013).
11
[12] Kamyar S., Mansor B.A., Mohsen Z., Wan M.Z.W.Y., Nor A.I.,ParvanehS. and Mansour G.M., Synthesis and Characterization of Silver/montmorillonite/ chitosan Bionanocomposites by Chemical Reduction Method and Their Antibacterial Activity, Int. J.Nanomedicine, 6: 271-284 (2011).
12
[13] Meshram S., Limaye R., Ghodke S., Nigam S., Sonawane S., Chikate R.,Continuous Flow Photocatalytic Reactor Using ZnO–Bentonitenanocomposite for Degradation of Phenol, Chemical Engineering Journal, 172(2): 1008-1015 (2011).
13
[14] Haghighizadeh A., Tan W.L., Mohammad A.B., Ghani S.A., Synthesis and Properties of Nanosized Silver Catalyst Supported on Chitosan-Silica Nanocomposites, AIP Conf. Proc., 1502: 255- 271 (2012)
14
[15] Zhai H.J., Sun D.W., and Wang H.S., Catalytic properties of Silica/Silver Nanocomposites, Nanoscience Nanotechnology, 6(7): 1968 - (2006).
15
[16] Rapsomanikis A., Papoulis D., Panagiotaras D., Kaplani E., Stathatos E., NanocrystallineTiO2 and Halloysite Clay Mineral Composite Films Prepared by Sol-Gel Method: Synergistic Effect and the Case of Silver Modification to the Photocatalytic Degradation of Basic Blue- 41 azo Dye in Water, Global NEST Journal, 16: 485-498 (2014).
16
[17] Nazar H.K., Sirajuddin, Razium A.S., Syed T.H.S., Keith R.H., Abdul R.K.,Synthesis and Characterization of Highly Efficient Nickel Nanocatalysts and Their Use in Degradation of Organic Dyes, International Journal of Metals, 2014: 1 - 10 (2014).
17
[18] Rodiansono R., Takayoshi H., Shogo S.,Total Hydrogenation of Biomass-Derived Furfural Over Raney Nickel-Clay Nanocomposite Catalysts, Indo. J. Chem., 13(2): 101- 107 (2013).
18
[19] Awwad, A.M., Albiss B.A., Salem N.M.,Antibacterial Activity of Synthesized Copper Oxide Nanoparticles Using Malvasylvestris Leaf Extract, SMU Med. J., 2:91-101 (2015).
19
[20] Sandipan C., Sudipta C., Bishnu P.C., Arun K.G.,Adsorptive Removal of Congo Red, A Carcinogenic Textile Dye by Chitosan Hydrobeads: Binding Mechanism, Equilibrium and Kinetics, Colloids and Surface A Physicochemical and Engineering Aspects, 299: 146-152 (2007).
20
[21] Jiwan S., Uma, Sushmita B., Yogesh C.S., A Very Fast Removal of Orange G from its Aqueous Solutions by Adsorption on Activated Saw Dust: Kinetic Modeling and Effect of Various Parameters, International Review of Chemical Engineering, 4(1):1-7 (2012).
21
[22] Armen B.A.,Theory of Global Sustainable Development Based on Microalgae in Bio and Industrial Cycles, Management-Changing Decisions in Areas of Climate Change and Waste Management, Journal of Sustainable Bioenergy Systems, 3(4): 287-297 (2013).
22
[23] Iqbal M.J., Ashiq M.N.,Adsorption of Dyes from Aqueous Solutions on Activated Charcoal, J. Hazard. Mater, 139: 57-66 (2007).
23
[24] Dotto G.L., Moura J.M., Cadaval T.R.S., Pinto L.A.A.,Application of Chitosan Films for the Removal of Food Dyes from Aqueous Solutions by Adsorption, Chemical Engineering Journal, 214: 8-16 (2013).
24
[25] Debabrata C., Vidya R.P., Anindita S., Moulik S.K., Removal of Some Common Textile Dyes from Aqueous Solution Using Fly Ash, J. Chem. Eng. Data, 55(12): 5653-5657 (2010).
25
[26] Oladipo O., Randy J.M., Peter W.S.,X-Ray Diffraction Study on Highly Ordered Mesostructured Thin Films, JCPDS-International Centre for Diffraction Data, Advances in X-ray Analysis, 45: 359-364 (2002).
26
[27] Hassan H. Hameed B.H.,Fenton-like Oxidation of Acid Red 1 Solutions Using Heterogeneous Catalyst Based on Ball Clay, International Journal of Environmental Science and Development, 2(3): 218-222 (2011).
27
[28] Saad M., Hajira T., Fakhra S.,Synthesis and Characterization of SnO-CoOnanocomposits by Bottom up Approach and Their Efficacy to the Treatment of Dyes Assisted Simulated Waste Water, Int. J. Curren. Res., 7(12): 23542-23550,
28
[29] Meshram S., Limaye R., Ghodke S., Nigam S., Sonawane S., Chikate R.,Continuous Flow Photocatalytic Reactor Using ZnO–Bentonitenanocomposite for Degradation of Phenol, Chemical Engineering Journal, 172(2): 1008-1015 , (2011).
29
[30] George A.K., Insik J., Marit N.H., Ahmed M.A., Jayeeta B., Bharam P.,Fluorinated Analogs of Malachite Green: Synthesis and Toxicity, Molecules, 13(4): 986-994 (2008).
30
[31] Bahareh S., Saeedeh H.,Synthesis of Kaolin/Ag Nanocomposite as an Efficient and Versatile Reagent for the Synthesis of 1,8-Dioxo-Octahydroxanthene Derivatives, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 44: 424-428 (2014).
31
[32] Ghulam M., Hajira T., Muhammad S., Nasir A.,Synthesis and Characterization of Cupric Oxide (CuO) Nanoparticles and Their Application for the Removal of Dyes, 12(47): 6650-6660 (2013).
32
[33] Mantosh K.S., Priya B., Papita D.J., Plant-Mediated Synthesis of Silver-Nanocomposite as Novel Effective Azo Dye Adsorbent, Applied Nanoscience, doi:10.1007/s13204-013-0286-x (2013).
33
[34] Hajira T., Muhammad S., Zainab Q.,Physiochemical Modification and Characterization of Bentonite Clay and Its Application for the Removal of Reactive Dyes, International Journal of Chemistry,5(3): 19- 32 (2013).
34
[35] Venkateswaran V., Priya T.,Equilibrium and Kinetics of Adsorption of Cationic Dyes by STISHOVITE-Clay –TiO2 Nanocomposite, Intrenational Journal of Modern Engineering Research (IJMER), 2(6): 3989-3995 (2012).
35
[36] Gholam R.M., Roghaye Z.J.,Removal Kinetic of Cationic Dye Using Poly (Sodium Acrylate)-Carrageenan/Na-Montmorillonite Nanocomposite Superabsorbents, Mater. Environ. Sci., 3(5): 895-906 (2012).
36
[37] Saad M., Hajira T., Khan J., Hameed U., Saud A., Synthesis of Polyaniline nanoparticles and their application for the removal of Crystal Violet dye by Ultrasonicated adsorption Process Based on Response Surface Methodology, Ultrasonic. Sonochem., 34: 600-608 (2017).
37
[38] Samarghandi M.R., Zarabi M., Noori Sepehr M., Panahi R., Foroghi M., Removal of Acid Red 14 by Pumice Stone as a Low Cost Adsorbent: Kinetic
38
and Equilibrium Study, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 31(3): 19-27 (2012).
39
[39] Yao-Jen T., Chen-Feng Y., Chien-Kuei C.J., Kinetics and Thermodynamics of Adsorption for Cd on Green Manufactured Nano-Particles, Hazard Mater., 235-236: 116-122 (2012).
40
[40] Mokhtari P., Ghaedi M., Dashtian K., Rahimi M.R., Purkait M.K., Removal of Methyl Orange by Copper Sulfide Nanoparticles Loaded Activated Carbon: Kinetic and Isotherm Investigation, Journal of Molecular, 219: 299-305 (2016).
41
[41] Vijayakumar G., Tamilarasan R., Dharmendirakumar M.J.,Adsorption, Kinetic, Equilibrium and Thermodynamic Studies on the Removal of Basic Dye Rhodamine-B from Aqueous Solution by the Use of Natural Adsorbent Perlite, Mater. Environ. Sci., 3(1): 157-170 (2012)
42
[42] SaadM., Hajira T.,Synthesis of Carbon Loaded γ-Fe2O3Nanocomposite and Their Applicability for the Selective Removal Of Binary Mixture of Dyes by Ultrasonic Adsorption Based on Response Surface Methodology, Ultrasonic. Sonochemis., 36: 393-408 (2017).
43
[43] Kamali M., Ghorashi S.A.A., Asadollahi M.A., Controllable Synthesis of Silver Nanoparticles Using Citrate as Complexing Agent: Characterization of Nanopartciles and Effect of pH on Size and Crystallinity, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 31(4): 21-28 (2012).
44
[44] Okewale A.O., Babayemi K.A., Olalekan A.P.,Adsorption Isotherms and Kinetics Models of Starchy Adsorbents on Uptake of Water from Ethanol – Water Systems, International Journal of Applied Science and Technology, 3(1): 35-42 (2013).
45
[45] Naghizadeh A., Ghafouri M., Synthesis and Performance Evaluation of Chitosan Prepared from Persian Gulf Shrimp Shell in Removal of Reactive Blue 29 Dye from Aqueous Solution (Isotherm, Thermodynamic and Kinetic Study), Iranian Journal of Chemistry and ChemicalEngineering (IJCCE), 36(3): 25-36 (2017).
46
ORIGINAL_ARTICLE
Reduction of Nitroaromatics to Amines with Cellulose Supported Bimetallic Pd/Co Nanoparticles
Pd and Co nanoparticles were deposited on cellulose for use as a heterogeneous catalyst in the bimetallic catalytic reduction reaction. The catalyst was characterized with Energy Dispersive X-Ray Spectroscopy, X-Ray Diffraction pattern, Thermal Gravimetric Analysis, Flame Atomic Absorption Spectroscopy, and Transmission Electron Microscopy, and applied in the reduction reaction of nitroaromatics using NaBH4 at room temperature. Aromatic amines were obtained as the sole product of the reduction reaction during 2h. This reaction has some advantages such as mild reaction conditions, high yield, green solvent, and recyclable catalyst. Also, the recovered catalyst is applicable in the reduction reaction for 4 times without a significant decrease in the activity.
https://ijcce.ac.ir/article_27407_9d5b9d9ec046e9953f5e1915635482d8.pdf
2018-06-01
23
31
10.30492/ijcce.2018.27407
Reduction
Nitroaromatics
Cellulose
Heterogeneous catalyst
Bimetallic
Palladium
Cobalt
Sajjad
Keshipour
s.keshipour@urmia.ac.ir
1
Department of Nanochemistry, Nanotechnology Research Center, Urmia University, Urmia, I.R. IRAN
LEAD_AUTHOR
Kamran
Adak
kamran.adak@yahoo.com
2
Department of Nanochemistry, Nanotechnology Research Center, Urmia University, Urmia, I.R. IRAN
AUTHOR
[1] Kiasat A.R., Zayadi M., Mohammad-Taheri F., Fallah-Mehrjard M., Simple, Practical and Eco-friendly Reduction of Nitroarenes with Zinc in the Presence of Olyethylene Glycol Immobilized on Silica Gel as a New Solid–liquid Phase Transfer Catalyst in Water, Iran. J. Chem. Chem. Eng. (IJCCE), 30(2): 37-41 (2011).
1
[2] Wienhöfer G., Sorribes I., Boddien A., Westerhaus F., Junge K., Junge H., Llusar R., Beller M., General and Selective Iron-catalyzed Transfer Hydrogenation of Nitroarenes Without Base, J. Am. Chem. Soc., 133(32): 12875-12879 (2011).
2
[3] Kelly S.M., Lipshutz B.H., Chemoselective Reductions of Nitroaromatics in Water at Room Temperature, Org. Lett., 16(1): 98-101 (2014).
3
[4] Yuste F., Saldana M., Walls F., Selective Reduction of Aromatic Nitro Compounds Containing o- and n-Benzyl Groups With Hydrazine and Raney Nickel, Tetrahedron Lett., 23(2): 147-148 (1982).
4
[5] Ram S., Ehrenkaufer R.E., A General Procedure for Mild and Rapid Reduction of Aliphatic and Aromatic Nitro Compounds Using Ammonium Formate as a Catalytic Hydrogen Transfer Agent, Tetrahedron Lett., 25(32): 3415-3418 (1984).
5
[6] Di Gioia M.L., Leggio A., Le Pera A., Liguori A., Napoli A., Perri F., Siciliano C., Determination by Gas Chromatography/Mass spectrometry of p-Phenylenediamine in Hair Dyes After Conversion to an Imine Derivative, J. Chromatogr. A, 1066(1-2): 143-148 (2005).
6
[7] Larock R.C., “Comprehensive Organic Transformations”, VCH: New York, 411–415 (1989).
7
[8] Kabalka G.W., Varma R.S., In: “Comprehensive Organic Synthesis”, Trost B.M., Fleming I., (Eds.); Pergamon Press: Oxford, Vol. 8, 363–379 (1991).
8
[9] Sauvé G. Rao V.S., In: “Comprehensive Organic Functional Group Transformations”, Katritzky A.R., Meth-Cohn O., Rees C.W., (Eds.); Pergamon Press: Oxford, Vol. 2, pp 737–817 (1995).
9
[10] Gowda S., Abiraj K., Gowda D.C., Reductive Cleavage of Azo Compounds Catalyzed by Commercial Zinc Dust Using Ammonium Formate or Formic Acid, Tetrahedron Lett., 43(7): 1329-1331 (2002).
10
[11] Sharma U., Kumar P., Kumar N., Kumar V., Singh B., Highly Chemo- and Regioselective Reduction of Aromatic Nitro Compounds Catalyzed by Recyclable Copper(II) as Well as Cobalt(II) Phthalocyanines, Adv. Synth. Catal., 352(11-12): 1834-1840 (2010).
11
[12] Junge K., Wendt B., Shaikh N., Beller M., Iron-Catalyzed Selective Reduction of Nitroarenes to Anilines Using Organosilanes, Chem. Commun., (10): 1769-1771 (2010).
12
[13] Sharma U., Kumar N., Verma P.K., Kumar V., Singh B., Zinc Phthalocyanine with PEG-400 as a Recyclable Catalytic System for Selective Reduction of Aromatic Nitro Compounds,Green Chem., 14(8): 2289-2293 (2012).
13
[14] Stiles M., Finkbeiner H.L., Chelation as a Driving Force in Synthesis. A New Route to α-Nitro Acids and α-Amino Acids, J. Am. Chem. Soc., 81(2): 505-506 (1959).
14
[15] Uberman P.M., García C.S., Rodríguez J.R., Martín S.E., PVP-Pd Nanoparticles as Efficient Catalyst for Nitroarene Reduction under Mild Conditions in Aqueous Media, Green Chem., 19(3): 739-748 (2017).
15
[16] Dowing R.S., Kunkeler P.J., Van Bekkum H., Catalytic Syntheses of Aromatic Amines, Catal. Today, 37(2): 121-136 (1997).
16
[17] Corma A., Serna P., Concepcion P., Calvino J., Transforming Nonselective into Chemoselective Metal Catalysts for the Hydrogenation of Substituted Nitroaromatics, J. Am. Chem. Soc., 130(27): 8748-8753 (2008).
17
[18] Blaser H.U., Steine H., Studer M., Selective Catalytic Hydrogenation of Functionalized Nitroarenes: An Update, Chem. Cat. Chem., 1(2): 210-221 (2009).
18
[19] Burk S.D., Danheiser R.L., “Handbook of Reagents for Organic Synthesis, Oxidizing and Reducing Agents”, Wiley-VCH: New York (1999).
19
[20] Satoh T., Suzuki S., Miyaji Y., Imai Z., Reduction of Organic Compounds with Sodium Borohydride-transition Metal Salt Systems: Reduction of Organic Nitrile, Nitro and Amide Compounds to Primary Amines, Tetrahedron Lett., 10(52): 4555-4558 (1969).
20
[21] Yoo S., Lee S., Reduction of Organic Compounds with Sodium Borohydride-copper(II) Sulfate System, Synlett, (7): 419-420 (1990).
21
[22] Osby J.O., Ganem B., Rapid and Efficient Reduction of Aliphatic Nitro Compounds to Amines, Tetrahedron Lett., 26(52): 6413-6416 (1985).
22
[23] Guo F., Ni Y., Ma Y., Xiang N., Liu C., Flowerlike Bi2S3 Microspheres: Facile Synthesis and Application in the Catalytic Reduction of 4-Nitroaniline, New J. Chem., 38(11): 5324-5330 (2014).
23
[24] Wu F., Qiu L.G., Ke F., Jiang X., Copper Nanoparticles Embedded in Metal–organic Framework MIL-101(Cr) as a High Performance Catalyst for Reduction of Aromatic Nitro Compounds. Inorg. Chem. Commun., 32: 5-8 (2013).
24
[25] Németh J., Kiss Á., Hell Z., Palladium-catalysed Transfer Hydrogenation of Aromatic Nitro Compounds - An Unusual Chain Elongation, Tetrahedron Lett., 54(45): 6094-6096 (2013).
25
[26] Obraztsova I.I., Eremenko N.K., Simenyuk G.Y., Eremenko A.N., Tryasunov B.G., Bimetallic Catalysts for the Hydrogenation of Aromatic Nitro Compounds, Solid Fuel Chem., 46(6): 364-367 (2012).
26
[27] Sheikhhosseini E., Sattaei Mokhtari, T., Faryabi M., Rafiepour A., Soltaninejad S., Iron Ore Pellet, A Natural and Reusable Catalyst for Synthesis of Pyrano[2,3-d]pyrimidine and Dihydropyrano[c] chromene Derivatives in Aqueous Media, Iran. J. Chem. Chem. Eng. (IJCCE), 35(1): 43-50 (2016).
27
[28] Mohammadi Ziarani G., Badiei A.R., Khaniania, Y., Haddadpour M., One Pot Synthesis of Polyhydroquinolines Catalyzed by Sulfonic Acid Functionalized SBA-15 as a New Nanoporous Acid Catalyst Under Solvent Free Conditions, Iran. J. Chem. Chem. Eng. (IJCCE), 29(2): 1-10 (2010).
28
[29] Keypour H., Noroozi M., Rashidi A., Shariati Rad M., Application of Response Surface Methodology for Catalytic Hydrogenation of Nitrobenzene to Aniline Using Ruthenium Supported Fullerene Nanocatalyst, Iran. J. Chem. Chem. Eng. (IJCCE), 34(1): 21-32 (2015).
29
[30] Saadatjou N., Jafari A., Synthesis and Characterization of Ru/Al2O3 Nanocatalyst for Ammonia Synthesis, Iran. J. Chem. Chem. Eng. (IJCCE), 34(1): 1-9 (2015).
30
[31] Habibi Y., Lucia L.A., Rojas O.J., Cellulose Nanocrystals: Chemistry, Self-assembly, and Applications, Chem. Rev., 110(6): 3479-3500 (2010).
31
[32] Reddy K.R., Kumar N.S., Cellulose-supported Copper(0) Catalyst for Aza-michael Addition, Synlett, (14): 2246-2250 (2006).
32
[33] Cirtiu C.M., Dunlop-Brière A.F., Moores A., Cellulose Nanocrystallites as an Efficient Support for Nanoparticles of Palladium: Application for Catalytic Hydrogenation and Heck Coupling Under Mild Conditions, Green Chem. 13(2): 288-291 (2011).
33
[34] Keshipour S., Shojaei S., Shaabani A., Palladium Nano-particles Supported on Ethylenediaminefunctionalized Cellulose as a Novel and Efficient Catalyst for the Heck and Sonogashira Couplings in Water, Cellulose, 20(2): 973-980 (2013).
34
[35] Keshipour S., Shaabani A., Copper(I) and Palladium Nanoparticles Supported on Ethylenediamine-functionalized Cellulose as an Efficient Catalyst for the 1,3-Dipolar Cycloaddition/Direct Arylation Sequence, Appl. Organometal. Chem., 28(2) 116-119 (2014).
35
[36] Keshipour S., Kalam Khalteh N., Oxidation of Ethylbenzene to Styrene Oxide in the Presence of Cellulose-Supported Pd Magnetic Nanoparticles, Appl. Organometal. Chem., 30(8) 653-656 (2016).
36
[37] Shaabani A., Keshipour S., Hamidzad M., Seyyedhamzeh M., Cobalt(II) Supported on Ethylenediamine-functionalized Nanocellulose as an Efficient Catalyst for Room Temperature Aerobic Oxidation of Alcohols, J. Chem. Sci., 126(1): 111-115 (2014).
37
[38] Shaabani A., Keshipour S., Hamidzad M., Shaabani S., Cobalt(II) Phthalocyanine Covalently Anchored to Cellulose as a Recoverable and Efficient Catalyst for the Aerobic Oxidation of Alkylarenes and Alcohols, J. Mol. Catal. A Chem., 395: 494-499 (2014).
38
[39] Keshipour S., Khezerloo M., Gold Nanoparticles Supported on Cellulose Aerogel as a New Efficient Catalyst for Epoxidation of Styrene, J. Iran. Chem. Soc., 14(5): 1107–1112 (2017).
39
[40] Keshipour S., Adak K., Pd(0) Supported on N-doped Graphene Quantum Dot Modified Cellulose as an Efficient Catalyst for the Green Reduction of Nitroaromatics. RSC Adv., 6(92): 89407–89412 (2016).
40
[41] Nandi D., Siwal S., Choudhary M., Mallick K., Carbon Nitride Supported Palladium Nanoparticles: An Active System for the Reduction of Aromatic Nitro-compounds, Appl. Catal. A Gen., 523: 31-38 (2016).
41
[42] Kumar P.S., Lokanatha Rai K.M., Reduction of Aromatic Nitro Compounds to Amines Using Zinc and Aqueous Chelating Ethers: Mild and Efficient Method for Zinc Activation, Chem. Pap., 66(8): 772-778 (2012).
42
[43] Zhao Z., Yang H., Li Y., Guo X., Cobalt-modified Molybdenum Carbide as an Efficient Catalyst for Chemoselective Reduction of Aromatic Nitro Compounds, Green Chem., 16(3): 1274-1281 (2014).
43
[44] Wen H., Yao K., Zhang Y., Zhou Z., Kirschning A., Catalytic Transfer Hydrogenation of Aromatic Nitro Compounds in Presence of Polymer-supported Nano-amorphous Ni–B Catalyst, Catal. Commun., 10(8): 1207-1211 (2009).
44
[45] Zamani F., Kianpour S., Fast and Efficient Reduction of Nitro Aromatic compounds Over Fe3O4/β-Alanine-acrylamide-Ni Nanocomposite as a New Magnetic Catalyst, Catal. Commun., 45(5): 1-6 (2014).
45
ORIGINAL_ARTICLE
An Efficient Green Approach for the Synthesis of Fluoroquinolones Using Nano Zirconia Sulfuric Acid as Highly Efficient Recyclable Catalyst in two Forms of Water
Various antibacterial fluoroquinolone compounds were prepared by the direct amination of 7-halo-6- fluoroquinolone-3-carboxylic acids with a variety of piperazine derivatives and (4aR,7aR)-octahydro-1H-pyrrolo[3,4-b] pyridine using Zirconia Sulfuric Acid (ZrSA) nanoparticle, as a catalyst in the presence of ordinary or magnetized water upon reflux condition. The results showed that ZrSA exhibited high catalytic activity towards the synthesis of fluoroquinolone derivatives in two forms of water. However, the magnetized water showed better results. Furthermore, the catalyst was recyclable and could be reused at least three times without any discernible loss in its catalytic activity. Overall, this new catalytic method for the synthesis of fluoroquinolone derivatives provides rapid access to the desired compounds in refluxing water following a simple work‐up procedure and avoids the use of harmful organic solvents. This method, therefore, represents a significant improvement over the methods currently available for the synthesis of fluoroquinolone derivatives.
https://ijcce.ac.ir/article_27405_c5f4d9ea1aa8e3af6b5f5a1397d45823.pdf
2018-06-01
33
42
10.30492/ijcce.2018.27405
Fluoroquinolone derivatives
Antibacterial
Fast and green synthesis
Zirconia sulfuric acid (ZrSA)
Ordinary or magnetized water
Ahmad
Nakhaei
nakhaei_a@yahoo.com
1
Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
LEAD_AUTHOR
Abolghasem
Davoodnia
adavoodnia@yahoo.com
2
Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
AUTHOR
Sepideh
Yadegarian
sepideh_yadegarian@yahoo.com
3
Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN
AUTHOR
[1] Fernandes P.B., Shipkowitz N., Bower R.R., Jarvis K.P., Weisz J., Chu D.T., In-Vitro and in-Vivo Potency of Five New Fluoroquinolones Against Anaerobic Bacteria, J. Antimicrob. Chemother., 18(6): 693–701 (1986).
1
[2] Stein G.E., Goldstein E.J., Fluoroquinolones and Anaerobes, Clin. Infect. Dis., 42(11): 1598–1607 (2006).
2
[3] Chen Y.L., Fang K.C., Sheu J.Y., Hsu S.L., Tzeng C.C., Synthesis and Antibacterial Evaluation of Certain Quinolone Derivatives, J. Med. Chem., 44(14): 2374–2377 (2001).
3
[4] Fujimaki K., Noumi T., Saikawa I., Inoue M., Mitsuhashi S., In Vitro and in Vivo Antibacterial Activities of T-3262, A New Fluoroquinolone, Antimicrob. Agents Chemother., 32(6): 827–833 (1988).
4
[5] Golet E.M., Strehler A., Alder A.C., Giger W., Determination of Fluoroquinolone Antibacterial Agents in Sewage Sludge and Sludge-Treated Soil Using Accelerated Solvent Extraction Followed by Solid-Phase Extraction, Anal. Chem., 74(21): 5455–5462 (2002).
5
[6] O'Donnell J.A., Gelone S.P., Fluoroquinolones, Infect. Dis. Clin. North Am., 14(2): 489–513 (2000).
6
[7] Zhanel G.G., Walkty A., Vercaigne L., Karlowsky J.A., Embil J., Gin A.S., Hoban D.J., The New Fluoroquinolones: A Critical Review, Can. J. Infect. Dis. Med. Microbiol., 10(3): 207–238 (1999).
7
[8] Llorente B., Leclerc F., Cedergren R., Using SAR and QSAR Analysis to Model the Activity and Structure of the Quinolone—DNA Complex, Bioorg. Med. Chem., 4(1): 61–71 (1996).
8
[9] Wentland M.P., Lesher G.Y., Reuman M., Gruett M.D., Singh B., Aldous S.C., Dorff P.H., Rake J.B., Coughlin S.A., Mammalian Topoisomerase II Inhibitory Activity of 1-cyclopropyl-6, 8-difluoro-1, 4-dihydro-7-(2, 6-dimethyl-4-pyridinyl)-4-oxo-3-Quinolinecarboxylic Acid and Related Derivatives, J. Med. Chem., 36(19): 2801–2809 (1993).
9
[10] Elsea S.H., Osheroff N., Nitiss J.L., Cytotoxicity of Quinolones Toward Eukaryotic Cells. Identification of Topoisomerase II as the Primary Cellular Target for the Quinolone CP-115,953 in Yeast, J. Biol. Chem., 267(19): 13150–13153 (1992).
10
[11] Oh Y.S., Lee C.W., Chung Y.H., Yoon S.J., Cho S.H., Syntheses of New Pyridonecarboxylic Acid Derivatives Containing 3‐, 5‐or 6‐quinolyl Substituents at N‐1 and Their Anti‐HIV‐RT Activities, J. Heterocycl. Chem., 35(3): 541–550 (1998).
11
[12] Karlowsky J.A., Adam H.J., Desjardins M., Lagacé-Wiens P.R., Hoban D.J., Zhanel G.G., Baxter M.R., Nichol K.A., Walkty A., Canadian Antimicrobial Resistance Alliance (CARA, 2013. Changes in Fluoroquinolone Resistance over 5 Years (CANWARD 2007–11) in Bacterial Pathogens Isolated in Canadian Hospitals, J. Antimicrob. Chemother., 68: i39–i46 (2013).
12
[13] Gootz T.D., Brighty K.E., Fluoroquinolone Antibacterials: SAR, Mechanism of Action, Resistance, and Clinical Aspects, Med. Res. Rev., 16(5): 433–486 (1996).
13
[14] Aubry A., Pan X.S., Fisher L.M., Jarlier V., Cambau E., Mycobacterium Tuberculosis DNA Gyrase: Interaction with Quinolones and Correlation with Antimycobacterial Drug Activity, Antimicrob. Agents Chemother., 48(4): 1281–1288 (2004).
14
[15] Mitscher L.A., Bacterial Topoisomerase Inhibitors: Quinolone and Pyridone Antibacterial Agents, Chem. Rev., 105(2): 559–592 (2005).
15
[16] Sriram D., Aubry A., Yogeeswari P., Fisher L.M., Gatifloxacin Derivatives: Synthesis, Antimycobacterial Activities, and Inhibition of Mycobacterium Tuberculosis DNA Gyrase, Bioorg. Med. Chem. Lett., 16(11): 2982–2985 (2006).
16
[17] Dubar F., Anquetin G., Pradines B., Dive D., Khalife J., Biot C., Enhancement of the Antimalarial Activity of Ciprofloxacin Using a Double Prodrug/Bioorganometallic Approach, J. Med. Chem., 52(24): 7954–7957 (2009).
17
[18] Shindikar A.V., Viswanathan C.L., Novel Fluoroquinolones: Design, Synthesis, and in Vivo Activity in Mice Against Mycobacterium Tuberculosis H 37 Rv, Bioorg. Med. Chem. Lett., 15(7): 1803–1806 (2005).
18
[19] Reddy P.G., Baskaran S., Microwave Assisted Amination of Quinolone Carboxylic Acids: an Expeditious Synthesis of Fluoroquinolone Antibacterials, Tetrahedron Lett., 42(38): 6775–6777 (2001).
19
[20] Kawakami K., Namba K., Tanaka M., Matsuhashi N., Sato K., Takemura M., Antimycobacterial Activities of Novel Levofloxacin Analogues, Antimicrob. Agents Chemother., 44(8): 2126–2129 (2000).
20
[21] Fisher L.M., Lawrence J.M., Josty I.C., Hopewell R., Margerrison E.E., Cullen M.E., Ciprofloxacin and the Fluoroquinolones: New Concepts on the Mechanism of Action and Resistance, Am. J. Med., 87(5): S2-S8 (1989).
21
[22] Grohe K., Heitzer H., Cycloaracylation of Enamines. 1. Synthesis of 4-quinolone-3-carboxylic Acids, Liebigs Ann. Chem., 1: 29–37 (1987).
22
[23] Petersen U., Grohe K., Kuck K.H., Microbicidal Agents Based on Quinolonecarboxylic Acid, U.S. Patent: 4563459 (1986).
23
[24] Petersen U., Schrock W., Habich D., Krebs A., Schenke T., Philipps T., Grohe K., Endermann R., Bremm K.D., Metzger K.G., Quinolonecarboxylic Acids, U.S. Patent: 5480879 (1996).
24
[25] Lee T.A., Khoo J.H., Song S.H., Process for Preparing Levofloxacin or Its Hydrate, Patent: WO2006009374 (2006).
25
[26] Hayakawa I., Atarashi S., Imamura M., Yokohama S., Higashihashi N., Sakano K., Ohshima M., Optically Active Pyridobenzoxazine Derivatives and Intermediates Thereof, U.S. Patent: 4985557 (1991).
26
[27] Hayakawa I., Hiramitsu T., Tanaka Y., Synthesis and Antibacterial Activities of Substituted 7-oxo-2, 3-dihydro-7H-pyrido [1, 2, 3-de][1, 4] Benzoxazine-6-carboxylic Acids, Chem. Pharm. Bull., 32(12): 4907–4913 (1984).
27
[28] “Global and Alliance for TB Drug Development Handbook of Anti-Tuberculosis Agents”, "Moxifloxacin". Tuberculosis, 88(2): 127–131(2008).
28
[29] Guruswamy B., Arul R., Synthesis, Characterization, Antimicrobial Activity of Novel N-Substituted β-Hydroxy Amines and β-Hydroxy Ethers Contained Chiral Benzoxazine Fluoroquinolones, Lett. Drug Des. Discov., 10(1): 86–93 (2013).
29
[30] Mohammadi Ziaran, G., Badiei A.R., Khaniania Y., Haddadpour M., One Pot Synthesis of Polyhydroquinolines Catalyzed by Sulfonic Acid Functionalized SBA-15 as a New Nanoporous Acid Catalyst under Solvent Free Conditions, Iran. J. Chem. Chem. Eng. (IJCCE), 29(2): 1–10 (2010).
30
[31] Davoodnia A., Yadegarian S., Nakhaei A., Tavakoli-Hoseini N., A Comparative Study of TiO2, Al2O3, and Fe3O4 Nanoparticles as Reusable Heterogeneous Catalysts in the Synthesis of Tetrahydrobenzo[a]xanthene-11-ones, Russ. J. Gen. Chem., 86(12): 2849–2854 (2016).
31
[32] Nakhaei A., Davoodnia A., Yadegarian S., Catalytic Activity of (NH4)42[Movi 72Mov 60O372(CH3COO)30(H2O)72]AS Highly Efficient Recyclable Catalyst for the Synthesis of Tetrahydrobenzo [B]Pyrans in Water, Heterocycl. Lett., 7(1): 35–44 (2017).
32
[33] Hasaninejad A., Zare A., Zolfigol M.A., Abdeshah M., Ghaderi A., Nami-Ana F., Synthesis of Poly-Substituted Quinolines via Friedländer Hetero-Annulation Reaction Using Silica-Supported P2O5 under Solvent-Free Conditions, Iran. J. Chem. Chem. Eng. (IJCCE), 30(1): 73–81 (2011).
33
[34] Keshwal B.S., Rajguru D., Acharya A.D., DBU as a Novel and Highly Efficient Catalyst for the Synthesis of 3, 5-Disubstituted-2, 6-dicyanoanilines Under Conventional and Microwave Conditions, Iran. J. Chem. Chem. Eng. (IJCCE), 35(1): 37–42 (2016).
34
[35] Sheikhhosseini E., Sattaei Mokhtari T., Faryabi M., Rafiepour A., Soltaninejad S., Iron Ore Pellet, A Natural and Reusable Catalyst for Synthesis of Pyrano [2, 3-d] pyrimidine and Dihydropyrano [c] chromene Derivatives in Aqueous Media, Iran. J. Chem. Chem. Eng. (IJCCE), 5(1): 43–50 (2016).
35
[36] Gohani, M., H van Tonder, J., CB Benzuidenhoudt, B., NaHSO4-SiO2: An Efficient Reusable Green Catalyst for Selective C-3 Propargylation of Indoles with Tertiary Propargylic Alcohols, Iran. J. Chem. Chem. Eng. (IJCCE), 34(3): 11–17 (2015).
36
[37] Nakhaei A., Yadegarian S., Synthesis of Tetrahydrobenzo [a] xanthene-11-one Derivatives Using ZrO2–SO3H as Highly Efficient Recyclable Nano-catalyst, J. Appl. Chem. Res., 11(3): 72–83 (2017).
37
[38] Mohammadi Ziarani G., Mousavi S., Lashgari N., Badiei A., Shakiba M., Application of Sulfonic Acid Functionalized Nanoporous Silica (SBA-Pr-SO3H) in the Green One-Pot Synthesis of Polyhydroacridine Libraries, Iran. J. Chem. Chem. Eng. (IJCCE), 32(4): 9–16 (2013).
38
[39] Chunhua X., Caiping Y., Adsorption Behavior of Cu(II) in Aqueous Solutions by SQD-85 Resin, Iran. J. Chem. Chem. Eng. (IJCCE), 32(2): 57–66 (2013).
39
[40] Nakhaei A., Hosseininasab N., Yadegarian S., Synthesis of 1, 4-Dihydropyridine Derivatives Using Nano-Zirconia Sulfuric Acid as Highly Efficient Recyclable Catalyst, Heterocycl. Lett., 7(1): 81–90 (2017).
40
[41] Mohanazadeh F., Rahimi S., HNO3/N, N-Diethylethanaminium-2-(Sulfooxy) Ethyl Sulfate as an Efficient System for the Regioselective of Aromatic Compounds, Iran. J. Chem. Chem. Eng. (IJCCE), 30(2): 73–77 (2011).
41
[42] Mokhtary M., Rastegar Niaki M., PolyVinylPolyPyrrolidone-Supported Boron Trifluoride (PVPP-BF3); Highly Efficient Catalyst for Oxidation of Aldehydes to Carboxylic Acids and Esters by H2O2, Iran. J. Chem. Chem. Eng. (IJCCE), 32(1): 43–48 (2013).
42
[43] Mohammadi Ziarani, G., Badiei, A., Azizi, M., Zarabadi, P., Synthesis of 3, 4-dihydropyrano [c] Chromene Derivatives Using Sulfonic Aacid Functionalized Silica (SiO2PrSO3H), Iran. J. Chem. Chem. Eng. (IJCCE), 30(2): 59–65 (2011).
43
[44] Salamatinia B., Hashemizadeh I., Ahmad Zuhairi A., Alkaline Earth Metal Oxide Catalysts for Biodiesel Production from Palm Oil: Elucidation of Process Behaviors and Modeling Using Response Surface Methodology, Iran. J. Chem. Chem. Eng., 32(1): 113–126 (2013).
44
[45] Feyzi M., Mirzaei A.A., Preparation and Characterization of CoMn/TiO2 Catalysts for Production of Light Olefins, Iran. J. Chem. Chem. Eng. (IJCCE), 30(1): 17–28 (2011).
45
[46] Fazeli A., Khodadadi A.A., Mortazavi Y., Manafi H., Cyclic Regeneration of Cu/ZnO/Al2O3 Nano Crystalline Catalyst of Methanol Steam Reforming for Hydrogen Production in a Micro-Fixed-Bed Reactor, Iran. J. Chem. Chem. Eng. (IJCCE), 32(3): 45–59 (2013).
46
[47] Sayama K., Arakawa H., Photocatalytic Decomposition of Water and Photocatalytic Reduction of Carbon Dioxide over ZrO2 Catalyst, J. Phys. Chem., 97(3): 531–533 (1993).
47
[48] Nakhaei A., Davoodnia A., Application of a Keplerate Type Giant Nanoporous Isopolyoxomolybdate as a Reusable Catalyst for the Synthesis of 1, 2, 4, 5-tetrasubstituted Imidazoles, Chin. J. Catal., 35(10): 1761–1767 (2014).
48
[49] Nakhaei A., Davoodnia A., Morsali A., Extraordinary Catalytic Activity of a Keplerate-Type Giant Nanoporous Isopolyoxomolybdate in the Synthesis of 1, 8-dioxo-octahydroxanthenes and 1, 8-dioxodecahydroacridines, Res. Chem. Intermed.,41(10): 7815-7826 (2015).
49
[50] Mirzaie Y., Lari J., Vahedi H., Hakimi M., Nakhaei A., Rezaeifard A., Fast and Green Method to Synthesis of Quinolone Carboxylic Acid Derivatives Using Giant-Ball Nanoporous Isopolyoxomolybdate as Highly Efficient Recyclable Catalyst in
50
Refluxing Water, J. Mex. Chem. Soc., 61(1): 35-40 (2017).
51
[51] Yadegarian S., Davoodnia A., Nakhaei A., Solvent-Free Synthesis of 1, 2, 4, 5-Tetrasubstituted Imidazoles Using Nano Fe3O4@ SiO2-OSO3H as a Stable and Magnetically Recyclable Heterogeneous Catalyst, Orient. J. Chem., 31(1): 573-579
52
[52] Davoodnia A., Nakhaei A., Fast and Solvent-Free Synthesis of Polyhydroquinolines Catalyzed by a Keplerate Type Giant Nanoporous Isopolyoxomolybdate as a Reusable Catalyst, Synth. React. Inorg. Metal-Org. Nano-Met. Chem., 46(7): 1073-1080 (2016).
53
[53] Davoodnia A., Nakhaei A., Tavakoli-Hoseini N., Catalytic Performance of a Keplerate-Type, Giant-Ball Nanoporous Isopolyoxomolybdate as a Highly Efficient Recyclable Catalyst for the Synthesis of Biscoumarins, Z. Naturforsch. B, 71(3): 219-225 (2016).
54
[54] Nakhaei A., Davoodnia A., Yadegarian S., Nano Isopolyoxomolybdate Catalyzed Biginelli Reaction for One-Pot Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones and 3,4-Dihydropyrimidin-2(1H)-thiones Under Solvent-Free Conditions, Russ. J. Gen. Chem., 86(12): 2870-2876(2016).
55
[55] Rohaniyan M., Davoodnia A., Nakhaei A., Another Application of (NH4) 42 [MoVI72MoV60O372 (CH3COO) 30 (H2O) 72] as a Highly Efficient Recyclable Catalyst for the Synthesis of Dihydropyrano [3, 2‐c] Chromenes, Appl. Organometal. Chem.,30(8): 626-629 (2016).
56
[56] Nakhaei A., Morsali A., Davoodnia A., An Efficient Green Approach to Aldol and Cross-Aldol Condensations of Ketones with Aromatic Aldehydes Catalyzed by Nanometasilica Disulfuric Acid in Water, Russ. J. Gen. Chem., 87(5): 1073-1078(2017).
57
[57] Kolvari E., Koukabi N., Hosseini M.M., Vahidian M., Ghobadi E., Nano-ZrO 2 Sulfuric Acid: A Heterogeneous Solid Acid Nano Catalyst for Biginelli Reaction under Solvent Free Conditions, RSC Advances, 6(9): 7419-7425 (2016).
58
[58] Amoozadeh A., Rahmani S., Bitaraf M., Abadi F. B., Tabrizian E., Nano-Zirconia as an Excellent Nano Support for Immobilization of Sulfonic Acid: A New, Efficient and Highly Recyclable Heterogeneous Solid Acid Nanocatalyst for Multicomponent Reactions, New J. Chem., 40(1): 770-780 (2016).
59
[59] Nakhaei A., Nano-Fe3O4@ZrO2-H3PO4 as an Efficient Recyclable Catalyst for the Neat Preparation of Thiazole Derivatives in Ordinary or Magnetized Water, Current Catal., 7(1): 72-78 (2018).
60
ORIGINAL_ARTICLE
DSA Preparation of Pt NPs @MIL-53(Fe) and Its Catalytic Behaviors
In this work, the effects of preparation methods such as CE oven, microwave irradiation, and ultrasound on the morphology, particle size and crystallinity of MIL-53(Fe) are firstly investigated. Furthermore, the methods are utilized to prepare Pt NPs@MIL-53(Fe). As a result, well-defined Pt NPs@MIL-53(Fe) prepared by microwave irradiation exhibits uniformed morphology, high crystallinity, and high-disperse Pt NPs, which has been confirmed by FT-IR, TG, N2 adsorption at 77K, TEM and PXRD. Pt NPs@MIL-53(Fe) composite can selectively catalyze the thiophene hydrogenation over nitrobenzene and benzothiophene hydrogenation. The result shows that the sulfur amount can rapidly be reduced to less than 10 ppm and the crystallinity of reacted Pt NPs@MIL-53(Fe) is unchangeable.
https://ijcce.ac.ir/article_34145_7aa7f252e68c81fea0f9ce15ba41ad28.pdf
2018-06-01
43
49
10.30492/ijcce.2018.34145
Directing self-assembly
Mono-disperse nano-particle
MIL-53(Fe)
Catalytic behavior
Ya-Feng
Li
liyafeng@ccut.edu.cn
1
School of Chemical Engineering, Changchun University of Technology, 130012, Changchun, P.R. CHINA
LEAD_AUTHOR
Siyu
Ni
2
School of Chemical Engineering, Changchun University of Technology, 130012, Changchun, P.R. CHINA
AUTHOR
Zhen
Wang
1721538095@qq.com
3
School of Chemical Engineering, Changchun University of Technology, 130012, Changchun, P.R. CHINA
AUTHOR
JingJing
Lu
1069236639@qq.com
4
School of Chemical Engineering, Changchun University of Technology, 130012, Changchun, P.R. CHINA
AUTHOR
Limei
Zhang
may4500@sohu.com
5
Computer Science and Engineering College, Changchun University of Technology, 130012, Changchun, P.R. CHINA
AUTHOR
[1] Suh M.P., Park H.J., Prasad T.K., Lim D.W., Hydrogen Storage in Metal-Organic Frameworks, Chem. Rev., 112: 782–835(2012).
1
[2] Sumida K., Rogow D.L., Mason J.A., McDonald T.M., Bloch E.D., Herm Z.R., Bae T.H., Long J.R., Carbon Dioxide Capture in Metal-Organic Frameworks, Chem. Rev., 112: 724–781 (2012).
2
[3] Kreno L.E., Leong K., Farha O.K., Allendorf M., Van Duyne R.P., Hupp J.T., Metal-Organic Framework Materials as Chemical Sensor, Chem. Rev., 112:1105–1125 (2012).
3
[4] Horcajada P., Gref R., Baati T., Allan P.K., Maurin G., Couvreur P., Férey G., Morris R.E., Serre C., Metal-Organic Frameworks in Biomedicine, Chem. Rev., 112: 1232–1268(2012).
4
[5] Lee J.Y., Farha O.K., Roberts J., Scheidt K.A., Nguyen S.B.T., Hupp J.T., Metal–Organic Framework Materials as Catalysts, Chem. Soc. Rev., 38: 1450–1459(2009).
5
[6] Tranchemontagne D.J., Mendoza-Cortés J.L., O’Keeffe M., Yaghi O.M., Secondary Building Units, Nets and Bonding in the Chemistry of Metal–Organic Frameworks, Chem. Soc. Rev., 38: 1257–1283(2009).
6
[7] Stephen S.Y.C., Samuel M.F.L., Jonathan P.H.C., Orpen A.G., Williams I.D., A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n, Science, 283: 1148-1150(1999).
7
[8] Serre C., Millange F., Thouvenot C., Noguès M., Marsolier G., Louër D., Férey G., Very Large Breathing Effect in the First Nanoporous Chromium(III)- Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·(H2O)y, J. Am. Chem. Soc., 124(45): 13519-13526(2002).
8
[9] Horcajada P., Serre C., Vallet-Regí M., Sebban M., Taulelle F., Férey G., Metal–Organic Frameworks as Efficient Materials for Drug Delivery, Angew. Chem. Int. Ed., 45(36): 5974–5978(2006).
9
[10] Férey G., Mellot-Draznieks C., Serre C., Millange F., Dutour J., Surblé S., Margiolaki I., A Chromium Terephthalate–Based Solid with Unusually Large Pore Volumes and Surface Area, Science, 309: 2040-2042(2005).
10
[11] Huang X.C., Lin Y.Y., Zhang J.P., Chen X.X., Ligand-Directed Strategy for Zeolite-Type Metal-Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies, Angew. Chem. Int. Ed., 45: 1557–1559(2006); Park K.S., Ni Z., Côté A.P., Choi J.Y., Huang R.D., Uribe-Romo F.J., Chae H.K., O’Keeffe M., Yaghi O.M., Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks, PNAS, 103(27): 10186–10191(2006).
11
[12] Cavka J.H., Jakobsen S., Olsbye U., Guillou N., Lamberti C., Bordiga S., Lillerud L.P., A New Zirconium Inorganic Building Brick forming Metal Organic Frameworks with Exceptional Stability, J. Am. Chem. Soc., 130: 13850–13851(2008).
12
[13] Zhu Q.L., Xu Q., Metal–Organic Framework Composites, Chem. Soc. Rev., 43: 5468-5512 (2014); Shen L., Wu W., Liang R., Lin R., Wu L., Highly Dispersed Palladium Nanoparticles Anchored on UiO-66(NH2) Metal-Organic Framework as a Reusable and Dual Functional Visible-Light-Driven Photocatalyst, Nanoscale, 5: 9374-9382 (2013); He J., Yan Z., Wang J., Xie J,, Jiang L., Shi Y., Yuan F., Yu F., Sun Y., Significantly Enhanced Potocatalytic Hydrogen Evolution under Visible Light over CdS Embedded on Metal–Organic Frameworks, Chem. Commun., 49: 6761-6763 (2013); Zhao M., Deng K., He L., Liu Y., Li G., Zhao H., Tang Z., Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions, J. Am. Chem. Soc., 136: 1738-1741(2014).
13
[14] Czaja A.U., Trukhan N., Müller U., Industrial Applications of Metal–Organic Frameworks, Chem. Soc. Rev., 38: 1284–1293(2009).
14
[15] Schlichte K., Kratzke T., Kaskel S., Improved Synthesis, Thermal Stability and Catalytic Properties of the Metal-Organic Framework Compound Cu3(BTC)2, Microporous Mesoporous Mater., 73: 81–88(2004).
15
[16] Henschel A., Gedrich K., Kraehnert R., Kaskel S., Catalytic Properties of MIL-101, Chem. Commun., 4192–4194(2008).
16
[17] Dhakshinamoorthy A., Garcia H., Catalysis by Metal Nanoparticles Embedded on Metal–Organic Frameworks, Chem. Soc. Rev., 41: 5262–5284(2012).
17
[18] Lu G. Li S.Z., Guo Z., Farha O.K., Hauser B.G., Qi X.Y., Wang Y., Wang X., Han S.Y., Liu X.G., DuChene J.S., Zhang H., Zhang Q.C., Chen X.D., Ma J., Loo S.C.J., Wei W.D., Yang Y.H., Hupp J.T., Huo F.W., Imparting Functionality to a Metal–Organic Framework Material by Controlled Nanoparticle Encapsulation, Nat. Chem., 4: 310–316(2012).
18
[19] Ameloot R., Roeffaers M.B.J., Cremer G.D., Vermoortele F., Hofkens J., Sels B.F., Vos D.D., Metal–Organic Framework Single Crystals as Photoactive Matrices for the Generation of Metallic Microstructures, Adv. Mater., 23: 1788-1791 (2011).
19
[20] Hermes S., Schröter M.K., Schmid R., Khodeir L., Muhler M., Tissler A., Fischer R.W., Fischer R.A., Metal@MOF: Loading of Highly Porous Coordination Polymers Host Lattices by Metal Organic Chemical Vapor Deposition, Angew. Chem. Int. Ed., 44: 6237–6241(2005).
20
[21] Tsuruoka T., Kawasaki H., Nawafune H., Akamatsu K., Controlled Self-Assembly of Metal–Organic Frameworks on Metal Nanoparticles for Efficient Synthesis of Hybrid Nanostructures, ACS Appl. Mater. Interfaces, 3: 3788-3791(2011).
21
[22] Rioux R.M., Song H., Hoefelmeyer J.D., Yang P., Somorjai G.A., High-Surface-Area Catalyst Design: Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica, J. Phys. Chem. B, 109: 2192-2202(2005).
22
[23] Férey G., Millange F., Morcrette M., Serre C., Doublet M.L., Grenèche J.M., Tarascon J.M., Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties, Angew. Chem. Int. Ed., 46: 3259-3263(2007); Horcajada P., Serre C., Maurin G., Ramsahye N.A., Balas F., Vallet-Regí M., Sebban M., Taulelle F., Férey G., Flexible Porous Metal-Organic Frameworks For a Controlled Drug Delivery, J. Am. Chem. Soc., 130: 6774-6780(2008).
23
[24] Gordon J., Kazemian H., Rohani S., Rapid and Efficient Crystallization of MIL-53(Fe) by Ultrasound and Microwave Irradiation, Microporous and Mesoporous Mater., 162: 36-43 (2012).
24
[25] Ai L., Li L., Zhang C., Fu J., Jiang J., MIL-53(Fe): A Metal–Organic Framework with Intrinsic Peroxidase-Like Catalytic Activity for Clorimetric Biosensing, Chemistry-A Eur. J., 19: 15105-15108(2013).
25
ORIGINAL_ARTICLE
γ-Fe2O3@HAP-Fe2+ NPs: An Efficient and Eco-Friendly Catalyst for the Synthesis of Xanthene Derivatives in Water
Efficient and environmentally friendly syntheses of xanthenes derivatives by using γ-Fe2O3@HAP-Fe2+ NPs as a catalyst has been carried out. The catalyst can be readily isolated by using an external magnet and no obvious loss of activity was observed when the catalyst was reused in eight consecutive runs. The procedure has several advantages, such as economic availability of catalyst, simple procedure, ease of product isolation, no harmful byproducts, less reaction time and high yields.
https://ijcce.ac.ir/article_30765_0f97834c821dbcd3a6652b3a15492b4c.pdf
2018-06-01
51
62
10.30492/ijcce.2018.30765
Magnetic nanoparticles
Xanthenes
γ-Fe2O3@HAP-Fe2+ NPs
Green solvent
Rahim
Hosseinzdeh Khanamiri
r_hosseinzadeh@sbu.ac.ir
1
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN
LEAD_AUTHOR
Esmail
Vessally
vessally@yahoo.com
2
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN
AUTHOR
Gholam Hossein
Shahverdizadeh
shahverdizadeh@iaut.ac.ir
3
Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
AUTHOR
Mirzaagha
Babazadeh
babazadeh@iaut.ac.ir
4
Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
AUTHOR
Ladan
Edjlali
l_edjlali@iaut.ac.ir
5
Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
AUTHOR
[1] a) Min B.K., Friend C.M., Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation, Chem. Rev., 107: 2709-2724 (2007).
1
b) Moghimi A., Hosseinzadeh-Khanmiri R., Shaabani A., Hamadani H., A Green Synthesis of Nitrones from Diamino Glyoxime Using Aldehydes and Ketones, J. Iran. Chem. Soc., 10: 929-936 (2013).
2
c) Moghimi A., Hosseinzadeh-Khanmiri R., Omrani I., Shaabani A., A New Library of 4(3H)- and 4,4′(3H,3H′)-quinazolinones and 2-(5-alkyl-1,2,4-oxadiazol-3-yl)quinazolin-4(3H)-one Obtained from Diaminoglyoxime, Tetrahedron Letters, 54: 3956-3959 (2013).
3
d) Hassanpour A., Hosseinzadeh-Khanmiri R., Abolhasani J., ZnO Nanoparticles as an Efficient, Heterogeneous, Reusable, and Ecofriendly Catalyst for One-Pot, Three-Component Synthesis of 3,4-Dihydropyrimidin-2(1H)-(thio)one Derivatives in Water, Synthetic Communications, 45: 727-733 (2015).
4
e) Hosseinzadeh- Khanmiri R., Moghimi A., Shaabani A., Valizadeh H., Ng S. W., Diaminoglyoxime as a Versatile Reagent in the Synthesis of bis(1,2,4-oxadiazoles), 1,2,4-Oxadiazolyl-Quinazolines and 1,2,4-oxadiazolyl-benzothiazinones, Mol. Divers., 18: 769-776 (2014).
5
f) Hosseinzadeh-Khanmiri R., Moghimi A., Shaabani A., Valizadeh H., Synthesis of 2-(1,2,4-oxadiazol-3-yl)quinazolin-4(3H)-ones from Diaminoglyoxime-based Nitrones, Ng S.W., Mol. Divers., 19: 501-510 (2015).
6
g)Hassanpour A., Hosseinzadeh-Khanmiri R., Babazadeh M., Edjlali L., ZnO NPs: an Efficient and Reusable Nanocatalyst for the Synthesis of Nitrones from DAG Using H2O as a Solvent at Room-Temperature,Res Chem Intermed, 42: 2221-2231 (2016).
7
h) Edjlali L., Hosseinzdeh-Khanamiri R., Titanium Dioxide Nanoparticles as Efficient Catalyst for the Synthesis of Pyran’s Annulated Heterocyclic Systems via Three-Component Reaction, Monatsh Chem., 147: 1221-1225 (2016).
8
i) Vessally E., Hosseinzadeh‐Khanmiri R., Ghorbani‐Kalhor E., Es’haghi M., Ejlali L., Eco-Friendly Synthesis of 3,4-dihydroquinoxalin-2-Amine, Diazepine-Tetrazole and Benzodiazepine-2-Carboxamide Derivatives with the Aid of MCM-48/H5PW10V2O40, Appl Organometal Chem., 31: e3729- (2017).
9
j) Babazadeh M., Hosseinzadeh-Khanmiri R., Zakhireh S., Eco-Friendly Synthesis of Benzoxazepine and Malonamide Derivatives in Aqueous Media, Appl. Organometal. Chem., 30: 514- (2016).
10
k) Mohammad Ziarani G., Saidian F., Gholamzadeh P., Badiei A., Abolhasani Soorki A., Green Synthesis of Pyrazol‑chromeno[2,3‑d]pyrimidinones using SBA-Pr-SO3H as an Efficient, Iran. J. Chem. Chem. Eng. (IJCCE), 36(6): 39-48 (2017).
11
l) Zhang J., Wang A., Wang Y., Wang H., Gui J., Heterogeneous Oxidative Desulfurization of Diesel Oil by Hydrogen Peroxide: Catalysis of an Amphipathic Hybrid Material Supported on SiO2, Chem. Eng. J., 245: 65-70 (2014).
12
m) Vessally E., Hosseinian A., Edjlali L., Babazadeh M., Hosseinzadeh-Khanmiri R., New Strategy for the Synthesis of Morpholine Cores: Synthesis from N-Propargylamines, Iran. J. Chem. Chem. Eng. (IJCCE), 36(3): 1-13 (2017).
13
[2] a) Tsang S.C., Caps V., Paraskevas I., Chadwick D., Thompsett D., Magnetically Separable, Carbon-Supported Nanocatalysts for the Manufacture of Fine Chemicals, Angew. Chem., 116: 5763- (2004).
14
b) Edjlali L., Hosseinzdeh-Khanamiri R., Abolhasani J., Fe3O4 Nano-Particles Supported on Cellulose as an Efficient Catalyst for the Synthesis of Pyrimido[4,5-b]quinolines in Water, Monatsh. Chem., 146: 1339-1342 (2015).
15
c) Ghorbani-Kalhor E., Behbahani M., Abolhasani J., Hosseinzadeh-Khanmiri R., Synthesis and Characterization of Modified Multiwall Carbon Nanotubes With Poly (N-Phenylethanolamine) and Their Application for Removal and Trace Detection of Lead Ions in Food and Environmental Samples, Food Anal. Method, 8: 1326-1334 (2015).
16
d) Behbahani M., Abolhasani J., Amini M.M., Sadeghi O., Omidi F., Bagheri A., Salarian M., Application of Mercapto Ordered Carbohydrate-Derived Porous Carbons for Trace Detection of Cadmium and Copper Ions in Agricultural Products, Food Chemistry, 173: 1207-1212 (2015).
17
e) Kalate Bojdi M., Behbahani M., Mashhadizadeh M.H., Bagheri A., Davarani S.S.H., Farahani A., Mercapto-Ordered Carbohydrate-Derived Porous Carbon Electrode as a Novel Electrochemical Sensor for Simple and Sensitive Ultra-Trace Detection of Omeprazole in Biological Samples, Materials Science and Engineering: C, 48: 213-219 (2015).
18
f) Fouladian H.R., Behbahani M., Solid Phase Extraction of Pb(II) and Cd(II) in Food, Soil, and Water Samples Based on 1-(2-Pyridylazo)-2-Naphthol-Functionalized Organic–Inorganic Mesoporous Material with the Aid of Experimental Design Methodology, Food Anal. Methods, 8: 982-993 (2015).
19
g) Mohammadi S., Musavi M., Abdollahzadeh F., Babadoust S., Hosseinian A., Application of Nanocatalysts in C-Te Cross-Coupling Reactions: An Overview, Chem. Rev. Lett. 1: 49-55 (2018).
20
h) Sarhandi S., Daghagheleh M., Vali M., Moghadami R., Vessally E., New Insight in Hiyama Cross-coupling Reactions: Decarboxylative, Denitrogenative and Desulfidative Couplings:
21
A Review, Chem. Rev. Lett., 1: 9-15 (2018).
22
i) Daghagheleh M., Vali M., Rahmani Z., Sarhandi S., Vessally E., A review on the CO2 Incorporation Reactions Using Arynes, Chem. Rev. Lett., 1: 23-30 (2018).
23
[3] a) Abolhasani J., Hosseinzadeh-Khanmiri R., Ghorbani-Kalhor E., Hassanpour A., Asgharinezhad A.A., Shekari N., Fathi A., An Fe3O4@SiO2@polypyrrole Magnetic Nanocomposite for the Extraction and Preconcentration of Cd(II) and Ni(II). Fathi, Anal. Methods, 7: 313- (2015).
24
b) Ghorbani-Kalhor E., Hosseinzadeh-Khanmiri R., Babazadeh M., Abolhasani J., Hassanpour A., Synthesis and Application of a Novel Magnetic Metal-Organic Framework Nanocomposite for Determination of Cd, Pb, and Zn in Baby Food Samples, Can. J. Chem., 93(5): 518-525 (2015).
25
c) Hassanpour A., Hosseinzadeh-Khanmiri R., Babazadeh M., Abolhasani J., Ghorbani-Kalhor E., Determination of Heavy Metal Ions in Vegetable Samples Using a Magnetic Metal–Organic Framework Nanocomposite Sorbent, Food Addit. Contam. Part A, 32: 725-736 (2015).
26
d) Ghorbani-Kalhor E., Hosseinzadeh-Khanmiri R., Abolhasani J., Babazadeh M., Hassanpour A., Determination of Mercury(II) Ions in Seafood Samples After Extraction and Preconcentration by a Novel Functionalized Magnetic Metal–Organic Framework Nanocomposite, J. Sep. Sci., 38: 1179-1186 (2015).
27
e) Babazadeh M., Hosseinzadeh-Khanmiri R., Abolhasani J., Ghorbani-Kalhor E., Hassanpour A., Solid Phase Extraction of Heavy Metal Ions from Agricultural Samples with the Aid of a Novel Functionalized Magnetic Metal–Organic Framework, RSC Adv., 5: 19884- (2015).
28
f) Vessally E., Ghasemisarabbadeih M., Ekhteyari Z., Hosseinzadeh-Khanmiri R., Ghorbani-Kalhor E., Ejlali L., Platinum Nanoparticles Supported on Polymeric Ionic Liquid Functionalized Magnetic Silica: Effective and Reusable Heterogeneous Catalysts for the Selective Oxidation of Alcohols in Water, RSC Adv., 6: 106769- (2016).
29
j) Salami Kalajahi M., Moqadam S., Mahdavian M., Synthesis and Characterization of Sunflower Oil-based Polysulfide Polymer/Cloisite 30B Nanocomposites, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 38(1): 185- 192 (2018).
30
[4] Chikazumi S., Taketomi S., Ukita M., Mizukami M., Miyajima H., Setogawa M., Kurihara Y., Physics of Magnetic Fluids, J. Magn. Magn. Mater., 65: 245-251 (1987).
31
[5] Christe Sonia Mary M., Sasikumar S., Sodium Alginate/Starch Blends Loaded with Ciprofloxacin Hydrochloride as a Floating Drug Delivery System - In Vitro Evaluation, Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 34(2): 25-31 (2015).
32
[6] Mornet S., Vasseur S., Grasset F., Verveka P., Goglio G., Demourgues A., Portier J., Pollert E., Duguet E., Magnetic Nanoparticle Design for Medical Applications, Prog. Solid State Chem., 34: 237-247 (2006).
33
[7] Graham D.L., Ferreira H.A., Freitas P.P., Magnetoresistive-Based Biosensors and Biochips, Trends. Biotechnol., 22(9): 455-462 (2004).
34
[8] Takafuji M., Ide S., Ihara H., Xu Z., Preparation of Poly(1-vinylimidazole)-Grafted Magnetic Nanoparticles and Their Application for Removal of Metal, Ions. Chem. Mater., 16: 1977-1983 (1977).
35
[9] Hyeon T., Chemical Synthesis of Magnetic Nanoparticles, Chem. Commun., 927 (2003).
36
[10] Senapati K.K., Borgohain C., Phukan P., Synthesis of Hghly Stable CoFe2O4 Nanoparticles and Their Use as Magnetically Separable Catalyst for Knoevenagel Reaction in Aqueous Medium, J. Mol. Catal. A: Chem., 339: 24-31 (2011).
37
[11] Zhang Q., Su H., Luo J., Wei Y.Y., A Magnetic Nanoparticle Supported Dual Acidic Ionic Liquid: A “Quasi-Homogeneous” Catalyst for the One-Pot Synthesis of Benzoxanthenes, Green Chem., 14: 201-208 (2012).
38
[12] Karaoğlu E., Baykal A., Senel M., Sözeri H., Toprak M.S., Synthesis and Characterization of Piperidine-4-Carboxylic Acid Functionalized Fe3O4 Nanoparticles as a Magnetic Catalyst for Knoevenagel Reaction, Mater. Res. Bull., 47: 2480- (2012).
39
[13] Abu-Reziq R., Wang D., Post M., Alper H., Platinum Nanoparticles Supported on Ionic Liquid-Modified Magnetic Nanoparticles: Selective Hydrogenation Catalysts, Adv. Synth. Catal., 349: 2145- (2007).
40
[14] Jiang Y.Y., Guo C., Xia H.S., Mahmood I., Liu C.Z., Liu H.Z., Magnetic Nanoparticles Supported Ionic Liquids for Lipase Immobilization: Enzyme Activity in Catalyzing Esterification, J. Mol. Catal. B: Enzym., 58: 103-109 (2009).
41
[15] Zheng X.X., Luo S.Z., Zhang L., Cheng J.P., Magnetic Nanoparticle Supported Ionic Liquid Catalysts for CO2 Cycloaddition Reactions, Green Chem., 11: 455- (2009).
42
[16] Kooti M., Afshari M., Phosphotungstic Acid Supported on Magnetic Nanoparticles as an Efficient Reusable Catalyst for Epoxidation of Alkenes, Mater. Res. Bull., 47: 3473-3478 (2012).
43
[17] Kiasat A.R., Nazari S., Magnetic Nanoparticles Grafted with β-cyclodextrin–polyurethane Polymer as a Novel Nanomagnetic Polymer Brush Catalyst for Nucleophilic Substitution Reactions of Benzyl Halides in Water, J. Mol. Catal. A: Chem., 365: 80-86 (2012).
44
[18] a) Kassaee M.Z., Masrouri H., Movahedi F., Sulfamic Acid-Functionalized Magnetic Fe3O4 Nanoparticles as an Efficient and Reusable Catalyst for One-Pot Synthesis of α-Amino Nitriles in Water, Appl. Catal. A: General, 395: 28-33 (2011).
45
b) Shahidi S., Farajzadeh P., Ojaghloo P., Karbakhshzadeh A., Hosseinian A., Nanocatalysts for Conversion of Aldehydes/Alcohols/Amines to Nitriles: A Review, Chem. Rev. Lett. 1: 37-44 (2018).
46
[19] Antony L.A.P., Slanina T., Sebej P., Šolomek T., Klan P., Fluorescein Analogue Xanthene-9-Carboxylic Acid: A Transition-Metal-Free CO Releasing Molecule Activated by Green Light, Org. Lett., 15: 4552-4555 (2013).
47
[20] Horrobina, D.F. Manku M.S., Roles of Prostaglandins Suggested by the Prostaglandin Agonist/Antagonist Actions of Local Anaesthetic, Anti-Arrhythmic, Anti-Malarial, Tricyclic Antidepressant and Methyl Xanthine Compounds. Effects on Membranes and on Nucleic Acid Function,Medical Hypotheses, 3: 71-86 (1977).
48
[21] Wang H., Lu L., Zhu S., Li Y., Cai W., The Phototoxicity of Xanthene Derivatives Against Escherichia Coli, Staphylococcus Aureus, and Saccharomyces Cerevisiae, Curr. Microbiol., 52: 21-26 (2006).
49
[22] Chibale K., Visser M., Schalkwyk D.V., Smith P.J., Saravanamuthu A., Fairlamb A.H., Exploring
50
the Potential of Xanthene Derivatives as Trypanothione Reductase Inhibitors and Chloroquine Potentiating Agents, Tetrahedron, 59: 2289-2296 (2003).
51
[23] Knight C.G., Stephens T., Xanthene-Dye-Labelled Phosphatidylethanolamines as Probes of Interfacial pH. Studies in Phospholipid Vesicles, Biochem. J., 258: 683-687 (1989).
52
[24] Bright G.R., Fisher G.W., Rogowska J., Taylor L., Fluorescence Ratio Imaging Microscopy: Temporal and Spatial Measurements of Cytoplasmic Ph, J. Cell Biol., 104: 1019-1033 (1987).
53
[25] Mirjalili B.B.F., Bamoniri A., Akbari A., BF3SiO2: an Efficient Alternative for the Synthesis of 14-aryl or Alkyl-14H-dibenzo[a,j]xanthenes, Tetrahedron, 49: 6454-6456 (2008).
54
[26] Bhowmik B.B., Ganguly P., Photophysics of Xanthene Dyes in Surfactant Solution, Spectrochim. Acta A., 61: 1997-2003 (2005).
55
[27] a) Teimouri A., Najafi Chermahini A., Ghorbanian L., The Green Synthesis of New Azo Dyes Derived from Salicylic Acid Derivatives Catalyzed via Baker’s Yeast and Solid Acid Catalysis, Chemija., 24(3): 59-66 (2013).
56
b) Shoja A., Shirini F., Abedini M., Zanjanchi M.A., BiVO4-NPs as a New and Efficient Nano-Catalyst for the Synthesis of 1,8-Dioxo-Octahydro Xanthenes, J Nanostruct Chem., 4: 110- (2014).
57
c) Haeri H. S., Rezayati S., Rezaee Nezhad E., Darvishi H., Three-Component Synthesis of Pyrano[2,3-d]pyrimidinone Derivatives Catalyzed by Ni2+ Supported on Hydroxyapatite-Core–Shell-γ-Fe2O3 Nanoparticles in Aqueous Medium, Res Chem Intermed, 42(5): 7594-7609 (2016).
58
d) Urinda S., Kundu D., Majee A., Hajra A., Indium Triflate-Catalyzed One-Pot Synthesis of 14-Alkyl or Aryl-14H-Dibenzo[a, j]Xanthenes in Water, Heteroatom Chemistry, 20: 232-234 (2009).
59
e) Zhang Q., Su H., Luo J., Wei Y. Y., A Magnetic Nanoparticle Supported Dual Acidic Ionic Liquid: A “Quasi-Homogeneous” Catalyst for the One-Pot Synthesis of Benzoxanthenes, Green Chem., 14: 201-208 (2012).
60
f) Jin T.-S., Zhang J.-S., Xiao J-C., Wang A-Q., Li T-S., Clean Synthesis of 1,8-Dioxo-Octahydroxanthene Derivatives Catalyzed by p-Dodecylbenezenesulfonic Acid in Aqueous Media, SYNLETT, 5: 0866-0870 (2004).
61
j) Mokhtary M., Refahati S., Polyvinylpolypyrrolidone-Supported Boron Trifluoride (PVPP-BF3): Mild and Efficient Catalyst for the Synthesis of 14-Aryl-14H-Dibenzo [a,j] Xanthenes and Bis(naphthalen-2-yl-sulfane) Derivatives, Dyes Pigments, 99: 378-381 (2013).
62
[28] a) Rad-Moghadam K., Azimi S.C., Mg(BF4)2 Doped in [BMIm][BF4]: A Homogeneous Ionic Liquid-Catalyst for Efficient Synthesis of 1,8-dioxo-Octahydroxanthenes, Decahydroacridines and 14-Aryl-14H-dibenzo[a,j]xanthenes, J. Mol. Catal. A: Chem., 363: 465-469 (2012).
63
b) Mahdavinia G.H., Ghanbari M., Sepehrian M., Kooti H.F., MCM-41 Functionalized Sulfonic Acid Catalyzed One-Pot Synthesis of 1,8- Dioxo-Octahydroxanthenes, J. Iran. Chem. Res., 3: 117-120 (2010).
64
c) Amini M., Seyyedhamzeh M.M., Bazgir A., Heteropolyacid: An Efficient and Eco-Friendly Catalyst for the Synthesis of 14-aryl-14H-dibenzo[a,j] xanthene, Appl. Catal., A., 323: 242-245
65
d) Su W., Yang D., Jin C., Zhang B., Yb(OTf)3 Catalyzed Condensation Reaction of β-Naphthol and Aldehyde in Ionic Liquids: a Green Synthesis of Aryl-14H-dibenzo[a,j]xanthenes, Tetrahedron Letters, 49: 3391-3394 (2008).
66
e) Kumar A., Sharma S., Awatar Maurya R., Sarkar J., Diversity Oriented Synthesis of Benzoxanthene and Benzochromene Libraries via One-Pot, Three-Component Reactions and Their Anti-proliferative Activity, J. Comb. Chem., 12: 20-24 (2010).
67
[29] a) Kokkirala S., Sabbavarapu N.M., Yadavalli V.D.N., β-Cyclodextrin Mediated Synthesis of 1,8-Dioxooctahydroxanthenes in Water, European Journal of Chemistry, 2(2): 272-275 (2011).
68
b) Khosropour A.R., Khodaei M.M., Moghannian H., A Facile, Simple and Convenient Method for the Synthesis of 14-Alkyl or Aryl-14-H-Dibenzo[a,j]xanthenes Catalyzed by p-TSA in Solution and Solvent-Free Conditions, Synlett, 2005(6): 0955-0958 (2005).
69
c) Jin T.S., Zhang J.S., Wang A.Q., Li T.S., Ultrasound-Assisted Synthesis of 1,8-dioxo-octahydroxanthene Derivatives Catalyzed by p-Dodecylbenzenesulfonic Acid in Aqueous Media, Ultrasonics Sonochemistry, 13(3): 220-224 (2006).
70
d) Boroujeni K.P., Heidari Z., Khalifeh R., Carbon Nanotube-Supported Butyl 1-Sulfonic Acid Groups as a Novel and Environmentally Compatible Catalyst for the Synthesis of 1,8-Dioxo-octahydroxanthenes, Acta Chim. Slov., 63: 602- (2016).
71
ORIGINAL_ARTICLE
Novel One-Pot Synthesis of Pyrazolopyranopyrimidinones Using Newly Produced γ-Alumina Nanoparticles as Powerful Catalyst
g-Alumina nanoparticles (g-Al2O3 NPs) were prepared via a new and simple synthetic route and characterized by field emission scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The catalytic activity of prepared g-Al2O3 NPs was investigated for the new one-pot, four-component synthesis of some fused tri-heterocyclic compounds containing pyrazole, pyran, and pyrimidine. In another investigation, the recyclability of the prepared nanocatalyst was also studied. It was proved that the nanoparticles can act effectively for at least four cycles without appreciable loss in activity. This novel procedure has some advantages such as high efficiency, simplicity, high rate, and environmental safety.
https://ijcce.ac.ir/article_28576_de660f47ce45c3097b058e30b64609e3.pdf
2018-06-01
63
71
10.30492/ijcce.2018.28576
γ-Al2O3 nanoparticles
One-Pot
Pyrazole
Pyran
Pyrimidine
Sajad
Kiani
kiani.sajad@hotmail.com
1
Young Researchers and Elite Club, Robatkarim Branch, Islamic Azad University, Robatkarim, I.R. IRAN
AUTHOR
Saeid
Khodabakhshi
saeidkhm@yahoo.com
2
Young Researchers and Elite Club, Robatkarim Branch, Islamic Azad University, Robatkarim, I.R. IRAN
LEAD_AUTHOR
Alimorad
Rashidi
rashidiam@ripi.ir
3
Nanotechnology Research Center, Research Institute of Petroleum Industry, Tehran, I.R. IRAN
AUTHOR
Ziba
Tavakoli
ziba.tavakoli@yahoo.com
4
Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, I.R. IRAN
AUTHOR
Sadegh
Dastkhoon
sun_boy200@yahoo.com
5
Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, I.R. IRAN
AUTHOR
[1] Wang D., Astruc D., Fast-Growing Field of Magnetically Recyclable Nanocatalysts, Chemical Reviews, 114(14): 6949-6985 (2014).
1
[2] Shahamirian M., Kiani S., Jorsaraei Talar A., Khodabakhshi S., Functionalized Nano Graphene Platelets as Green Catalyst to Synthesize New and Known Benzoyl-1, 4-diazanaphthalene and Study of Their Local Aromaticity, Polycyclic Aromatic Compounds, 37(1): 81-91 (2017).
2
[3] Saadatjou N., Jafari A., Sahebdelfar S., Synthesis and Characterization of Ru/Al2O3 Nanocatalyst for Ammonia Synthesis, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 34(1): 1-9 (2015).
3
[4] Karami B., Nikoseresht S., Khodabakhshi S., Novel Approach to Benzimidazoles Using Fe 3 O 4 Nanoparticles as a Magnetically Recoverable Catalyst, Chinese Journal of Catalysis, 33(2): 298-301 (2012).
4
[5] Khalafi-Nezhad A., Divar M., Panahi F., Magnetic Nanoparticles-Supported Tungstic Acid (MNP-TA): an Efficient Magnetic Recyclable Catalyst for the One-Pot Synthesis of Spirooxindoles in Water, RSC Advances, 5(3): 2223-2230 (2015).
5
[6] Dehno Khalaji A., Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 35(2): 17-20 (2016).
6
[7] Kale S.R., Kahandal S., Burange A., Gawandeb M.B., Jayaram R.V., A Benign Synthesis of 2-amino-4H-Chromene in Aqueous Medium Using Hydrotalcite (HT) as a Heterogeneous Base Catalyst, Catalysis Science & Technology, 3(8): 2050-2056 (2013).
7
[8] Gawande M.B., Pandey R.K., Jayaram R.V., Role of Mixed Metal Oxides in Catalysis Science—Versatile Applications in Organic Synthesis, Catalysis Science & Technology, 2(6): 1113-1125 (2012).
8
[9] Dastkhoon S., Tavakoli Z., Khodabakhshi S., Baghernejad M., Khaleghi Abbasabadi M., Nanocatalytic One-Pot, Four-Component Synthesis of Some New Triheterocyclic Compounds Consisting of Pyrazole, Pyran, and Pyrimidinone Rings, New Journal of Chemistry, 2015.
9
[10] Bhattacharyya P., Pradhan K., Paul S., Das A.R., Nano Crystalline ZnO Catalyzed One Pot Multicomponent Reaction for an Easy Access of Fully Decorated 4H-Pyran Scaffolds and Its Rearrangement to 2-Pyridone Nucleus in Aqueous Media, Tetrahedron Letters, 53 (35): 4687-4691 (2012).
10
[11] Karami B., Hoseini S.J., Eskandari K., Ghasemi A., Nasrabadi H., Synthesis of Xanthene Derivatives by Employing Fe3O4 Nanoparticles as an Effective and Magnetically Recoverable Catalyst in Water, Catalysis Science & Technology, 2(2): 331-338 (2012).
11
[12] Kuo, S.C., Huang L.J., Nakamura H., Studies on Heterocyclic Compounds. 6. Synthesis and Analgesic and Antiinflammatory Activities of 3, 4 Dimethylpyrano [2, 3-c] Pyrazol-6-one Derivatives, Journal of Medicinal Chemistry, 27(4): 539-544 (1984).
12
[13] Dastkhoon S., Tavakoli Z., Khodabakhshi S., Baghernejad M., Khaleghi Abbasabadi M., Nanocatalytic One-Pot, Four-Component Synthesis of Some New Triheterocyclic Compounds Consisting of Pyrazole, Pyran, and Pyrimidinone Rings, New Journal of Chemistry, 39 (9): 7268-7271 (2015).
13
[14] El-Agrody A.M., Fouda A.M., Al-Dies A.-A.M., Studies on the Synthesis, in Vitro Antitumor Activity of 4H-benzo [h] Chromene, 7H-benzo [h] Chromene [2, 3-d] Pyrimidine Derivatives and Structure–Activity Relationships of the 2-, 3-and 2, 3-Positions, Medicinal Chemistry Research, 23(6): 3187-3199 (2014).
14
[15] Karami B., Haghighijou Z., Farahi M., Khodabakhshi S., One-Pot Synthesis of Dihydropyrimidine-Thione Derivatives Using Tungstate Sulfuric Acid (TSA) as a Recyclable Catalyst, Phosphorus, Sulfur, and Silicon and the Related Elements, 187(6): 754-761 (2012).
15
[16] Kiani S., Samimi A., Rashidi A., Novel One-Pot Dry Method for Large-Scale Production of Nano γ-Al2O3, Monatshefte für Chemie-Chemical Monthly, 147(7): 1153-1159 (2016).
16
[17] Rahmani F., Haghighi M., Estifaee P., Synthesis and Characterization of Pt/Al2O3–CeO2 Nanocatalyst Used for Toluene Abatement from Waste Gas Streams at Low Temperature: Conventional vs. Plasma–Ultrasound Hybrid Synthesis Methods, Microporous and Mesoporous Materials, 185: 213-223 (2014).
17
[18] Kiani S., Mansouri Zadeh M., Khodabakhshi S., Rashidi A., Moghadasi J., Newly Prepared Nano Gamma Alumina and Its Application in Enhanced oil Recovery: an Approach to Low-Salinity Waterflooding, Energy & Fuels, 30(5): 3791-3797 (2016).
18
[19] Contreras C., Sugita S., Ramos E., Preparation of Sodium Aluminate from Basic Aluminum Sulfate, Advances in Technology of Materials and Materials Processing Journal, 8(2): 122 (2006).
19
[20] Yu J., Bai H., Wang J., Li Z., Jiao C, Liu Q., Zhanga M., Liu L., Synthesis of Alumina Nanosheets via Supercritical Fluid Technology with High Uranyl Adsorptive Capacity, New Journal of Chemistry, 37(2): 366-372 (2013).
20
[21] Han S., Chen J., Zheng P., Qing P., Characterization of Nanosized Al2O3 Powder Synthesized by Thermal-Assisted MOCVD and Pasma-Assisted MOCVD, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 30(3): 83-88 (2011).
21
[22] Karami B., Eskandari K., Khodabakhshi S., An Efficient Synthesis of New Khellactone-Type Compounds Using Potassium Hydroxide as Catalyst Via One-Pot, Three-Component Reaction, Journal of the Iranian Chemical Society,11(3): 631-637 (2014).
22
[23] Karami B., Tae M., Khodabakhshi S., Jamshidi S., Synthesis of 1, 3-Dithiane and 1, 3-Dithiolane Derivatives by Tungstate Sulfuric Acid: Recyclable and Green Catalyst, Journal of Sulfur Chemistry, 33(1): 65-74 (2012).
23
[24] Khodabakhshi S., Karami B., Eskandari K., Hoseini S.J., Rashidi A., Graphene Oxide Nanosheets Promoted Regioselective and Green Synthesis of New Dicoumarols, RSC Advances, 4(34): 17891-17895 (2014).
24
[25] Li X.-T., Zhao A-D., Moa L-P., Zhang H., Meglumine Catalyzed Expeditious Four-Component Domino Protocol for Synthesis of Pyrazolopyranopyrimidines in Aqueous Medium, RSC Advances, 4(93): 51580-51588 (2014).
25
[26] Chng L.L., Erathodiyil N., Ying J.Y., Nanostructured Catalysts for Organic Transformations, Accounts of Chemical Research, 46(8): 1825-1837 (2013).
26
ORIGINAL_ARTICLE
Investigation of Organic Complexes of Imidazolines Based on Synthetic Oxy- and Petroleum Acids as Corrosion Inhibitors
The mixture of Synthetic Petroleum Acids (SPA) and oxyacids (OSPA) have been synthesized on the basis of naphthenic-paraffinic hydrocarbons separated from 217-349°C fractions of Azerbaijan oils in the presence of the salts of Natural Petroleum Acids (NPA). The acid number of the obtained (SPA+OSPA) was 165 mgKOH/g, the yield was 40%. Imidazoline derivatives have been synthesized based on the mixture of SPA+OSPA and polyethylene polyamine (PEPA) and their complexes were prepared with CH3COOH and HCOOH. The inhibition action of these complexes on steel corrosion in 1% NaCl solution saturated with CO2 has been studied at 50°C. The results showed that all compounds are good inhibitors and the inhibition efficiencies in the presence of imidazoline derivatives based on SPA+OSPA were 93% and 97% at 25 and 50 ppm, respectively. The activation parameter study suggests the chemisorption for all inhibitors. The obtained values for Gibbs free energy show that the compounds are spontaneously adsorbed on the metal surface by chemisorptions. The image of the steel surface proved that the formed protective film on the electrode surface was stable. The adsorption of the studied compounds on steel surface follows the Langmuir adsorption isotherm.
https://ijcce.ac.ir/article_34146_546b75d1d021a8c9e21e848597e388ff.pdf
2018-06-01
73
79
10.30492/ijcce.2018.34146
Diesel fraction
Synthetic petroleum acids
oxy acids
CO2 corrosion
Inhibition
Imidazoline derivatives
Lala
Afandiyeva
efendiyevalm7@gmail.com
1
Institute of Petrochemical Processes, Azerbijan National Academy of Sciences (ANAS), AZERBIJAN
LEAD_AUTHOR
Vagif
Abbasov
azmea_nkpi@box.az
2
Institute of Petrochemical Processes, Azerbijan National Academy of Sciences (ANAS), AZERBIJAN
AUTHOR
Leylufer
Aliyeva
leylufer-ipcp@rambler.ru
3
Institute of Petrochemical Processes, Azerbijan National Academy of Sciences (ANAS), AZERBIJAN
AUTHOR
Saida
Ahmadbayova
saida.ahmadbayova@gmail.com
4
Institute of Petrochemical Processes, Azerbijan National Academy of Sciences (ANAS), AZERBIJAN
AUTHOR
Emin
Azizbeyli
emin.azizbeyli@mail.ru
5
Institute of Petrochemical Processes, Azerbijan National Academy of Sciences (ANAS), AZERBIJAN
AUTHOR
Hany M.
El-Lateef Ahmed
hany_shubra@yahoo.co.uk
6
Chemistry Department, College of Science, King Faisal University, Al Hufuf, 31982 Al Hassa, SAUDI ARABIA
AUTHOR
[1] Hany M Abd El-Lateef, Mohamed Ismael, Ibrahim Mohamed, Novel Schiff Base Amino Acid as Corrosion Inhibitors for Carbon Steel in CO2-Saturated 3.5% NaCl Solution: Experimental and Computational Study, Corrosion Reviews. 33: 77–97 (2015).
1
[2] Abd El-Lateef H. M., Abbasov V.M., Aliyeva L.I., Qasimov E.E., Ismayilov I.T., Inhibition of Carbon Steel Corrosion in CO2-Saturated Brine Using Some Newly Surfactants Based on Palm Oil: Experimental and Theoretical Investigations, Mater. Chem. Phys, 142: 502-512 (2013).
2
[3] Abd El-Lateef H. M., Abbasov V.M., Aliyeva L.I., Khalaf M. M., Novel Naphthenate Surfactants Based on Petroleum Acids and Nitrogenous Bases as Corrosion Inhibitors for C1018-Type Mild Steel in CO2-Saturated Brine, Egyptian Journal of Petroleum, 24: 175–182 (2015).
3
[4] Afandiyeva L.M., The Kinetic Effect of CO2 Corrosion by Imidazoline Derivatives Based on Synthetic Oxy- and Petroleum Acids, J. of Advances in chemistry, 12(1): 3944-3949 (2015)
4
[5] Farelas F., Ramirez A., Carbon Dioxide Corrosion Inhibition of Carbon Steels Through Bis-Imidazoline Compounds Studied by EIS, Int. J. Electrochem. Sci., 5: 797-814 (2010)
5
[6] Shaker N.O., Badr E.E., Kandeel E.M., Adsorption and Inhibitive Properties of Fatty Imidazoline Surfactants on Mild Steel, Pelagia Research Library Der Chemical Sinica, 2(4): 6-35 (2011).
6
[7] Abbasov V.M., Abd El-Lateef H.M., Aliyeva L.I., The CO2 Corrosion Inhibition of Carbon Steel C1018 by Some Novel Complex Surfactants Based on Petroleum Acids and Nitrogen-Containing Ccompounds, J. of Advances in Materials and Corrosion, 2: 26-32 (2013)
7
[8] Abbasov V.M., Mamedova T.A., Ismailov E.G., Askerova E.N., Teyubov Kh.Sh., Gasankhanova N.V., Alieva S.K., Catalytic Production of Olefins Using Natural Halloysite Nanotubes, Catalysis in Industry, 6 (3): 170-175 (2014)
8
[9]Aliyeva L.I., Afandiyeva L.M., Valiyeva F.M., Determination of Optimal Parameters for Obtaining Synthetic Oil Acids and Oxyacids Mixture from the Catalytic Oxidation of Naphthene-Paraffinic Hydrocarbons of Diesel Distillation, International Journal of Scientific Engineering and Applied Science (IJSEAS), 2(3): 232-239 (2016)
9
[10] Abbasov V.M., Afandiyeva L.M., Agamaliyeva D.B., et all., Investigation Imidazoline Derivatives Obtained from Synthetic Petroleum Acids as Corrosion Inhibitor, J. Advances in Chemistry, 11(1): 3372-3381 (2015)
10
[11] Song F.M., Kirk D.W., Graydon J.W., Cormack D.E., Predicting Carbon Dioxide Corrosion of bare Steel under an Aqueous Boundary Layer, J. Corrosion, 60 (8): 736-748 (2004).
11
[12] Taleb H.I. Zour M.A.: Corrosion Inhibition of Mild Steel Using Fig Leaves Extract in Hydrochloric Acid Solution, Int. J. Electrochem. Sci., 6: 6442-6455 (2011)
12
[13] Abdel-Gaber A.M, Abd-El-Nabey B.A, Khamis E., Abd-El-Khalek D.E., A natural Extract as Scale and Corrosion Inhibitor for Steel Surface in Brine Solution, J. Desalination, 278 (1): 337-342 (2011).
13
[14] Flis J., Zakroczymski T., Impedance Study of Reinforcing Steel in Simulated Pore Solution with Tannin, J. Electrochem.Soc., 143: 2458-2464 (1996)
14
[15] Szklarska-Smialowska Z., Mankowski J., Crevice Corrosion of Stainless Steels in Sodium Chloride Solution, J. Corr. Sci., 18 (11): 953-960 (1978)
15
[16] Balaji J., Sethuraman M. G., Corrosion Protection of Copper with Hybrid Sol-Gel Containing 1H-1, 2, 4-triazole-3-thiol, Iran. J. Chem. Chem. Eng. (IJCCE), 35(4): 61-71 (2016)
16
[17] Hany M. Abd El-Lateef, Kamal A. Soliman, Ahmed H. Tantawy., Novel synthesized Schiff Base-based Cationic Gemini Surfactants: Electrochemical Investigation, Theoretical Modeling and Applicability as Biodegradable Inhibitors for Mild Steel Against Acidic Corrosion, Journal of Molecular Liquids, 232: 478–498 (2017)
17
[18] Hany M Abd El-Lateef, Ahmed H. Tantawy, Synthesis and Evaluation of Novel Series of Schiff Base Cationic Surfactants as Corrosion Inhibitors for Carbon Steel in Acidic/Chloride Media: Experimental and Theoretical Investigations, RSC Adv., 6: 8681-8700 (2016)
18
[19] Hany M. Abd El-Lateef, Experimental and Computational Investigation on the Corrosion Inhibition Characteristics of Mild Steel by Some Novel Synthesized Imines in Hydrochloric Acid Solutions, Corrosion Science, 92: 104–117 (2015).
19
ORIGINAL_ARTICLE
Catalytic Oxidation of 4-Methylpyridine on Modified Vanadium Oxide Catalysts
The reaction of gas-phase oxidation of 4-methylpyridine on individual V2O5, binary and ternary vanadium-oxide catalysts was studied. These catalysts were modified by additives of SnO2 and TiO2. It was found that modifying V2O5 leads to increase the activity of binary contacts. Upon transition from binary V2O5-SnO2 and V2O5-TiO2 catalysts to the ternary system of V2O5-TiO2-SnO2, a higher increase in activity is observed. This extension of activity leads to increase conversion of initial substance and shifting the maximum yield of intermediate pyridine-4-carbaldehyde and isonicotinic acid to the low-temperature area. To research the mechanism of promotion, we used the quantum chemical method of Density Functional Theory. It was found that the promoting effect of SnO2 and TiO2 was caused by increasing a proton affinity of vanadyl oxygen (PAV=O). Upon transition from binary clusters to the ternary system of V2O5-TiO2-SnO2 the synergism effect is observed. It is shown that by transfer of a proton to vanadyl oxygen and formation of a new O−H bond the energy is emitted. This energy compensates a heterolytic C−H bond cleavage. It was found that the promoting effect of SnO2 and TiO2 causes the decrease of deprotonation enthalpy of the methyl substituent of the chemisorbed substrate. The results of the calculations agree with the experimental data on the influence of oxide modifiers on activity and selectivity of the studied catalysts in 4-methylpyridine oxidation.
https://ijcce.ac.ir/article_30920_98e72260e141889a5136e49f371f2d91.pdf
2018-06-01
81
89
10.30492/ijcce.2018.30920
4-Methylpyridine
Oxidation
Vanadium oxide catalyst
Mechanism
density functional theory
Pavel
Vorobyev
pavel.vr@mail.ru
1
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
AUTHOR
Tatyana
Mikhailovskaya
tanya2855@mail.ru
2
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
AUTHOR
Olga
Yugay
yu.ok@mail.ru
3
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
LEAD_AUTHOR
Anna
Serebryanskaya
srbr-anna@mail.ru
4
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
AUTHOR
Nikolay
Chukhno
chukhno1947@mail.ru
5
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
AUTHOR
Aldan
Imangazy
kazpetrochem@gmail.com
6
A.B. Bekturov Institute of Chemical Sciences, Almaty, Republic of KAZAKHSTAN
AUTHOR
[1] Rubtsov M., Mikhlina E., Furshtatova B.J., Obtaining of Isonicotinic Acid, Appl. Chem., 29: 946–948 (1956). (in Russian)
1
[2] Yugay O., Mikhailovskaya T., Sembaev D., Vorobyev Р., Oxidation of 3- and 4-methylpyridines on Vanadia-Anatase and Vanadia-Rutile Catalysts, Eur. Chem. Tech. J., 4: 337–342 (2012).
2
[3] Shishido T, Preparation of Crystalline CrVO4 Catalyst by Soft Chemistry Technique and Application for Vapor-Phase Oxidation of Picolines, J. Jap. Petrol. Inst., 54(4): 225–236 (2011).
3
[4] Suvorov B., Kagarlitskiy A., Afanasyeva T., Okislenie Organicheskih Soedinenij. Soobshhenie XCIII. Parofaznoe Okislenie Nekotoryh 4-alkilpiridinov na Plavlenom Vanadievo-Titanovom Katalizatore, Izvestiya AN KazSSR, Ser Chem (Chemical Bulletin of the Kazakh SSR Academy of Sciences), 1: 51–55 (1974). [in Russian]
4
[5] Shimanskaya M., Leitis L., Skolmeistere P., Yovel I., Golender L., “Vanadium Catalysts of Heterocyclic Compounds Oxidation”, Zinantne, Riga (1990). [in Russian]
5
[6] Bhattacharyya S.K., Kar A.K. Vapour Phase Oxidation of 4-Picoline to Isonicotinic Acid in Fluidized Bed, Indian J. Appl. Chem., 30: 42−47 (1967).
6
[7] Bhattacharyya S.K., Shankar V., Kar A.K., Catalytic Vapor Phase Oxidation of monomethylpyridines to pyridinecarboxylic Acids, Ind. Eng. Chem. Prod. Res. Dev., 5(1): 65−72 (1966).
7
[8] Martin A., Lücke B., Niclas H.-J., Förster A. Vapor-Phase Oxidation of 4-picoline to Pyridine-4-Carboxaldehyde on Vanadium Phosphate Catalyst, React. Kinet. Catal. Lett., 43(2): 583-588 (1991).
8
[9] Kulkarni S.J., Ramachandra R.R., Subrahmayam M., Farsinavis S., Kanta R.P., Rama R.A.V., Oxidation and Ammoxidation of 4-picoline over Vanadium-Silico-Aluminophosphate Catalysts, Ind. J. Chem. Sect. A, 35: 740−745 (1996).
9
[10] Yang Gao-Jun, Huang Hai-Feng, Lu Han-Feng, Liu Hua-Yan, Chen Yin-Fei, Oxidation of 4-picoline to Isonicotinic Acid on V-Ti-O Catalysts, J. Chem. Eng. Chinese U., 3:448–453 (2007).
10
[11] Hoеlderich W., Verfahren Zur Herstellung von Isonikotinsaeure, DE Patent 10146088 (2003).
11
[12] Koсh W., Holthausen M.C., “Chemist’s Guide to Density Functional Theory”, 2nd Ed., Wiley-VCH, Weinheim (2001).
12
[13] Becke A.D., Density-Functional Thermochemistry. III. The Role of Exact Exchange, J. Chem. Phys., 98: 5648 (1993).
13
[14] Lee C., Yang W., Parr R.G., Development of the Colle–Salvetti Correlation-Energy Formula Into a Functional of the Electron Density, Phys. Rev. B, 37: 785 (1988).
14
[15] Ganduglia-Pirovano M.V., Hofmann A., Sauer J., Oxygen Vacancies in Transition Metal and Rare Earth Oxides: Current State of Understanding and Remaining Challenge, Surface Science Reports, 62: 219–270 (2007).
15
[16] Sachtler W.M.H., Dorgelo G.J.H., Fahrenfort J., Voorhoeve R.J., Correlations between Catalytic and Thermodynamic Parameters of Transition Metal Oxides, Rec. Trav. Chim, 89: 460−480 (1970).
16
[17] Yoshida S., Murakami T., Tarama K. 51:195 Structural Study on Promoting Actions of Titanium Dioxide and Stannic Oxide on Vanadium Pentoxide Catalysts, Bull. Inst. Chem. Res., Kyoto Univ , 51(4): 195-205 (1973).
17
[18] Sembaev D.Kh., Suvorov B.V., Saurambaeva L.I., Suleimanov Kh.T., O Svjazi Mezhdu Fazovym Sostavom i Kataliticheskim Dejstviem Okisnyh Vanadievo-Titanovyh Kontaktov v Reakcii Parofaznogo Okislenija o-Ksilola, Kinetika i Kataliz (Russian Journal Kinetics and Catalysis), 20: 750-755 (1979). [in Russian]
18
[19] Sagitullin R S., Shkil’ G P., Nosonova I.I., Ferber A.A., Synthesis of Pyridine Bases by the Chichibabin Method (Review), Chem. Heterocycl. Compd., 32(2):127–140 (1996)
19
[20] Cram D.J., “Fundamentals of Carbanion Chemistry”, Academic Press, New York–London (1965).
20
[21] Witko M., Tokarz R., Haber J., Quantum Chemical Calculations of Molecular Properties of V2O5 Clusters, J. Mol. Catal., 66(2): 205−214 (1991).
21
[22] Witko M., Tokarz R., Haber J., The Role of Atom Which Terminate Clusters: Quantum Chemical Study, J. Mol. Catal., 66(3): 357−366 (1991).
22
ORIGINAL_ARTICLE
Preparation of Fe Substituted ZnO Nanoparticles and Investigation of Their Magnetic Behaviors
Nano-powders of diluted magnetic semiconductor Zn1-xFexO (0.0≤ x ≤0.1) were prepared via the sol-gel auto-combustion method. Crystal structure and phase identification carried out by X-Ray Diffraction (XRD) analysis. Mean crystallite size of the powders was estimated by Scherrer's formula. As M-H loops of the Fe substituted ZnO showed ferromagnetic behavior. The results of X-Ray Photoelectron Spectroscopy (XPS) showed that there is a mixture of Fe3+ and Fe2+ ions in all Fe substituted samples. Antiferromagnetic interaction between neighboring Fe3+-Fe2+ ions suppressed the ferromagnetic behavior of the samples at higher doping concentrations of Fe.
https://ijcce.ac.ir/article_30590_d0c37d3a0ac46939272afe9bfbe5f805.pdf
2018-06-01
91
95
10.30492/ijcce.2018.30590
Diluted magnetic semiconductor
Zinc oxide
Sol-gel auto-combustion method
Ahmad
Hasanpour
hasanpour88@gmail.com
1
Physics Department, Ahvaz Branch, Faculty of Science Islamic Azad University, Ahvaz, I.R. IRAN
LEAD_AUTHOR
[1] Ohno H., Toward Functional Spintronics, Science, 291[5505]: 840-841 (2001).
1
[2] Yang S.Y., Pakhomov A.B., Hund S.T., Wong C.Y., Origin of Room-Temperature Ferromagnetism in Cobalt-Doped ZnO,IEEE. Trans. Mag, 38: 2877-2879 (2002).
2
[3] Pan F., Song C., Liu X.J., Yang Y.C., Zeng F., Ferromagnetism and Possible Application in Spintronics of Transition-Metal-Doped ZnO Films, Materials Science and Engineering: R: Reports, 62(1), 1-35 (2008).
3
[4] Özgur Ü., Alivov Y.I., Liu C., Teke A., Reshchikov V., Avrutin, JChoH. Morkoc S., A Comprehensive Review of ZnO Materials and Devices, J. Appl.Phys., 98(4): 11- (2005).
4
[5] Pearton S.J., Abernathy C.R., Overberg M.E., Thaler G.T., Norton D.P., Theodoropoulou, N., Hebard A.F., Park Y.D., Ren F.,. Kim J., Boatner L. A.,, Wide Bandgap Ferromagnetic Semiconductors and Oxides, J. Appl. Phys., 93(1): 1-13 (2003).
5
[6] Ashok Kumar S., Chen S.M., A Comprehensive Review of ZnO Materials and Devices, Anal.Lett., 41: 141-158 (2008).
6
[7] Hung M.H., Mao S., Feick H., Yan H., Wu Y., Kind H., Weber E., Russo R., Yang P., Effects of Local Gas-Flow Field on Synthesis of Oxide Nanowires During, Science, 292: 1897-1899 (2001).
7
[8] Tirosh E., Markovich G., Control of Defects and Magnetic Properties in colloidal HfO2 Nanorods, Advanced Materials, 19(18): 2608-2612 (2007).
8
[9] Wang Q., Sun Q., Chen G., Kawazoe Y., Jena P., Vacancy-Induced Magnetism in ZnO, Phys. Rev. B, 77(20): 205411- (2008).
9
[10] Zuo X., Yng S., Yang A., Duan W., Vittoria C., Harris V.G., Ferromagnetism in Pure Wurtzite Zinc Oxide, J.Appl.Phys., 105(7): 07C508- (2009).
10
[11] Zhang S., Ogale S.B., Yu W., Gao X., Liu T., Ghosh S., Das G.P., Wee A.T.S., Greene R.L., Vankatesan T., Comparison of Nb- and Ta-Doping of Anatase TiO2 for Transparent, Adv.Mater., 21: 2282-2287 (2009).
11
[12] Qingyu X., Shengqiang Z., Heidemari S., Magnetic Properties of ZnO Nanopowders, J. Alloy. Comp., 487: 665-667 (2009).
12
[13] Kuo C.L., Kou T.J., Huang M.H., Hydrothermal Synthesis of ZnO Microspheres and Hexagonal Microrods with Sheetlike and Platelike Nanostructures,J. Phys. Chem. B, 109: 20115-20121 (2005).
13
[14] Karthinkeyan B., Pandiyarajan T., Simple room Temperature Synthesis and Optical Studies on Mg Doped ZnO Nanostructures, J. Lumin., 130: 2317-2321 (2010)
14
[15] Yadav R.S., Pandey A.C., Sanjay S.S., Optical Properties of Europium Doped Bunches of Zno Nanowires Synthesized by Co-Precipitation Method, Chalcogenide Let., 6: 233-239 (2009).
15
[16] Liu C., Meng D., Pang H., Wu X., Xie J., Yu X., Chen L., Liu X., Influence of Fe-Doping on the Structural, Optical and Magnetic Properties of ZnO Nanoparticles, J. Mag. Mag. Mate., 324: 3356–3360 (2012).
16
[17] Muneer M.Ba-AbbadAbdul Amir H. Kadhum Abu BakarMohamad Mohd S.Takriff Kamaruzzaman Sopia, Visible Light Photocatalytic Activity of Fe3+-Doped ZnO Nanoparticle Prepared Via Sol–Gel TechniqueChemosphere, 91(11): 1604-161 (2013).
17
[18] Pandiyarajan T., Udayabhaskar R., Karthikeyan B., Role of Fe Doping on Structural and Vibrational Properties of ZnO Nanostructures, Appl.Phys. A, 107: 411-419 (2012).
18
[19] Kumar S., Gautam S., Kim Y.J., Koo B.H., Chae H., Lee C.G., Ferromagnetism in Fe Doped ZnO Synthesized by Co, J. Ceram. Soci. Japan, 1175: 616-618 (2009).
19
[20] Kas R., Sevinc E., Topal U., Acar H.Y., A Universal Method for the Preparation of Magnetic and Luminescent Hybrid Nanoparticles, The Journal of Physical Chemistry C, 114(17), 7758-7766 (2010).
20
[21] Hong Y.Y., Zhang S.Z., Di G.Q., Li H.Z., Zheng Y., Ding J., Wei D.G., Preparation, Characterization and Application of Fe3O4/ZnO Core/Shell Magnetic Nanoparticles, Materials Research Bulletin, 43: 2457-2468 (2008).
21
[22] Bonanni A., Dietl T., A Story of High-Temperature Ferromagnetism in ... - RSC Publishing, Chem. Soc. Rev., 39: 528-539 (2010).
22
[23] Yosida K., “Theory of Magnetism”, Springer, Berlin, (1996).
23
[24] Zheng N, Introduction to Dilute Magnetic Semiconductors, Department of Physics and Astronomy, The University of Tennessee, Knoxville (2008).
24
ORIGINAL_ARTICLE
The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids
The oxidation of Mandelic Acids (MA) to the corresponding oxoacids with tripropylammonium fluorochromate (TriPAFC) in aqueous acetic acid has been studied. The reaction is first order with respect to [TriPAFC], [MA] and [H+]. The oxidation of α-deuteriomandelic acid shows the presence of a primary kinetic isotope effect (kH/kD = 5.54 at 303 K). The reaction has been found to be catalyzed by H+ ions. The various thermodynamic parameters for the oxidation have been reported and discussed along with the validity of the isokinetic relationship. The Exner plot showed that all the selected mandelic acids are oxidized by the same mechanism.
https://ijcce.ac.ir/article_34157_24b4cab187ac79a6376e982c316be8bc.pdf
2018-06-01
97
105
10.30492/ijcce.2018.34157
Mandelic acid
Tripropylammonium fluorochromate
Hammett plot
Iso-kinetic temperature
Shanmugam
Shanthi
shanthinithi2007@gmail.com
1
Research and Development Centre, Bharathiar University, Coimbatore – 641 046, Tamil Nadu, INDIA
AUTHOR
Basim Hussain
Asghar
basim15@yahoo.com
2
Department of Chemistry, Faculty of Applied Sciences, Umm Al-Qura University, P.O. Box: 9569, Makkah, SAUDI ARABIA
AUTHOR
Syed Sheik
Mansoor
smansoors2000@yahoo.co.in
3
Department of Chemistry, C. Abdul Hakeem College (Autonomous), Melvisharam - 632 509, Tamil Nadu, INDIA
LEAD_AUTHOR
[1] Bhuvaneshwari D.S., Elango K.P., Correlation Analysis of Reactivity in the Oxidation of Anilines by Nicotinium Dichromate in Nonaqueous Media, Int. J. Chem. Kinet., 38: 657–665 (2006).
1
[2] Bhuvaneshwari D.S., Elango K.P., Effect of Preferential Solvation on the Kinetics and Thermodynamics of Oxidation of Anilines by Nicotinium Dichromate, Z. Naturforsch., 60b: 1105– 1111 (2005).
2
[3] Garg D., Kothari S., Kinetics and Mechanism of the Oxidation of Some α-hydroxy Acids by Hexamethylene Tetramine-Bromine, J. Chem. Sci., 26: 333-338 (2004).
3
[4] Anjana, Sharma P.K., Banerji K.K., Kinetics and Mechanism of the Oxidation of α-hydroxy Acids by Benzyltrimethylammonium Chlorobromate, J. Chem. Sci., 111: 741-746 (1999).
4
[5] Tewari K.C., Singh H.N., Singh V.S., Kinetics of Oxidation of α-Hydroxy Acids by Ceric Sulfate, Bull. Chem. Soc. Japan., 49: 2852-2854 (1976).
5
[6] Dave I., Sharma V., Banerji K.K., Kinetics and Mechanism of Oxidation of Some α-hydoxy Acids byQuinolinium Fluorochromate, Indian J. Chem., 39A: 728-733 (2000).
6
[7] Kumbhat V., Sharma P.K., Banerji K.K., Kinetics and Mechanism of the Oxidation of Some α-hydroxy Acids by 2,2′-Bipyridinium Chlorochromate, Int. J. Chem. Kinet., 34: 248-254 (2000).
7
[8] Baghmar M., Sharma P.K., Kinetics and Mechanism of Oxidation of Some α-hydoxy Acids byTetrabutylammonium Tribromide, Indian J. Chem., 40A: 311-315 (2001).
8
[9] Kothari A., Kothari S., Banerji K.K., Kinetics and Mechanism of Oxidation of some α-hydoxy Acids by Butyltriphenylphosphonium Dichromate, Indian J. Chem., 39A: 734-739 (2000).
9
[10] Pohani P., Anjana, Sharma P.K., Kinetics and Mechanism of Oxidation of Some α-hydoxy Acids by Benzyltriethylammonium Chlorochromate, Indian J. Chem., 45A: 2218-2223 (2006).
10
[11] Banerji J., Sharma P.K., Banerji K.K., Kinetics and Mechanism of the Oxidation of Some α-hydroxy Carboxylic Acids by (bis(trifluoroacetoxy)iodo) benzene, Indian J. Chem., 46A: 445-448 (2007).
11
[12] Swami P., Yajurvedi D., Mishra P., Sharma P.K., Oxidation of Some α-hydroxy Acids by Tetraethylammonium Chlorochromate: a Kinetic and Mechanistic Study, Int. J. Chem. Kinet., 42: 50–55 (2010).
12
[13] Vyas N., Daiya A., Choudhary A., Sharma M., Sharma V., Kinetics and Mechanism of Oxidation of Some α-hydoxy Acids byQuinolinium Chlorochromate, Eur. Chem. Bull., 2: 859-865 (2013).
13
[14] Mahjob A.R., Ghammami S., Kassaee M.K., Tetramethylammonium Fluorochromate (VI): a New and Efficient Oxidant for Organic Substrates, Tetrahedron Lett., 44: 4555-45557 (2003).
14
[15] Ghammamy S., Mazareey M., Tributylammonium Chlorochromate, (C4H9)3NH[CrO3Cl] (TriBACC): A New, Mild and Stable Oxidant for Organic Substrates, J. Serb. Chem. Soc., 70: 687-693 (2005).
15
[16] Acharya S.P., Rane R.A., Trimethylammonium Chlorochromate (TMACC). a New, Mild, Stable, Efficient and Inexpensive Chromium(VI) Oxidation Reagent, Synthesis., 127-128 (1990).
16
[17] Patwari S.B., Khansole S.V., Vibhute Y.B., Kinetics and Mechanism of Oxidation of Aniline and Substituted Anilines by Isoquinolinium Bromochromate in Aqueous Acetic Acid, J. Iran. Chem. Soc., 6: 399-404 (2009).
17
[18] Oezguen B., Yaylaoglu A., Sendil K., 4-Benzylpyridinium Fluorochromate: An Efficient and Selective Oxidant for Organic Substrates, Monatshefte für Chemie, 138: 161-163 (2007).
18
[19] Kassaee M.Z., Sayyed-Alangi S.Z., Sajjadi-Ghotbabadi H., Synthesis and Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Oxidant, Molecules., 9: 825-829 (2004).
19
[20] Koohestani B., Javanshir Z., Ghammamy S., Mehrani K., Afrand H., Saghatforoush L., Synthesis and Characterization of a New Oxidation Reagent: Tetrahexylammonium Chlorochromate, (C6H13)4N[CrO3Cl], J. Mex. Chem. Soc., 52: 116-119 (2008).
20
[21] Malani N., Baghmar M., Sharma P.K., Kinetics and Mechanism of the Oxidation of Some Organic Sulfides by Morpholinium Chlorochromate, Int. J. Chem. Kinet., 41: 65–72 (2009).
21
[22] Ghammamy S., Hashemzadeh A., Tripropylammonium Fluorochromate (TriPAFC): A Convenient New Reagent for Oxidation of Organic Substrates, Bull. Korean Chem. Soc., 25: 1277-1279 (2004).
22
[23] Mansoor S.S., Shafi S.S., Oxidation of Aniline and Some para-substituted Anilines by Benzimidazolium Fluorochromate in Aqueous Acetic Acid Medium - A Kinetic and Mechanistic study, Arab. J. Chem., 7: 171–176 (2014).
23
[24] Mansoor S.S., Shafi S.S., Oxidation of Aliphatic Alcohols by Triethylammonium Chlorochromate in Non-Aqueous Medium - A Kinetic and Mechanistic Study, Arab. J. Chem., 7: 312–318 (2014).
24
[25] Asghar B.H., Mansoor S.S., Hussain A.M., Malik V.S., Aswin, K., Sudhan, S.P.N., Oxidation of Aliphatic Aldehydes by Benzimidazolium Fluorochromate in Non-Aqueous medium – A Kinetic and Mechanistic Study, Arab. J. Chem., 10: S2115–S2123 (2017).
25
[26] Mansoor S.S., Malik V.S., Aswin K., Logaiya L., Hussain A.M., Kinetics and Thermodynamics of Oxidation of Some Thio Acids by Tripropylammonium Fluorochromate in N, N-Dimethyl Formamide and Acetic Acid Mixture, J. Saudi Chem. Soc., 20: S77-S84 (2016).
26
[27] Malik V.S., Asghar B.H., Mansoor S.S., Kinetics and the Mechanism of Oxidation of Methoxy Benzaldehydesby Benzimidazolium Fluorochromate in an Aqueous Acetic Acid Medium, J. Taibah Univ. Sci., 10: 131–138 (2016).
27
[28] Mansoor S.S., Shafi S.S., Studies on the Kinetics of Tripropylammonium Fluorochromate Oxidation of Some Aromatic Alcohols in Non-Aqueous Media, J. Mol. Liq., 155: 85-90 (2010).
28
[29] Mansoor S.S., Shafi S.S., Oxidation of Benzhydrol by Tributylammonium Chlorochromate: a Kinetic and Mechanistic Study, Reac. Kinet. Mech. Cat., 100: 21–31(2010).
29
[30] Amis E.S., “Solvent Effects on Reaction Rates and Mechanisms”, Academic Press, New York 42 (1967).
30
[31] Lente G., Fabian I., Poe A.J., A Common Misconception About the Eyring Equation, New J. Chem., 29: 759 – 760 (2005).
31
[32] Exner O., Streitwiser J.R., Talt R.W., “Progress in Physical Organic Chemistry”, John Wiley, New York 41 (1973).
32
[33] Leffler J.F., Grunwald E., “Rates and Equilibrium of Organic Reactions”, Wiley, New York (1963).
33
[34] Hammett L.P., “Physical Organic Chemistry”, 1st ed., McGraw-Hill, New York (1940).
34
[35] Mehnert R., Brede O., Janovsky I., Pulse Radiolysis of Aqueous Solutions of Thiosulphate, Radiat. Phys. Chem., 23: 463-468 (1984).
35
[36] Wiberg K.B., “Physical Organic Chemistry”, John Wiley, New York (1963).
36
[37] Littler J.S., Oxidations of Olefins, Alcohols, Glycols and other Organic Compounds, by Inorganic Oxidants Such as Chromium(VI), Manganese(VII), Iodine(VII), Lead(IV), Vanadium(V) and Halogens, Considered in the Light of the Selection Rules for Electrocyclic Reactions, Tetrahedron., 27: 81 – 91 (1971).
37
[38] Brown H.C., Okamoto Y., Electrophilic Substituent Constants, J. Am. Chem. Soc., 80: 4979-4987 (1958).
38
ORIGINAL_ARTICLE
Conceptual Design of n-Butyl Acetate Synthesis Process by Reactive Distillation Using Residue Curve Maps
Residue curve maps are a powerful tool for the preliminary design of Reactive Distillation (RD). In this study, residue curve maps of the n-butyl acetate synthesis reaction were calculated based on the Langmuir–Hinshelwood–Hougen–Watson kinetic and UNIQUAC models to calculate the physical properties of the system. The results showed that the unstable node branch emerged from the n-butyl acetate/water edge, moved toward the chemical equilibrium surface with increasing Damköhler number, and no ternary reactive azeotropic point appeared when the reaction was added. Conceptual design of n-butyl acetate synthesis by reactive distillation based on residue curve maps is presented. Based on the simulation results, both the energy consumption and the total annual cost were lower than previously reported values.
https://ijcce.ac.ir/article_34158_75d5f9aefdd1695c59375aefe2b4770c.pdf
2018-06-01
107
115
10.30492/ijcce.2018.34158
Residue curve map
N-butyl acetate
Conceptual design
Reactive distillation
Huidong
Zheng
1
School of Chemical Engineering, Fuzhou University, Fuzhou, 350108, Fujian, P.R. CHINA
AUTHOR
Hui
Tian
tianhuiyt@163.com
2
College of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005, Shandong, P.R. CHINA
LEAD_AUTHOR
Yanyi
Shen
3
School of Chemical Engineering, Fuzhou University, Fuzhou, 350108, Fujian, P.R. CHINA
AUTHOR
Jie
Wang
4
School of Chemical Engineering, Fuzhou University, Fuzhou, 350108, Fujian, P.R. CHINA
AUTHOR
Suying
Zhao
394318806@qq.com
5
School of Chemical Engineering, Fuzhou University, Fuzhou, 350108, Fujian, P.R. CHINA
LEAD_AUTHOR
[1] Li C.S., Daisuke H., Suzuki K., N-butyl Acetate Synthesis Via Reactive Distillation: Thermodynamic, Process Design, Computers & Applied Chemistry, 1124: 1585-1589 (2009).
1
[2] Liao A.P., Tong Z.F., Synthesis of Butyl Acetate Catalyzed by Amberlyst, Chemical Reaction Engineering & Technology, 11: 406-408 (1995).
2
[3] Arpornwichanop A., Koomsup K., Assabumrungrat S., Hybrid Reactive Distillation Systems for n-butyl Acetate Production from Dilute Acetic Acid, Journal of Industrial & Engineering Chemistry, 14: 796-803 (2008).
3
[4] Hanika J., Kolena J., Smejkal Q., Butyl Acetate via Reactive Distillation: Modelling and Experiment, Chemical Engineering Science, 54: 5483-5490 (1999).
4
[5] Steinigeweg S., Gmehling J., n-Butyl Acetate Synthesis Via Reactive Distillation: Thermodynamic Aspects, Reaction Kinetics, Pilot-Plant Experiments, and Simulation Studies, Industrial & Engineering Chemistry Research, 41: 5483-5490 (2002).
5
[6] Gangadwala J., Radulescu G., Kienle A., Sundmacher K., Computer Aided Design of Reactive Distillation Processes for the Treatment of Waste Waters Polluted with Acetic Acid, Computers & Chemical Engineering, 31: 1535-1547 (2007).
6
[7] Jimenex L., Costa-Lopez J., The Production of Butyl Acetate and Methanol Via Reactive and Extractive Distillation. II Process Modeling, Dynamic Simulation, and Control Strategy, Industrial & Engineering Chemistry Research, 41: 6735-6744 (2002).
7
[8] Jimenez L., Wanhschafft Q.M., Julka V., Analysis of Residue Curve Maps of Reactive and Extractive Distillation Units, Computers & Chemical Engineering, 25: 635-642 (2001).
8
[9] Marcelino C.R., Juan G.S.H., Adrian B.P., A Short Method to Calculate Residue Curve Maps in Multireactive and Multicomponent Systems, Industrial & Engineering Chemistry Research, 50: 2157-2166 (2011).
9
[10] Peters M., Kauchali S., Hildebrandt D., Glasser D., Application of Membrane Residue Curve Maps to Batch and Continuous Processes, Industrial & Engineering Chemistry Research, 47: 2361-2376 (2008).
10
[11] Huang Y.S., Kai S., Schlünder E.U., Theoretical and Experimental Study on Residue Curve Maps of Propyl Acetate Synthesis Reaction, Chemical Engineering Science, 60: 3363-3371 (2005).
11
[12] Sánchez-Daza O., Escobar G.V., Zárate E.M., Muñoz E.O., Reactive Residue Curve Maps a New Study Case, Chemical Engineering Journal, 117: 123-129 (2006).
12
[13] Almeida-Rivera C.P., Swinkels P.L.J., Grievink J., Designing Reactive Distillation Processes: Present and Future, Computers & Chemical Engineering, 28: 1997-2020 (2004).
13
[14] Duarteet C., Loureiro J.M., Effect of Adsorption on Residue Curve Maps for Heterogeneous Catalytic Distillation Systems, Industrial & Engineering Chemistry Research, 43: 3242-3250 (2004).
14
[15] Zheng H.D., Tian H., Zou W.H., Huang Z.X., Residue Curve Maps of n-butyl Acetate Synthesis Reaction, Journal of Central South University of Technology, 20: 50-56 (2013).
15
[16] Wang X.D., Wang Q.L., Ye C.S., Dong X.L., Qiu T., Feasibility Study of Reactive Distillation for the Production of Propylene Glycol Monomethyl Ether Acetate Through Transesterification, Industrial & Engineering Chemistry Research, 56: 7149-7159 (2017).
16
[17] José S.L.V., Izabela D.G., Miguel Á.G.G., Vapour-Liquid Equilibrium and Distillation Scheme for the Hydrochloric Acid-Ethanol-Water Ternary Mixture, Canadian Journal of Chemical Engineering, 94: 2380-2385 (2016).
17
[18] You X.Q., Gu J.L., Peng C.J., Shen W.F., Liu H.L., Improved Design and Optimization for Separating Azeotropes with Heavy Component as Distillate through Energy-Saving Extractive Distillation by Varying Pressure, Industrial & Engineering Chemistry Research, 56: 9156-9166 (2017).
18
[19] Thakur S.S., Ojasvi Kumar V., Kaistha N., Continuous Diisobutylene Manufacturing: Conceptual Process Design and Plantwide Control, Computers & Chemical Engineering, 97: 59-75 (2017).
19
[20] Dacruz F.E., Manousiouthakis V.I., Process Intensification of Reactive Separator Networks Through the IDEAS Conceptual Framework, Computers & Chemical Engineering, 105: 39-55 (2017).
20
[21] Sorbier L., Bazer-Bachi F., Moreaud M., Moizan-Basle V., Mean Penetration Depth of Metals in Hydrodemetallation Catalysts, Chemical Engineering Science, 155: 186-193 (2016).
21
[22] Mizzi B., Meyer M., Prat L., Augier F., Leinekugel-Le-Cocq D., General Design Methodology for Reactive Liquid-Liquid Extraction: Application to Dicarboxylic Acid Recovery in Fermentation Broth, Chemical Engineering and Processing, 113: 20-34 (2017).
22
[23] Qiu T., Huang Z.X., Cheng C.B., Wu Y.X., Kinetics of Synthesis n-butyl Acetate over Cation-Exchange Resin Catalyst, Chemical Reaction Engineering & Technology, 25: 355-359 (2009).
23
[24] Elan G., “Aspen Plus User Guide, Version 10.2.California, Aspen Technology (1998).
24
[25] Cheng N.L., “Handbook of Solvents”, Chemical Industry, Beijing (2007).
25
[26] Lee H.Y., Huang H.P., Chien I.L., Control of Reactive Distillation Process for Production of Ethyl Acetate, Journal of Process Control, 17: 363-377 (2007).
26
[27] Zheng H.D., Lin M.M., Qiu T., Shen Y.Y., Tian H.; Zhao S.Y., Simulation Study of Direct Hydration of Cyclohexene to Cyclohexanol Using Isophorone as Cosolvent, Chemical Engineering Research & Design, 117: 346-354 (2017).
27
[28] Xu Y., Ng F.T.T., Rempel G.L., Comparison of a Pseudo-homogeneous Nonequilibrium Dynamic Model and a Three-phase Nonequilibrium Dynamic Model for Catalytic Distillation, Industrial & Engineering Chemistry Research, 44: 6171-6180 (2005).
28
[29] Tian H., Zheng H.D., Huang ZH.X., Qiu T., Wu Y.X., Novel Procedure for co-Production of Ethyl Acetate and n-Butyl Acetate by Reactive Distillation, Industrial & Engineering Chemistry Research, 51: 5535-5541 (2012).
29
ORIGINAL_ARTICLE
Electrochemical Oxidation of Flavonoids and Interaction with DNA on the Surface of Supramolecular Ionic Liquid Grafted on Graphene Modified Glassy Carbon Electrode
The study of the interaction between DNA and small molecules such as drugs is one of the current general interest and importance. In this paper, the electrochemical investigation of the interaction between some flavonoids such as rutin, quercetin, and hesperidin with dsDNA on the surface of Supramolecular Ionic Liquid grafted on the Graphene Oxide Modified Glassy Carbon Electrode (SIL-GO/GCE) is reported for the first time. The apparent binding constant (K) of the interaction between flavonoids and dsDNA was calculated using the current titrations. The apparent binding constants (K) of rutin, quercetin and hesperidin were calculated to be 4.3×105, 2.1×105 and 9.2×1-6 M-1, respectively. Furthermore, the electrochemical behavior of rutin on the surface of SIL-GO/GCE was studied in details using cyclic voltammetry and linear sweep voltammetry. The mechanism of the electrochemical redox reaction of rutin was proposed. When DNA was added into flavonoid solutions, their cathodic peak currents were decreased with few changes in the peak potentials. Furthermore, the interaction between rutin and bovine serum albuminwas studied using differential pulse voltammetry. In conclusion, the SIL-GO/GCE provides a promising platform for the study of the interaction between DNA and small molecules.
https://ijcce.ac.ir/article_29058_0ccee18aa1e9a61b3b273acda88cb325.pdf
2018-06-01
117
125
10.30492/ijcce.2018.29058
Graphene oxide
Supramolecular ionic liquids
Electrochemical techniques
Flavonoids-DNA interactions
Fahimeh
Tavakolyan Pour
tavakolyan_f@yahoo.com
1
Department of Chemistry, Faculty of Science, Science & Research Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
Syed
Waqifhusain
syedwaqifhusain@yahoo.com
2
Department of Chemistry, Faculty of Science, Science & Research Branch, Islamic Azad University, Tehran, I.R. IRAN
LEAD_AUTHOR
Hossein
Rastegar
mhrastegar2@yahoo.com
3
Food and Drug Control Reference Laboratories, 408-Valiasr Street, Tehran, I.R. IRAN
AUTHOR
Mohammad
Saber Tehrani
drmsabertehrani@yahoo.com
4
Department of Chemistry, Faculty of Science, Science & Research Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
Parviz
Abroomand Azar
parvizabroomand@gmail.com
5
Department of Chemistry, Faculty of Science, Science & Research Branch, Islamic Azad University, Tehran, I.R. IRAN
AUTHOR
[1] Tian X., Li F., Zhua L., Ye B., Study On the Electrochemical Behavior of Anticancer Herbal Drug Rutin and Its Interaction with DNA, J. Electroanal. Chem., 621: 1–6 (2008).
1
[2] Li H., Mei W.J., Xu Z.H., Pang D.W., Ji L.N., Lin Z.H., Electrochemistry Of a Novel Monoruthenated Porphyrin and Its Interaction with DNA, J. Electroanal. Chem., 600: 243-250 (2007).
2
[3] Li C., Liu S.L., Guo L.H., Chen D.P., A New Chemically Amplified Electrochemical System for DNA Detection in Solution, Electrochem. Commun., 7: 23-28 (2005).
3
[4] Singh B., Laffir F., Dickinson C., McCormac T., Dempsey E., Carbon Supported Cobalt and Nickel Based Nanomaterials for Direct Uric Acid Determination, Electroanalysis, 23: 79-89 (2011).
4
[5] Hegde N.R., Kumara Swamy B.E., Shetti N.P., Nandibewoor S.T., Electro-oxidation and Determination of Gabapentin at Gold Electrode, J. Electroanal. Chem., 635: 51-57 (2009).
5
[6] Bagheri A., Hosseini H., Electrochemistry of Raloxifene on Glassy Carbon Electrode and Its Determination in Pharmaceutical Formulations and Human Plasma, Bioelectrochemistry,88: 164-170 (2012).
6
[7] Hosseini H., Ahmar H., Dehghani A., Bagheri A., Fakhari A.R., Amini M.M., Au-SH-SiO2 Nanoparticles Supported on Metal-organic framework (Au-SH-SiO2@Cu-MOF) as a Sensor for Electrocatalytic Oxidation and Determination of Hydrazine, Electrochim. Acta, 88: 301-309 (2013).
7
[8] Uslu B., Dogan B., Ozkan S.A., Electrochemical Studies of Ganciclovir at Glassy Carbon Electrodes and its Direct Determination in Serum and Pharmaceutics by Square Wave and Differential Pulse Voltammetry, Anal. Chim. Acta, 537: 307-313 (2005).
8
[9] Guiyun X., Jinshi F., Kui J., Studies on the Electrochemical Property of Dinuclear Copper(II) Complex Containing Dimethylglyoxime and Its Interaction with DNA, Electroanalysis, 20: 1209–1214 (2008).
9
[10] Wang F., Xu Y., Zhao J., Hu S., Electrochemical Oxidation of Morin and Interaction with DNA, Bioelectrochemistry, 70: 356–362 (2007).
10
[11] Zhang J.J., Wang B., Li Y.F., Jia W.L., Cui H., Wanga H.S., Electrochemical Study on DNA Damage Based on the Direct Oxidation of 8-Hydroxydeoxyguanosine at an Electrochemically Modified Glassy Carbon Electrode, Electroanalysis, 20: 1684–1689 (2008).
11
[12] Suzen S., Dermircigil B.T., Buyukbingol E., Ozkan S.A., Electroanalytical Evaluation and Determination of 5-(3′-indolyl)-2-thiohydantoin Derivatives by Voltammetric Studies: Possible Relevance to in Vitro Metabolism, New J. Chem., 27: 1007–1011 (2003).
12
[13] Kauffmann J.M., Vire J.C., Extraction—Spectrophotometric Determination of Nickel with 4-chloro-2-nitroso-1-naphthol and Crystal Violet, Anal. Chim. Acta, 273: 329–334 (1993).
13
[14] Russo A., Acquaviva R., Campisi A., Sorrenti V., Di Giacomo C., Virgata G., Barcellona M.L., Vanella A., Bioflavonoids as Antiradicals, Antioxidants and DNA Cleavage Protectors, Cell Biol. Toxicol. 16: 91-98 (2000).
14
[15] Bohm H., Boeing H., Hempel J., Raab B., Kroke A., Flavonols, Flavone and Anthocyanins as Natural Antioxidants of Food and Their Possible Role in the Prevention of Chronic Diseases, Z Ernahrungswiss. 37: 147-163 (1998).
15
[16] Temerk Y.M., Ibrahim M.S., Kotb M., Schuhmann W., Interaction of Antitumor Flavonoids with dsDNA in the Absence and Presence of Cu(II), Anal. Bioanal. Chem., 405: 3839–3846 (2013).
16
[17] Kang J., Zhuo L., Lu X., Liu H., Zhang M., Wu H., Electrochemical Investigation on Interaction Between DNA with Quercetin and Eu–Qu3 Complex, J. Inorganic Biochemistry, 98: 79–86 (2004).
17
[18] Zatloukalová M., Křen V., Gažák R., Kubala M., Trouillas P., Ulrichová J., Electrochemical Investigation of Flavonolignans and Study of Their Interactions with DNA in the Presence of Cu(II), Bioelectrochemistry, 82: 117–124 (2011).
18
[19] Chen D., Feng H., Li J., Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications, Chem. Rev., 112: 6027−6053 (2012).
19
[20] Georgakilas V., Otyepka M., Bourlinos A.B., Chandra V., Kim N., Kemp K.C., Hobza P., Zboril R., Kim K.S., Functionalization of Graphene: Covalent and Non-covalent Approaches, Derivatives and Applications, Chem. Rev., 112: 6156−6214 (2012).
20
[21] Lotya M., King P.J., Khan U., De S., Coleman J.N., High-Concentration, Surfactant-Stabilized Graphene Dispersions, ACS nano, 4: 3155–3162 (2010).
21
[22] Patil A.J., Vickery J.L., Scott T.B., Mann S., Aqueous Stabilization and Self-Assembly of Graphene Sheets into Layered Bio-Nanocomposites Using DNA, Advanc. Mater., 21: 3159–3164 (2009).
22
[23] Shih C.J., Lin S., Strano M.S., Blankschtein D., Understanding the Stabilization of Liquid-Phase-Exfoliated Graphene in Polar Solvents: Molecular Dynamics Simulations and Kinetic Theory of Colloid Aggregation, J. Am. Chem. Soc., 132: 14638–14648 (2010).
23
[24] Lonkar S.P., Bobenrieth A., Winter J.D., Gerbaux P., Raquez J.-M., Dubois P., A Supramolecular Approach Toward Organo-dispersible Graphene and Its Straightforward Polymer Nanocomposites, J. Mater. Chem., 22: 18124-18126 (2012).
24
[25] Ji Q., Honma I., Paek S.-M., Akada M., Hill J.P., Vinu A., Ariga K., Layer-by-Layer Films of Graphene and Ionic Liquids for Highly Selective Gas Sensing, Angew. Chem. Int. Ed., 49: 9737–9739 (2010).
25
[26] Hasan, K.U., Sandberg, M.O, Nur, O, Willander, M., Polycation Stabilization of Graphene Suspensions, Nano. Res. Lett., 6: 493-498 (2011).
26
[27] Zhou X., Wu T., Ding K., Hu B., Hou M., Han B., Dispersion of Graphene Sheets in Ionic liquid [bmim][PF6] Stabilized by an Ionic Liquid Polymer, Chem. Commun., 46: 386-388 (2010).
27
[28] Gao F., Qi X., Cai X., Wang Q., Gao F., Sun W., Electrochemically Reduced Graphene Modified Carbon Ionic Liquid Electrode for the Sensitive Sensing of Rutin., Thin Solid Films, 520: 5064–5069 (2012).
28
[29] Bard A.J., Faulkner L.R., “Electrochemical Methods, Fundamentals and Applications”, John Wiley & Sons Inc., New York, (2001).
29
[30] Pang D.W., Abruna H.D., Micromethod for the Investigation of the Interactions Between DNA and Redox-Active Molecules. Anal. Chem, 70: 3162–3169 (1998).
30
[31] Rodriguez M., Bard A.J., Electrochemical Studies of the Interaction of Metal Chelates with DNA. Anal. Chem., 62: 2658–2662 (1990).
31
[32] Temerk Y.M., Ibrahim M.S., Kotb M., Voltammetric and Spectroscopic Studies on Binding of Antitumor Morin, Morin-Cu complex and Morin-beta-cyclodextrin with DNA, Spectrochim. Acta A, 71: 1830–1836 (2009).
32
ORIGINAL_ARTICLE
Determination of the Colorants in Various Samples by Chemometric Methods Using Statistical Chemistry
partial least square and principal component regression methods were applied to various mixtures of Allura Red and Brilliant Blue to determine the concentrations. Colorants, at the same time, were analyzed with UV-spectrophotometry in chemical separation. The obtained experimental data have been evaluated by chemometric methods as Partial Least Squares (PLS) and Principle Component Regression (PCR). In the first step, the synthetic mixtures containing three-color material were examined, and the obtained results were applied to the PCR and PLS. In the next step, using PLS and PCR methods, the quantities of Allura Red and Brilliant Blue in commercial beverage, samples were measured at the same time. The results were compared statistically.
https://ijcce.ac.ir/article_34168_2a0219546dc7196c61142d7e28c0e960.pdf
2018-06-01
127
134
10.30492/ijcce.2018.34168
PLS
PCR
Allura red
Brilliant blue
Guzide
Pekcan Ertokus
guzideertokus@sdu.edu.tr
1
Department of Chemistry, Faculty of Science & Art, Süleyman Demirel University, 32260 Isparta, TURKEY
LEAD_AUTHOR
[1] Capitan –Valley L., Fernandez M.D., De Orbe I., Avidad. R., Simultaneous Determination Of Colorants Tartrazine. Ponceau 4R And Sunset Yellow FCF In Foodstuffs By Solid Phase Spectrophotometry Using Partial Least Squares Multivariate Calibration, Talanta, 47: 861-868 (1998).
1
[2] Aktaş A.H., Pekcan. G., Simultaneous Spectrohotometric Determination of Tartrazine, Sunset Yellow and Allura Red in Commercial Products by Artificial Neural Network Calibration, Asian Journal of Chemistry, 18(3): 2025-2031 (2006).
2
[3] Berzas-Nevado J.J., Rodriguez Flores J., Guiberteau Cabanillas C., Villasenor Llerena. M.J., Contento Salcedo A., Resolution of Ternary Mixtures of Tartrazine. Sunset Yellow And Ponceau 4R by Derivative Spectrophotometric Ratio Spectrum-Zero Crossing Method In Commercial Foods, Talanta, 48: 933-942 (1998).
3
[4] Ni Y., Gang. X., Simultaneous Spectrophotometric Determination of Mixtures of Food Colorants, Analytica Chimica Acta, 354: 163- 171 (1997).
4
[5] Afkhami A., Sarlak N., Zarei A.R., Simultaneous Kinetic Spectrophotometric Determination of Cyanide and Thiocyanate Using the Partial Least Squares (PLS) Regression, Talanta, 71: 893-899 (2007).
5
[6] Lopez-de-Alba P.L., Wrobel-Kaczmarczyk K., Wrobel K., Lopez-Martinez L.,Hernandez J.A., Spectrophotometric Determination of Allura Red (R40) in Soft Drink Powders Using the Universal Calibration Matrix for Partial Least Squares Multivariate Method, Analytica Chimica Acta, 330: 19-29 (1996).
6
[7] Dinç E., Özdemir A., Baleanu D., Comparative Study of the Continuous Wavelet Transform, Derivative and Partial Least Squares Methods Applied to the Overlapping Spectra for the Simultaneous Quantitative Resolution of Ascorbic Acid and Acetylsalicylic Acid in Effervescent Tablets, Journal of Pharmaceutical and Biomedical Analysis, 37: 569-575 (2005).
7
[8] Hemmateenejad B., Akhond M., Samari F., A Comparative Study between PCR and PLS in Simultaneous Spectrophotometric Determination of Diphenylamine. Aniline and Phenol: Effect of Wavelength Selection, Spectrochimica Acta Part A. Molecular and Biomolecular Spectroscopy, 67: 958-965 (2007).
8
[9] Akhound M., Tashkhourian J., Hemmateenejad B., Simultaneous Determination of Ascorbic. Citric and Tartaric Acids by Potentiometric Titration with PLS Calibration, Journal of Analytical Chemistry, 61(8):804-808 (2006).
9
[10] Aktaş A.H., Yaşar. S., Potentiometric Titration of Some Hidroxylated Benzoic Acids and Cinnamic Acids by Artificial Neural Network Calibration, Acta Chim. Slovenica, 51: 273-282 (2004).
10
[11] Dinç E., Aktaş A.H., Üstündağ Ö., New Liquid Chromatography- Chemometric Approach for the Determination of Sunset Yellow and Tartrazine in Commercial Preparation, Journal of Aoac International, 88(6): 1748-1755 (2005).
11
[12] Dinç E., Özdemir A., Aksoy H., Üstündağ Ö., Baleanu. D., Chemometric Determination of Naproxen Sodium and Pseudoephedrine Hydrochloride in Tablets by HPLC, Chemical & Pharmaceutical Bulletin, 54(4): 415-421 (2006).
12
[13] Berzas J.J., Rodríguez J., Castañeda G., Partial Least Squares Method in the Analysis by Square Wave Voltammetry. Simultaneous Determination of Sulphamethoxypyridazine and Trimethoprim, Analytica Chimica Acta , 349 (1-3):303-311
13
[14] Ni Y., Gong X., Simultaneous Spectrophotometric Determination of Mixtures of Food Colorants, Analytica Chimica Acta, 354 (1-3): 163-171 (1997).
14
[15] Rajalahti T., Kvalheim O.M., Multivariate Data Analysis In Pharmaceutics: A Tutorial Review, International Journal of Pharmaceutics, 417, 280-290 (2011).
15
[16] Zhang G., Pan J., Simultaneous Spectrophotometric Determination of Atrazine and Cyanazine by Chemometric Methods, Spectrochimica Acta Part A, 78: 238-242 (2011).
16
[17] Kumar N., Bansal A., Sarma G.S., Rawal R.K., Chemometrics Tools Used In Analytical Chemistry: A Overview, Talanta, 123: 186-199 (2014).
17
[18] Barimani S., Kleinebudde P., Evaluation Of In-Line Raman Data for End-Point Determination of a Coating Process: Comparison of Science-Based Calibration, PLS-Regression and Univariate Data Analysis, Europian Journal Of Pharmaceutics And Biopharmaceutics, 119” 28-35 (2017).
18
[19] Jalalvand A.R., Goicoechea H.C., Applications of Electrochemical Data Analysis by Multivariate Curve Resolution-Alternating Least Squares, Trends In Analytical Chemistry, 88” 134-166 (2017).
19
[20] Üstündağ Ö., Dinç E., Özdemir N., Tilkan M.G., Comparative Application of PLS and PCR Methods to Simultaneous Quantitative Estimation and Simultaneous Dissolution Test of Zidovudine-Lamivudine Tablets, Acta Chim.Slov., 62: 437-444 (2015).
20
[21] Aktaş A.H., Kitiş F., Spectrophotometric Simultaneous Determination of Caffeine and Paracetamol in Commercial Pharmaceutical by Principal Component Regression, Partial Least Squares and Artificial Neural Networks Chemometric Methods, Croatica Chemica Acta, 87(1): 69-74 (2014).
21
[22] Kenneth R.B., “Chemometrics: A Practical Guide”, John Wiley & Sons. Inc., New York (1998).
22
[23] Brereton R.C., "Applied Chemometrics for Scientists", John Wiley & Sons. Inc., New York (2007).
23
[24] https://www.causeweb.org/cause/archive/ repository/ Minitab/Minitab.pdf .[16.10.2017]
24
ORIGINAL_ARTICLE
Nyquist Plots Prediction Using Neural Networks in Corrosion Inhibition of Steel by Schiff Base
The corrosion inhibition effect of N,N′-bis(n-Hydroxybenzaldehyde)-1,3-Propandiimine on mild steel has been investigated in 1 M HCl using electrochemical impedance spectroscopy. A predictive model was presented for Nyquist plots using an artificial neural network. The proposed model predicted the imaginary impedance based on the real part of the impedance as a function of time. The model took into account the variations of the real impedance and immersion time of steel in a corrosive environment, considering constant corrosion inhibitor concentrations. The best-fit training data set was obtained with eleven neurons in the hidden layer for Schiff base inhibitor, which made it possible to predict the efficiency. On the validation data set, simulations and experimental data test were in good agreement. The developed model can be used for the prediction of the real and imaginary parts of the impedance as a function of time.
https://ijcce.ac.ir/article_29963_e7a35453d456cdc0c55535404c4354e7.pdf
2018-06-01
135
143
10.30492/ijcce.2018.29963
Impedance
Neural network
Corrosion
Inhibitor
Kazem
Akbarzade
akbarzade@yahoo.com
1
Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, I.R. IRAN
AUTHOR
Iman
Danaee
danaee@put.ac.ir
2
Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, I.R. IRAN
LEAD_AUTHOR
[1] Hegazy M.A., Aiad I., 1-Dodecyl-4-(((3-Morpholinopropyl)imino)methyl)pyridin -1- Ium Bromide as a Novel Corrosion Inhibitor for Carbon Steel During Phosphoric Acid Production, J. Ind. Eng. Chem. 31: 91-99 (2015).
1
[2] Shabani-Nooshabadi M., Ghandchi M.S., Santolina Chamaecyparissus Extract as a Natural Source Inhibitor for 304 Stainless Steel Corrosion in 3.5% NaCl, J. Ind. Eng. Chem. 31: 231-237 (2015).
2
[3] Hoseinzadeh A.R., Danaee I., Maddahy, M.H., RashvandAvei, M., Taurine as a Green Corrosion Inhibitor for AISI 4130 Steel Alloy in Hydrochloric Acid Solution. Chem. Eng. Comm., 201: 380-402 (2014).
3
[4] ChaitraT.K., Mohana K.N.S., Tandon H.C., Thermodynamic, Electrochemical and Quantum Chemical Evaluation of Some Triazole Schiff Bases as Mild Steel Corrosion Inhibitors in Acid Media, J. Mol. Liq., 211: 1026-1038 (2015).
4
[5] Verma C., Ebenso E.E., Bahadur I., Obot I.B., Quraishi M.A., 5-(Phenylthio)-3H-pyrrole-4-Carbonitriles as Effective Corrosion Inhibitors for Mild Steel in 1 M HCl: Experimental and Theoretical Investigation, J. Mol. Liq., 212: 209-218 (2015).
5
[6] Park J.K., Jeong N.H., Corrosion Inhibition Effect of Ester Containing Cationic Gemini Surfactants on Low Carbon Steel, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 85-93 (2016).
6
[7] Abderrahim K., Abderrahmane S., Millet J.P., Inhibition of Copper Corrosion by Ethanolamine in 100 ppm NaCl, Iran. J. Chem. Chem. Eng. (IJCCE) 35: 89-98 (2016).
7
[8] Gholami M., Danaee I., Maddahy M.H., RashvandAvei M., Correlated ab Initio and Electroanalytical Study on Inhibition Behavior of 2‑Mercaptobenzothiazole and Its Thiole−Thione Tautomerism Effect for the Corrosion of Steel (API 5L X52) in Sulphuric Acid Solution. Ind. Eng. Chem. Res. 52: 14875−14889 (2013).
8
[9] Danaee I., Ghasemi O., Rashed G. R., RashvandAvei M., Maddahy M.H., Effect of Hydroxyl Group Position on Adsorption Behavior and Corrosion Inhibition of Hydroxybenzaldehyde Schiff Bases: Electrochemical and Quantum Calculations. J. Mol. Struct. 1035, 247-259 (2013).
9
[10] Balaji J., Sethuraman M.G., Corrosion Protection of Copper with Hybrid Sol-Gel Containing 1H-1, 2, 4-triazole-3-thiol, Iran. J. Chem. Chem. Eng. (IJCCE) 35: 61-71 (2016).
10
[11] Ghasemi O., Danaee I., Rashed G.R., RashvandAvei M., Maddahy M.H., Inhibition effect of a synthesized N, N′-bis(2-hydroxybenzaldehyde)-1, 3-propandiimine on Corrosion of Mild Steel in HCl. J. Cent. South Univ. 20: 301-311 (2013).
11
[12] Dasami P.M., Parameswari K., Chitra S., Corrosion Inhibition of Mild Steel in 1 M H2SO4 by Thiadiazole Schiff Bases, Measurement, 69: 195-201 (2015).
12
[13] Jafari H., Danaee I. Eskandari H., RashvandAvei M., Electrochemical and Theoretical Studies of Adsorption and Corrosion Inhibition of N,N′-Bis(2-hydroxyethoxyacetophenone) -2,2-dimethyl -1,2-propanediimine on Low Carbon Steel (API 5L Grade B) in Acidic Solution. Ind. Eng. Chem. Res., 52: 6617-6632 (2013).
13
[14] Saha S. K., Ghosh P., Hens A., Murmu N.C., Banerjee P., Density Functional Theory and Molecular Dynamics Simulation Study on Corrosion Inhibition Performance of Mild Steel by Mercapto-Quinoline Schiff Base Corrosion Inhibitor, Physica E, 66: 332-341 (2015).
14
[15] Colorado-Garrido D., Serna S., Cruz-Chávez M., Hernández J.A., Campillo B., Artificial Neural Networks for Electrochemical Impedance Spectroscopy Sour Corrosion Predictions of Nano-modified Microalloyed Steels, Electronics, Robotics and Automotive Mechanics Conference, 210: 185-190 (2010).
15
[16] Silva C.D.L.D., Junior G.C., Morais A.P.D., Marchesan G., Guarda F.G.K., A Continually Online Trained Impedance Estimation Algorithm for Transmission Line Distance Protection Tolerant to System Frequency Deviation, Electr. Pow. Syst. Res. 147: 73-80 (2017).
16
[17] Conesa C., Sánchez L.G., Seguí L., Fito P., Laguarda-Miró N., Ethanol Quantification in Pineapple Waste by an Electrochemical Impedance Spectroscopy-Based System and Artificial Neural Networks, Chemometr. Intell. Lab. 161: 1-7 (2017).
17
[18] Ghanadzadeh H., Daghbandan A., Akbarizadeh M., Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2)), Iran. J. Chem. Chem. Eng. (IJCCE), 33: 67-73 (2014).
18
[19] Ehsani M.R., Bateni H., Razi Parchikolaei G., Modeling of Oxidative Coupling of Methane over Mn/Na2WO4/SiO2 Catalyst Using Artificial Neural Network, Iran. J. Chem. Chem. Eng. (IJCCE), 32: 107-114 (2013).
19
[20] Ahmmed I.S., Mohamed H.A., Nayef G.M., Decentralized Advanced Model Predictive Controller of Fluidized-Bed for Polymerization Process, Iran. J. Chem. Chem. Eng. (IJCCE), 31: 91-117 (2012).
20
[21] Azari A., Shariaty-Niassar M., Alborzi M., Short-term and Medium-term Gas Demand Load Forecasting by Neural Networks, Iran. J. Chem. Chem. Eng. (IJCCE), 31: 77-84 (2012).
21
[22] Magharei A., Vahabzadeh F., Sohrabi M., Rahimi Kashkouli Y., Maleki M., Mixture of Xylose and Glucose Affects Xylitol Production by Pichia guilliermondii: Model Prediction Using Artificial Neural Network, Iran. J. Chem. Chem. Eng. (IJCCE), 31: 119-131 (2012).
22
[23] Abbasi M., Soleymani A.R., Parssa J.B., Operation Simulation of a Recycled Electrochemical Ozone Generator Using Artificial Neural Network, Chem. Eng. Res. Des., 92: 2618-2625 (2014).
23
[24] Chen F.F., Breedon M., White P., Chu C., Mallick D., Thomas S., Sapper E., Cole I., Correlation between Molecular Features and Electrochemical Properties Using an Artificial Neural Network, Mater. Des. 112: 410-418 (2016).
24
[25] Panchal I., Sawhney I.K., Sharma A.K., Dang A.K., Classification of Healthy and Mastitis Murrah Buffaloes by Application of Neural Network Models Using Yield and Milk Quality Parameters, Comput. Electron. Agr. 127: 242-248 (2016).
25
[26] Rolich T., Rezic I., Curkovic L., Estimation of Steel Guitar Strings Corrosion by Artificial Neural Network, Corros. Sci. 52: 996-1002 (2010).
26
[27] Sun Y., Chen Y., Yuan Y., Wang G., Dynamic Adjustment of Hidden Layer Structure for Convex Incremental Extreme Learning Machine, Neurocomputing, 261: 83-93 (2017).
27
[28] Yang Z.X., Zhao G.H., Rong H.J., Yang J., Adaptive Backstepping Control for Magnetic Bearing System via Feedforward Networks with Random Hidden Nodes, Neurocomputing 174: 109-120 (2016).
28
[29] Matias T., Souza F., Araújo R., Antunes C.H., Learning of a Single-Hidden Layer Feedforward Neural Network Using an Optimized Extreme Learning Machine, Neurocomputing 129: 428-436 (2014).
29
[30] Jafari H., Danaee I., Eskandari H., RashvandAvei M., Combined Computational and Experimental Study on the Adsorption and Inhibition Effects of N2O2 Schiff Base on the Corrosion of API 5L Grade B Steel in 1 mol/L HCl, J. Mater. Sci. Technol., 30: 239-252 (2014).
30
[31] Danaee I., Kinetics and Mechanism of Palladium Electrodeposition on Graphite Electrode by Impedance and Noise Measurements, J. Electroanal. Chem., 662: 415–420 (2011).
31
[32] Macdonald J.R., Note on the Parameterization of the Constant Phase Admittance Element. Solid State Ion., 13: 147–149 (1984).
32
[33] Hoseinzadeh A.R., Danaee I., Maddahy M.H., Thermodynamic and Adsorption Behaviour of Vitamin B1 as a Corrosion Inhibitor for AISI 4130 Steel Alloy in HCl Solution, Z. Phys. Chem., 227: 403-417 (2013).
33
[34] RameshKumar S., Danaee I., RashvandAvei M., Vijayan M., Quantum Chemical and Experimental Investigations on Equipotent Effects of (+)R and (−)S Enantiomers of Racemic Amisulpride as Eco-Friendly Corrosion Inhibitors for Mild steel in Acidic Solution, J. Mol. Liq., 212: 168-186 (2015).
34
[35] Danaee I., Niknejad Khomami M., Attar A.A., Corrosion Behavior of AISI 4130 Steel Alloy in Ethylene Glycol–Water Mixture in Presence of Molybdate, Mater. Chem. Phys., 135: 658–667 (2012).
35
[36] Martin O., De Tiedra P., Lopez M., Artificial Neural Networks for Pitting Potential Prediction of Resistance Spot Welding Joints of AISI 304 Austenitic Stainless Steel, Corros. Sci. 52: 2397-2402 (2010).
36
[37] Ramana K.V.S., Anita T., Mandal S., Kaliappan S., Shaikh H., Sivaprasad P.V., Dayal, R.K., Khatak H.S., Effect of Different Environmental Parameters on Pitting Behavior of AISI Type 316L Stainless Steel: Experimental Studies and Neural Network Modeling, Mater. Des., 30: 3770-3775 (2009).
37
[38] Khadom A.A., Modeling of Corrosion Reaction Data in Inhibited Acid Environment Using Regressions and Artificial Neural Networks, Korean J. Chem. Eng., 30, 2197-2204 (2013).
38
ORIGINAL_ARTICLE
Sorption of Thorium Using Magnetic Graphene Oxide Polypyrrole Composite Synthesized from Water Hyacinth Roots
Polypyrrole magnetic graphene oxide (PPy/MGO) composites have been synthesized from a natural source (water hyacinth roots) using polymerization technique for Th(IV) ions pre-concentration from aqueous solutions. The effects of controlling factor have been studied using the batch technique. The obtained results show that the maximum Th(IV) adsorption capacity by PPy/MGO composite is 277.8 mg/g at pH 4, which is higher than traditional adsorbents. PPy/MGO composite also presents excellent regeneration/reuse property. The PPy/MGO was thoroughly characterized by a number of techniques namely, Fourier transforms infrared, Raman, as well as X-ray diffraction, thermogravimetric and Energy-Dispersive X-ray (EDX). Due to the high adsorption capacity of Th (IV), PPy/MGO composite can be used in nuclear fuel achievement and for Th(IV) environmental pollution cleanup.
https://ijcce.ac.ir/article_34205_37cadff96c7af48ded2044efd7da2b62.pdf
2018-06-01
145
160
10.30492/ijcce.2018.34205
Thorium
Polypyrrole
Graphene oxide
Composite
Adsorption
Mohamed
Gado
parq28@yahoo.com
1
Nuclear Materials Authority, 530 P.O. Box Maadi, Cairo, EGYPT
LEAD_AUTHOR
[1] Brugge D., deLemos J.L., Oldmixon B., Exposure Pathways and Health Effects Associated with Chemical and Radiological Toxicity of Natural Uranium: A Review, Rev. Environ. Health, 20: 177- (2005).
1
[2] Metwally E., Kinetic Studies for Sorption of Some Metal Ions From Aqueous Acid Solutions onto TDA Impregnated Resin, J. Radional. Nucl. Chem., 270: 559- (2006).
2
[3] Sharma P., Tomar R., Synthesis and Application of an Analogue of Mesolite for the Removal of Uranium(VI), Thorium(IV), and Europium(III) From Aqueous Waste, Microporous Mesoporous Mater, 116: 641- (2008).
3
[4] Tang Y.Z., Reeder R.J., Uranyl and Arsenate Cosorption on Aluminum Oxide Surface, Geochim. Cosmochim. Acta, 73: 2727- (2009).
4
[5] Shao D.D., Li J.X., Wang X.K., Poly(amidoxime)-Reduced Graphene Oxide Composites as Adsorbents for the Enrichment of Uranium from Seawater, Sci. China Chem., 57: 1449- (2014).
5
[6] Gado M., Morsy A., Preparation of Poly-Aniline-Magnetic Porous Carbon Composite for Using as Uranium Adsorbent, American Journal of Materials Synthesis and Processing, 2: 32- (2017).
6
[7] Olmez Aytas S., Akyil S., Eral M., Adsorption and Thermodynamic Behavior of Uranium on Natural Zeolite, J. Radioanal. Nucl. Chem., 260: 119- (2004).
7
[8] Shahwan T., Erten H.N., Characterization of Sr2+ Uptake on Natural Minerals of Kaolinite and Magnetise Using XRPD SEM/EDS, and DRIFT, Radiochim. Acta, 93: 225- (2005).
8
[9] Shehata F.A., Attallah M.F., Borai E.H., Hilal M.A., Abo-Aly M.M., Sorption Reaction Mechanism of Some Hazardous Radionuclides From Mixed Waste by Impregnated Crown Ether onto Polymeric Resin, Appl. Radiat. Isot., 68: 239- (2010).
9
[10] Atia A.A., Studies on the Interaction of Mercury(II) and Uranyl with Modified Chitosan Resins, Hydrometallurgy, 80: 13- (2005).
10
[11] Li W.J., Tao Z.Y., Comparative Study on Th(IV) Sorption on Alumina and Silica From Aqueous Solutions, J. Radioanal. Nucl. Chem., 254: 187- (2002).
11
[12] Seko N., Tamada M., Yoshii F., Current Status of Adsorbent for Metal Ions with Radiation Grafting and Crosslinking Techniques, Nucl. Instrum. Methods Phys. Res. Sect. B 236: 21- (2005).
12
[13] Vivero-Escoto J.L., Carboni M., Abney C.W., DeKrafft K.E., Lin, Organofunctionalized Mesoporous Silicas for Efficient Uranium Extraction, Microporous Mesoporous Mater., 180: 22- (2013).
13
[14] Prasada Rao T., Metilda P., Mary Gladis J., Preconcentration Techniques for Uranium(VI) and Thorium(IV) Prior to Analytical Determination - An Overview, Talanta, 68: 1047- (2006).
14
[15] Prabhakaran D., Subramanian M.S., Selective Extraction of U(VI) Th(IV), and La(III) From Acidic Matrix Solutions and Environmental Samples Using Chemically Modified Amberlite XAD-16 Resin, Anal. Bioanal. Chem., 379: 519- (2004).
15
[16] Donat R., Esen K., Cetisli H., Aytas S., Adsorption of Uranium(VI) onto Ulva sp.-Sepiolite Composite, J Radioanal Nucl Chem, 279: 253- (2008).
16
[17] Ilton E.S., Wang Z.M., Boily J.F., Qafoku O., Rosso K.M., Smith S.C., The Effect of pH and Time on the Extractability and Speciation of Uranium (VI) Sorbed to SiO2, Environ. Sci. Technol., 46: 6604- (2012).
17
[18] Ims S., Ek S., Ulusoy U., Uranium and Lead Adsorption onto Bentonite and Zeolite Modified with Polyacrylamidoxime, J Radioanal Nucl. Chem., 292: 41- (2012).
18
[19] Belgacem A., Rebiai R., Hadoun H., Khemaissia S., Belmedani M., The Removal of Uranium (VI) From Aqueous Solutions onto Activated Carbon Developed from Grinded Used Tire, Environ. Sci. Pollut. Res., 21: 684- (2014).
19
[20] Schierz A., Za¨nker H., Aqueous Suspensions of Carbon Nanotubes: Surface Oxidation, Colloidal Stability and Uranium Sorption, Environ. Pollut., 157: 1088- (2009).
20
[21] Li Z.J., Chen F., Yuan L.Y., Liu Y.L., Zhao Y.L., Chai Z.F., Shi W.Q., Uranium (VI) Adsorption on Graphene Oxide Nanosheets From Aqueous Solutions, Chem. Eng. J., 210: 539- (2012).
21
[22] Su Q., Pang S., Alijani V., Li C., Feng X., Müllen K., Composites of Graphene with Large Aromatic Molecules, Adv. Mater., 21: 3191- (2009).
22
[23] Zhao G., Li J., Ren X., Chen C., Wang X., Few-Layered Graphene Oxide Nanosheets as Superior Sorbents for Heavy Metal Ion Pollution Management, Environ. Sci. Technol., 25: 10454- (2011).
23
[24] Li D., MU M., Je S.G., Kaner R.B., Wallance G., Processable Aqueous Dispersions of Graphene Nanosheets, Nat. Nanotechnol., 3: 101- (2008).
24
[25] Yuan W., Shi G., Graphene-Based Gas Sensors, J. Mater. Chem. A., 1: 10078- (2013).
25
[26] Harshal P., Mungse H.P., Sharma O.P., Hiroyuki Sugimura H., Khatri O.P., Hydrothermal Deoxygenation of Graphene Oxide in Sub- and Supercritical Water, J. Mater. Chem., 4: 22589- (2014).
26
[27] Konwer S., Boruah R., Dolui S.K., Studies on Conducting Polypyrrole/Graphene Oxide Composites as Supercapacitor Electrode, J. Electron Mater, 40: 2248- (2011).
27
[28] Zhang S., Hao Y.Y., Liu J., Aksay I.A., Lin Y.H., Graphene-Polypyrrole Nanocomposite as a Highly Efficient and Low Cost Electrically Switched Ion Exchanger for Removing ClO4– From Wastewater, ACS Appl Mater Interf, 3: 3633- (2011).
28
[29] Zhu Y., Murali S., Cai W., Li X., Suk J.W., Potts J.R., Ruoff R.S., Graphene and Graphene Oxide: Synthesis, Properties, and Applications, Advanced Materials, 22: 3906- (2010).
29
[30] Huang X., Yin Z., Wu S., Qi X., He Q., Zhang Q., Yan Q., Boey F., Zhang H., Graphene-based Materials: Synthesis, Characterization, Properties, and Applications, Small, 7: 1876- (2011).
30
[31] Liu Y., Dong X., Chen P., Biological and Chemical Sensors Based on Graphene Materials, Chemical Society Reviews, 41: 2283- (2012).
31
[32] Machado B.F., Serp P., Graphene-based Materials for Catalysis, Catalysis Science & Technology, 2: 54- (2012).
32
[33] Sharma P., Tomar R., Synthesis and Application of an Analogue of Mesolite for the Removal of Uranium(VI), Thorium(IV), and Europium(III) from Aqueous Waste, Microporous Mesoporous Mater, 116: 641- (2008).
33
[34] Mowafy E.A., Aly H.F., Extraction Behaviours of Nd(III), Eu(III) La(III), Am(III), and U(VI) with Some Substituted Malonamides from Nitrate Medium, Solvent Extr. Ion Exch., 20: 177- (2002).
34
[35] Condamines N., Musikas C., The Extraction by N.N-Dialkylamides. II. Extraction of Actinide Cations, Solvent Extr. Ion Exch., 10: 69-100 (1992).
35
[36] Ardois C., Musikas C., Fattahi M., Abbe A.C., Selective Actinide Solvent Extraction Used in Conjunction with Liquid Scintillation, J. Radioanal. Nucl. Chem., 226: 241- (1992).
36
[37] Zhen X., Chao G., In Situ Polymerization Approach to Graphene-Reinforcednylon-6 Composites, Macromolecules, 43: 6716- (2010).
37
[38] Guobo H., Suqing C., Pingan S., Pingping L., Chenglin W., Huading L., Combination Effects of Graphene and Layered Double Hydroxides on Intumescent Flame-Retardant Poly (methyl methacrylate) Nanocomposites, Appl. Clay Sci., 88–89: 78- (2014).
38
[39] Chenlu B., Lei S., Weiyi X., Bihe Y., Charles A.W., Jianliu H., Yuqiang G., Yuan H., Preparation of Graphene by Pressurized Oxidation and Multiplex Reduction and Its Polymer Nanocomposites by Masterbatch-Based Melt Blending, J. Mater. Chem., 22: 6088- (2012).
39
[40] Massart R., Preparation of Aqueous Magnetic Liquids in Alkaline and Acidic Media. IEEE Trans Magn., 17: 1247- (1981).
40
[41] Yao J., Sun Y., Yang M., Duan Y., Chemistry, Physics and Biology of Graphene-Based Nanomaterials: New Horizons for Sensing, Imaging and Medicine, Journal of Materials Chemistry, 22: 14313- (2012).
41
[42] Shapiro, L., Brannock N.W., “Rapid Analysis of Silicate, Carbonate and Phosphate Rocks”, U.S. Geo. Surv., Bull, V. 1144, 56 p (1962).
42
[43] Chen C., Wang X., Sorption of Th (IV) to Silica as a Function of pH, Humic/Fulvic Acid, Ionic Strength, Electrolyte Type, Applied Radiation and Isotopes, 65: 155- (2007) (2007).
43
[44] Gado M., Zaki S., Studies on Thorium Adsorption Characteristics upon Activated Titanium Hydroxide Prepared from Rosetta Ilmenite Concentrate, Int. J. Waste Resources, 6: 1000194- (2015).
44
[45] Yang X., Xu M.S., Qiu W.M., Chen X.Q., Deng M., Zhang J.L., Iwai H., Watanabe E., Chen H.Z., Graphene Uniformly Decorated with Gold Nanodots: in Situ Synthesis, Enhanced Dispersibility and Its Applications, J. Mater. Chem., 21: 8096- (2011).
45
[46] Cho G., Fung B.M., Glatzhofer D.T., Lee J.S., Shul Y.G., Preparation and Characterization of Polypyrrole-Coated Nanosized Novel Ceramics, Langmuir, 17: 456- (2001).
46
[47] Tian B., Zerbi G., Lattice Dynamics and Vibrational Spectra of Polypyrrole, J. Chem. Phys., 92: 3886- (1990).
47
[48] Mahmud H.N.M.E., Kassim A., Zainal Z., Yunus W.M.M., Fourier Transform Infrared Study of Polypyrrole–Poly(vinyl alcohol) Conducting Polymer Composite Films: Evidence of Film Formation and Characterization, J. Appl. Polym. Sci., 100: 4107- (2006).
48
[49] Zhang X.T., Zhang J., Liu Z.F., Robinsonb C., Enhanced Capacitance and Rate Capability of Graphene/Polypyrrole Composite as Electrode Material for Supercapacitors, J. Power Sources, 196: 1852- (2004).
49
[50] Wang H.L., Hao Q.L., Yang X.J., Lu L.D., Wang X., Graphene Oxide Doped Polyaniline for Supercapacitors, Electrochem. Commun., 11: 1158–1161 (2009).
50
[51] Bissessur R., Liu P.K.Y., Scully S.F., Intercalation of Polypyrrole Into Graphite Oxide, Synth. Met., 156: 1023- (2006).
51
[52] Fan W., Gao W., Zhang C., Tjiu W.W., Pan J.S., Liu T.X., Self-Assembly of Hierarchical Fe3O4 Microsphere/Graphene Nanosheet Composite: Towards a Promising High-Performance Anode for Li-Ion Batteries, J. Mater Chem., 22: 25108- (2012).
52
[53] Guo H.L., Wang X.F., Qian Q.Y., Wang F.B., Xia X.H., A Green Approach to the Synthesis of Graphene Nanosheets, ACS Nano, 3: 2653- (2009).
53
[54] Xu J., Wang K., Zu S.-Z., Han B.-H., Wei Z., Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage, ACS Nano, 4: 5019- (2010).
54
[55] Deng X., Lü L., Li H., Luo F., The Adsorption Properties of Pb(II) and Cd(II) on Functionalized Graphene Prepared by Electrolysis Method, J. Hazard. Mater., 183: 923- (2010).
55
[56] Li Y., Zhang P., Du Q., Peng X., Liu T., Wang Z., Xia Z., Zhang W., Wang K., Zhu H., Wu D., Adsorption of Fluoride from Aqueous Solution by Graphene, J. Coll. Interf. Sci., 363: 348- (2011).
56
[57] Yang S.T., Chen S., Chang Y., Cao A., Liu Y., Wang H., Removal of Methylene Blue from Aqueous Solution by Graphene Oxide, J. Coll. Interf. Sci., 359: 24- (2011).
57
[58] Bhaumik M., Leswifi T.Y., Maity A., Srinivasu V.V., Onyango M.S., Removal of Fluoride from Aqueous Solution by Polypyrrole/Fe3O4 Magnetic Nanocomposite, J. Hazard. Mater., 186: 150- (2011).
58
[59] Ballav N., Mishra S., Maity A., High Efficient Removal of Chromium(VI) Using Glycine Doped Polypyrrole Adsorbent from Aqueous Solution, Chem. Eng. J., 198–199: 536- (2012).
59
[60] Bao Q., Zhang D., Qi P., Synthesis and Characterization of Silver Nanoparticle and Graphene Oxide Nanosheet Composites as a Bactericidal Agent for Water Disinfection, J. Coll. Interf. Sci., 360: 463- (2011).
60
[61] De Faria D.L.A., Silva S.V., de Oliveira M.T., Raman Microspectroscopy of Some iron Oxides and Oxyhydroxides, J. Raman Spectrosc., 28: 873- (1997).
61
[62] Bersani D., Lottici P.P., Montenero A., Micro-Raman Investigation of Iron Oxide Films and Powders Produced by Sol–Gel Syntheses, J. Raman Spectrosc., 30: 355- (1999).
62
[63] Bora C., Dolui S.K., Fabrication of Polypyrrole/ Graphene Oxide Nanocomposites by Liquid/Liquid Interfacial Polymerization and Evaluation of Their Optical, Electrical and Electrochemical Properties, Polymer, 53: 923- (2012).
63
[64] Kuilla T., Bhadra S., Yao D., Kim N.H., Bose S., Lee J.H., Recent Advances in Graphene Based Polymer Composites, Prog. Polym. Sci., 35: 1350- (2010).
64
[65] Lerf A., Klinowski J., Structure of Graphite Oxide Revisited, J. Phys. Chem. B., 102: 4477- (1998).
65
[66] KruegerGrasser R., Weiss A., Selective Liquid Sorption Properties of Hydrophobized Graphite Oxide Nanostructures, Colloid Polym. Sci., 276: 570- (1998).
66
[67] Liu P., Xiao M., Preparation and Characterization of Poly(vinyl acetate)-Intercalated Graphite Oxide Nanocomposite, J. Mater. Chem., 10: 933- (2000).
67
[68] Teksoz S., Acar C., Unak P., Hydrolytic Behavior of Th4+, UO2 2+, and Ce3+ Ions at Various Temperatures,
68
J. Chem. Eng. Data, 54: 1183- (2009).
69
[69] Li Y., Du Q., Liu T., Sun J., Jiao Y., Xia Y., Xia L., Wang Z., Zhang W., Wang K., Zhu H., Wu D., Equilibrium, Kinetic and Thermodynamic Studies on the Adsorptionof Phenol onto Graphene, Materials Research Bulletin, 47: 1898- (2012).
70
[70] Wang H., Yuan X., Wu Y., Huang H., Zeng G., Liu Y., Wang X., Lin N., Qi Y., Adsorption Characteristics and Behaviors of Graphene Oxide for Zn(II) Removal from Aqueous Solution, Applied Surface Science, 279: 432- (2013).
71
[71] Liu Y.H., Wang Y.Q., Zhang Z.B., Cao X.H., Nie W.B., Li Q., Hua R., Removal of Uranium from Aqueous Solution by a Low Cost and High-Efficient Adsorbent, Applied Surface Science, 273: 68- (2013).
72
[72] Anirudhan T.S., Suchithra P.S., Senan P., Tharun A.R., Kinetic Equilibrium Pro-Files of Adsorptive Recovery of Thorium(IV) from Aqueous Solutions Using Poly(methacrylic acid) Grafted Cellulose/Bentonite Superabsorbent Composite, Industrial & Engineering Chemistry Research, 51: 4825- (2012).
73
[73] Sheng G., Hu J., Wang X., Sorption Properties of Th(IV) on the Raw Diatomite-Effects of Contact Time, pH, Ionic Strength and Temperature, Appl. Radiat. Isot., 66: 1313- (2008).
74
[74] Moulin C., Amekraz B., Hubert S., Moulin V., Study of Thorium Hydrolysis Species by Eectrospray-Ionization Mass Spectrometry, Analytica Chimica Acta, 441: 269- (2001).
75
[75] Chen C., Wang X., Sorption of Th (IV) to Silica as a Function of pH, Humic/Fulvic Acid, Ionic Strength, Electrolyte Type, Applied Radiation and Isotopes, 65: 155- (2007).
76
[76] Deng X.J., Lu L.L., Li H.W., Luo F., The Adsorption Properties of Pb(II) and Cd(II) on Functionalized Graphene Prepared by Electrolysis Method, J. Hazard Mater, 183: 923- (2010).
77
[77] Manos M.J., Kanatzidis M.G., Layered Metal Sulfides Capture Uranium from Seawater, J. Am. Chem. Soc., 134: 16441- (2012).
78
ORIGINAL_ARTICLE
Application of the Modified Biochar from Sewage Sludge for Removal of Pb(II) from Aqueous Solution: Kinetics, Equilibrium and Thermodynamic Studies
An adsorbent Modified Biochar (MB) made from sewage sludge was characterized with FT-IR spectra and SEM image. The effects of contact time, solution temperature, pH and initial concentration on the adsorption performance Pb(II) onto MB was investigated in a batch adsorption experiment. Results showed that MB had great adsorption capacity, due to the existence of hydroxyl, carboxyl, ether, alcohol and amino groups. As the contact time prolonged, the adsorption quantity of MB increased sharply first and then tended to the balance. The adsorption capacity increased slightly with the temperature increase. The effect of pH on the absorbability of MB was non-linear, and the maximum adsorption capacity was obtained when the pH was approximately 6. The adsorption capacity increased abruptly first and then become slowly with the initial concentration increase. Compared with the pseudo-first-order, the pseudo-second-order kinetic models were more suitable to test the kinetic experimental data. Equilibrium data were analyzed using the Langmuir and Freundlich isotherm models and it was found to correspond to the Langmuir isotherm model better.
https://ijcce.ac.ir/article_30331_9d3415339016ae878e2ecaea18144824.pdf
2018-06-01
161
169
10.30492/ijcce.2018.30331
Pb(II)
Modified biochar
Adsorption kinetics
Adsorption isotherms
Adsorption mechanism
Lequn
Zhang
lequn_zhang@126.com
1
Key Laboratory of Western China’ s Environmental System, Ministry of Education, College of Resource and Environment, Lanzhou University, Lanzhou 730000, Gansu, P.R. CHINA
AUTHOR
Tao
Yu
yu_tao1@126.com
2
School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, P.R. CHINA
AUTHOR
Zhongren
Nan
zhongren_nan@sina.com
3
Key Laboratory of Western China’ s Environmental System, Ministry of Education, College of Resource and Environment, Lanzhou University, Lanzhou 730000, Gansu, P.R. CHINA
AUTHOR
Zhenjun
Wu
zhenjun_wu1@qq.com
4
chool of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, P.R. CHINA
AUTHOR
Bin
Li
bin_li1@163.com
5
chool of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, P.R. CHINA
AUTHOR
Shunyi
Li
wzydx2003@163.com
6
chool of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, P.R. CHINA
LEAD_AUTHOR
[1] Shi Z., Zou P., Guo M., Yao S., Adsorption Equilibrium and Kinetics of Lead Ion onto Synthetic Ferrihydrites, Iran. J. Chem. Chem. Eng. (IJCCE), 34(3): 25-32 (2015).
1
[2] Blázquez G., Martín-Lara M.A., Tenorio G., Calero M., Batch Biosorption of Lead(II) from Aqueous Solutions by Olive Tree Pruning Waste: Equilibrium, Kinetics and Thermodynamic Study, Chem. Eng. J., 168(1), 170 (2011).
2
[3] Huang K., Zhu H., Removal of Pb2+ from Aqueous Solution by Adsorption on Chemically Modified Muskmelon Peel, Environ. Sci. Pollut. Res., 20(7): 4424-4434 (2017).
3
[4] Li Y.H., Di Z., Ding J., Wu D., Luan Z., Zhu Y., Adsorption Thermodynamic, Kinetic and Desorption Studies of Pb2+ on Carbon Nanotubes, Water Res., 39(4): 605-609 (2005).
4
[5] Shakeri A., Hazeri N., Valizadeh J., Hashemi E., Kakhky A.R.M., Removal of Lead (II) from Aqueous Solution Using Cocopeat: An Investigation on the Isotherm and Kinetic, Iran. J. Chem. Chem. Eng. (IJCCE), 31(3): 45-50 (2012).
5
[6] Kratochvil D., Volesky B., Advances in the Biosorption of Heavy Metals, Trends in Biotechnology, 16(7): 291-300 (1998).
6
[7] Bailey S.E., Olin T.J., Bricka R.M., Adrian D.D., A Review of Potentially Low-Cost Sorbents for Heavy Metals, Water Res., 33(11): 2469-2479 (1999).
7
[8] Yousef R.I., El-Eswed B., Al-Muhtaseb A.H., Adsorption Characteristics of Natural Zeolites as Solid Adsorbents for Phenol Removal from Aqueous Solutions: Kinetics, Mechanism, and Thermodynamics Studies, Chem. Eng. J., 171(3): 1143-1149 (2011).
8
[9] Nekoo S.H., Shohreh F., Experimental Study and Adsorption Modeling of COD Reduction by Activated Carbon for Wastewater Treatment of Oil Refinery, Iran. J. Chem. Chem. Eng. (IJCCE), 3(32):81-89 (2013).
9
[10] Muftan H.E.-N., Sulaiman A.-Z., Alhaji M., Reduction of COD in Refinery Wastewater Through Adsorption on Date-pit Activated Carbon, J. Hazard. Mater., 13(1-3):750-757 (2010).
10
[11] Yang Y., Sheng G., Enhanced Pesticide Sorption by Soils Containing Particulate Matter from Crop Residue Burns, Environ. Sci. Technol., 37(16), 3635-3639 (2003).
11
[12] Zhu D., Kwon S., Pignatello, J.J., Adsorption of Single-Ring Organic Compounds to Wood Charcoals Prepared under Different Thermochemical Conditions, Environ. Sci. Technol., 39(11), 3990-3998 (2005).
12
[13] Wang X., Sato T., Xing B., Competitive Sorption of Pyrene on Wood Chars, Environ. Sci. Technol., 40(10), 3267-3272 (2006).
13
[14] Yu X., Pan L., Ying G., Kookana R.S., Enhanced and Irreversible Sorption of Pesticide Pyrimethanil by Soil Amended with Biochars, J. Environ. Sci., 22(4), 615-620 (2010).
14
[15] Chen D.Z., Zhang J.X., Chen J.M., Adsorption of Methyl Tert-butyl Ether Using Granular Activated Carbon: Equilibrium and Kinetic Analysis, Int. J. Env. Sci. Tech., 7(2):235-242 (2010).
15
[16] Wu Z., Li S., Wan J., Wang Y., Cr(VI) Adsorption on an Improved Synthesised Cross-Linked Chitosan Resin, J. Mol. Liq., 170, 25-29 (2012).
16
[17] Yan H., Zhang W., Kan X., Dong L., Jiang Z., Li H., Yang H., Cheng R., Sorption of Methylene Blue by Carboxymethyl Cellulose and Reuse Process in a Secondary Sorption, Colloids Surf., A., 380(1-3): 143-151 (2011).
17
[18] Ho Y.S., McKay G., Sorption of Dye from Aqueous Solution by Peat, Chem. Eng. J., 70(2): 115-124 (1998).
18
[19] D’Arcy R.L., Watt I.C., 1970. Analysis of Sorption Isotherms of Non-Homogeneous Sorbents, Trans. Faraday Soc., 66: 1236-1245 (1970).
19
[20] Laus R., Costa T.G., Szpoganicz B., Fávere V.T., Adsorption and Desorption of Cu(II), Cd(II) and Pb(II) Ions Using Chitosan Crosslinked with Epichlorohydrin-Triphosphate as the Adsorbent, J. Hazard. Mater., 183(1-3): 233-241 (2010).
20
[21] Swiatkowski A., Pakula M., Biniak S., Walczyk M., Influence of the Surface Chemistry of Modified Activated Carbon on Its Electrochemical Behaviour in the Presence of Lead(II) Ions, Carbon, 42(15): 3057-3069 (2004).
21
[22] Lodeiro P., Barriada J.L., Herrero R., Sastre de Vicente M.E., The Marine Macroalga Cystoseira Baccata as Biosorbent for Cadmium(II) and Lead(II) Removal: Kinetic and Equilibrium Studies, Environ. Pollut., 142(2): 264-273 (2006).
22
[23] Acharya J., Sahu J.N., Mohanty C.R., Meikap B.C, Removal of Lead(II) from Wastewater by Activated Carbon Developed from Tamarind Wood by Zinc Chloride Activation, Chem. Eng. J., 149(1-3): 249-262 (2009).
23
[24] Chen X., Chen G., Chen L., Chen Y., Lehmann J., McBride M.B., Hay A.G., Adsorption of Copper and Zinc by Biochars Produced from Pyrolysis of Hardwood and Corn Straw in Aqueous Solution, Bioresour. Technol., 102(19): 8877-8884 (2011).
24
[25] Chen S., Yue Q., Gao B., Xu X., Equilibrium and Kinetic Adsorption Study of the Adsorptive Removal of Cr(VI) Using Modified Wheat Residue, J. Colloid Interface Sci., 349(1): 256-264 (2010).
25
[26] Sheela T., Nayaka Y.A., Viswanatha R., Basavanna S., Venkatesha T.G., Kinetics and Thermodynamics Studies on the Adsorption of Zn(II), Cd(II) and Hg(II) From Aqueous Solution Using Zinc Oxide Nanoparticles
26
ORIGINAL_ARTICLE
Attenuation Kinetics and Desorption Performance of artocarpus altilis Seed Husk for Co (II), Pb (II) and Zn (II) Ions
The potential of Bread Fruit (artocarpus altilis)Seed Husk (BFSH) as low-cost biosorbent for the removal of Pb (II), Zn (II) and Co (II) ions from aqueous solution was investigated. The adsorbent was characterized by the Fourier Transform InfraRed (FT-IR)spectroscopy, Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). The batch methodology was utilized to determine the effect of pH, metal ion concentration, adsorbent dose, contact time and temperature on biosorption. Data generated were fitted into appropriate isotherm, kinetic and thermodynamic models. The effect of pH showed an increase in adsorption of metals with an increase in pH and an optimum pH of 5.0 was obtained for Pb (II), while 6.0 were obtained for Co (II) and Zn (II) ions biosorption. An equilibrium sorption contact time of 30, 40 and 60 min was obtained for Co (II), Zn (II) and Pb (II) ions respectively. The biosorption of metal ions was in the order Co (II) > Pb (II) > Zn (II). In general, the Freundlich model provided a better fit than the Langmuir, Tempkin, and Dubinin-Radushkevich isotherm models with R2 values greater than 0.9. The pseudo-first-order kinetic model was applicable in the adsorption of Pb (II) and Zn (II) ions while the pseudo-second-order model provided the best fit for Co (II) ion adsorption. The adsorption mechanism was found to be controlled by the liquid film diffusion model (R2>0.9) rather than the intraparticle diffusion model (R2<0.9). Thermodynamics revealed a spontaneous, feasible, exothermic physisorption process and over 60% of the metal ions were desorbed using 0.1M HCl and 0.1M NaOH as eluent. The results showed that BFSH could be utilized as low cost adsorbent for the removal of toxic heavy metals from solution.
https://ijcce.ac.ir/article_30205_cbfedeb72392807c081b01d774ef530c.pdf
2018-06-01
171
186
10.30492/ijcce.2018.30205
Biomass
Biosorption
Breadfruit
seed husk
heavy metals
Isotherm
Kinetics
Kovo Godfrey
Akpomie
kovo.akpomie@unn.edu.ng
1
Department of Pure & Industrial Chemistry, University of Nigeria, Nsukka, NIGERIA
LEAD_AUTHOR
Linda Obiageli
Eluke
lyneluke@gmail.com
2
Department of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, NIGERIA
AUTHOR
Vincent Ishmael Egbulefu
Ajiwe
vieajiwe@gmail.com
3
Department of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, NIGERIA
AUTHOR
Christopher Onyemeziri
Alisa
coalisa2002@gmail.com
4
Department of Chemistry, Federal University of Technology, Owerri, NIGERIA
AUTHOR
[1] Kobya M., Demirabis E., Senturk E., Ice M., Adsorption of Heavy Metals Ions From Aqueous Solution by Activated Carbon Prepared from Apricot Stone, Bioresource Technol., 96: 1518-1521 (2005).
1
[2] Dawodu F.A., Akpomie K.G., Ogbu I.C., Application of Kinetic Rate Equations on the Removal of Copper (II) Ions by Adsorption unto Aloji Kaolinite Clay Mineral, Inter. J. Multidisc. Sci. Eng., 3:21-26 (2012).
2
[3] Barka N., Abdennouri M., Makhfouk M.E., Qouezal S., Biosorption Characteristics of Cadmium and Lead Onto eco-Friendly Dried Cactus (opuntia ficus indica) Cladodes, J. Environ. Chem. Eng., 1: 144-149 (2013).
3
[4] Egila J.N., Dauda B.E.N., Jimoh T., Biosorptive Removal of Cobalt (II) Ions from Aqueous Solution by amaranthus hydidus L. Stalk Waste, African J. Biotechnol., 9: 8192-8198 (2010).
4
[5] Etukudoh A.B., Akpomie K.G., Obi N.D., Chimezie P.E., Agbo A.E., The Potential of a Natural Clay Mineral (nsu clay) for the Adsorption of Lead (II) Ions From Aqueous Stream, Der Pharma Chemica, 8: 9-15 (2016).
5
[6] Dawodu F.A., Akpomie K.G., Simultaneous Adsorption of Ni (II) and Mn (II) Ions From Aqueous Solution unto Nigerian Kaolinite Clay, J. Mater. Res. Technol., 3:129-141 (2014).
6
[7] Abuh M.A., Akpomie K.G., Nwagbara N.K., Nwafor E.C., Equilibrium Isotherm Studies for the Biosorption of Cu (II) and Zn (II) From Aqueous Solution by Unmodified Lignocellulosic Fibrous Layer of Palm Tree Trunk: Single Component System, Inter. J. Eng. Sci. Invent., 2: 27 – 35 (2013).
7
[8] Liang S., Guo X., Feng N., Tian Q., Isotherm, Kinetics and Thermodynamics Studies of Adsorption of Cu(II) From Aqueous Solution by Mg2+/ K+ Type Orange Peel Adsorbents, J. Hazard. Mater. 174: 756-762 (2010).
8
[9] Nuhoglu Y., Malkoc E., Thermodynamics and Kinetic Studies for Environmentally Friendly Ni (II) Biosorption Using Waste Pomace of Olive Oil Factory, Bioresource Technol., 100: 2375-2380 (2009).
9
[10] Das B., Mondal N.K., Calcareous Soil as a New Adsorbent Toremove Lead From Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Study’ Univ. J. Environ. Res., 1: 515-530 (2011).
10
[11] Akpomie K.G., Dawodu F.A., Efficient Abstraction of Nickel (II) and Manganese (II) From Solution unto an Alkaline-Modified Montmorillonite, J. Taibah Uni. Sci., 8: 343-356 (2014).
11
[12] Santamarina J.C., Klein K.A., Wang Y.H., Prencke E., Specific Surface: Determination and Relevance, Can. Geotech. J., 39: 233-241 (2002).
12
[13] Mall D.I., Srivastava V.C., Agarwal N.K., Removal of Orange-G and Methyl Violet Dyes by Adsorption onto Bagasse Fly Ash-Kinetic Study and Equilibrium Isotherm Analysis, Dyes and Pigments 69: 210-223 (2006).
13
[14] ASTM standard. Standard Test Method for Moisture, Total ash and Volatile Content in Activated Carbon, Philadelphia (PA) (1999).
14
[15] Ekpete O.A., Horsfall J.M., Preparation and Characterization of Activated Carbon From Fluted Pumpkin Stem Waste, Res. J. Chem. Sci., 3: 10-17 (2011).
15
[16] Imamoglu M., Tekir O., Removal of Copper (II) and Lead (II) Ions From Aqueous Solution by Adsorption on Activated Carbon from a New Precursor Hazelnut Husks, Desalination, 228: 108-113 (2008).
16
[17] Taffarel S.R., Rubio J., On the Removal of Manganese Ions by Adsorption unto Natural and Activated Chilean Zeolites, Miner. Eng., 22: 336-343 (2009).
17
[18] Unuabonah E.I., Adebowale K.O., Olu-Owolabi B.I., Yang L.Z., Kong L.X., Adsorption of Pb (II) and Cd (II) from Aqueous Solution unto Sodium Tetraborate Modified Kaolinite Clay: Equilibrium and Thermodynamic Studies, Hydrometallurgy, 93:1-9 (2008).
18
[19] Akpomie K.G., Dawodu F.A., Treatment of an Automobile Effluent from Heavy Metal Contamination by an Eco Friendly Montmorillonite, J. Advanced Res., 6: 1003-1013 (2015).
19
[20] Kumar A., Prasad B., Mishra I.M., Isotherm and Kinetic Studies for Acrylic Acid Removal Using Powdered Activated Carbon, J. Hazard. Mater., 176: 774-783 (2010).
20
[21] Guler U.A., Sarioglu M., Single and Binary Biosorption of Cu (II), Ni (II) and Methylene Blue by Raw and Pretreated Spirogyra Sp: Equilibrium and Kinetic Modeling, J. Environ. Chem. Eng., 1: 369-377 (2013).
21
[22] Yadav S.K., Singh D.K., Sinha S., Chemical Carbonization of Papaya Seed Originated Charcoals for Sorption of Pb (II) From Aqueous Solution, J. Environ. Chem. Eng., 2:9-19 (2014).
22
[23] Tsai W.T., Chen H.R., Removal of Malachite Green From Aqueous Solution Using Low Cost Chlorella Based Biomass, J. Hazard. Mater. 175: 844-849 (2010).
23
[24] Erdem E., Karapinar N., Donat R., The Removal of Heavy Metal Cations by Natural Zeolites, J. Colloid Interfac. Sci. 280:309-314 (2004).
24
[25] Igberase E., Osifo P., Ofomaja A., The Adsorption of Cu (II) Ions by Polyaniline Grafted Chitosan Beads From Aqueous Solution: Equilibrium, Kinetic and Desorption Studies, J. Environ. Chem. Eng., 2: 362-369 (2014).
25
[26] Gautam R.K., Mudhoo A., Lofrano G., Chattopadhyaya M.G., Biomass Derived Biosorbents for Metal Ions Sequestration: Adsorbent Modification and Activation Methods and Adsorbent Regeneration, J. Environ. Chem. Eng., 2: 239-259 (2014).
26
[27] Langmuir I., The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum, J. Amer. Chem. Soc., 40: 1361-1403 (1918).
27
[28] Nimmala A.R., Lakshimipathy R., Sarada N.C., Application of citrullus lanatus rind as Biosorbent for Removal of Trivalent Chromium From Aqueous Solution, Alexand. Eng. J., 53: 969-975 (2014).
28
[29] Yang L., Chen P., Biosorption of Hexavalent Chromium onto Raw and Chemically Modified Sargassum sp, Bioresource Technol., 213: 208-216 (2007).
29
[30] Freundlich H.M.F., Over the Adsorption in Solution. J. Phys. Chem., 57: 385-471 (1906).
30
[31] Argun M. E, Dursun S, Ozdemir C, Karatas M., Heavy Metal Adsorption by Modified Oak Sawdust: Thermodynamics and Kinetics, J. Hazard. Mater., 141: 77-85 (2007).
31
[32] Temkin M.I., Pyzhev V., Kinetics of Ammonia Synthesis on Promoted Iron Catalyst, Acta. Physicochem., 12: 327-400 (1940).
32
[33] Akpomie K.G., Dawodu F.A., Adebowale K.O., Mechanism on the Sorption of Heavy Metals From Binary Solution by a Low Cost Montmorillonite and Its Desorption Potential, Alexand. Eng. J., 54: 757-767 (2015).
33
[34] Meitei M.D., Prasad M.N., Lead (II) and Cadmium (II) Biosorption on Spirodela Polyrhiza (L) Schleiden Biomass, J. Environ. Chem. Eng., 1: 200-207 (2013).
34
[35] Li Y., Xia B., Zhao Q., Liu F., Zhang P., Du Q., Wang D., Li D., Wang Z., Xia Y., Removal of Copper Ions From Aqueous Solution by Calcium Alginate Immobilized Kaolin, J. Environ. Sci., 23: 404-411 (2011).
35
[36] Ahluwalia S.S., Goyal D., Microbial and Plant Derived Biomass for Removal of Heavy Metals From Wastewater, Bioresource Technol., 98: 2243-2257 (2007).
36
[37] Nomanbhay S.M., Palanisamy K., Removal of Heavy Metals From Industrial Wastewaters Using Chitosan Coated Oil Palm Shell Charcoal, Elect. J. Biotechnol., 8: 43-53 (2005).
37
[38] Shi Z., Zou P., Guo M., Yao S., Adsorption Equilibrium and Kinetics of Lead ion Onto Synthetic Ferrihydrites, Iran. J. Chem. Chem. Eng. (IJCCE), 34(3): 25-32 (2015).
38
[39] Marziyeh S.M., Somajeh R., Mahmoud T., Cadmium Removal From Aqueous Solution Using Saxaul Tree Ash, Iran. J. Chem. Chem. Eng. (IJCCE), 35(3): 45-52 (2016).
39
[40] Mandal S., Sahu M.K., Patel R.K., Adsorption Studies of Arsenic (III) Removal From Water by Zirconium Polycrylamide Hybrid Materials, Water Res. Ind., 4: 51-67 (2013).
40
[41] Amer M.W., Khalil F.I., Awwad A.M., Adsorption of Lead, Zinc and Cadmium Ions on Polyphosphate-Modified Kaolinite, J. Environ. Chem. Ecotoxicol., 2: 001-008 (2010).
41
[42] Gupta V.K., Jain C.K., ImranA., Sharma M., Saini V.K., Removal of Cadmium and Nickel From Wastewater Using Bagasse fly Ash- a Sugar Industry Waste, Water Research, 37: 4038-4044 (2003).
42
[43] Omar E.A., Neama A.R., Maha M.E., A Study of the Removal Characteristics of Heavy Metals from Wastewater by Low Cost Adsorbents, J. Advance. Res., 2: 297-303 (2011).
43
[44] Zenasni M.A., Benfarhi S., Merlin A., Molina S., Meroufel B., Adsorption of Cu (II) on Maghnite from Aqueous Solution: Effect of pH, Initial Concentration, Interaction Time and Temperature, Natural Science, 4: 856-868 (2012).
44
[45] Guerra D.J.L., Mello I., Resende R., Silva R., Application as adsorbents of Natural and Functionalized Brazilian Bentonite in Pb (II) Adsorption: Equilibrium, Kinetic, pH and Thermodynamic Effects, Water Res. Ind., 4: 32-50 (2013).
45
[46] Ekere N.R., Agwogie A.B., Ihedioha J.N., Studies of Biosorption of Pb, Cd and Cu from Aqueous Solution Using Adasonia Digita Root Powders, Inter. J. Phytoremed., 18: 116-125 (2015).
46
[47] Nwadiogbu J.O., Okoye P.A.C., Ajiwe V.I.E, Nnaji N.J.N., Hydrophobic Treatment of Corn Cob by Acetylation: Kinetic and Thermodynamic Studies, J. Environ. Chem. Eng., 2: 1699-1704 (2014).
47
[48] Vinod V.T.P., Sashidhar R.B., Sukumar A.A., Competitive Adsorption of Toxic Heavy Metal Contaminants by Gum Kondagogu: a Natural Hydrocolloid, Colloids Surf. B, 75: 490-495 (2010).
48
ORIGINAL_ARTICLE
Microencapsulation of Butyl Palmitate in Polystyrene-co-Methyl Methacrylate Shell for Thermal Energy Storage Application
MicroEncapsulated Phase Change Materials (MEPCM) are green materials which could be used for thermal energy saving applications in buildings as a non-pollutant method for environmental. PCMs could passively reduce peak cooling loads in hot seasons because of their high energy storage capacities at a constant temperature. Purpose of this paper is manufacturing Microencapsulated PCM (MPCM) products for use in gypsum wall applications, with the aim of expanding in use from butyl palmitate in polystyrene-co-methyl methacrylate shells. This type of microencapsules synthesis had not been previously described in the literature, nor patented. PCM (butyl palmitate) can be encapsulated by these processes and in the form of core-shell structure with use of different stirring rates and hybridized suspension agents. SEM micrographs of microencapsulated MPCMs show that spherical microcapsules were obtained with a narrow PSD (0-150 μm) with a stirring rate of 800 rpm and hybridized suspension agent (TCP). About, 65 % (wt.) of MPCMs was butyl palmitate with 70.6 J/g of latent heat energy which indicates the applicability of this synthesis MPCMs for thermal energy storage in gypsum walls. Our synthesis results on the basis of suspension like polymerization process show good encapsulation efficiency with proper thermal energy storage capacity in gypsum walls.
https://ijcce.ac.ir/article_32648_06d3de4f784c9c95e449599f144f320f.pdf
2018-06-01
187
194
10.30492/ijcce.2018.32648
Phase Change Materials
Microencapsulation
Suspension-like
Styrene
Methyl methacrylate
Behrouz
Mohammadi Khoshraj
b.mohammadi@tpco.ir
1
R&D Center of Tabriz Petrochemical Company, P.O.Box: 51745-354, Tabriz, I.R. IRAN
LEAD_AUTHOR
Fardin
Seyyed Najafi
fsnajafi@tpco.ir
2
R&D Center of Tabriz Petrochemical Company, P.O.Box: 51745-354, Tabriz, I.R. IRAN
AUTHOR
Jalal
Mohammadi Khoshraj
mohammadi@raberashidi.ac.ir
3
Rabe-Rashidi University, P.O.Box: 51749-69611, Tabriz, I.R. IRAN
AUTHOR
Heydar
Ranjbar
h.ranjbar@tpco.ir
4
R&D Center of Tabriz Petrochemical Company, P.O.Box: 51745-354, Tabriz, I.R. IRAN
AUTHOR
[1] Dwivedi V.K., Tiwari P., Tiwari S., “Importance of Phase Change Material (PCM) in Solar Thermal Applications: A Review”, Proceedings of the International Conference on Emerging Trends in Electrical, Electronics and Sustainable Energy Systems (ICETEESES), Sultanpur, India, 11–12 March (2016).
1
[2] Mehling H., Cabeza F., “Heat and Cold Storage with PCM”, Springer-Verlag Berlin Heidelberg (2008).
2
[3] Gkanas E.I., Grant D.M., Kzhouz M., Stuart A.D., Manickam K., Walker G.S., Efficient Hydrogen Storage in up-Scale Metal Hydride Tanks as Possible Metal Hydride Compression Agents Equipped with Aluminum Extended Surfaces, Int. J. Hydrog. Energy, 41: 10795–10810 (2016).
3
[4] Souayfane F., Fardoun F., Biwole P., Phase Change Materials (PCM) for Cooling Applications in Buildings: A Review, Energy Build., 129: 396–431 (2016).
4
[5] Thambidurai M., Panchabikesan K., Mohan K.N., Ramalingam V., Review on Phase Change Material Based Free Cooling of Buildings—The Way Toward Sustainability, J. Energy Storage, 4: 74–88 (2015).
5
[6] Kosny J., PCM-Enhanced Building Components— An Application of Phase Change Materials in Building Envelopes and Internal Structures; Springer International Publishing: Steinhausen, Switzerland, (2015).
6
[7] Graci, A.D., Cabeza L.F., Phase Change Materials and Thermal Energy Storage for Buildings, Energy Build., 103: 414–419 (2015).
7
[8] Lin W., Ma Z., Cooper P., Sohel M.I., Yang L., Thermal Performance Investigation and Optimization of Buildings with Integrated Phase Change Materials and Solar Photovoltaic Thermal Collectors, Energy Build., 116: 562–573 (2015).
8
[9] Zhou D., Zhao C.Y., Tian Y., Review on Thermal Energy Storage with Phase Change Materials (PCMs) in Building Applications, Appl. Energy, 92: 593-605 (2012).
9
[10] Dubey R., Shami T.C., Bhasker R., Microencapsulation Technology and Applications. Defence Science Journal, 59(1): 82-95 (2009).
10
[11] Sanchez L., Sanchez V., Lucas A., Carmona M., Rodriguez J.F., Microencapsulation of PCMs with a Polystyrene Shell, Colloid Polym. Sci., 285: 1377-1385 (2007).
11
[12] Sanchez L., Sanchez V., Lucas A., Carmona M., Rodriguez J.F., Influence of Operation Conditions on the Microencapsulation of PCMs by Means of Suspension-Like Polymerization, Colloid Polym. Sci., 286 (8-9): 1019-1027 (2008).
12
[13] Sanchez L., Rodriguez J. F., Romero A., Borreguero A.M., Carmona M., Sanchez P., Microencapsulation of PCMs with a Styrene-Methyl Methacrylate Copolymer Shell by Suspension-Like Polymerization, Chem. Eng. J., 157: 216–222 (2010).
13
[14] You M., Wang X., Zhang X., Zhang L., Wang J., Microencapsulated n-Octadecane with Styrene-Divinybenzene co-Polymer Shells, J. Polym. Res., 18: 49-58 (2010).
14
[15] Sanchez L., Tsavalas J., Sundberg D., Sanchez P., Rodriguez J.F., Synthesis and Characterization of Paraffin Wax Microcapsules with Acrylic Based Polymer Shells, Ind. Eng. Chem. Res., 49: 12204-12211 (2010).
15
[16] Sanchez L., Carmona M., De lucas A., Sanchez P., Rodriguez J.F., Scale-up of a Suspension-like Polymerization Process for the Microencapsulation of Phase Change Materials, J. Microencapsulation, 27(7): 583-593 (2010).
16
[17] Sanchez P., Sanchez-Fernandez M. V., Romero A., Rodriguez J.F., Sanchez-Silva L., Development of Thermo-Regulating Textiles Using Paraffin Wax Microcapsules, Thermochim Acta, 498: 16-21 (2010).
17
[18] Sanchez L., Lacasa E., Carmona M., De lucas A., Rodriguez J.F., Sanchez P., Applying an Experimental Design to Improve the Characteristics of Microencapsules Containing Phase Change Materials for Fabric Uses, Ind. Eng. Chem. Res., 47: 9783-9790 (2008).
18
[19] Ma Y., Sun S., Li J., Tang G., Preparation and Thermal Reliabilities of Microencapsulated Phase Change Materials with Binary Cores and Acrylate-Based Polymer Shells, Thermochimica Acta, 588: 38-46 (2014).
19
ORIGINAL_ARTICLE
Determination of Volumetric Mass Transfer Coefficient in Gas-Solid-Liquid Stirred Vessels Handling High Solids Concentrations: Experiment and Modeling
Rigorous analysis of the determinants of volumetric mass transfer coefficient (kLa) and its accurate forecasting are of vital importance for effectively designing and operating stirred reactors. Majority of the available literature is limited to systems with low solids concentration, while there has always been a need to investigate the gas-liquid hydrodynamics in tanks handling high solid loadings. Several models have been proposed for predicting kLa values, but the application of neuro-fuzzy logic for modelingkLa based on combined operational and geometrical conditions is still unexplored. In this paper, an ANFIS (adaptive neuro-fuzzy inference system) model was designed to map three operational parameters (agitation speed (RPS), solid concentration, superficial gas velocity (cm/s)) and one geometrical parameter (number of curved blades) as input data, to kLa as output data. Excellent performance of ANFIS’s model in predicting kLa values was demonstrated by various performance indicators with a correlation coefficient of 0.9941.
https://ijcce.ac.ir/article_34210_9bdd490572273e14174f5f153d7b7fef.pdf
2018-06-01
195
212
10.30492/ijcce.2018.34210
Artificial intelligence-based modeling
Adaptive neuro-fuzzy inference system
Artificial neural networks
Volumetric mass transfer coefficient
Stirred vessels
Meysam
Davoody
meysamdavoody@yahoo.com
1
Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
AUTHOR
Abdul Aziz
Abdul Raman
azizraman@um.edu.my
2
Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
LEAD_AUTHOR
Seyedali
Asgharzadeh Ahmadi
seyedali.asgharzadeh@gmail.com
3
Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
AUTHOR
Shaliza
Binti Ibrahim
shaliza@um.edu.my
4
Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
AUTHOR
Rajarathinam
Parthasarathy
rch@rmit.edu.au
5
School of Civil, Environmental, and Chemical Engineering, RMIT University, City Campus 3001, AUSTRALIA
AUTHOR
[1] Nienow A., Konno M., Bujalski W., Studies on Three-Phase Mixing: A Review and Recent Results, Chemical Engineering Research & Design, 64(1): 35-42 (1986).
1
[2] Frijlink J., Bakker A., Smith J., Suspension of Solid Particles with Gassed Impellers, Chemical Engineering Science, 45(7): 1703-1718 (1990).
2
[3] Rewatkar V.B., Rao K.R., Joshi J.B., Critical Impeller Speed for Solid Suspension in Mechanically Agitated Three-Phase Reactors. 1. Experimental Part, Industrial & Engineering Chemistry Research, 30(8): 1770-1784 (1991).
3
[4] Dutta N., Pangarkar V., Critical Impeller Speed for Solid Suspension in Multi‐Impeller Three Phase Agitated Contactors, The Canadian Journal of Chemical Engineering, 73(3): 273-283 (1995).
4
[5] Saravanan K., Patwardhan A., Joshi J., Critical Impeller Speed for solid Suspension in Gas Inducing Type Mechanically Agitated Contactors, The Canadian Journal of Chemical Engineering, 75(4): 664-676 (1997).
5
[6] Doran P.M., Design of Mixing Systems for Plant Cell Suspensions in Stirred Reactors, Biotechnology Progress, 15(3): 319-335 (1999).
6
[7] Dohi N., et al., Suspension of Solid Particles in Multi‐Impeller Three‐Phase Stirred Tank Reactors, The Canadian Journal of Chemical Engineering, 79(1): 107-111 (2001).
7
[8] Fishwick R., Winterbottom J., Stitt E., Effect of Gassing Rate on Solid–Liquid Mass Transfer Coefficients and Particle Slip Velocities in Stirred Tank Reactors, Chemical Engineering Science, 58(3): 1087-1093 (2003).
8
[9] Kluytmans J., et al., Mass Transfer in Sparged and Stirred Reactors: Influence of Carbon Particles and Electrolyte, Chemical Engineering Science, 58(20): 4719-4728 (2003).
9
[10] Martín M., Montes F.J., Galán M.A., Mass Transfer Rates From Bubbles in Stirred Tanks Operating with Viscous Fluids, Chemical Engineering Science, 65(12): 3814-3824 (2010).
10
[11] Danckwerts P.V., Lannus A., Gas‐Liquid Reactions, Journal of The Electrochemical Society, 117(10): 369C-370C (1970).
11
[12] Van't Riet K., Review of Measuring Methods and Results in Nonviscous Gas-Liquid Mass Transfer in Stirred Vessels, Industrial & Engineering Chemistry Process Design and Development, 18(3): 357-364 (1979).
12
[13] Beenackers A., Van Swaaij W., Mass Transfer in Gas-Liquid Slurry Reactors, Chemical Engineering Science, 48(18): 3109-3139 (1993).
13
[14] Nienow A.W., “Aeration, Biotechnology”, In: Kirk-Othmer Encyclopedia of Chemical Technology, (2003).
14
[15] Puthli M.S., Rathod V.K., Pandit A.B., Gas–Liquid Mass Transfer Studies with Triple Impeller System on a Laboratory Scale Bioreactor, Biochemical Engineering Journal, 23(1): 25-30 (2005).
15
[16] Garcia-Ochoa F., Gomez E., Bioreactor Scale-up and Oxygen Transfer Rate in Microbial Processes: an Overview, Biotechnology Advances, 27(2): 153-176 (2009).
16
[17] Nigam K.D., Schumpe A., “Three-Phase Sparged Reactors”, (1996).
17
[18] Conway K., Kyle A., Rielly C.D., Gas–Liquid–Solid Operation of a Vortex-Ingesting Stirred Tank Reactor, Chemical Engineering Research and Design, 80(8): 839-845 (2002).
18
[19] Mehta V., Sharma M., Mass Transfer in Mechanically Agitated Gas-Liquid Contactors, Chemical Engineering Science, 26(3): 461-479 (1971).
19
[20] Gentile F., et al., Some Effects of Particle Wettability in Agitated Solid‐Gas‐Liquid Systems: Gas‐Liquid Mass Transfer and the Dispersion of Floating Solids, The Canadian Journal of Chemical Engineering, 81(3‐4): 581-587 (2003).
20
[21] Kawase Y., et al., Gas-Liauid Mass Transfer in Three‐Phase Stirred Tank Reagors: Newtonian and Non‐Newtonian Fluids, The Canadian Journal of Chemical Engineering, 75(6): 1159-1164
21
[22] Tagawa A., Dohi N., Kawase Y., Volumetric Gas− Liquid Mass Transfer Coefficient in Aerated Stirred Tank Reactors with Dense Floating Solid Particles, Industrial & Engineering Chemistry Research, 51(4): 1938-1948 (2011).
22
[23] Robinson C.W., Wilke C.R., Oxygen Absorption in Stirred Tanks: A Correlation for Ionic Strength Effects, Biotechnology and Bioengineering, 15(4): 755-782 (1973).
23
[24] Robinson C.W., Wilke C.R., Simultaneous Measurement of Interfacial Area and Mass Transfer Coefficients for a Well—Mixed Gas Dispersion in Aqueous Electrolyte Solutions, AIChE Journal, 20(2): 285-294 (1974).
24
[25] Hassan I.T.M., Robinson C.W., Oxygen Transfer in Mechanically Agitated Aqueous Systems Containing Dispersed Hydrocarbon, Biotechnology and Bioengineering, 19(5): 661-682 (1977).
25
[26] Hassan I.T.M., Robinson C.W., Measurement of Bubble Size Distribution in Turbulent Gas-Liquid Dispersions, Chemical Engineering Research & Design, : 62- (1984).
26
[27] Kralj F., Sinc̆ić D., Hold-up and Mass Transfer in a Two- and Three-Phase Stirred Tank Reactor, Chemical Engineering Science, 39(3): 604-607 (1984).
27
[28] Iglesias Nuno A., et al., Optimisation of Fishing Predictions by Means of Artificial Neural Networks, Anfis, Functional Networks and Remote Sensing Images, Expert Systems with Applications, 29(2): 356-363 (2005).
28
[29] Prakash Maran J., et al., Artificial Neural Network and Response Surface Methodology Modeling in Mass Transfer Parameters Predictions During Osmotic Dehydration of Carica Papaya L., Alexandria Engineering Journal, (2013).
29
[30]. Lertworasirikul S., Saetan S., Artificial Neural Network Modeling of Mass Transfer During Osmotic Dehydration of Kaffir Lime Peel, Journal of Food Engineering, 98(2): 214-223 (2010).
30
[31] Garcı́a-Ochoa F., Castro E.G., Estimation of Oxygen Mass Transfer Coefficient in Stirred Tank Reactors Using Artificial Neural Networks, Enzyme and Microbial Technology, 28(6): 560-569 (2001).
31
[32] Fu K., et al., Experimental Study on Mass Transfer and Prediction Using Artificial Neural Network for CO2 Absorption into Aqueous DETA, Chemical Engineering Science, 100(0): 195-202 (2013).
32
[33] Ochoa-Martínez C.I., Ayala-Aponte A.A., Prediction of Mass Transfer Kinetics During Osmotic Dehydration of Apples Using Neural Networks, LWT - Food Science and Technology, 40(4): 638-645 (2007).
33
[34] Wieland D., Wotawa F., Wotawa G., From Neural Networks to Qualitative Models in Environmental Engineering, Computer-Aided Civil and Infrastructure Engineering, 17(2): 104-118 (2002).
34
[35] Jang J.S.R., ANFIS: Adaptive-Network-Based Fuzzy Inference System, IEEE Transactions on Systems, Man, and Cybernetics, 23: 665-685 (1993).
35
[36] Rahmanian B., et al., Prediction of MEUF Process Performance Using Artificial Neural Networks and ANFIS Approaches, Journal of the Taiwan Institute of Chemical Engineers, 43(4): 558-565 (2012).
36
[37] Mehrabi M., Pesteei S.M., Pashaee G T., Modeling of Heat Transfer and Fluid Flow Characteristics of Helicoidal Double-Pipe Heat Exchangers Using Adaptive Neuro-Fuzzy Inference System (ANFIS), International Communications in Heat and Mass Transfer, 38(4): 525-532 (2011).
37
[38] Rezaei E., et al., Modeling the Free Convection Heat Transfer in a Partitioned Cavity Using ANFIS, International Communications in Heat and Mass Transfer, 39(3): 470-475 (2012).
38
[39] Mullai P., et al., Experiments and ANFIS Modelling for the Biodegradation of Penicillin-G Wastewater Using Anaerobic Hybrid Reactor, Bioresource Technology, 102(9): 5492-5497 (2011).
39
[40] Khazraee S.M., Jahanmiri A.H., Composition Estimation of Reactive Batch Distillation by Using Adaptive Neuro-Fuzzy Inference System, Chinese Journal of Chemical Engineering, 18(4): 703-710 (2010).
40
[41] Heidari E., Ghoreishi S.M., Prediction of Supercritical Extraction Recovery of EGCG Using Hybrid of Adaptive Neuro-Fuzzy Inference System and Mathematical Model, The Journal of Supercritical Fluids. 82(0): 158-167 (2013).
41
[42] Yetilmezsoy K., Fingas M., Fieldhouse B., An Adaptive Neuro-Fuzzy Approach for Modeling of Water-in-Oil Emulsion Formation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 389(1–3): 50-62 (2011).
42
[43] Moon J.W., et al., Comparative Study of Artificial Intelligence-Based Building Thermal Control Methods – Application of Fuzzy, Adaptive Neuro-Fuzzy Inference System, and Artificial Neural Network, Applied Thermal Engineering, 31(14–15): 2422-2429 (2011).
43
[44] Varol Y., et al., Prediction of Flow Fields and Temperature Distributions Due to Natural Convection in a Triangular Enclosure Using Adaptive-Network-Based Fuzzy Inference System (ANFIS) and Artificial Neural Network (ANN), International Communications in Heat and Mass Transfer, 34(7): 887-896 (2007).
44
[45] Rahman M.S., Rashid M.M., Hussain M.A., Thermal Conductivity Prediction of Foods by Neural Network and Fuzzy (ANFIS) Modeling Techniques, Food and Bioproducts Processing, 90(2): 333-340 (2012).
45
[46] Van Weert G., Van Der Werff D., Derksen J.J., Transfer of O2 From Air to Mineral Slurries in a Rushton Turbine Agitated Tank, Minerals Engineering, 8(10): 1109-1124 (1995).
46
[47] Guillard F., Trägårdh C., Mixing in Industrial Rushton Turbine-Agitated Reactors under Aerated Conditions, Chemical Engineering and Processing: Process Intensification, 42(5): 373-386 (2003).
47
[48] Yapici K., et al., Numerical investigation of the Effect of the Rushton Type Turbine Design Factors on Agitated Tank Flow Characteristics, Chemical Engineering and Processing: Process Intensification, 47(8): 1340-1349 (2008).
48
[49] Taghavi M., et al., Experimental and CFD Investigation of Power Consumption in a Dual Rushton Turbine Stirred Tank, Chemical Engineering Research and Design, 89(3): 280-290 (2011).
49
[50] Wu H., Arcella V., Malavasi M., A Study of Gas–Liquid Mass Transfer in Reactors with Two Disk Turbines, Chemical Engineering Science, 53(5): 1089-1095 (1998).
50
[51] Ochieng A., et al., Mixing in a Tank Stirred by a Rushton Turbine at a Low Clearance, Chemical Engineering and Processing: Process Intensification, 47(5): 842-851 (2008).
51
[52] Nienow A.W., Gas-Liquid Mixing Studies: A Comparison of Rushton Turbine with Some Modern Impellers, Trans, IChemE, 74: 417-423 (1996).
52
[53] Van't Riet K., Smith J.M., TheBehaviors of Gas-Liquid Mixtures Near Rushton Turbine Blades, Chemical Engineering Science, 28: 1031-1037 (1993).
53
[54] Van't Riet K., Boom J.M., Smith J.M., Power Consumption, Impeller Coalescence and Recirculation in Aerated Vessels, Chemical Engineering Research and Design, 54: 124-131 (1976).
54
[55] Warmoeskerken M.M.C.G., Smith J.M., The Hallow Blade Agitator for Dispersion and Mass Transfer, Chemical Engineering Science, 67: 193-198 (1989).
55
[56] McCulloch W.S., Pitts W., A Logical Calculus of the Ideas Immanent in Nervious Activity, Bulletin of Mathematical Biophysics, 9: 127-147 (1943).
56
[57] Duranton M., Image Processing by Neural Networks, Micro IEEE, 12-19 (1996).
57
[58] Marinai S., Artificial Neural Networks for document Analysis and Recognition, IEEE Transactions on Pattern Analysis and Machine Intelligence, 7: 23-35 (2005).
58
[59] Zhenyuan W., Yilu L., Neural Network and Expert System Diagnose Transformer Faults, IEEE Computer Applications in Power, 12: 50-55 (2000).
59
[60] Abu-Mostafa Y.S., Financial Model Calibration Using Consistency Hints, IEEE Transactions on Neural Networks, 12: 791-808 (2001).
60
ORIGINAL_ARTICLE
Beneficiation of Low-Grade Laterite Nickel by Calcination-Magnetic Separation Method
In this research, Effect of thermal treatment on beneficiation of low-grade laterite nickel by calcination-magnetic separation method was studied. In order to determine the components and elements of the sample, to recognize the main and minor minerals and their bond, and phase transformation caused by thermal treatment, Chemical analysis (XRF and ICP), microscopic studies and XRD analysis were done, respectively. SEM analysis was done to study the content of nickel and other minerals. In order to determine the phase transformation of the sample because of calcination treatment, thermal analysis of DTA/TG and XRD analysis, before and after of calcination were done. Wet magnetic separation tests with two methods of calcination-magnetic separation and only magnetic separation were done on the sample and the results in grade and recovery of nickel concentrate were compared. According to results, nickel content in the sample was0.94%. Main minerals of laterite sample were Hematite, Goethite, Quartz, and dolomite and minor minerals were Magnetite and minerals of serpentine group. Furthermore, there is no independent nickel mineral in the sample. SEM studies declared that nickel was substituted in iron-containing minerals (Hematite and Goethite). XRD and thermal analysis (DTA/TG) showed that at 350 °C, Goethite transformed to Hematite and at 750 °C, Hematite transformed widely to Magnetite. Calcination of feed at 750°C followed by wet magnetic separation with the magnetic field of 6000 Gauss in comparison with alone magnetic separation caused an increase in recovery and grade of magnetic concentrate to 12.7% and 0.41%, respectively. Results showed that an increase in temperature of more than 750 °C, caused a decrease in recovery and grade of nickel in magnetic concentrate.
https://ijcce.ac.ir/article_28221_128ddaa445424635a5e4f82bb8233b53.pdf
2018-06-01
213
221
10.30492/ijcce.2018.28221
Phase transformation
Calcination
Nickel laterite
Magnetic separation
Parvane
Razi
razi_parvaneh@yahoo.com
1
Department of Mine Engineering, Imam Khomeini International University (IKIU), P.O. Box 34148-96818 Qazvin, I.R. IRAN
AUTHOR
Rahman
Ahmadi
r.ahmadi32@gmail.com
2
Department of Mine Engineering, Imam Khomeini International University (IKIU), P.O. Box 34148-96818 Qazvin, I.R. IRAN
LEAD_AUTHOR
[1] Yang J., Zhang G., Ostrovski O., Jahanshahi Sh., Changes in an Australian Laterite ore in the Process of Heat Treatment, Minerals Engineering, 54: 110-115(2013).
1
[2] Abedini A., Calagari A.A., The mineralogy and Geochemistry of Permian Lateritic Ores in East of Shahindezh, West-Azarbaidjan Province, Iranian Society of Crystallography and Mineralogy, 20(3): 59-73(2012).
2
[3] Dalvi A., Bacon G., “The Past and the Future of Nickel Laterites”, PDAC 2004 – International Convention, Trade Show & Investors Exchange, 7-10 March (2004).
3
[4] King M., “Nickel Laterite Technology - Finally a New Dawn”, JOM, 35-39(2005).
4
[5] Onodera J., Inoue T., Imaizumi T., Attempts at the Beneficiation of Lateritic Nickel Ore, International Journal of Mineral Processing, 19: 25-42(1987).
5
[6] Li J., X., Hu Q., Wang Z., Zhou Y., Zheng J., Liu W., Li, L., Effect of Pre-Roasting on Leaching of Laterite, Hydrometallurgy. 99(2):84-88(2009).
6
[7] Valix M., Cheung W.H., Study of Phase Transformation of Laterite Ores at High Temperature, Minerals Engineering, 15:607-612(2002).
7
[8] Sedigh M., “Recovery of Nickel from Fars-Bavanat Laterite Reserve”, Postgraduate Thesis, Engineering Faculty, University of Tehran(2013).
8
[9] Buyukakinci E., Topkaya Y.A., Extraction of Nickel from Lateritic Ores at Atmospheric Pressure with Agitation Leaching, Hydrometallurgy, 97: 33-38 (2009).
9
[10] Rhamdhani M.A., Hayes P.C., Jak E., Nickel Laterite Part 2-Thermodynamic Analysis of Phase Transformations Occurring During Reduction Roasting, Mineral Processing and Extractive Metallurgy, 118(2009).
10
[11] Agacayak T., Zedef V., Dissolution Kinetics of a Lateritic Nickel ore in Sulphuric Acid Medium, Acta Montanistica Slovakia, 17:33-41(2012).
11
[12] Guo X., Shi W., Li D., Tian Q., Leaching Behavior of Metals from Limonitic Laterite ore by High Pressure Acid Leaching, Transactions of Nonferrous Metals Society of China, 21:191-195(2011).
12
[13] McDonald R.G., Whittington B.I., Atmospheric Acid Leaching of Nickel Laterites Review Part I. Sulphuric Acid Technologies, Hydrometallurgy, 91:35-55(2008).
13
[14] McDonald R.G., Whittington B.I, Atmospheric Acid Leaching of Nickel Laterites Review. Part II. Chloride and Bio-Technologies, Hydrometallurgy, 91:56-69(2008).
14
[15] Curlook W., “Direct Atmospheric Leaching of Saprolitic Nickel Laterites with Sulfuric Acid”, In: Imrie, W.P., Lane, D.M. (Eds.), International Laterite Nickel Symposium. TMS, Warrendale, 385–398(2004).
15
[16] Keskinkilic E., Pournaderit S., Geveci A., Topkaya Y., Calcination Characteristic of Llaterite Ores from the Central Region of Anatolia, The Journal of the Southern African Institute of Mining and Metallurgy. 112: 877-882(2012).
16
[17] Prasad P.S.R., Prasad K.S., Chaitanya V.K., Babu E.V.S.S.K., Sreedhar B., Murthy S.R., In-Situ FTIR Study on the Dehydration of Natural Goethite, Journal of Asian Earth Sciences, 27:503–511(2006).
17
[18] Walter D., Buxbaum G., Laqua W., The Mechanism of the Thermal Transformation from Goethite to Hematite, Journal of Thermal Analytical and Calorimetry, 63:733–748 (2001).
18
[19] Watari F., Delavignette P., Amelinckx S., Electron Microscopic Study of Dehydration Transformation. II, Journal of Solid State Chemistry, 29: 417–427(1979).
19
[20] Gualtieri A.F., Venturelli P., In-Situ Study of the Goethite-Hematite Phase Transformation by Real Time Synchrotron Powder Diffraction, American Mineralogist, 84: 895-904 (1999).
20
[21] Ozdemir O., Dunlop J.D. Intermediate Magnetite Formation During Dehydration of Goethite, Earth and Planetary Science Letters,177: 59-67 (2000).
21
[22] Zhu D.Q., Cui Y., Hapugoda S., Douglas J., Upgrading Low Nickel Content Laterite Ores Using Selective Reduction Followed by Magnetic Separation’, International Journal of Mineral Processing, : 106-109 (2012).
22
[23] Lebid M., Omari M., Effects of the Solvent and Calcination Temperature on LaFeO3Catalysts for Methanol Oxidation, Iranian Journal of Chemical and Chemical Engineering (IJCCE). 35(3):75-81(2016).
23
[24] Ilschner B., Grant N.J., Russell K.C., “Materials Beneficiation”, Springer-Verlag Inc., New York (1991).
24
ORIGINAL_ARTICLE
Reservoir Rock Characterization Using Wavelet Transform and Fractal Dimension
The aim of this study is to characterize and find the location of geological boundaries in different wells across a reservoir. Automatic detection of the geological boundaries can facilitate the matching of the stratigraphic layers in a reservoir and finally can lead to a correct reservoir rock characterization. Nowadays, the well-to-well correlation with the aim of finding the geological layers in different wells is usually done manually. For a rather moderate-size field with a large number of wells (e.g., 150 wells), the construction of such a correlation by hand is a quite complex, labor-intensive, and time-consuming. In this research, the wavelet transform as well as the fractal analysis, with the aid of the pattern recognition techniques, are used to find the geological boundaries automatically. In this study, we manage to use the wavelet transforms approach to calculate the fractal dimension of different geological layers. In this process, two main features, the statistical characteristics as well as the fractal dimensions of a moving window, are calculated to find a specific geological boundary from a witness well through different observation wells. To validate the proposed technique, it is implemented in seven wells of one of the Iranian onshore fields in the south-west of Iran. The results show the capability of the introduced automatic method in detection of the geological boundaries in well-to-well correlations.
https://ijcce.ac.ir/article_27647_8c29d0af3a845c44475e0957daf11a4e.pdf
2018-06-01
223
233
10.30492/ijcce.2018.27647
Wavelet transform
Fractal
Geological boundary
Pattern recognition
Well-log
Seyyed Mohammad Amin
Partovi
mohammadamin.partovi@modares.ac.ir
1
Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
AUTHOR
Saeid
Sadeghnejad
sadeghnejad@modares.ac.ir
2
Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Afshari S., Aminshahidy B., Pishvaie M.R., Well Placement Optimization Using Differential Evolution Algorithm, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 34(2): 109-116 (2015).
1
[2] Biniaz Delijani E., Pishvaie M.R., Bozorgmehry Boozarjomehry R., Distance Dependent Localization Approach in Oil Reservoir History Matching:
2
A Comparative Study, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 33(1): 75-91 (2014).
3
[3] Sadeghnejad S., Masihi M., Pishvaie M., Shojaei A., King P.R., Utilization of Percolation Approach
4
to Evaluate Reservoir Connectivity and Effective Permeability: A Case Study on North Pars Gas Field, Scientia Iranica. Volume, 18(6): 1391-1396 (2011).
5
[4] Sadeghnejad S., Masihi M., Pishvaie M., Shojaei A., King P.R., Estimating the Connected Volume of Hydrocarbon During Early Reservoir Life by Percolation Theory, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects,36(3): 301-308 (2010).
6
[5] Partovi S.M.A., Sadeghnejad S., Fractal Parameters and Well-Logs Investigation Using Automated Well-to-Well Correlation, Computers & Geosciences, 103: 59-69 (2017).
7
[6] Rivera Vega N., “Reservoir Characterization Using Wavelet Transforms”, Master Thesis, Texas A&M University (2004).
8
[7] Zoraster S., Paruchuri R., Darby S., “Curve Alignment for Well-to-Well Log Correlation”, SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers (2004).
9
[8] Yuan X., Guo Y., Yu Y., Shen Y., Shao Y., Correlation and Analysis of Well-Log Sequence with Milankovitch Cycles as Rulers: A Case Study of Coal-Bearing Strata of Late Permian in Western Guizhou, International Journal of Mining Science and Technology, 23(4): 563-568 (2013).
10
[9] Perez-Muñoz T., Velasco-Hernandez J., Hernandez-Martinez E., Wavelet Transform Analysis for Lithological Characteristics Identification in Siliciclastic Oil Fields, Journal of Applied Geophysics, 98: 298-308 (2013).
11
[10] Lapkovsky V.V., Istomin A.V., Kontorovich V.A, Berdov V.A., Correlation of Well Logs as a Multidimensional Optimization Problem, Russian Geology and Geophysics, 56(3): 487-492 (2015).
12
[11] Dorigo M., “Optimization, Learning and Natural Algorithms”, Ph. D. Thesis, Politecnico di Milano, Italy. (1992).
13
[12] Lee C.Y., An Algorithm for Path Connections and Its Applications, Electronic Computers, IRE Transactions, (3): 346-365 (1961).
14
[13] Subhakar D., Chandrasekhar E., Reservoir Characterization Using Multifractal Detrended Fluctuation Analysis of Geophysical Well-Log Data, Physica A: Statistical Mechanics and Its Applications, 445: 57-65 (2016).
15
[14] Ye S.-J., Wellner R.W., Dunn P.A., “Rapid and Consistent Identification of Stratigraphic Boundaries and Stacking Patterns in Well Logs-An Automated Process Utilizing Wavelet Transforms and Beta Distributions”, SPE Middle East Oil & Gas Show and Conference. Society of Petroleum Engineers (2017).
16
[15] Kadkhodaie A., Rezaee R., Intelligent Sequence Stratigraphy Through a Wavelet-Based Decomposition of Well Log Data, Journal of Natural Gas Science and Engineering, 40: 38-50. 2017.
17
[16] Nie L., Shouguo W., Jianwei W., Zheng L., Lin X., Rui L., Continuous Wavelet Transform and Its Application to Resolving and Quantifying the Overlapped Voltammetric Peaks, Analytica Chimica Acta, 450(1): 185-192 (2001).
18
[17] Misiti M., Misiti Y., Oppenheim G., Poggi J.M., Matlab Wavelet Toolbox User's Guide. Version 3. (2004).
19
[18] Liu X., Wang H., Gu H., Fractal Characteristic Analysis of Electrochemical Noise with Wavelet Transform, Corrosion Science, 48(6): 1337-1367 (2006).
20
[19] Iftekharuddin K.M., Parra C., “Multiresolution-Fractal Feature Extraction and Tumor Detection: Analytical Modeling and Implementation”, Optical Science and Technology, SPIE's 48th Annual Meeting, International Society for Optics and Photonics (2003).
21
[20] Peitgen H.-O., Jürgens H., Saupe D., Chaos and “Fractals: New Frontiers of Science”, Springer Science & Business Media. (2006).
22
[21] Riedi R.H., Crouse M.S., Riberio V.J., Baraniuk R.G.,
23
A Multifractal Wavelet Model with Application to Network, Traffic, Information Theory, IEEE Transactions on., 45(3): 992-1018 (1999).
24
[22] Mandelbrot B.B., Van Ness J.W., Fractional Brownian Motions, Fractional Noises and Applications. SIAM Review, 10(4): 422-437 (1968).
25
[23] Cavanaugh J.E., Wang Y., Davis J.W., Locally Self-Similar Processes and Their Wavelet Analysis, Handbook of Statistics, 21: 93-135 (2003).
26
[24] Jacquet G., Harba R., “Wavelet Based Estimator for Fractional Brownian Motion: An Experimental Point of View”, Signal Processing Conference, 2004 12th European. IEEE (2004).
27
[25] Goncalves P., Riedi R., “Wavelet Analysis of Fractional Brownian Motion in Multifractal Time. in 17° Colloque Sur le Traitement du Signal et Des Images”, FRA, 1999. GRETSI, Groupe d’Etudes du Traitement du Signal et des Images (1999).
28
[26] Taqqu M.S., Teverovsky V., Willinger W., Estimators for Long-Range Dependence: An Empirical Study, Fractals, 3(04): 785-798 (1995).
29
[27] Higuchi T., Approach to an Irregular Time Series on the Basis of the Fractal Theory, Physica D: Nonlinear Phenomena, 31(2): 277-283 (1988).
30
[28] Beran J., “Statistics for Long-Memory Processes, volume 61 of Monographs on Statistics and Applied Probability”, New Y ork: Chapman and Hall. (1994).
31
[29] Soltani S., Simard P., Boichu D., Estimation of the Self-Similarity Parameter Using the Wavelet Transform, Signal Processing, 84(1): 117-123 (2004).
32
[30] Turcotte D.L., “Fractals and Chaos in Geology and Geophysics”, Cambridge University Press. (1997).
33
[31] Sadeghnejad S., Partovi S.M.A., “Reservoir Rock Characterization Using Wavelet Transform and Fractals Analysis”, The 9th International Chemical Engineering Congress & Exhibition (IChEC 2015), Shiraz, Iran (2015).
34
[32] Fitch P.J.R., Lovell M.R., Davies S.J., Pritchard T., Harvey P.K., An Integrated and Quantitative Approach to Petrophysical Heterogeneity, Marine and Petroleum Geology, 63: 82-96 (2015).
35
ORIGINAL_ARTICLE
A Recyclable Poly(ionic liquid)s Enzyme Reactor for Highly Efficient Protein Digestion
One of the most significant tasks for proteomic research and industrial applications, is the preparation of recyclable enzyme reactor. Herein, a novel recyclable enzyme reactor has been developed based on monodispersed spherical poly(quaternary ammonium ionic liquid)s particles immobilized trypsin. A new quaternary ammonium ionic liquids functional monomer was first synthesized. The ionic liquids functional monomer was then copolymerized with ethylene glycol dimethacrylate by precipitation polymerization. The resultant monodispersed spherical particle showed a large surface area (231 m2/g) and high binding capacity for trypsin (200 mg/g) due to the large surface area and strong interaction. The polymer microsphere loaded trypsin was used as an enzyme reactor for the digestion of standard protein, semi-complex samples and skim milk, respectively. The results indicated that the enzyme reactor exhibited highly efficient protein digestion and excellent stability. The digestion time of the present ionic liquids enzyme reactor for the digestion of protein, the solution could be reduced to even 5 min. The ionic liquids enzyme reactor showed excellent reusability and could be reused for more than four times. When it was kept at 4 °C for 12 d, and used for skim milk digestion, the obtained MALDI-TOF score could also reach 88 with 29 matched peptides.
https://ijcce.ac.ir/article_34212_9fc075ef79dbdb1d7687a846d4cbba99.pdf
2018-06-01
235
246
10.30492/ijcce.2018.34212
Enzyme reactor
Ionic liquids
Poly(ionic liquids)
Protein
Mingxue
Xie
1510953513@qq.com
1
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, P.R. CHINA
AUTHOR
Rina
Su
surinaa2@163.com
2
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, P.R. CHINA
AUTHOR
Qiliang
Deng
yhdql@tust.edu.cn
3
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, P.R. CHINA
LEAD_AUTHOR
[1] Rogers R.D., Voth G.A., Ionic liquids, Acc. Chem. Res., 40:1077-1078 (2007).
1
[2] Wang J.L., Yao H.W., Nie Y., Zhang X.P., Li J.W., Synthesis and Characterization of the Iron-Containing Magnetic Ionic Liquids, J. Mol. Liq., 169: 152-155 (2012).
2
[3] Mao G.X., Zhu A.F., The Aggregation Behavior of Short Chain Hydrophilic Ionic Liquids in Aqueous Solutions, Iran. J. Chem. & Chem. Eng. (IJCCE), 32: 77-82 (2013).
3
[4] Hallett J.P., Welton T., Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis 2, Chem. Rev., 111:3508–3576 (2011).
4
[5] Wasserscheid P., Keim W., Ionic Liquids-New Solutions for Transition Metal Catalysis, Angew Chem. Int. Edit., 39:3772–3789 (2000).
5
[6] Wang H., Gurau G., Rogers R.D., Ionic Liquid Processing of Cellulose, Chem. Soc. Rev., 41:1519-1537 (2012).
6
[7] Walsh D.A., Lovelock K.R., Licence P., Ultramicroelectrode Voltammetry and Scanning Electrochemical Microscopy in Room-Temperature Ionic Liquid Electrolytes, Chem. Soc. Rev., 39: 4185–4194 (2010).
7
[8] Dupont J., Scholten J.D., On the Structural and Surface Properties of Transition-Metal Nanoparticles in Ionic Liquids, Chem. Soc. Rev., 39: 1780–1804 (2010).
8
[9] Bideau J.L., Viau L., Vioux A., Ionogels, Ionic Liquid Based Hybrid Materials, Chem. Soc. Rev., 40: 907–925 (2011).
9
[10] Kragl U., Eckstein M., Kaftzik N., Enzyme Catalysis in Ionic Liquids, Curr. Opin. Chem. Biol., 13: 565-571 (2002).
10
[11] Gao W.W., Zhang F. X., Zhang G.X., Zhou C.H., Key Factors Affecting the Activity and Stability of Enzymes in Ionic Liquids and Novel Applications in Biocatalysis, Biochem. Eng. J., 99: 67-84 (2015).
11
[12] Barron C.C., Sponagle B.J.D., Arivalagan P., Cunha G.B.D., Optimization of Oligomeric Enzyme Activity in Ionic Liquids Using Rhodotorula Glutinis Yeast Phenylalanine Ammonia Lyase, Enzyme Microbial Tech., 96: 151-156 (2017).
12
[13] Ou G.N., He B.Y., Halling P., Ionization Basis for Activation of Enzymes Soluble in Ionic Liquids, Biochim. Biophys. Acta, 1860: 1404-1408 (2016).
13
[14] Solhtalab M., Karbalaei-Heidari H. R., Absalan G., Tuning of Hydrophilic Ionic Liquids Concentration: A Way to Prevent Enzyme Instability, J. Molecular Catalysis B: Enzymatic, 122: 125-130 (2015).
14
[15] Misuk V., Breuch D., Löwe H., Paramagnetic Ionic Liquids as “Liquid Fixed-Bed” Catalysts in Flow Application, Chem. Eng. J., 173: 536-540 (2011).
15
[16] Han J., Wang Y., Liu Y., Li Y., Lu Y., Yan Y.S., Ionic Liquid-Salt Aqueous Two-Phase Extraction Based on Salting-Out Coupled with High-Performance Liquid Chromatography for the Determination of Sulfonamides in Water and Food, Anal. Bioanal. Chem., 405: 1245-1255 (2013).
16
[17] Sahiner N., Demir S., Yildiz S., Magnetic Colloidal Polymeric Ionic Liquid Synthesis and Use in Hydrogen Production, Colloid. Surface. A, 449: 87-95 (2014).
17
[18] Eftekhari A., Saito T., Synthesis and Properties of Polymerized Ionic Liquids, Eur. Poly. J., 90:245-272 (2017).
18
[19] Men Y.J., Kuzmicz D., Yuan JY., Poly(ionic liquid) Colloidal Particles, Current Opinion Colloid & Inter. Sci., 19: 76-83 (2014).
19
[20] Paino M.Á., Bonilla A.M., Fabal F.L., Garcés J.L., Heuts J.P.A., García M.F., Effect of Glycounits on the Antimicrobial Properties and Toxicity behavior of Polymers Based on Quaternized DMAEMA, Biomacromolecules, 16: 295-303 (2015).
20
[21] Rantwijk F.V., Sheldon R. A., Biocatalysis in Ionic Liquids, Chem. Rev., 107:2757-2785 (2007).
21
[22] Huang J., Wang F., Ye M., Zou H., Enrichment and Separation Techniques for Large-Scale Proteomics Analysis of the Protein Post-Translational Modifications, J Chromatogr A., 1372: 1-17 (2014).
22
[23] Qiao J., Kim J.Y., Wang Y.Y., Qi L., Wang F.Y., Moon M.H., Trypsin Immobilization in Ordered Porous Polymer Membranes for Effective Protein Digestion, Anal. Chim. Acta., 906: 56-64 (2016).
23
[24] Switzar L., Giera M., Niessen W.M.A., Protein Digestion: an Overview of the Available Techniques and Recent Developments, J. Proteome. Res., 12: 1067-1077 (2013).
24
[25] Sun X., Cai X., Wang R.Q., Xiao J., Immobilized Trypsin on Hydrophobic Cellulose Decorated Nanoparticles Shows Good Stability and Reusability for Protein Digestion, Anal. Biochem., 477: 21-27 (2015).
25
[26] Yuan H.M., Zhang L.H., Zhang Y.K., Preparation of High Efficiency and Low Carry-Over Immobilized Enzymatic Reactor with Methacrylic Acid–Silica Hybrid Monolith as Matrix for On-Line Protein Digestion, J. Chromatogr. A, 1371:48-57 (2014).
26
[27] Wang H.P., Jiao F.L., Gao F.Y., Zhao X.Y., Zhao Y., Shen Y.H., Covalent Organic Framework-Coated Magnetic Graphene as a Novel Support for Trypsin Immobilization, Anal. Bioanal. Chem., 409: 2179-2187 (2017).
27
[28] Fan C., Shi Z., Pan Y., Song Z., Zhang W., Zhao X., Dual Matrix-Based Immobilized Trypsin for Complementary Proteolytic Digestion and Fast Proteomics Analysis with Higher Protein Sequence Coverage, Anal Chem., 86(3): 1452-1458 (2014).
28
[29] Karamatollah R., Feral T., Changes in Enzyme Efficiency During Lipase-Catalyzed Hydrolysis of Canola Oil in a Supercritical Bioreactor, Iran. J. Chem. Chem. Eng. (IJCCE), 25(4): 25-35 (2006).
29
[30] Jiang B., Yang K., Zhang L., Liang Z., Peng X., Zhang Y., Dendrimer-Grafted Graphene Oxide Nanosheets as Novel Support for Trypsin Immobilization to Achieve Fast on-Plate Digestion of Proteins, Talanta, 122: 278-284 (2014).
30
[31] Cheng G., Zheng S.Y., Construction of a High-Performance Magnetic Enzyme Nanosystem for Rapid Tryptic Digestion, Scientific Reports, 4:6947 (2014).
31
DOI: 10.1038/srep06947
32
[32] Shi C., Deng C., Li Y., Zhang X., Yang P., Hydrophilic Polydopamine-Coated Magnetic Graphene Nanocomposites for Highly Efficient Tryptic Immobilization, Proteomics, 14: 1457-1463 (2014).
33
[33] Cao Y., Wen L.Y., Svec F., Tan T.W., Lv Y.Q., Magnetic AuNP@Fe3O4 Nanoparticles as Reusable Carriers for Reversible Enzyme Immobilization, Chem. Eng. J., 286: 272-281 (2016).
34
[34] Lin Z.A., Xiao Y., Wang L., Yin Y.Q., Zheng J.N., Yang H.H., Chen, G.N., Facile Synthesis of Enzyme–Inorganic Hybrid Nanoflowers and Their Application as an Immobilized Trypsin Reactor for Highly Efficient Protein Digestion, RSC Adv., 4: 13888-13891 (2014).
35
[35] Haupt K., Bueno S.M.A., Vijayalakshmi M.A., Interaction of Human Immunoglobulin G with l-Histidine Immobilized onto Poly(ethylene vinyl alcohol) Hollow-Fiber Membranes, J. Chromatogr. B, 674: 13-21 (1995).
36
[36] Jin L., He D., Li Z., Wei M., Protein Adsorption on Gold Nanoparticles Supported by a Layered Double Hydroxide, Mat. Lett., 77: 67-70 (2012).
37
[37] Bellezza F., Alberani A., Posati T., Tarpani L., Latterini L., Cipiciani A., Protein Interactions with Nanosized Hydrotalcites of Different Composition, J. Inorg. Biochem., 106: 134-142 (2012).
38
[38] Shi C., Deng C., Li Y., Zhang X., Yang P., Hydrophilic Polydopamine-Coated Magnetic Graphene Nanocomposites for Highly Efficient Tryptic Immobilization, Proteomics, 14: 1457-1463 (2014).
39
[39] Cao Y., Wen, L.Y., Svec F., Tan T.W., Lv Y.Q., Magnetic AuNP@Fe3O4 Nanoparticles as Reusable Carriers for Reversible Enzyme Immobilization, Chem. Eng. J., 285(15): 272-281 (2016).
40
[40] Ruan G.H., Wei M.P., Chen Z.Y., Su R.H., Du F.Y., Zheng Y.J., Novel Regenerative Large-Volume Immobilized Enzyme Reactor:Preparation, Characterization and Application, J. Chromatogr. B, 967: 13-20 (2014).
41