@article { author = {Piroozmand, Mahtab and Safari, Nasser and Samadi, Abbas Ali}, title = {Catalyzed Oxidation of Cyclohexene and Cyclooctene with First Row Transition etallophthalocyanines}, journal = {Iranian Journal of Chemistry and Chemical Engineering}, volume = {25}, number = {4}, pages = {85-89}, year = {2006}, publisher = {Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR}, issn = {1021-9986}, eissn = {}, doi = {10.30492/ijcce.2006.8036}, abstract = {First row transition metal complexes of phthalocyanine are employed as catalysts for the oxidation of cyclohexene and cyclooctene using iodosylbenzene and pentafluoroiodosyl benzene. The catalysis was performed in dichloromethane: methanol:water (80:18:2) solvent mixture.  The products of the catalysis for cyclohexene are epoxycyclohexane, 2-cyclohexene-1-ol and 2-cyclohexene-1-one whereas for cyclooctene it is specifically cyclooctene oxide.  For cyclohexene oxidation epoxide yield and selectivity is in the order of MnII > FeIII > FeII > CoII > CrIII > NiII > CuII , while for 2-cyclohexene-1-one production the ability of the catalysts are in the order of  NiII > CoII > CuII > CrIII > FeIII > FeII > MnII .}, keywords = {Oxidation,Cyclohexene,Cyclooctene,Phthalocyanine,Catalyzed Oxidation}, url = {https://ijcce.ac.ir/article_8036.html}, eprint = {https://ijcce.ac.ir/article_8036_4e036cb15d8ecb5fc7947a5ac20bbaf6.pdf} }