@article { author = {Timur, Mahir and Demetgül, Cahit}, title = {Synthesis and Metal Ion Uptake Studies of Silica Gel-Immobilized Schiff Base Derivatives and Catalytic Behaviors of their Cu(II) Complexes}, journal = {Iranian Journal of Chemistry and Chemical Engineering}, volume = {36}, number = {4}, pages = {111-122}, year = {2017}, publisher = {Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR}, issn = {1021-9986}, eissn = {}, doi = {10.30492/ijcce.2017.28716}, abstract = {New silica supported Schiff base ligands were prepared by the condensation reaction of 4,6-diacetylresorcinol with silica-gel derivatives, which modified with 3-aminopropyltriethoxysilane and N-(2-aminoethyl) -3-aminopropyltrimethoxysilane. Metal ion uptake capacities of these compounds were studied towards of selected transition metal (Cd(II), Cu(II), Co(II), Mn(II), Pb(II) and Ni(II)) cations in an aqueous medium. In addition, Cu(II) complexes of these ligands were prepared by using heterogeneous reaction conditions. The synthesized compounds were characterized by using elemental analysis, FT-IR, DR-UV-vis., CP/MAS 13C-NMR, AAS, XRD and TGA techniques. Moreover, the morphological and chemical properties of these compounds were investigated by using a scanning electron microscope (SEM) coupled to an energy-dispersive X-ray spectrometer (EDX). The catalytic performances of the Cu(II) complexes were investigated on H2O2 decomposition. These complexes displayed good catalytic activities towards the decomposition of H2O2 as heterogeneous catalysts.}, keywords = {Schiff Base,Metal-ion uptake,Heterogeneous catalysts,4,6-diacetylresorcinol (DAR),Silica gel}, url = {https://ijcce.ac.ir/article_28716.html}, eprint = {https://ijcce.ac.ir/article_28716_ca336b4fa79944734e0120e1380e05c1.pdf} }