%0 Journal Article %T 3-Nitro, 1-Amino Guanidine and 5-Hydrazino-1H-Tetrazole Derivatives as New Energetic Materials %J Iranian Journal of Chemistry and Chemical Engineering %I Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR %Z 1021-9986 %A Aboudi, Javad %A Bayat,, Yadollah %A Abedi, Yaghub %A Nabati, Mehdi %A Mahkam, Mehrdad %D 2015 %\ 06/01/2015 %V 34 %N 2 %P 1-16 %! 3-Nitro, 1-Amino Guanidine and 5-Hydrazino-1H-Tetrazole Derivatives as New Energetic Materials %K Energetic materials %K Nitrogen-rich compounds %K Amino guanidine %K Tetrazole %K Triazine %K Triazole %R 10.30492/ijcce.2015.14081 %X The synthesis of 3-amino-1-nitroguanidine (3-ANQ) and 5-hydrazino tetrazole (5-HT) derivatives as new energetic materials are described. Reaction of 3-ANQ with triethyl orthoformate leads to the formation of 3-nitramino triazole while no reaction was observed whit 5-HT. Addition of NaN3 to a mixture of 3-ANQ and triethyl orthoformate, afforded 1-nitroguanidyl tetrazole in excellent yield. On the other hand, these compounds showed different reactivity toward dicyandiamide. Cyclization of 5-HT with dicyandiamide in EtOH/Water reflux caused formation of 3,5-Diamino-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazole in good yield, nitration of which afforded 3,5-Dinitramino-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazole as a potentially new high energetic molecule. No reaction was observed between 3-ANQ and dicyandiamide. The reaction of 3-ANQ and 5-HT were exanimated with trichloro triazine (TCT). 5-HT gave mixture of products while no reaction between 3-ANQ and TCT was detected. Unusual hydrazone condensation was observed between 3-ANQ and acetone, when acetone/water mixture used as solvent at 0 °C. %U https://ijcce.ac.ir/article_14081_86bb6264b80809756c70263cc4479b2b.pdf