ORIGINAL_ARTICLE
Growth and Optical Properties Investigation of Pure and Al-doped SnO2 Nanostructures by Sol-Gel Method
SnO2 nanoparticles with different percentage of Al (5%, 15%, and25%) were synthesized by sol-gel method. The structure and nature of nanoparticles are determined by of X-ray diffraction analysis. Also, morphology of the samples is evaluated by SEM. Moreover, the optical properties of the samples are investigated with UV-Visible and FT-IR. The XRD patterns are indicated that all samples and incorporation aluminum ions into the SnO2 lattice have tetragonal rutile structure. The crystalline size of nanoparticles is decreased with increasing the Al percentage. The SEM results confirmed that the size of nanoparticles decreases with increasing the Al percentage. Also, FT-IR and UV-Visible results showed that the optical band gap of nanoparticles increases with the increasing the Al percentage. Finally, we have used the EDX analysis to study the chemical composition of the products. Pure tin and oxygen have been observed. The doped samples showed the existence of Al atoms in the samples of the crystal structure of SnO2.
https://ijcce.ac.ir/article_23801_58b4cc2712ec27e8b2ea8aaf18424ae9.pdf
2017-10-01
1
8
10.30492/ijcce.2017.23801
nanoparticles
SnO2
Sol-gel
Al-doped
Optical Properties
Ali Reza
Razeghizadeh
razeghizadeh@yahoo.com
1
Department of Physics, Faculty of Science, Payamenoor University, P.O. Box 19395-3697 Tehran, I.R. IRAN
LEAD_AUTHOR
Lila
Zalaghi
leylazalaghi@yahoo.com
2
Department of Physics, Faculty of Science, Payamenoor University, P.O. Box 19395-3697 Tehran, I.R. IRAN
AUTHOR
Iraj
Kazeminezhad
i.kazeminezhad@scu.ac.ir
3
Department of Physics, Faculty of Science, Shahid Chamran University of Ahvaz, I.R. IRAN
AUTHOR
Vahdat
Rafee
v.rafee@gmail.com
4
Department of Physics, Faculty of Science, Payamenoor University, P.O. Box 19395-3697 Tehran, I.R. IRAN
AUTHOR
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[11] Paraguay-Delgado F., Antúnez-Flores W., Miki-Yoshida M., Aguilar-Elguezabal A., Santiago P., Diaz R., Ascencio J.A., Structural Analysis and Growing Mechanisms for Long SnO2 Nanorods Synthesized by Spray Pyrolysis, Nanotechnology, 16(6: 688 (2005).
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[13] Mishra S., Ghanshyam C., Ram N., Singh S., Bajpai R.P., Bedi R.K., Alcohol Sensing of Tin Oxide Thin Film Prepared by Sol-Gel Process, Bulletin of Materials Science, 25(3): 231-234 (2002).
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[14] Kose H., Aydin A.O., Akbulut H., The Effect of Temperature on Grain Size of SnO2 Nanoparticles Synthesized by Sol Gel Method, Acta Physica Polonica A, 12 (2): 345-347(2014).
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[15] Tripathy S.K., Hota B.P., Influence of the Substrates Nature on Optical and Structural Characteristics of SnO2 Thin Film Prepared by Sol-Gel Technique, Journal of Nano-and Electronic Physics, 5(3): 3012-1 (2013).
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[16] Gaber A., Abdel-Rahim M.A., Abdel-Latief A.Y., Abdel-Salam M.N., Influence of Calcination Temperature on the Structure and Porosity of Nanocrystalline SnO2 Synthesized by a Conventional Precipitation Method, Int. J. Electrochem Sci., 9(1): 81-95 (2014).
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[17] Goswami Y.C., Kumar V., Rajaram P., Ganesan V., Malik M.A., O’Brien P., Synthesis of SnO2 Nanostructures by Ultrasonic-Assisted Sol–Gel Method, Journal of Sol-Gel Science and Technology, 69(3): 617-624 (2014).
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[18] Kim M., Marom N., Bobbitt S., Chelikowsky J.R., The Electronic and Structural Properties of SnO2 Nanoparticles Doped with Antimony and Fluorine, In APS Meeting Abstracts, 1: 44011 (2014).
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[20] Gu F., Wang S.F., Lü M.K., Zhou G.J., Xu D., Yuan D.R., Photoluminescence Properties of SnO2 Nanoparticles Synthesized by Sol-Gel Method, The Journal of Physical Chemistry B, 108(24): 8119-8123 (2004).
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[21] Razeghizadeh A., Elahi E., Rafee V., Investigation of UV-Vis Absorbance of TiO2 Thin Films Sensitized with the Mulberry Pigment Cyanidin by Sol-Gel Method. Nashrieh Shimi va Mohandesi Shimi Iran, 35(2): 1-8 (2016). [in Persian]
21
[22] Razeghizadeh A., Mahmoudi Ghalvandi M., Sohillian F., Rafee V., The Effect of Substrate on Structural and Electrical Properties of Cu3N Thin Film by DC Reactive Magnetron Sputtering. Physical Chemistry Research. 5(3):497-504 (2017).
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29
ORIGINAL_ARTICLE
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety
A series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes. The resulting aminoxanthenes converted to thiourea derivatives via their reaction with methyl isothiocyanate. The final products were synthesized through the reaction of thiourea derivatives with dialkylacetylene dicarboxylates. All of the steps were carried out under easy and mild reaction conditions in the absence of expensive catalysts or esoteric starting materials. The structures of compounds 3a-c and the final products were characterized according to their physical constants, spectral data such as NMR, IR spectra and also elemental analysis.
https://ijcce.ac.ir/article_24714_83da0648f883d15c460a03bf9448353e.pdf
2017-10-01
9
16
10.30492/ijcce.2017.24714
1, 8-dioxo-octahydroxanthene
4-thiazolidinone
dialkyl acetylene dicarboxylate
dimedone
1, 3-cyclohexanedione
Maryam
Robati
robati63@gmail.com
1
Department of Chemistry, Faculty of Science, Kerman Branch, Islamic Azad University, P.O. Box 7635131167 Kerman, I.R. IRAN
AUTHOR
Dadkhoda
Ghazanfari
dadkhodaghbk@gmail.com
2
Department of Chemistry, Faculty of Science, Kerman Branch, Islamic Azad University, P.O. Box 7635131167 Kerman, I.R. IRAN
AUTHOR
Mohammad Reza
Islami
mrislami@uk.ac.ir
3
Department of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 76169 14111 Kerman, I.R. IRAN
LEAD_AUTHOR
Kazem
Saidi
saidik@uk.ac.ir
4
Department of Chemistry, Shahid Bahonar University of Kerman, P.O. Box 76169 14111 Kerman, I.R. IRAN
AUTHOR
[1] El-Brashy A.M., Metwally M.E., El-Sepai F.A., Spectrophotometric Determination of Some Fluoroquinoloneantibacterials by Binary Complex Formation with Xanthene Dyes, ILFarmaco, 59(10): 809-817 (2004).
1
[2] Chibale K., Visser M., Schalkwyk D.V., Smith P.J., Saravanamuthu A., Fairlamb A.H., Exploring the Potential of Xanthene Derivatives as Trypanothione Reductase Inhibitors and Chloroquine Potentiating Agents, Tetrahedron, 59(13): 2289-2296 (2003).
2
[3] Omolo J.J., Johnson M.M., Van Vuuren S.F., De Koning C.B., The Synthesis of Xanthones, Xanthenediones, and Spirobenzofurans: Their Antibacterial and Antifungal Activity, Bioorg. Med. Chem. Lett., 21(23): 7085-7088 (2011).
3
[4] Bhowmik B.B., Ganguly P., Photophysics of Xanthene Dyes in Surfactant Solution, Spectrochim. Acta, Part A, 61(9): 1997-2003 (2005).
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[7] Cunico W., Gomes C. R. B.,Vellasco, J. W., Chemistry and Biological Activities of 1, 3-Thiazolidin-4-Ones, Mini Rev. Org. Chem., 5(4): 336-344 (2008).
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[11] Ghorbani M., Mohammadi B., Saraii M., Masoumi B., Abbasian M., Ramazani A., Slepokura K., Lis K., A Three-Component Reaction for the Synthesis of 1-azabicyclo[3.1.0]hexane-3-enes, Org. Lett., 18(19): 4759–4761 (2016)
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[12] Taran J., Ramazani A., Joo S.W., Ślepokura K., Lis T., Synthesis of Novel α-(acyloxy)-α-(quinolin-4-yl)acetamides by a Three-Component Reaction between an Isocyanide, Quinoline-4-Carbaldehyde, and Arenecarboxylic Acids, Hellv. Chem. Acta., 97(8): 1088-1096 (2014).
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[13] Ramazani A., Khoobi M., Torkaman A., Nasrabadi F.Z., Forootanfar H., Shakibaie M., Jafari M., Ameri A., Emami S., Faramarzi M.A., Foroumadi A., Shafiee A., One-Pot, Four-Component Synthesis of Novel Cytotoxic Agents 1-(5-aryl-1,3,4-oxadiazol-2-yl)-1-(1H-pyrrol-2-yl)Methanamines, Eur. J. Med. Chem., 78: 151-156 (2014).
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[14] Ramazani A., Mahyari A.T., Rouhani M., Rezaei A., A Novel Three-Component Reaction of a Secondary Amine and a 2-Hydroxybenzaldehyde Derivative with an Isocyanide in the Presence of Silica Gel: An Efficient One-Pot Synthesis of Benzo[b]furan Derivatives, Tetrahedron lett., 50: 5625-5627 (2009).
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[15] Ramazani A., Rezaei A., Novel One-Pot, Four-Component Condensation Reaction: An Efficient Approach for the Synthesis of 2, 5-Disubstituted 1, 3, 4-oxadiazole derivatives by a Ugi-4CR/aza-Wittig Sequence, Org. Lett., 12(12): 2852-2855 (2016).
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[16] Kazemizadeh A.R., Ramazani A., Three Component Reaction of Indane-1, 2, 3-Trione, Tosylmethyl Isocyanide and Benzoic Acid Derivatives, Arkivoc, 15: 159-165 (2008).
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[17] Ramazani A., Joo S.W., Nasrabadi F.Z., Environmentally Green Synthesis of Thioformamide Derivatives, Turk J Chem, 37: 405-412 (2013).
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[18] Mortazavi Z.F., Islami M.R., Khaleghi M., Highly Stereoselective Synthesis of Saccharin-Substituted β-Lactams via in Situ Generation of a Heterosubstituted Ketene and a Zwitterionic Intermediate as Potential Antibacterial Agents,
18
Org. Lett., 17(12): 3034-3037(2015).
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[20] Hosseinkhani B., Islami M.R., Hosseinkhani S., Highly Stereoselective Synthesis of Isoindole Derivatives Containing an Azetidinone Ring, Synlett 26(16): 2277-2279 (2015).
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[21] Islami M.R., Allen A.D., Vukovic S., Tidwell T.T., N-Pyrrolylketene: a Nonconjugated Heteroaryl Ketene, Org. Lett., 13(3): 494-497 (2011).
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[22] Fang D., Gong K., Liu, Z.L., Synthesis of 1, 8-Dioxo-Octahydroxanthenes Catalyzed by Acidic Ionic Liquids in Aqueous Media, Catal. Lett., 127(3): 291-295 (2009).
23
[23] Kaya M., Demir E., Bekci, H., Synthesis, Characterization and Antimicrobial Activity of Novel Xanthene Sulfonamide and Carboxamide Derivatives, J. Enzyme Inhib. Med. Chem., 28(5): 885-893 (2013).
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25
ORIGINAL_ARTICLE
Synthesis of Polyfunctionalized Pyrroles by a PPh3-Promoted Condensation Reaction Between Ammonium Acetate, Dialkyl Acetylenedicarboxylate and Arylglyoxals
A simple and efficient synthesis of some polyfunctionalized pyrrole derivatives by a triphenylphosphine-promoted condensation reaction between dialkyl acetylenedicarboxylates, arylglyoxals, and ammonium acetate is described. This present method carries several advantages, such as good yields, a simple procedure, non-hazardous reaction conditions and starting from easily accessible substrates
https://ijcce.ac.ir/article_24034_50a107f0890169e7b711284eda7082a9.pdf
2017-10-01
17
22
10.30492/ijcce.2017.24034
Dialkyl acetylenedicarboxylates
Triphenylphosphine
Ammonium acetate
Intramolecular Wittig reaction
Arylglyoxals
Hossein
Anaraki-Ardakani
hosseinanaraki@yahoo.com
1
Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, I.R. IRAN
LEAD_AUTHOR
Parisa
Nkomanesh
p.nikoomanesh85@gmail.com
2
Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, I.R. IRAN
AUTHOR
[1] Gribble G.W., In: “Comprehensive Heterocyclic Chemistry I”I, Vol. 2; Katriztky A. R., Rees C. W., Scriven E. F. V., Eds., Elsevier: Oxford, 207(1996).
1
[2]Jones R.A., Bean G.P., “The Chemistry of Pyrroles”; Academic Press: London, 1(1977).[3] Bean G.P., In: “The Chemistry of Heterocyclic Compounds”; Jones A. R. Ed.; Wiley: New York, Vol. 48, Part 1, Chapter 2, p 105(1990).
2
[4] (a) Fan H., Peng J., Hamann M.T., Hu J.F., Lamellarins and Related Pyrrole-Derived Alkaloids From Marine Organisms, Chem. Rev., 108(1): 264-287(2008).
3
(b) Estevez V., Villacampa M., Menendez J.C., Multicomponent Reactions for the Synthesis of Pyrroles, Chem. Soc. Rev., 39: 4402-4421(2010).
4
[5] Dieter R.K., Yu H., A Facile Synthesis of Polysubstituted Pyrroles, Org. Lett., 2(15): 2283-2286 (2000).
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[6] Iwasawa N., Maeyama K., Saitou M., Reactions of Propargyl Metallic Species Generated by the Addition of Alkynyllithiums to Fischer-Type Carbene Complexes, J. Am. Chem. Soc., 119(6): 1486-1487 (1997).
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[7] Furstner A., Weintritt H., Hupperts, A., A New Titanium-Mediated Approach to Pyrroles: First Synthesis of Lukianol a and Lamellarin-o-Dimethyl Ether, J. Org. Chem., 60: 6637-6641(1995).
7
[8] Katritzky A.R., Jiang J., Steel J., 1-Aza-1,3-Bis(triphenylphosphoranylidene)propane: A Novel: CHCH2N: Synthon, J. Org. Chem., 59(16):4551-4555 (1994).
8
[9] Chen N., Lu Y., Cadamasetti K., Hurt C.R., Norman M.K., Fotsch C., A Short, Facile Synthesis of 5-Substituted 3-Amino-1H-pyrrole-2-carboxylates, J. Org. Chem., 65(8): 2603-2605 (2000).
9
[10] Bharadwaj A.R., Scheidt K.A.,Catalytic Multicomponent Synthesis of Highly Substituted Pyrroles Utilizing a One-Pot Sila-Stetter/Paal−Knorr Strategy,Org. Lett., 6(23):2465-2468 (2004).
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[11] Chien T.C., Meade E.A., Hinkley J.M., Townsend L.B., Facile Synthesis of 1-Substituted 2-Amino-3-Cyanopyrroles: New Synthetic Precursors for 5,6-Unsubstituted Pyrrolo[2,3-d]Pyrimidines, Org. Lett., 6(17) :2857-2859 (2004).
11
[12] Nair V., Nair J.S., Vinod A.U., Rath N.P., Triphenylphosphine Promoted Addition of Dimethyl Acetylenedicarboxylate to 1, 2-Benzoquinones: Facile Synthesis of Novel γ-Spirolactones, J. Chem. Soc. Perkin Trans 1, 3129-3130 (1997).
12
[13]Anary-Abbasinejad M., Anaraki-Ardakani H., Hosseini-Mehdiabad H., One-Pot Synthesis of Stable Phosphorus Ylides by Three-Component Reaction between Dimethyl Acetylenedicarboxylate, Semicarbazones, and Triphenylphosphine. Phosphorus, Sulfur and Silicon, 188: 1440-1446 (2008).
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[14] Yavari I., Hekmat-Shoar R., Zonouzi A., A New and Efficient Route to 4-Carboxymethylcoumarins Mediated by Vinyl Tiphenylphosphonium Salt, Tetrahedron Lett, 39(16): 2391-2392 (1998).
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[15] Yavari I., Adib M., Hojabri L., Vinyltriphenylphosphonium Salt Mediated Serendipitous Synthesis of Arylimin Ophosphoranes, Tetrahedron, 58:7213-7219 (2002).
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[16]( a) Kamijo S., Kanazawa C., YamamotoY., Copper- or Phosphine-Catalyzed Reaction of Alkynes with Isocyanides. Regioselective Synthesis of Substituted Pyrroles Controlled by the Catalyst, J. Am. Chem. Soc, 127(25):9260–9266 (2005).
16
(b) Kamijo S., Kanazawa C., YamamotoY., Phosphine-Catalyzed Regioselective Heteroaromatization between Activated Alkynes and Isocyanides Leading to Pyrroles, Tetrahedron Letters, 46(52) :2563–2566 (2005).
17
[17] Maghsoodlou M.T., Rostami Charati F., Habibi Khorassani S.M., Khosroshahrodi M., Makha M., Synthesis of Pyrrole Phosphonate Esters: Emphasis on Pyrrole NH Acids and Dialkylacetylenic Esters Substitution, Iran. J. Chem. Chem. Eng. (IJCCE), 27(1): 105-113 (2008).
18
[18] Anaraki-Ardakani H., Mosslemin M.H., Anary-Abbasinejad M., Mirhosseini S.H., Shams N., A Facile Route to the Synthesis of Polyfunctionalized Pyrroles, Arkivoc, xi: 343-349(2010).
19
[19] Anaraki-Ardakani H., Noei M., Tabarzad A., Facile Synthesis of N-(arylsulfonyl)-4-ethoxy-5-oxo-2,5-dihydro-1H-pyrolle-2,3-dicarboxylates by One-Pot Three-Component Reaction, Chinese Chemical Letters, 23(1):45-48(2012).
20
[20] Azizian J., Karimi A. R., Arefrad H., Mohammadi A.A., Mohammadizadeh M.R., A Novel One-Pot, Four Component Synthesis of Some Densely Functionalized Pyrroles, Molecular Diversity, 6: 223-226 (2003).
21
[21] Kassaee M.Z., Masrouri H., Movahedi F., Partovi T., One-Pot Four-Component Synthesis of Tetrasubstituted Pyrroles, Helvetica Chimica Acta, 91(2): 227-231 (2008).
22
[22] Azizian J., Hosseini J., Mohammadi M. k., Sheikholeslami F., Efficient Route for the Synthesis of Highly Substituted Pyrroles, Synthetic Communications, 40(23): 3472-3479 (2010).
23
[23] Anaraki-Ardakani H., Hassanabadi A., Fazilnia A ., Tabarzad A., Heidari-Rakati T., A Facile Route to the Synthesis of 2,5-Dihydropyrrole Derivatives, Journal of Chemical Research, 38(1) 9-11(2014).
24
[24] Anary-Abbasinejad M., Dehghanpour-Farashah H., Hassanabadi A., Anaraki-Ardakani, H., Shams N., Three-Component Reaction of Triphenylphosphine, Dialkyl Acetylenedicarboxylate, and 2-Aminothiazole or 2-Aminobenzothiazole in the Presence of Arylglyoxals: An Efficient One-Pot Synthesis of Highly Functionalized Pyrroles, Synth. Commun., 42:1877-1884(2012).
25
[25] Arduengo A.J., Stewart C.A., Low Coordinate Hypervalent Phosphorus, Chem. Rev., 94, 1215-1237(1994).
26
[26] Yavari I., Khorramabadi-Zad A., Rashidi-Ranjbar P., Fallah-Bagher-Shaidaii H., Reaction between Trimethyl Phosphite and Dimethyl Acetylenedicarboxylate in the Presence of 5 5-Dimethylcyclohexane-1,3-Dione, J. Mol. Struct. (Theochem) 389(1):155-158 (1977).
27
[27] Burgada R., Leroux Y., Khoshnieh Y.O.E., Synthese et Structure d'un Trialcoxy-1,1,1 Phospholev Premier Modele Pentacoordine Contenant Le Cycle Phosphole, Tetrahedron Lett., 22:3533-3536 (1981).
28
[28] Cadogan J.I.G., “Organophosphorus Reagents in Organic Synthesis”, Academic Press, New York, (1979).
29
ORIGINAL_ARTICLE
Electrosynthesis, Characterization and Corrosion Inhibition Study of DBSA-doped Polyaniline Coating on 310 Stainless Steel
The synthesis of polyaniline doped with dodecylbenzene sulphonic acid (Pani-DBSA) coatings on 310 stainless steel (310 SS) surfaces has been investigated by using the galvanostatic method. The synthesized coatings were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible absorption spectrometry and Scanning Electron Microscopy (SEM).The anticorrosion performances of Pani-DBSA coatings were investigated in 5% NaCl solution by the potentiodynamic polarization technique and Electrochemical Impedance Spectroscopy (EIS). The corrosion rate of Pani-DBSA coated 310 SS was found ∼30 times lower than bare 310 SSand potential corrosion increased from -0.84 V versus Ag/AgCl for uncoated 310 SS to -0.71 V versus Ag/AgCl for Pani-DBSA coated 310 SS electrodes. Electrochemical measurements indicate that Pani-DBSA coated have good inhibiting properties with a mean efficiency of ~96% at 5 mA cm-2 current density applied to 310 SS corrosion in chloride media. The results of this study clearly ascertain that the Pani-DBSA has an outstanding potential to protect 310 SS against corrosion in a chloride environment.
https://ijcce.ac.ir/article_26368_ff8c26a5b9236f4ec8419b53c30e7c2f.pdf
2017-10-01
23
32
10.30492/ijcce.2017.26368
Electrosynthesis
310 Stainless Steel
Corrosion
EIS
dodecylbenzene sulphonic acid
Yaser
Jafari
y.j.arisman@gmail.com
1
Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I.R. IRAN
AUTHOR
Sayed Mehdi
Ghoreishi
s.m.ghoreishi@kashanu.ac.ir
2
Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I.R. IRAN
LEAD_AUTHOR
Mehdi
Shabani-Nooshabadi
m.shabani@kashanu.ac.ir
3
Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I.R. IRAN
AUTHOR
[1] Olad A., Rasouli H., Enhanced Corrosion Protective Coating Based on Conducting Polyaniline/Zinc Nanocomposite, J. Appl. Poly. Sci., 115: 2221-7 (2010).
1
[2] Zeybek B., Pekmez N.O., Kılıç E., Electrochemical Synthesis of Bilayer Coatings of Poly (N-Methylaniline) and Polypyrrole on Mild Steel and Their Corrosion Protection Performances, Electrochim. Acta., 56: 9277-86(2011).
2
[3] Lu H., Zhou Y., Vongehr S., Hu K., Meng X., Electropolymerization of PANI Coating in Nitric Acid for Corrosion Protection of 430 SS, Synt. Meta., 161: 1368-76(2001).
3
[4] Eftekhari A., Yazdani B., Morphological Effects of Ni Nanostructures on Electropolymerization of Aniline, J. Appli. Poly. Sci., 122: 1579-86 (2011).
4
[5] Arslan A., Hur E., Electrochemical Storage Properties of Polyaniline-, Poly (N-methylaniline)-, and Poly (N-ethylaniline)-Coated Pencil Graphite Electrodes, Chem. Pap., 68:504-15(2011).
5
[6] Mert B.D., Solmaz R., Kardaş G., Yazıcı B., Copper/ polypyrrole Multilayer Coating for 7075 Aluminum AlloyProtection, Prog. Org. Coat., 72: 748-54 (2011).
6
[7] Ozyilmaz A., Akdag A., Polyaniline, Poly (N-methylaniline) and Poly (aniline-co-N-methylaniline) Coatings on Stainless Steel, Tran. IMF., 89:215-24 (2011).
7
[8] Ozyilmaz A.T., Akdag A., Karahan I.H., Ozyilmaz G., Electrochemical Synthesis of Polyaniline Films on Zinc-Cobalt Alloy Deposited Carbon Steel Surface in Sodium Oxalate, Prog. Org. Coat., 77: 872-9 (2014).
8
[9] Ozyilmaz A.T., Akdag A., Karahan I.H., Ozyilmaz G., The Influence of Polyaniline (PANI) Coating on Corrosion Behaviour of Zinc–Cobalt Coated Carbon Steel Electrode, Prog. Org. Coat.,76: 993-7 (2013).
9
[10] Gupta G., Birbilis N., Cook A., Khanna A., Polyaniline-Lignosulfonate/Epoxy Coating for Corrosion Protection of AA2024-T3, Corr. Sci., 67: 256-67 (2013).
10
[11] Zhang Y., Shao Y., Zhang T., Meng G., Wang F., High Corrosion Protection of a Polyaniline/Organophilic Montmorillonite Coating for Magnesium Alloys, Prog. Org. Coat., 76: 804-11 (2013).
11
[12] Shabani‐Nooshabadi M., Mollahoseiny M., Jafari Y., Electropolymerized Coatings of Polyaniline on Copper by Using the Galvanostatic Method and Their Corrosion Protection Performance in HCl Medium, Surf. Inter. Anal., 46: 472-9 (2014).
12
[13] Wu G., More K.L., Johnston C.M., Zelenay P., High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt, Science., 332: 443-7 (2011).
13
[14] Hung W.I., Hung C.B., Chang Y.H., Dai J.K., Li Y., He H., Synthesis and Electroactive Properties of Poly (Amidoamine) Dendrimers with an Aniline Pentamer Shell, J. Mat. Chem., 21: 4581-7 (2011).
14
[15] Huang T.C., Su Y.A., Yeh T.C., Huang H.Y., Wu C.P., Huang K.Y., Advanced Anticorrosive Coatings Prepared from Electroactive Epoxy–SiO2 Hybrid Nanocomposite Materials, Electrochim. Acta., 56: 6142-9(2011).
15
[16] Hermas A.E.A., Salam M.A., Al-Juaid S.S., In Situ Electrochemical Preparation of Multi-Walled Carbon Nanotubes/Polyaniline Composite on the Stainless Steel, Prog. Org. Coat., 76: 1810-3 (2013).
16
[17] Li Y., Zhang H., Wang X., Li J., Wang F., Growth Kinetics of Oxide Films at the Polyaniline/Mild Steel Interface, Corro. Sci., 53: 4044-9 (2011).
17
[18] Mostafaei A., Nasirpouri F., Epoxy/Polyaniline–ZnO Nanorods Hybrid Nanocomposite Coatings: Synthesis, Characterization and Corrosion Protection Performance of Conducting Paints, Prog. Org. Coat., 77:146-59 (2014).
18
[19] Thakur V.K., Ding G., Ma J., Lee P.S., Lu X., Hybrid Materials and Polymer Electrolytes for Electrochromic Device Applications, Adv. Mat., 24: 4071-96 (2012).
19
[20] Jia W., Su L., Lei Y., Pt Nanoflower/Polyaniline Composite Nanofibers Based Urea Biosensor. Biosen. Bioelec., 30:158-64 (2011).
20
[21] Kim T.G., Shin H., Lim D.W., Biomimetic Scaffolds for Tissue Engineering, Advan. Fun. Mat., 22: 2446-68 (2012).
21
[22] Cheng F., Liang J., Tao Z., Chen J., Functional Materials for Rechargeable Batteries, Advan. Mat., 23:1695-715 (2011).
22
[23] Cao Y., Xiao L., Sushko M.L., Wang W., Schwenzer B., Xiao J., Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications, Nano. lett., 12: 3783-7(2012).
23
[24] Yuan L., Xiao X., Ding T., Zhong J., Zhang X., Shen Y., Paper‐Based Supercapacitors for Self‐Powered Nanosystems, Angew. Chem., 124: 5018-22( 2012).
24
[25] Han J., Li L., Fang P., Guo R., Ultrathin MnO2 Nanorods on Conducting Polymer Nanofibers as a New class of Hierarchical Nanostructures for High-Performance Supercapacitors, J. Phy. Chem. C., 116: 15900-7 (2012).
25
[26] Chang C.M., Weng C.J., Chien C.M., Chuang T.L., Lee T.Y., Yeh J.M., Polyaniline/Carbon Nanotube Nanocomposite Electrodes with Biomimetic Hierarchical Structure for Supercapacitors, J. Mat. Chem. A., 1: 14719-28 (2013).
26
[27] Yang X., Li B., Wang H., Hou B., Anticorrosion Performance of Polyaniline Nanostructures on Mild Steel, Prog. Org. Coat., 69: 267-71 (2010).
27
[28] Radhakrishnan S., Rao C.R., Vijayan M., Performance of Conducting Polyaniline‐DBSA and Polyaniline‐DBSA/Fe3O4 Composites as Electrode Materials for Aqueous Redox Supercapacitors, J. Appl. Poly. Sci., 122: 1510-8 (2011).
28
[29] Diniz F., De Andrade G., Martins C., De Azevedo W., A Comparative Study of Epoxy and Polyurethane Based Coatings Containing Polyaniline-DBSA Pigments for Corrosion Protection on Mild Steel, Prog. Org. Coat., 76: 912-6 (2013).
29
[30] Shabani-Nooshabadi M., Ghoreishi S., Behpour M., Direct Electrosynthesis of Polyaniline–Montmorrilonite Nanocomposite Coatings on Aluminum Alloy 3004 and Their Corrosion Protection Performance, Corro. Sci., 53: 3035-42 (2011).
30
[31] Gopi D., Govindaraju K., Kavitha L., Basha K.A., Synthesis, Characterization and Corrosion Protection Properties of Poly (N-vinyl carbazole-co-glycidyl methacrylate) Coatings on Low Nickel Stainless Steel, Prog. Org. Coat., 71: 11-8 (2011).
31
[32] Ganash A., Al-Nowaiser F., Al-Thabaiti S., Hermas A., Protection of Stainless Steel by the Electrodeposition of Polyaniline/poly (o-phenylenediamine) Composite Layers, J. Sol. Sta. Electrochem., 17: 849-60 (2013).
32
[33] Sathiyanarayanan S., Karpakam V., Kamaraj K., Muthukrishnan S., Venkatachari G., Sulphonate Doped Polyaniline Containing Coatings for Corrosion Protection of Iron, Surf. Coat. Techn., 204: 1426-31(2010).
33
[34] Ali Fathima Sabirneeza A., Subhashini S., A Novel Water‐Soluble, Conducting Polymer Composite for Mild Steel Acid Corrosion Inhibition, J. Appl. Poly. Sci., 127: 3084-92 (2013).
34
[35] Negm N., Ghuiba F., Tawfik S., Novel Isoxazolium Cationic Schiff Base Compounds as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid, Corro. Sci., 53: 3566-75 (2011).
35
[36] Jafari Y., Ghoreishi S.M., Shabani-Nooshabadi M., Electrochemical Deposition and Characterization of Polyaniline-Graphene Nanocomposite Films and Its Corrosion Protection Properties, J. Poly. Rese., 23: 1-13 (2016).
36
[37] Zhang X., Yan X., He Q., Wei H., Long J., Guo J., Electrically Conductive Polypropylene Nanocomposites with Negative Permittivity at Low Carbon Nanotube Loading Levels., ACS. Appl. Mate. Interf., 7: 6125-38 (2015).
37
[38] Shabani-Nooshabadi M., Karimian-Taheri F., Electrosynthesis of a Polyaniline/Zeolite Nanocomposite Coating on Copper in a Three-Step Process and the Effect of Current Density on Its Corrosion Protection Performance, RSC. Adva., 5(117): 6601-10 (2015).
38
[39] Jafari Y., Shabani‐Nooshabadi M., Ghoreishi S.M., Electropolymerized Coatings of Poly (o‐anisidine) and Poly (o‐anisidine)‐TiO2 Nanocomposite on Aluminum Alloy 3004 by Using the Galvanostatic Method and Their Corrosion Protection Performance, Poly. Adva. Techn., 25: 279-87 (2014).
39
[40] Huang T.C., Yeh T.C., Huang H.Y., Ji W.F., Chou Y.C., Hung W.I., Electrochemical Studies on Aniline-Pentamer-Based Electroactive Polyimide Coating: Corrosion Protection and Electrochromic Properties, Electrochim. Acta., 56: 10151-8 (2011).
40
[41] Ghoreishi S., Shabani-Nooshabadi M., Behpour M., Jafari Y., Electrochemical Synthesis of Poly (o-anisidine) and Its Corrosion Studies as a Coating on Aluminum Alloy 3105, Prog. Org. Coat., 74: 502-10 (2012).
41
ORIGINAL_ARTICLE
Controlled Green Synthesis of Silver Nanoparticles Using Culture Supernatant of Filamentous Fungus
The focus of this study was to evaluate the effects of some parameters influencing the size and size distribution of the silver nanoparticles (AgNPs) produced by culture supernatant of Fusarium oxysporum. Results revealed that in the reaction solution containing equal volume of silver nitrate and culture supernatant; pH, temperature, and light source can control the AgNP’s characteristics. The particle size decreased with an increase in pH. The average size of AgNPs, formed in reaction solutions, decreased as temperature increased from 40 °C to 121 °C. The smallest AgNPs with the highest polydispersity (average size of 14nm and PDI of 0.37) were obtained in reaction solution incubated at 121 °C. Also, the use of UV radiation in reaction solution resulted in the production of the very small AgNPs with the narrowest size distribution (average size of 9.7nm and PDI of 0.2). X-ray diffraction analysis verified the crystalline nature of synthesized AgNPs. Also, transmission electron microscopy analysis confirmed the production of spherical shape nanoparticles.
https://ijcce.ac.ir/article_25020_d8675584558408db5b722bdcd5b989c9.pdf
2017-10-01
33
42
10.30492/ijcce.2017.25020
Silver nanoparticles (AgNPs)
Controlled Biosynthesis
Fusarium oxysporum
culture supernatant
Sepideh
Hamedi
se_hamedi@sbu.ac.ir
1
Bio-Refinery Group, Faculty of New Technologies Engineering, Shahid Beheshti University, Po.Box 47815-168, Mazandaran, Zirab Campus, I.R. IRAN
AUTHOR
Seyed Abbas
Shojaosadati
shoja_sa@modares.ac.ir
2
Biotechnology group, Chemical Engineering Faculty, Tarbiat Modares University, P.O. Box 14115-114 Tehran, I.R. IRAN
LEAD_AUTHOR
Soheila
Shokrollahzadeh
shokrollahzadeh@yahoo.com
3
Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), P.O. Box 15815-3538 Tehran, I.R. IRAN
LEAD_AUTHOR
Sameereh
Hashemi-Najaf Abadi
s.hashemi@modares.ac.ir
4
Biotechnology group, Chemical Engineering Faculty, Tarbiat Modares University, P.O. Box 14115-114 Tehran, I.R. IRAN
AUTHOR
[1] Zhang X., Yan S., Tyagi R.D., Surampalli R.Y., Synthesis of Nanoparticles by Microorganisms and Their Application in Enhancing Microbiological Reaction rates, Chemosphere, 82: 489-494 (2011).
1
[2] Shivaji S., Madhu S., Singh S., Extracellular Synthesis of Antibacterial Silver Nanoparticles Using Psychrophilic Bacteria, Process Biochem., 46: 1800-1807 (2011).
2
[3] Otari S.V., Patil R.M., Nadaf N.H., Ghosh S.J., Pawar S.H., Green Biosynthesis of Silver Nanoparticles From an Actinobacteria Rhodococcus sp, Mater. Lett., 72: 92-94 (2012).
3
[4] Das V.L., Thomas R., Varghese R.T., Soniya E.V., Mathew J., Radhakrishnan E.K., Extracellular Synthesis of Silver Nanoparticles by the Bacillus Strain CS 11 Isolated From Industrialized Area, 3 Biotech, 4: 121-126 (2013).
4
[5] Musarrat J., Dwivedi S.,S ingh B.R., Al-Khedhairy A.A., Azam A., Naqvi A., Production of Antimicrobial Silver Nanoparticles in Water Extracts of the Fungus Amylomyces rouxii Strain KSU-09, Bioresour. Technol., 101: 8772-8776 (2010).
5
[6] Zaki S., El Kady M.F., Abd-El-Haleem D., Biosynthesis and Structural Characterization of Silver Nanoparticles From Bacterial Isolates, Mater. Res. Bull., 46: 1571-1576 (2011).
6
[7] Malhotra A., Dolma K., Kaur N., Rathore Y.S., Ashish,Mayilraj S., Choudhury A.R., Biosynthesis of Gold and Silver Nanoparticles Using a Novel Marine Strain of Stenotrophomonas, Bioresour. Technol., 142: 727-731 (2013).
7
[8] Yousefi N. ,Pazouki M., Alikhani Hesari F., Alizadeh M., Statistical Evaluation of the Pertinent Parameters in Bio-synthesis of Ag/MWf-CNT Composites Using Plackett-Burman Design and Response Surface Methodology, Iran. J. Chem. Chem. Eng. (IJCCE), 35: 51-62 (2016).
8
[9] Wei X., Luo M., Li W.,Yang L., Liang X., Xu L., Kong P., Liu H., Synthesis of Silver Nanoparticles by Solar Irradiation of Cell-Free Bacillus amyloliquefaciens Extracts and AgNO3, Bioresour. Technol., 103: 273-278 (2012).
9
[10] Ramamurthy C.H., Padma M., Mariya Samadanam I.D., Mareeswaran R., Suyavaran A., Kumar M.S., Premkumar K., Thirunavukkarasu C., The Extracellular Synthesis of Gold and Silver Nanoparticles and Their Free Radical Scavenging and Antibacterial Properties, Colloids Surf., B, 102: 808-815 (2013).
10
[11] Narayanan K.B., Sakthivel N., Facile Green Synthesis of Gold Nanostructures by NADPH-Dependent Enzyme from the Extract of Sclerotium rolfsii, Colloids Surf., A, 380: 156-161 (2011).
11
[12] Faghri Zonooz N., Salouti M., Extracellular Biosynthesis of Silver Nanoparticles Using Cell Filtrate of Streptomyces sp. ERI-3, Sci. Iran., 18: 1631-1635 (2011).
12
[13] Jain N., Bhargava A., Majumdar S., Tarafdar J.C., Panwar J., Extracellular Biosynthesis and Characterization of Silver Nanoparticles Using Aspergillus flavus NJP08: A Mechanism Perspective, Nanoscale, 3: 635-641 (2011).
13
[14] Ahmad A., Mukherjee P., Senapati S., Mandal D., Khan M.I., Kumar R., Sastry M., Extracellular Biosynthesis of Silver Nanoparticles Using the Fungus Fusarium oxysporum, Colloids Surf., B, 28: 313-318 (2003).
14
[15] Moteshafi H., Mousavi S.M., Shojaosadati S.A., The Possible Mechanisms Involved in Nanoparticles Biosynthesis, J. Ind. Eng. Chem, 18: 2046-2050 (2012).
15
[16] Mohammadian A., Shojaosadati S.A., Rezaee M.H., Fusarium oxysporum Mediates Photogeneration of Silver Nanoparticles, Sci. Iran., 14: 323-326 (2007).
16
[17] Bala M., Arya V., Biological Synthesis of Silver Nanoparticles From Aqueous Extract of Endophytic Fungus Aspergillus fumigatus and Its Antibacterial Action, Int. J. Nanomater. Biostruct, 3: 37-41 (2013).
17
[18] Balaji D.S., Basavaraja S. ,Deshpande R., Mahesh D.B., Prabhakar B.K., Venkataraman A., Extracellular Biosynthesis of Functionalized Silver Nanoparticles by Strains of Cladosporium cladosporioides Fungus, Colloids Surf., B, 68: 88-92 (2009).
18
[19] Hamedi S., Shojaosadati S.A., Shokrollahzadeh S., Hashemi-Najafabadi S., Extracellular Biosynthesis of Silver Nanoparticles Using a Novel and
19
Non-Pathogenic Fungus, Neurospora intermedia: Controlled Synthesis and Antibacterial Activity, World J. Microbiol. Biotechnol., 30: 693-704 (2014).
20
[20] Honary S., Barabadi H., Gharaei-Fathabad E., Naghibi F., Green Synthesis of Copper Oxide Nanoparticles Using Penicillium aurantiogriseum, Penicillium citrinum and Penicillium waksmanii, Dig. J. Nanomater. Bios., 7: 999-1005 (2012).
21
[21] Shukla M.K., Singh R.P. ,Reddy C.R.K., Jha B., Synthesis and Characterization of Agar-Based Silver Nanoparticles and Nanocomposite Film with Antibacterial Applications, Bioresour. Technol., 107: 295-300 (2012).
22
[22] Ghaseminezhad S.M., Hamedi S., Shojaosadati S.A., Green Synthesis of Silver Nanoparticles by a Novel Method: Comparative Study of Their Properties, Carbohydr. Polym., 89: 467-472 (2012).
23
[23] Prathna T.C., Chandrasekaran N., Raichur A.M., Mukherjee A., Biomimetic Synthesis of Silver Nanoparticles by Citrus limon (Lmon) Aqueous Extract and Theoretical Prediction of Particle Size, Colloids Surf., B, 82: 152-159 (2011).
24
[24] Sanghi R., Verma P., pH Dependant Fungal Proteins in the ‘Green’ Synthesis of Gold Nanoparticles, Adv. Mater. Lett., 1: 193-199 (2010).
25
[25] Oza G., Pandey S., Shah R., Sharon M., A Mechanistic Approach for Biological Fabrication of Crystalline Gold Nanoparticles Using Marine Algae, Sargassum wightii, Eur. J. Exp. Biol., 2: 505-512 (2012).
26
[26] Jagtap U.B., Bapat V.A., Green Synthesis of Silver Nanoparticles Using Artocarpus heterophyllus Lam. Seed Extract And Its Antibacterial Activity, Ind. Crops Prod., 46: 132-137 (2013).
27
[27] Mohammed Fayaz A., Balaji K., Kalaichelvan P.T., Venkatesan R., Fungal Based Synthesis of Silver Nanoparticles-An Effect of Temperature on the Size of Particles, Colloids Surf., B, 74: 123-126 (2009).
28
[28] Park J., Joo J., Kwon G.S., Jang Y., Hyeon T., Angew, Synthesis of Monodisperse Spherical Nanocrystals, Angew. Chem. Int. Ed., 46: 4630-4660 (2007).
29
[29] Bhainsa K.C., D'Souza S.F., Extracellular Biosynthesis of Silver Nanoparticles Using the Fungus Aspergillus fumigatus, Colloids Surf., B, 47: 160-164 (2006).
30
[30] El-Batal A., Hashem A.-A., Abdelbaky N., Gamma Radiation Mediated Green Synthesis of Gold Nanoparticles Using Fermented Soybean-Garlic Aqueous Extract and Their Antimicrobial Activity, SpringerPlus C7 - 129, 2: 1-10 (2013).
31
[31] Henglein A.,Meisel D., Radiolytic Control of the Size of Colloidal Gold Nanoparticles, Langmuir, 14: 7392-7396 (1998).
32
[32] Akhavan A., Kalhor H.R., Kassaee M.Z., Sheikh N., Hassanlou M., Radiation Synthesis and Characterization of Protein Stabilized Gold Nanoparticles, Chem. Eng. J., 159: 230-235 (2010).
33
ORIGINAL_ARTICLE
Synthesis, Characterization and in Vitro Antimicrobial Screening of the Xanthate Derivatives and their Iron(II) Complexes
Seven reported xanthate ligands and their new Fe(II) complexes of formulaNa[Fe(R-OCSS)3], where R is ethyl-, propyl-, butyl-, pentyl-, Hexyl-, heptyl- and octyl-xanthate have been synthesized. They have been characterized using elemental analysis, molar conductance, FT-IR, UV-Vis and 1H NMR spectroscopic techniques and melting-, decomposition-points for ligands and complexes respectively. All the ligands and their Fe(II) complexes have been evaluated for their antimicrobial activity against four gram-positive bacteria, four gram-negative bacteria and three fungi by agar disc diffusion technique. The MIC values of the compounds exhibited significant antifungal activity but showed lower antibacterial activity. The iron(II) complexes are found to possess higher antimicrobial activity than their counterpart ligands thus improving its antimicrobial efficacy. Hydrocarbon chain length of the ligands coordinated to Fe(II) centers seemed to be important for their antifungal as well as antibacterial activities.
https://ijcce.ac.ir/article_25477_eff3f79ae10aae35e82f68726896c71e.pdf
2017-10-01
43
54
10.30492/ijcce.2017.25477
Xanthate
Fe(II) complex
Antifungal activity
Antibacterial activity
Hassan
Mansouri Torshizi
hmtorshizi@hamoon.usb.ac.ir
1
Department of Chemistry, University of Sistan and Baluchestan, Zahedan, I.R. IRAN
LEAD_AUTHOR
Sareh
Zareian-Jahromi
sareh_zareianjahromi@yahoo.com
2
Department of Chemistry, University of Sistan and Baluchestan, Zahedan, I.R. IRAN
AUTHOR
Maram
Saeidifar
m.saidifar@gmail.com
3
Department of Nanotechnology and Advanced Materials, Materials and Energy Research Center, Karaj, I.R. IRAN
AUTHOR
Ali
Ghasemi
m_saidifar@yahoo.com
4
Department of Biology and Microbiology, University of Sistan and Baluchestan, Zahedan, I.R. IRAN
AUTHOR
Hamed
Ghaemi
saeidifar@merc.ac.ir
5
Islamic Azad University, Neyshabur Branch, Neyshabur, I.R. IRAN
AUTHOR
Ali
Heydari
hmtorshizi@gmail.com
6
Department of Chemistry, University of Sistan and Baluchestan, Zahedan, I.R. IRAN
AUTHOR
[1] Antonio F.S., Débora F.B., Lis R.V. F., Natália A.C., Geziel R.A., Margareth B., Alberto A.C., Ademir N., Daniela C.M.R., Ademir D.A., Study of the Antimicrobial Activity of Metal Complexes and Their Ligands Through Bioassays Applied to
1
Plant Extracts, Rev. Bras. Farmacogn., 24: 309-315 (2014).
2
[2] Bouchoucha A., Terbouche A., Zaouani M., Derridj F., Djebbar S., Iron and Nickel Complexes with Heterocyclic Ligands: Stability, Synthesis, Spectral Characterization, Antimicrobial Activity, Acute and Subacute Toxicity, J. Trace Elem. Med Biol.,27: 191-202 (2013).
3
[3] Sabounchei S.J., Pourshahbaz M., Salehzadeh S., Bayat M., Karamian R., Asadbegy M., Khavasi H.R., New Chlorine Bridged Vinuclear Silver(I) Complexes of Bidentate Phosphorus Ylides: Synthesis, Spectroscopy, Theoretical and Anti-Bacterial Studies, Polyhedron, 85: 652-664 (2015).
4
[4] Sharma A., Jain A., Saxena S., The Structure–Activity Relationship of Some Hexa coordinated dimethyl Tin(IV) Complexes of Fluorinated β-diketone/β-Diketones and Sterically Congested Heterocyclic β-Diketones, Appl. Organomet. Chem., 29: 499-508 (2015).
5
[5] Kiran T., Prasanth V.G., Balamurali M.M., Vasavi C.S., Munusami P., Sathiyanarayanan K.I., Pathak M., Synthesis, Spectroscopic Characterization and in Vitro Studies of New Heteroleptic Copper (II) Complexes Derived From 2-Hydroxy Napthaldehyde Schiff’s Bases and N, N Donor Ligands: Antimicrobial, DNA Binding and Cytotoxic Investigations, Inorg. Chim. Acta., 433: 26-34 (2015).
6
[6] Alijanianzadeh M., Saboury A.A., Mansuri-Torshizi H., Haghbeen K., Moosavi-Movahedi A.A., The Inhibitory Effect of Some New Synthesized Xanthates on Mushroom Tyrosinase Activities, J. Enzyme Inhibition and Medicinal Chemistry, 22: 239-246 (2007).
7
[7] Hanif M., Chohan Z.H., Synthesis, Spectral Characterization and Biological Studies of Transition Metal(II) Complexes with Triazole Schiff Bases, Appl. Organomet. Chem., 27: 36-44 (2012).
8
[8] Saboury A.A., Alijanianzadeh M., Mansouri- Torshizi H., The Role of Alkyl Chain Length in the Inhibitory Effect n-alkyl Xanthates on Mushroom Tyrosinase Activities, Acta Biochim. Pol., 54: 183-191 (2007).
9
[9] Geraldo M.D., Daniele C.M., Camila A.C., Jaqueline A.F.d., Isabella P.F., Eucler B.P., James L.W., Solange M.S.V.W., Klaus K., Isolda C.M., Heloisa B., Synthesis, Characterisation and Biological Aspects of Copper(II) Dithiocarbamate Complexes, [Cu{S2CNR(CH2CH2OH)}2], (R=Me, Et, Pr and CH2CH2OH), J. Mol. Struct, 988: 1-8 (2011).
10
[10] Anthony C.E., Damian C.O., Cyril U., Eno E.E., Mixed Ligand Complexes of N-Methyl-N-phenyl Dithiocarbamate: Synthesis, Characterisation, Antifungal Activity, and Solvent Extraction Studies of the Ligand, Bioinorg. Chem. Appl., 2015: 1-8 (2015).
11
[11] Syed Q.S., Mohammad R.K., Synthesis of 99mTcN-Clinafloxacin Dithiocarbamate Complex and Comparative Radiobiological Evaluation in Staphylococcus Aureus Infected Mice, World J. Nucl. Med., 13: 154-158 (2014).
12
[12] Mohammad T., Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) Complexes with Diisobutyl dithiocarbamato Ligand, E-J. Chem., 8: 2020-2023 (2011).
13
[13] Saad E.A., Hasan A.M., Synthesis and Characterization of Mn(II), Fe(II) and Co(II) Complexes with 4-Hydroxypiperidinedithiocarbamate and their Adducts with Neutral Bases, Raf. J. Sci., 25: 53-61 (2014).
14
[14] Mohammad T., Mohammad A., Investigation on Transition Metal Complexes with Sulphur and Nitrogen Containing Ligand Derived from Diethylamine, Asian J. Chem., 22: 2465-2467 (2010).
15
[15] Nabipour H., Synthesis of a New Dithiocarbamate Cobalt Complex and Its Nanoparticles with the Study of Their Biological Properties, Int. J. Nano. Dim., 1: 225-232 (2011).
16
[16] Núñez C., Fernández-Lodeiro A., Fernández-Lodeiro J., Carballo J., Capelo J.L., Lodeiro C., Synthesis, Spectroscopic Studies and in Vitro Antibacterial Activity of Ibuprofen and Its Derived Metal Complexes, Inorg. Chem. Commun., 45: 61-65 (2014).
17
[17] Xu B., Kong X.L., Zhou T., Qiu D.H., Chen Y.L., Liu M.S., Yang R.H., Hider R.C., Synthesis, Iron(III)-Binding Affinity and in Vitro Evaluation of 3-Hydroxypyridin-4-One Hexadentate Ligands as Potential Antimicrobial Agents, Bioorg. Med. Chem. Let., 21: 6376-6380 (2011).
18
[18] PramanikH.A.R., Paul P.C., MondalP., Bhattacharjee C.R., Mixed Ligand Complexes of Cobalt(III) and Iron(III) Containing N2O2-Chelating Schiff Base: Synthesis, Characterisation, Antimicrobial Activity, Antioxidant and DFT Study, J. Mol. Struct., 1100: 506-512 (2015).
19
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33
ORIGINAL_ARTICLE
Influences of NCO/OH and triol/diol Ratios on the Mechanical Properties of Nitro-HTPB Based Polyurethane Elastomers
The present study describes the effect of NCO/OH and triol/diol ratios on the mechanical properties of Nitro functionalized Hydroxyl-terminated polybutadiene (Nitro-HTPB) elastomers. The progress of the cure reaction of Nitro-HTPB and toluene diisocyanate (TDI) is evaluated by following up the variations in the IR absorption bands of the NCO stretching and the CO Stretching. Experiments are carried out at NCO/OH ratios (R values) ranging from 0.8 to 1.2 and triol/diol ratios in the range of 0.05-0.7. Also as the R-value increases, the tensile strength increases, and elongation decreases. The rubbery character of elastomers is improved followed by increased rigidity with an increase in triol/diol value of 0.05. In general, desirable mechanical properties were achieved for the polyurethane elastomers of Nitro-HTPB as a novel energetic binder.
https://ijcce.ac.ir/article_25250_bfaa1389527c87e693e72d02cc3482cc.pdf
2017-10-01
55
63
10.30492/ijcce.2017.25250
Mechanical properties
Elastomer
Nitro-HTPB
Polyurethane
TDI
Hadi
Abusaidi
hadinet79@gmail.com
1
Department of Chemistry and Chemical Engineering, Faculty of Chemistry, Malek-Ashtar University of Technology (MUT), Tehran, I.R. IRAN
AUTHOR
Hamid Reza
Ghaieni
h.r.ghaieni@gmail.com
2
Department of Chemistry and Chemical Engineering, Faculty of Chemistry, Malek-Ashtar University of Technology (MUT), Tehran, I.R. IRAN
LEAD_AUTHOR
Mostafa
Ghorbani
mostafa.110164@gmail.com
3
Department of Chemistry and Chemical Engineering, Faculty of Chemistry, Malek-Ashtar University of Technology (MUT), Tehran, I.R. IRAN
AUTHOR
[1] Gopala Krishnan P.S., Ayyaswamy K., Nayak S., Hydroxy Terminated Polybutadiene: Chemical Modifications and Applications, J. Macromol. Sci. Part A, 50(1): 128-138 (2013).
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[2] DeLuca L., Galfetti, L., Maggi F., Colombo G., Merotto L., Boiocchi M., Paravan C., Reina A., Tadini P., Fanton L., Characterization of HTPB-Based Solid Fuel Formulations: Performance, Mechanical Properties, and Pollution, Acta Astronaut., 92(2): 150-162 (2013).
2
[3] Agrawal J.P., Recent Trends in High-Energy Materials, Prog. Energ. Combust. 24(1): 1-30 (1998).
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[4] Colclough M.E., Desai H., Millar R.W., Paul N.C., Stewart M.J., Golding P., Energetic Polymers as Binders in Composite Propellants and Explosives, Polym. Advan. Technol. 5(9): 554-560 (1994).
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[5] Badgujar D., Talawar M., Asthana S., Mahulikar P., Advances in Science and Technology of Modern Energetic Materials: an Overview, J. Hazard. Mater. 151(2): 289-305 (2008).
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[7] Abdullah M., Gholamian F., Zarei A., Investigation of Composite Solid Propellants Based on Nitrated Hydroxyl-Terminated Polybutadiene Binder, J. Propul. Power. 30(3): 862-864 (2014).
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[8] Colclough M., Paul N., Nitrated Hydroxy-Terminated Polybutadiene: Synthesis and Properties, Am. Chem. Soc. 623: 97-103 (1996).
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[9] Wang Q., Wang L., Zhang X., Mi Z., Thermal Stability and Kinetic of Decomposition of Nitrated HTPB, J. Hazard. Mater. 172(2): 1659-1664 (2009).
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[10] Sankar R.M., Roy T.K., Jana T., Functionalization of Yerminal Varbon atoms of Hydroxyl Terminated Polybutadiene by Polyazido Nitrogen Rich Molecules, Bull. Mater. Sci. 34(4): 745-754 (2011).
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[11] Gross M.L., Hedman T.D., Son S.F., Jackson T.L., Beckstead, M.W., Coupling micro and Meso-Scale Combustion Models of AP/HTPB Propellants, Combust. Flame 160(5): 982-992 (2013).
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[12] Nagamachi M.Y., Oliveira J.I.S., Kawamoto A.M., Rita de Cássia L.D., ADN - The New Oxidizer Around the Corner for an Environmentally Friendly Smokeless Propellant, J. Aerosp. Technol. Manag. 1(2): 153-160 (2011).
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[14] Abusaidi H., Ghaieni H.R., Pourmortazavi S.M., Motamed-Shariati S.H., Effect of Nitro Content on Thermal Stability and Decomposition Kinetics of Nitro-HTPB, J. Therm. Anal. Calorim. 124(2): 935-941 (2016).
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[15] Kumari D., Balakshe R., Banerjee S., Singh H., Energetic Plasticizers for Gun & Rocket Propellants, Rev. J. Chem., 2(3): 240-262 (2012).
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[17] Rao K.P., Sikder A.K., Kulkarni M.A., Bhalerao M.M., Gandhe B.R., Studies on n‐Butyl Nitroxyethylnitramine (n‐BuNENA): Synthesis, Characterization and Propellant Evaluations, Propell. Explos Pyrotech. 29(2): 93-98 (2004).
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22
ORIGINAL_ARTICLE
The Effect of Ziziphora clinopodioides Essential Oil and Nisin on Chemical and Microbial Characteristics of Fish Burger during Refrigerated Storage
Ziziphora clinopodioides is from the genus of Ziziphora and family of Lamiaceae,which grows in Iran and Turkey. This study was conducted to preserve the chemical and microbial quality of trout fish burger during storage using Ziziphora clinopodioides essential oil (ZEO) individually and in combination with nisin. Firstly, the chemical composition of ZEO was determined using GC-MS analysis. Different treatments of trout fish burger were formulated using ZEO and nisin as natural preservatives, stored in refrigerator for 20 days and were analyzed for chemical (pH and Total Volatiles Base-Nitrogen (TVB-N)) and microbial (total viable count, psychotropic counts, Enterobacteriaceae count and Pseudomonas spp count) characteristics.at 5-day intervals.The Results indicated a yield of 1% (w/w) for ZEO isolation and Pulegone (40.09%), Menthone (13.76%) and Isomenthone (12.31%) were identified as the major components of phytochemicals of ZEO. According to the obtained results combination of ZEO and nisin had the strongest effect on chemical and microbial quality of fish burger; however, their individual use had significant effects on preserving the chemical and microbial quality of fish burger as well. based on results of this study, formulation of ZEO and Nisin in fish burger especially in combinations can prolong its shelf life and control chemical and microbial changes during storage at 4˚ C.
https://ijcce.ac.ir/article_24338_024fb6056adf9c3ffc25efefdc8bc3f5.pdf
2017-10-01
65
75
10.30492/ijcce.2017.24338
Chemical composition
Chemical quality
Fish burger
Total volatile base nitrogen
Ziziphora clinopodioides
Reza
Shahinfar
shahinfar56@yahoo.com
1
Department of Food Hygiene and Aquaculture, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
saeid
khanzadi
khanzadi@um.ac.ir
2
Department of Food Hygiene and Aquaculture, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
LEAD_AUTHOR
Mohammad
Hashami
mo_hashemi@hotmail.com
3
Departments of Nutrition, Faculty of Medicine, Mashhad University of Medical Sciences, Mashhad, I.R. IRAN
AUTHOR
Mohammad
Azizzadeh
azizzadeh@gmail.com
4
Department of Clinical Science, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
Aram
Bostan
arambostan@yahoo.com
5
Food Nanotechnology Department, Research Institute of Food Science and Technology (RIFST), Mashhad, I.R. IRAN
AUTHOR
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64
ORIGINAL_ARTICLE
Sensory Analysis of Fish Burgers Containing Ziziphora clinopodioides Essential Oil and Nisin: The Effect of Natural Preservatives and Microencapsulation
The present study aimed to evaluate the effect of free and microencapsulated Ziziphora clinopodioides Essential Oil (ZEO) and Nisin individually and in combinationon sensory characteristic and shelf life of fish burger during 20 days of storage at 4±1˚C. Fish burgers were prepared and treated with free and microencapsulated form of ZEO and Nisin in 15 treatments and evaluated by 20 stable semi-trained people using a 9-point hedonic screen method on days 0, 5, 10, 15, 20. The chemical composition of fish burgers was also analyzed at the first day of storage. Results indicated that both microencapsulation and combinational use of ZEO and Nisin improved sensorial scores of treated samples during 20-day storage at 4±1˚C (P< 0.05), and samples containing microencapsulated ZEO and Nisin showed the strongest effect on preserving the sensorial quality of fish burgers.
https://ijcce.ac.ir/article_26640_0f75b9f8e56e720544b553c0906b68f4.pdf
2017-10-01
77
88
10.30492/ijcce.2017.26640
Hedonic scale
Sensory analysis
Fish burger
encapsulation
Reza
Shahinfar
shahinfar56@yahoo.com
1
Department of Food Hygiene and Aquaculture, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
Saeid
Khanzadi
khanzadi@um.ac.ir
2
Department of Food Hygiene and Aquaculture, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
LEAD_AUTHOR
Mohammad
Hashami
mo_hashemi@hotmail.com
3
Departments of Nutrition, Faculty of Medicine, Mashhad University of Medical Sciences, Mashhad, I.R. IRAN
AUTHOR
Mohammad
Azizzadeh
azizzadeh@gmail.com
4
Department of Clinical Science, Faculty of Veterinary Medicine, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN
AUTHOR
Aram
Bostan
arambostan@yahoo.com
5
Food Nanotechnology Department, Research Institute of Food Science and Technology (RIFST), Mashhad, I.R. IRAN
AUTHOR
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62
ORIGINAL_ARTICLE
Cyanogen, Methylacetylene, Hydroquinone, Ethylacetylene, Aniline, Pyrrole, and Ethanol Detection by Using BNNT: DFT Studies
Electrical sensitivity of a Boron Nitride Nano Tube (BNNT) was examined toward hydroquinone (C6H4(OH)2), cyanogens (C2N2), methylacetylene (C3H4), ethylacetylene (C4H6), aniline (C6H5NH2), ethanol (C2H5OH), pyrrole (C4H5N), molecules by using Density Functional Theory (DFT) calculations at the B3LYP/6-31G(d) level of theory. In considering the dsorption energy (Ead) of those molecules on the BNNT are sequenced: C6H5NH2(Ead= -47.55kcal/mol)> C4H5N (Ead=-26.66kcal/mol) >C2H5OH(Ead= -25.91kcal/mol)> (CN)2(Ead=-20.70kcal/mol)> C6H4(OH)2(Ead= -20.21kcal/mol) >C3H4(Ead=-12.73kcal/mol)> C4H6(Ead=-11.19kcal/mol). According to this comparison aniline molecule with Ead=-47.55 kcal/mol has the most adsorption energy among all molecules. Calculations showed that when the nanotube was doped by Si and Al atoms, the amount of HOMO/LUMO energy gap (Eg) reduced significantly. This reduced showed that BNNT is a suitable semiconductor after doping and the doped BNNT in the presence of those gases generates an electrical signal and therefore can be used potentially for gas sensors. Recent researches demonstrate that Boron nitride nanotube is a suitable adsorbent for detection and separation of those compounds.
https://ijcce.ac.ir/article_24715_62e89f6530851d4a5c4cd4d7084bf278.pdf
2017-10-01
89
98
10.30492/ijcce.2017.24715
sensor
Nanotube
DFT
BNNT
Sahar
Mohajeri
sahar_mohajeri@yahoo.com
1
Department of Chemistry, Ardabil Branch, Islamic Azad University, Ardabil, I.R. IRAN
LEAD_AUTHOR
Maziar
Noei
maziar.noei@hotmail.com
2
Department of Chemistry, College of Chemical Engineering , Mahshahr Branch, Islamic Azad University, Mahshahr, I.R. IRAN
AUTHOR
Nazanin
Molaei
nazanin.molaei611@gmail.com
3
Department of Chemistry College of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, I.R. IRAN
AUTHOR
[1] Yousefi N., Pazouki M., Alikhani Hesari F., Alizadeh M., Statistical Evaluation of the Pertinent Parameters
1
in Biosynthesis of Ag/MWf-CNT Composites Using Plackett-Burman Design and Response Surface Methodology, Iran. J. Chem. Chem. Eng. (IJCCE), 35(2): 51-62 (2016).
2
[2] Hongmei J., Shuqin W., Wenfang D., Youming Z., Yueming T., Qingji X., Ming M., Graphene-Like Carbon Nanosheets as a New Electrode Material for Electrochemical Determination of Hydroquinone and Catechol, Talanta, 164:300-306 (2017).
3
[3] Noei M., Ebrahimikia M., Saghapour Y., Khodaverdi M., Salari A.A., Ahmadaghaei N., Removal of Ethyl Acetylene Toxic Gas from Environmental Systems Using AlN Nanotube, J. Nanostruct. Chem., 5(2): 213-217 (2015).
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[10] Karimi P., Effects of Structure and Partially Localization of the π Electron Clouds of Single-Walled Carbon Nanotubes on the Cation-π Interactions, Iran. J. Chem. Chem. Eng.(IJCCE), 35(3):35-43 (2016).
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[11] Noei M., Asadi H., Salari A.A., Hosseini Mahjoob S.M.R., Adsorption of Pyridine by Using BN Nanotube: A DFT study, Indian Journal of Fundamental and Applied life Sciences, 4(2): 679-685 (2014).
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[12] Lin X., Chen D.Q., Zhong B., Yang J.L., Purification of Yard-Glass shaped boron nitride nanotubes, Iran. J. Chem. Chem. Eng. (IJCCE), 33(1):29-36 (2014).
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[13] Noei M., Ghaemizadeh M., Adsorption of Ethanol by Using BN Nanotube: A DFT Study, Int. J. New Chemistry, 1(1):22-29 (2014).
14
[14] Moghimi M., Baei M.T., Nanostructures’ Study of Chemisorptions of O2 Molecule on Al (100) Surface, Journal of Saudi Chemical Society, 18(5):469-473 (2014).
15
[15] Peyghan A.A., Yourdkhani S., Noei M., Working Mechanism of a BC3 Nanotube Carbon Monoxide Gas Sensor, Commun. Theor. Phys, 60(1):113-118 (2013).
16
[16] Beheshtian J., Noei M., Soleymanabadi H., Peyghan A.A., Aamonia Monitoring by Carbon Nitride Nanotubes: A Density Functional Study, Thin Solid Films, 534(null):650-654 (2013).
17
[17] Noei M., Salari A.A., Ahmadaghaei N., Bagheri Z., Peyghan A.A., DFT Study of the Dissociative Adsorption of HF on an AlN Nanotube, C. R. Chimie, 16(11):985-989 (2013).
18
[18] Tonigold K., Grob A., Adsorption of Small Aromatic Molecules on the (111) Surfaces of Nobel Metals: A Density Functional Theory Study with Semiempirical Corrections for Dispersion Effects, J. Chem. Phys, 132(22): 224701-10 (2010).
19
[19] Sarma J.V.N., Rahman A., Jayaganthan R., Chowdhury R., Haranath D., Al-doped ZnO Nanostructured Thin Films: Density Functional Theory and Experiment, Int. J. Nanosci., 14(4): 1550015-1550028 (2015).
20
[20] Breedon M., Spencer M.J.S., Yarovsky I., Adsorption of NO2 on Oxygen Deficient ZnO(2101) for Gas Sensing Applications: A DFT Study, J. Phys. Chem. C., 114(39):16603-16610 (2010).
21
[21] Najafpour J., Zohari N., The Structure and Chemical Bond of FOX-7: The AIM Analysis and Vibrational Normal Modes, Iran. J. Chem. Chem. Eng.(IJCCE), 30(3):113-120 (2011).
22
[22] Salari A., Ebrahimikia M., Ahmadaghaei N., Dehdari B., Noei M., Pyrrole Detection by BeO Nanotube: DFT Studies, Int. J. New Chemistry, 1(3):134-144 (2014).
23
[23] Noei M., Probing the Electronic Sensitivity of BN and Carbon Nanotubes to Carbonyl Sulfide: A Theoretical Study, Journal of Molecular Liquids, 224(A):757-762 (2016).
24
[24] Peygan A.A., Hadipour N.L., Bagheri Z., Effects of Al Doping and Double-Antisite Defect on the Adsorption of HCN on a BC2N Nanotue: Density Functional Theory Studies, J. Phys. Chem. C, 117(5):2427-2432 (2013).
25
[25] Beheshtian J., Peygan A.A., Noei M., Sensing Behavior of Al and Si Doped BC3 Graphenes to Formaldehyde, Sensors and Actuators B: Chemical, 181:829-834 (2013)
26
[26] Shokuhi Rad A., First Principles Study of Al-Doped Graphene as Nanostructure Adsorbent for NO2 and N2O:DFT Calculations, Applied Surface Science, 357(A):1217-1224 (2015).
27
[27] Peygan A.A., Noei M., Electronic Response of nano-Sized Cages of ZnO and MgO to Presence of Nitric Oxide, Chinese journal of chemical physics, 26(2):231-236 (2013).
28
ORIGINAL_ARTICLE
Incorporation of Copper/Melamine Complexes in Silica Surface Andtheir Sorption Activity of Organic Dye
The efficiency and performance of supported melamine/ copper complexes, S/[CuCl2(Mel)2].2MeOH, as a new adsorbent, for the adsorptive removal of Indigo Carmine (IC) from aqueous solutions, has been evaluated with respect to several experimental conditions including contact time, initial IC concentration, temperature and adsorbent dosage. The maximum removal percentage (approximately 84%) was observed when used 0.05 g/L of S/[CuCl2(Mel)2].2MeOH, 1.5 x 10-5mol/L of initial IC concentration and contact time of 15min. The experimental data were analyzed by the Langmuir, Freundlich, and Tempkin isotherm models. The monolayer adsorption capacity of S/[CuCl2(Mel)2].2MeOHwas found to be 16.8 x 10-3mol/g by using Langmuir isotherm model. The calculation of the thermodynamic parameters such as Gibbs free energy, entropy and enthalpy changes of the ongoing adsorption process indicated the feasibility and endothermic nature of IC adsorption. The kinetics study suggested that the adsorption of IC onto S/[CuCl2(Mel)2].2MeOH proceeds according to the pseudo-second-order model.
https://ijcce.ac.ir/article_30021_fe0c69a07a74898af5c9606ba806f343.pdf
2017-10-01
99
114
10.30492/ijcce.2017.30021
Melamine complexes
Characterization
Removal
Adsorption
indigo Carmine
Rehab G.
Elsharkawy
relsharkawy@yahoo.com
1
Chemistry Department, Faculty of Science, Tanta University, Tanta, EGYPT
LEAD_AUTHOR
[1] Refat M.S., Adam A.- M.A., El-Sayed M.Y., Biomarkers Charge-Transfer Complexes of Melamine with Quinol and Picric Acid: Synthesis, Spectroscopic, Thermal, Kinetic and Biological Studies, Arabian Journal of Chemistry, 10: S3482-S3492 (2014).
1
[2] Xu L.-F., Chen X.-L., Hu H.-M., Wang B.-C., Syntheses, Structures and Electrochemical Properties of Two Co-Crystal Copper(II) Melamine Complexes, Journal of Molecular Structure, 892: 163-167 (2008).
2
[3] Zhang J., LiZ.-J., WenY.-H., KangY., ChengJ.-K., YaoY.-G., Syntheses and Structures of Two Novel Ag(I) Complexes: [μ3-2-(4-pyridyl)Ethanesulfonato-N,O,O′]-Aqua-Silver(I) and Melamine-[2-(4-pyridyl)Ethanesulfonato-N]-Silver(I), Journal of Molecular Structure, 697:185-189 (2004).
3
[4] Acharya S.N.G., Gopalan R.S., Kulkarni G.U., Venkatesan K., Bhattacharya S., Novel Organic Porous Solids with Channel and Layered Structures From 1, 3, 5-Triazine-2, 4, 6-Triaminehexaacetic Acid and Its Calcium Salt, Chem. Commun.,15: 1351-1352 (2000).
4
[5] Sharif M.A., Aghabozorg H., Shokrollahi A., Kickelbick G., Moghimi A., Shamsipur M. Novel Proton Transfer Compounds Containing 2,6-Pyridine dicarboxylic Acid and Melamine and Their PbII Complex: Synthesis, Characterization, Crystal Structure and Solution Studies, Polish J. Chem., 80: 847-863 (2006).
5
[6] Feng W., Lv C., Yang L., Cheng J., Yan C., Determination of Melamine Concentrations in Dairy Samples, LWT-food Science and Technology, 47:147-153 (2012).
6
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ORIGINAL_ARTICLE
Optimization of Pb(II) Adsorption onto Australian Pine Cones-Based Activated Carbon by Pulsed Microwave Heating Activation
This study proposed a novel method for preparing activated carbon from Australian Pine cones (APCs) to optimize Pb(II) adsorption. Based on an analysis conducted, the APCs dried powder consisted of approximately 51.32 wt% of cellulose and 21.15 wt% of lignin on average. Experiments in batch mode at 100-rpm stirring speed, pH 4.7 (± 0.3) and 27 oC (± 2 oC) were conducted to obtain the maximum adsorption capacity of Australian Pine cones activated carbon(the APCs AC) over the independent variables of contact time, initial Pb(II) concentration in solution, the concentration of NaOH activator and Pulsed Microwave Heating (PMH). As the result, the maximum Pb(II) adsorption capacity was obtained when using the APCs AC with 1 M NaOH and the PMH activation. It follows Langmuir Isotherm Model (LIM) and the pseudo-second-order kinetics model (PSOKM) with the correlation coefficients (R2) being 0.993 and 1, respectively. The LIM maximum Pb(II) adsorption capacity was 166.667 mg/g, the PSOKM maximum equilibrium Pb(II) adsorption capacity was 151.515 mg/g reached in 120-min contact time, and the PSOKM kinetics constant was 0.295 g/mg.min for 1571.89 mg/L of initial Pb(II) concentration. This optimum condition was reasonable because the PMH resulted from the dominant active site of the functional group of hydroxyl on the APCs AC for Pb(II) adsorption as shown by Fourier Transform Infrared Spectroscopy analysis, and more pores were shown in Scanning Electron Microscopy (SEM) analysis.
https://ijcce.ac.ir/article_30035_6ce2e90cef9d2542dc6426d94fbb4eb7.pdf
2017-10-01
115
127
10.30492/ijcce.2017.30035
Australian pine cones
Adsorption
Isotherm
Kinetics, Pulsed microwave heating
Optimization
Abrar
Muslim
abrar.muslim@che.unsyiah.ac.id
1
Process Technology Laboratory, Department of Chemical Engineering,Engineering Faculty, Syiah Kuala University, Banda Aceh, Post Code 23111, INDONESIA
LEAD_AUTHOR
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52
[53] Muslim A., Zulfian, Ismayanda M.H., Devrina E., Fahmi H., Adsorption of Cu(II). From the Aqueous Solution by Chemical Activated Adsorbent of Areca Catechu Shell, Journal of Engineering Science and Technology, 10(12), 1654–1666 (2015).
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[59] Kikuchi Y., Qian, Q., Machida, M., Tatsumoto, H., Effect of ZnO Loading to Activated Carbon on Pb(II) Adsorption From Aqueous Solution, Carbon, 44(2): 195–202 (2006).
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[61] Ricordel S., Taha, S., Cisse, I., Dorange, G., Heavy Metals Removal by Adsorption Ontopeanut Husks Carbon: Characterization, Kinetic study and Modeling, Separation and Purification Technology, 24(3), 389–401 (2001).
61
ORIGINAL_ARTICLE
Response Surface Methodology Optimization of Cobalt (II) and Lead (II) Removal from Aqueous Solution Using MWCNT-Fe3O4 Nanocomposite
The present investigation describes the evaluation of feasibility of MWCNT-Fe3O4 nanocomposite toward adsorptive removal of Co(II) and Pb(II) from aqueous solution in batch mode. The Fe3O4–MWCNT hybrid was prepared using a simple one-pot strategy via in situ growth of Fe3O4 magnetic nanoparticles onto the surface of the MWCNTs. The Fe3O4–MWCNT hybrid was characterized by X-ray diffractometry and Field Emission Scanning Electron Microscopy (FESEM). A Response Surface Methodology (RSM) with a Central Composite Design (CCD) was employed to evaluate the effects of solution pH, contact time, temperature, initial heavy metal concentration and adsorbent dosage on the removal efficiency of the heavy metals. Results of analysis of variance (ANOVA) showed that the initial metal concentration and absorbent dosage and their interaction effect were the most significant parameters for Co(II) ion removal. Adsorbent dosage, pH and initial metal concentration had significant influences on the removal efficiency of Pb(II) ions. The optimum pH, time, temperature, initial concentration of metals and adsorbent dosage were found to be 6.5,25 min, 40 °C, 35 mg/L, and 48.3 mg/50mL, respectively. Maximum removal of Pb(II) and Co(II) in optimum condition was 90.2 and 79.34% respectively. Results indicated that nanocomposite can be used as an effective adsorbent for effluent decontamination especially in Pb–Co bearing wastewaters. The equilibrium data were well fitted by the Langmuir model. The removal mechanism of metal ions followed adsorption and ion exchange processes.
https://ijcce.ac.ir/article_25481_e741a3f944163118e6d3cba1ecc3a9a7.pdf
2017-10-01
129
141
10.30492/ijcce.2017.25481
Nanocomposite
Removal
Cobalt
Lead
RSM
Milad
Goleij
milad.goleij@hotmail.com
1
Department of Chemical Engineering, Shahrood Branch, Islamic Azad University, Shahrood, I.R. IRAN
AUTHOR
Hossein
Fakhraee
hossein.fakhraee@hotmail.com
2
Department of Passive Defense Research Group, Logistics and Crisis Management, Malek Ashtar University of Technology, Tehran, I.R. IRAN
LEAD_AUTHOR
[1] Fenglian F.u., Qi W., Removal of Heavy Metal Ions From Wastewaters: A Review, Journal of Environmental Management, 92(3):65-81 (2011).
1
[2] Barakat M.A., New Trends in Removing Heavy Metals From Industrial Wastewater, Arabian Journal of Chemistry, 4(4):361–377 (2011).
2
[3] Lim A.P., Aris A.H., A Review on Economically Adsorbents on Heavy Metals Removal in Water and Wastewater, Reviews in Environmental Science and Bio/Technology, 13(2):163-181 ( 2014).
3
[4] Solat Sana, Reza Roostaazad, Soheila Yaghmaei, Biosorption of Uranium (VI) from Aqueous Solution by Pretreated Aspergillus Niger Using Sodium Hydroxide, Iran. J. Chem. Chem. Eng.(IJCCE) 34(1):65-74 (2015).
4
[5] Marziyeh Sanchooli Moghaddam, Somayeh Rahdar, Mahmoud Taghavi, Cadmium Removal from Aqueous Solutions Using Saxaul Tree Ash, Iran. J. Chem. Chem. Eng.(IJCCE), 35(3):45-52 (2016).
5
[6] Bhatti Haq Nawaz, Khadim Rubina, Hanif Muhammad Asif, Biosorption of Pb(II) and Co(II) on Red Rose Waste Biomass, Iran. J. Chem. Chem. Eng.(IJCCE), 30(4):81-87 (2011).
6
[7] Xiao-fei T., et al., Biochar-based Nano-Composites for the Decontamination of Wastewater: A Review Bioresource Technology, Bioresource Technology, 212:318–333 (2016).
7
[8] Ghasemi, Z., H. Younesi, A. Akbar Zinatizadeh, Kinetics and Thermodynamics of Photocatalytic Degradation of Organic Pollutants in Petroleum Refinery Wastewater over Nano-TiO2 Supported on Fe-ZSM-5, Journal of the Taiwan Institute of Chemical Engineers, 65:357–366 (2016).
8
[9] Liwei F., Zhang S., Zhang X., Zhou H., Lub Z., Wang S., Removal of Arsenic from Simulation Wastewater Using Nano-Iron/Oyster Shell Composites, Journal of Environmental Management, 156(1):109–114 (2015).
9
[10] Chen H., Luo H.J., Lan Y.C., Dong T.T., Hu B.J., Wang Y.P., Removal of Tetracycline From Aqueous Solutions Using Polyvinylpyrrolidone (PVP-K30) Modified Nanoscale Zero Valent Iron, J. Hazard. Mater, 92:44-53 (2011).
10
[11] Khan N.A., Khan K.A., Islam M., “Water and Wastewater Treatment using Nano-technology” Chemistry of Phytopotentials: Health, Energy and Environmental Perspectives , Springer Berlin Heidelberg Section C , 315-318 (2012).
11
[12] Ming H., Shujuan Z., Bingcai P., Heavy Metal Removal From Water/Wastewater by Nanosized Metal Oxides: A Review, Journal of Hazardous Materials, 211–212(15):317–331 (2012).
12
[13] Byung Hyo K., Michael J. H., Jongnam Park, Synthesis, Characterization, and Application of Ultrasmall Nanoparticles, Chem. Mater, 26(1):59–71 (2014).
13
[14] Mandavian A.R., Mirrahimi M.A.S., Efficient Separation of Heavy Metal Cations by Anchoring Polyacrylic Acid on Superparamagnetic Magnetite Nanoparticles Through Surface Modification, Chem. Eng. J, 159:264–271 (2010).
14
[15] Chen Y.H., Li F.A., Kinetic Study on Removal of Copper (II) Using Goethite and Hematite Nano-Photocatalysts,
15
J. Colloid Interface Sci, 347:277–281 (2010).
16
[16] Badruddoz A.Z.M., Tay A.S.H., Tan P.Y., Hidajat K., Uddin M.S., Carboxymethyl-beta-cyclodextrin Conjugated Magnetic Nanoparticles as Nano-Adsorbents for Removal of Copper Ions: Synthesis and Adsorption Studies, J. Hazard. Mater, 185:1177–1186 (2011).
17
[17] Ihsanullaha A., Adnan M. A., Tahar L., Heavy Metal Removal from Aqueous Solution by Advanced Carbon Nanotubes: Critical Review of Adsorption Applications. Separation and Purification Technology, 157(8):141–161 (2016).
18
[18] Wang H., Yan N., Li Y., Zhou X.H., Chen J., Yu B.X., Gong M., Chen Q.W., Fe Nanoparticle-Functionalized Multi-Walled Carbon Nanotubes: One-Pot Synthesis and Their Applications in Magnetic Removal of Heavy Metal Ions, J. Mater. Chem, 22: 9230- 9236 (2012).
19
[19] Jun X.U.Y., Arrigo R., Xi L.I.U., Sheng S.D., Characterization and Use of Functionalized Carbon Nanotubes for the Adsorption of Heavy Metal Anions, New Carbon Mater, 26:57-62 (2011).
20
[20] Khaldi F.A.A., Sharkh B.A., Abulkibash A.M., Atieh M.A., Cadmium Removal by Activated Carbon, Carbon Nanotubes, Carbon Nanofibers, and Carbon Fly ash: A Comparative Study, Desalin. Water Treat, 53:1417–1429 (2015).
21
[21] Hadavifar M., Bahramifar N., Younesi H., Li Q., Adsorption of Mercury ions from Synthetic and Real Wastewater Aqueous Solution by Functionalized Multi-Walled Carbon Nanotube with Both Amino and Thiolated Groups, Chem. Eng. J, 237:217–228 (2014).
22
[22] Moghaddam H.K., Pakizeh M., Experimental Study on Mercury Ions Removal From Aqueous Solution by MnO2/CNTs Nanocomposite Adsorbent, J. Indus. Eng. Chem, 21:221–229 (2015).
23
ORIGINAL_ARTICLE
Total Acid Number Reduction of Naphthenic Acid Using Subcritical Methanol: A Kinetic Study
The aim of this study is to explore the capability of subcritical methanol to reduce the acidity of naphthenic acids and to determine reaction kinetics for large-scale reactor design.The experiments were carried out in a 25 mL autoclave reactor (China) at temperatures of 70-120oC, Methanol Partial Pressures (MPPs) of 0.1-1.5 MPa, and reaction times of 0-60 min. The total acid number content of the samples was analyzed using ASTM D 974 techniques. Experimental results reveal that total acid number reduction of naphthenic acids increased with increasing reaction temperature, MPP, and reaction time. Approximately 74.20% total acid number was reduced at a temperature of 120oC, a MPP of 1 MPa, and a reaction time of 60 min. Experimental data revealed that total acid number removal reaction kinetics followed second-order kinetics with an activation energy of 11.27 kcal/mol. Therefore, subcritical methanol is able to reduce the total acid number of naphthenic acids without the addition of any catalyst.
https://ijcce.ac.ir/article_30026_8d050423e5870e158315cebb1d81d12f.pdf
2017-10-01
143
148
10.30492/ijcce.2017.30026
Naphthenic acid
Subcritical methanol
Total acid number
Petroleum oil
Reaction kinetics
Pradip
Mandal
pradipbd2002@yahoo.com
1
Centre of Research in Ionic Liquids, Universiti Teknologi Petronas, 32610 Bandar Seri Iskandar, Perak, MALAYSIA
LEAD_AUTHOR
Huda
Nasir
hudasyamilahnasir@gmail.com
2
Department of Petroleum Engineering, Universiti Teknologi Petronas, 32610 Bandar Seri Iskandar, Perak, MALAYSIA
AUTHOR
[1] Hardacre C., Goodrich P., Anderson K., Processing for Removing Organic Acids From Crude Oil and Crude Oil Distillates, U.S. Pat. No. 20120132564 A1 (2012).
1
[2] Wang Y.-Z., Zhong D.-L., Duan H.-L., Song C.-M., Han X.-T., Ma X.-R., Removal of Naphthenic Acids From Crude Oils by Catalytic Decomposition Using Mg–Al Hydrotalcite/γ-Al2O3 as a Catalyst, Fuel, 134:499-504 (2014). DOI:10.1016/J.FUEL.2014.06.026.
2
[3] Clemente J.S., Fedorak P.M., A Review of the Occurance, Analyses, Toxicity, and Bodegradation of Naphthenic Acids, Chemosphere, 60 (5): 585-600 (2005).
3
DOI:10.1016/J.CHEMOSPHERE.2005.02.065.
4
[4] Headley J.V., McMartin D.W., A Review of the Occurrence and Fate of Naphthenic Acids in Aquatic Environments, J. Environ. Sci. Health A, 39(8): 1989-2010 (2004).
5
DOI: 10.1081/ESE-120039370.
6
[5] Scott A.C., MacKinnon M.D., Fedork P.M., Naphthenic Acids in Athabasca Oil Sands Tailing Waters are Less Biodegradable than Commercial Naphthenic Acids, Environ. Sci. Technol., 39(21): 8388-8394 (2005).
7
DOI: 10.1021/es051003k.
8
[6] Mandal P.C., Wahyudiono, Sasaki M., Goto M., Reduction of Total Acid Number (TAN) of Naphthenic Acid (NA) Using Supercritical Water for Reducing Corrosion Problems of Oil Refineries, Fuel, 94: 620-623(2012).
9
DOI:10.1016/J.FUEL.2011.11.008.
10
[7] Kane R., Cayard M., A Comprehensive Study on Naphthenic Acid Corrosion, Corrosion 2002, NACE International, Houston, U.S.A., Paper No. 02555, 1-16 (2002).
11
[8] Shukri N. M., Bakar W. A., Jaafar J., Majid Z.A., Removal of Naphthenic Acids From High Acidity Korean Crude Oil Utilizing Catalytic Deacidification Method, J. Ind. Eng. Chem., 28: 110-110 (2015). DOI:10.1016/J.JIEC.2015.02.005.
12
[9] Wang Y.-Z., Li, J.-Y., Sun X.-Y., Duan H.-L., Song C.-M., Zhang M.-M., Liu Y.-P., Removal of Naphthenic Acids From Crude Oils by Fixed-Bed Catalytic Esterification, Fuel, 116: 723-728 (2014).
13
DOI:10.1016/J.FUEL.2013.08.047.
14
[10] Ding L., Rahimi P., Hawkins R., Bhatt S., Shi Y., Naphthenic Acid Removal From Heavy Oils on Alkaline Earth-Metal Oxides and ZnO Catalyst, Appl. Catal. A-Gen., 371(1-2): 121-130 (2009).
15
DOI:10.1016/J.APCATA.2009.09.040.
16
[11] Zhang A., Ma Q., Wang K., Tang Y., Goddard W.A., “Improved Processes to Remove Naphthenic Acids, Final Technical Report”, California Institute of Technology, Pasadena, CA, DE-FC26-02NT15383, 1-96 (2005).
17
[12] Quiroga-Becerra H., Mejia-Miranda C., Laverde-Cataño D., Hernandez-López M., Gomez-Sánchez M., A Kinetic Study of Esterification of Naphthenic Acids From a Colombian Heavy Crude Oil, CT&F- Ciencia, Tecnologia y Futuro, 4(5): 21-32 (2012). ISSN 0122-5383.
18
[13] Rudolf M.F., Process for Removing Naphthenic Acids From Hydrocarbon Oils, U.S. Pat. No. 2227811 A (1941).
19
[14] Oh H.Y., Park J.H., Rhee Y.W., Kim J.N., Decarboxylation of Naphthenic Acid Using Alkaline Earth Metal Oxide, J. Ind. Eng. Chem., 17(4): 788-793 (2011).
20
DOI:10.1016/J.JIEC.2011.05.024.
21
[15] Mandal P.C., Wahyudiono, Sasaki M., Goto M., Non-Catalytic Reduction of Total Acid Number (TAN) of Naphthenic Acids (NAs) Using Supercritical Methanol, Fuel Process. Technol., 106: 641-644 (2013).
22
DOI:10.1016/J.FUPROC.2012.09.058.
23
[16] Kulawska M., Sadlowski J., Skrzypek J., Kinetics of the Esterification of Maleic Anhydride with Octyl, Decyl or Dodecyl Alcohol Over Dowex Catalyst, React. Kinet. Catal. Lett., 85(1): 51-56(2005).
24
[17] Wang Y., Chu Z., Qiu B., Liu C., Zhang Y., Removal of Naphthenic Acids From a Vacuum Fraction Oil with an Ammonia Solution of Ethylene Glycol, Fuel, 85(17-18): 2489-2493 (2006).
25
DOI:10.1016/J.FUEL.2006.04.032.
26
[18] Tesser R., Di Serio M., Guida M., Natasi M., Santhacesaria E., Kinetics of Oleic Acid Esterification with Methanol in the Presence of Triglycerides, Ind. Eng. Chem. Res., 44(21): 7978-7982 (2005).
27
DOI:10.1021/ie050588o.
28
[19] Mandal P.C., Shiraishi T., Wahyudiono, Sasaki M., Goto M., Kinetics and Reaction Pathways for Heptylbenzene Decomposition in Supercritical Water, J. Chem. Eng. Jpn., 44(7): 486-493 (2011)
29
DOI: 10.1252/jcej.10we296.
30
ORIGINAL_ARTICLE
Experimental Determination of Continuous Phase Overall Mass Transfer Coefficients Case Study: Kühni Extraction Column
The aim of this study is to explore the capability of subcritical methanol to reduce the acidity of naphthenic acids and to determine reaction kinetics for large-scale reactor design.The experiments were carried out in a 25 mL autoclave reactor (China) at temperatures of 70-120oC, Methanol Partial Pressures (MPPs) of 0.1-1.5 MPa, and reaction times of 0-60 min. The total acid number content of the samples was analyzed using ASTM D 974 techniques. Experimental results reveal that total acid number reduction of naphthenic acids increased with increasing reaction temperature, MPP, and reaction time. Approximately 74.20% total acid number was reduced at a temperature of 120oC, a MPP of 1 MPa, and a reaction time of 60 min. Experimental data revealed that total acid number removal reaction kinetics followed second-order kinetics with an activation energy of 11.27 kcal/mol. Therefore, subcritical methanol is able to reduce the total acid number of naphthenic acids without the addition of any catalyst.
https://ijcce.ac.ir/article_26471_73b33dd0fbb7a616c8563e5ff6be32a5.pdf
2017-10-01
149
161
10.30492/ijcce.2017.26471
Kühni Column
Overall Mass Transfer Coefficients
Mass Transfer Direction
Sherwood Number
Mehdi
Asadollahzadeh
mehdiasadollahzadeh@iust.ac.ir
1
Department of Chemical Engineering, Iran University of Science and Technology (IUST), P.O. Box 16765-163 Tehran, I.R. IRAN
LEAD_AUTHOR
Rezvan
Torkaman
rtorkaman@aeoi.org.ir
2
Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, P.O. Box 11365-8486 Tehran, I.R. IRAN
AUTHOR
Meisam
Torab-Mostaedi
mmostaedi@aeoi.org.ir
3
Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, P.O. Box 11365-8486 Tehran, I.R. IRAN
AUTHOR
[1] Kislik V.S., "Solvent Extraction: Classical and Novel Approaches", Elsevier, New York (2012).
1
[2] Aguailar M., Cortina J.L., "Solvent extraction and liquid membranes", CRC Press, New York (2013).
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[3] Jaradat M., Attarakih M., Bart H.J., Population Balance Modeling of Pulsed (Packed and Sieve-Plate) Extraction Columns: Coupled Hydrodynamic and Mass Transfer, Ind. Eng. Chem. Res., 50: 14121-14135 (2011).
3
[4] Asadollahzadeh M., Torab-Mostaedi M., Shahhosseini Sh., Ghaemi A., Experimental Investigation of Dispersed Phase Holdup and Flooding Characteristics in a Multistage Column Extractor, Chem. Eng. Res. Des., 105: 177-187 (2016).
4
[5] Torkaman R., Asadollahzadeh M., Torab-Mostaedi M., Determination of Slip and Characteristic Velocities in Reactive Extraction with Experiments in the Oldshue-Rushton Column and Presence of Samarium and Gadolinium Metals, Chem. Eng. Process, 111: 7-13 (2017).
5
[6] Asadollahzadeh M., Torab-Mostaedi M., Shahhosseini Sh. Ghaemi A., Holdup, Characteristic Velocity and Slip Velocity between Two Phases in a Multi-Impeller Column for High/Medium/Low Interfacial Tension Systems, Chem. Eng. Process, 100: 65-78 (2016).
6
[7] Godfrey J.C., Slater M.J., "Liquid-Liquid Extraction Equipment", Wiley, New York (1994).
7
[8] Thornton J. D., "Science and Practice of Liquid-Liquid Extraction", Oxford University Press, Oxford (1992).
8
[9] Ghorbanian S.A., Abolghasemi H., Radpour S.R., Modelling of Mean Drop Size in a Extraction Spray Column and Developing a New Model, Iran. J. Chem. Chem. Eng. (IJCCE), 30: 89-96 (2011).
9
[10] Yuan S., Jin S., Chen Z., Yuan Y., Yin H., An Improved Correlation of the Mean Drop Size in a Modified Scheibel Extraction Column, Chem. Eng. Technol., 37: 2165-2174 (2014).
10
[11] Ritcey G.M., Ashbrook A.W., "Solvent Extraction: Principles and Applications to Process Metallurgy", Elsevier, New York (1984).
11
[12] Abolghasemi H., Moosavian M.A., Radpour S.R., The Effects of a Surfactant Concentration on the Mass Transfer in a Mixer-Settler Extractor, Iran. J. Chem. Chem. Eng. (IJCCE), 25: 9-15 (2006).
12
[13] Li N.N., Ziegler E.N., Effect of Axial Mixing on Mass Transfer in Extraction Columns, Ind. Eng. Chem., 59: 30-36 (1967).
13
[14] Bart H.G., Drumm C., Attarakih M.M., Process Intensification with Reactive Extraction Columns, Chem. Eng. Process, 47: 57-65 (2008).
14
[15] Henton J.E., Cavers S.D., Continuous-Phase Axial Dispersion in Liquid–Liquid Spray Towers, Ind. Eng. Chem. Fund., 9: 384-392 (1970).
15
[16] Geankoplis C.J., Sapp J.B., Arnold F.C., Marroquin G., Axial Dispersion Coefficients of the Continuous Phase in Liquid–Liquid Spray Towers, Ind. Eng. Chem. Fund. , 21: 306-311 (1982).
16
[17] Nosratinia F., Omidkhah M.R., Bastani D., Saifkordi A.A., Investigation of Mass Transfer Coefficient under Jetting Conditions in a Liquid-Liquid Extraction System, Iran. J. Chem. Chem. Eng. (IJCCE), 29: 1-12 (2010).
17
[18] Hafez M.M., Baird M.H.I., Nirdosh I., Flooding and Axial Dispersion in Reciprocating Plate Extraction Column, Can. J. Chem. Eng. , 57: 150-158 (1979).
18
[19] Parthasarathy P., Sriniketan G., Srinivas N.S., Varma Y.B.G., Axial Mixing of Continuous Phase in Reciprocating Plate Columns, Chem. Eng. Sci., 39: 987-995 (1984).
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[20] Kumar A., Hartland S., Prediction of Continuous-Phase Axial Mixing Coefficients in Pulsed Perforated-Plate Extraction Columns, Ind. Eng. Chem. Res., 28: 1507-1513 (1989).
20
[21] Moghadam E.H., Bahmanyar H., Heshmatifar F., Kasaie M., Ziaei-Azad H., The Investigation of Mass Transfer Coefficients in a Pulsed Rgular Packed Column Applying SiO2 Nanoparticles, Sep. Purif. Technol., 176: 15-22 (2017).
21
[22] Míšek T., Berger R., Schroter J., "Standard Test Systems for Liquid Extraction Studies", EFCE Publ. Ser. (1985).
22
[23] Kumar A., Hartland S., Prediction of Axial Mixing Coefficients in Rotating Disc and Asymmetric Rotating Disc Extraction Columns, Can. J. Chem. Eng., 70: 77-87 (1992).
23
[24] Skelland A.H.P., "Diffusional Mass Transfer", Wiley, New York (1974).
24
[25] Lochiel A.C., Calderbank P.H., Mass Transfer in the Continuous Phase Around Axisymmetric Bodies of Revolution, Chem. Eng. Sci., 19: 471-484 (1964).
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[26] Brauer H., "Stoffaustausch Einschliesslich Chemischer Reaktionen", Verlag Sauerlander, Aarau, Switzerland (1971).
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[27] Clift R., Grace J.R., Weber M.E., "Bubbles, Drops and Particles", Academic Press, New York (1978).
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[28] Garner F.H., Foord A., Tayeban M., Mass Transfer From Circulating Drops, J. Appl. Chem., 9: 315-323 (1959).
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[29] Weber M.E., Mass TRansfer From Spherical Drops at High Reynolds Numbers, Ind. Eng. Chem. Fundam., 14: 365-366 (1975).
29
[30] Steiner L., Mass-Transfer Rates From Single Drops and Drop Swarms, Chem. Eng. Sci., 41: 1979-1986 (1986).
30
[31] Kumar A., Hartland S., Correlations for Prediction of Masstransfer Coefficients in Single Drop Systems and Liquid-Liquidextraction Columns, Chem. Eng. Res. Des., 77: 372-384 (1999).
31
[32] Torab-Mostaedi M., Safdari S.J., Moosavian M.A., Maragheh M.G., Mass Transfer Coefficiens in a Hanson Mixer-Settler Extraction Column, Braz. J. Chem. Eng., 25: 473-481 (2008).
32
[33] Torab-Mostaedi M., Safdari J., Mass Transfer Coefficients in a Pulsed Packed Extraction Column, Chem. Eng. Process, 48: 1321-1326 (2009).
33
[34] Torab-Mostaedi M., Jalilvand H., Outokesh M., Dispersed Phase Holdup in a Pulsed Disc and Doughnut Extraction Column, Braz. J. Chem. Eng., 28: 313-323 (2011).
34
[35] Torab-Mostaedi M., Asadollahzadeh M., Mass Transfer Performance in an Asymmetric Rotating Disc Contactor, Chem. Eng. Res. Des., 94: 90-97 (2015).
35
[36] H. Grober, Die Erwarmung and Abkuhlung einfacher Geometrischer Korper, Z. Var. Dtsch. Ing., 69: 705-711 (1925).
36
[37] Kronig R., Brink J.C., On the Theory of Extraction From Falling Drops, Appl. Sci. Res., 2: 142-154 (1950).
37
[38] Handlos A.E., Baron T., Mass and Heat Transfer From Drops in Liquid–Liquid Extraction, AIChE J., 3: 127-136 (1957).
38
ORIGINAL_ARTICLE
Optimization and Kinetic Studies of Ultrasound-Assisted Extraction on Polyphenols from Satsuma Mandarin (Citrus Unshiu Marc.) Leaves
The present article includes the Ultrasound-Assisted Extraction (UAE) of Citrus unsiu Marc. leaves rich in polyphenols. The best possible combinations of solvent, pH of the media, solvent/solid ratio, extraction time, extraction temperature and particle size were obtained for the maximum extraction of Total Phenolic Compounds (TPC) and Total Flavonoid Compounds (TFC) by using One-Factor-at-a-Time (OFAT) approach. The optimum extraction conditions of TPC were as follows: pH 4 in water; solvent/solid ratio of 20:1; extraction time, 54 min; and extraction temperature, 53ºC. On the other hand, pH 2 in water, solvent/solid ratio of 42:1, 48 min and 58ºC were found to be the optimal conditions for the extraction of TFC. The solvent selection was the most effective parameter for the related system. Additionally, several kinetic models (Film theory, Peleg model, first-order mechanism model and second order mechanism model) were employed to examine the kinetics of UAE.
https://ijcce.ac.ir/article_30032_3f958be91f99b5b37fcb0234cae01573.pdf
2017-10-01
163
171
10.30492/ijcce.2017.30032
Citrus unshiu Marc. leaves
Ultrasound-assisted extraction
surfactant
One-factor-at-a-time optimization
Total phenolic content
Total flavonoid content
Zeynep
Ciğeroğlu
zilbay@gmail.com
1
Istanbul University, Engineering Faculty, Department of Chemical Engineering, 34320 Avcılar, Istanbul, TURKEY
LEAD_AUTHOR
Ş. İsmail
Kırbaşlar
krbaslar@istanbul.edu.tr
2
Istanbul University, Engineering Faculty, Department of Chemical Engineering, 34320 Avcılar, Istanbul, TURKEY
AUTHOR
Selin
Şahin
selins@istanbul.edu.tr
3
Istanbul University, Engineering Faculty, Department of Chemical Engineering, 34320 Avcılar, Istanbul, TURKEY
AUTHOR
Gökben
Köprücü
koprucugokben@gmail.com
4
Istanbul University, Engineering Faculty, Department of Chemical Engineering, 34320 Avcılar, Istanbul, TURKEY
AUTHOR
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ORIGINAL_ARTICLE
Numerical Investigation of Fluid Mixing in a Micro-Channel Mixer with Two Rotating Stirrers by Using the Incompressible SPH Method
Fluid mixing is a crucial and challenging process for microfluidic systems, which are widely used in biochemical processes. Because of their fast performance, active micromixers that use stirrer blades are considered for biological applications. In the present study, by using a robust and convenient Incompressible Smoothed Particle Hydrodynamics (ISPH) method, miscible mixing within a two-blade micromixer is investigated. The problem discussed herein is represented by an active micromixer comprising two stir-bars that rotate to mix the fluids. Because of its Lagrangian nature, Smoothed Particle Hydrodynamics is an appropriate and convenient method for simulating moving boundary problems and tracking the particles in the mixing process. Previous investigations have been carried out for mixing flow for a low Schmidt number. However, a low Schmidt number is barely applicable for liquid mixing. Hence, in the present study, the Schmidt number is considered to be Sc=1000. The present results show that the two-blade micro-channel mixer considerably improves the mixing rate in comparison with the one-blade micro-channel mixer.
https://ijcce.ac.ir/article_27256_16ae1b75b5baebc9aa80dd698746c4c6.pdf
2017-10-01
173
183
10.30492/ijcce.2017.27256
Micromixer
SPH
Two-stirrer
Rahim
Shamsoddini
shamsoddini.rahim@gmail.com
1
Department of Mechanical Engineering, Sirjan University of technology, Sirjan,, I.R. IRAN
LEAD_AUTHOR
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